Palaeoenvironmental and palaeoecological change on the northern Tethyan carbonate platform during the Late Barremian to earliest Aptian

A major shift from Urgonian oligotrophic carbonate accumulation to orbitolinid‐rich mixed siliciclastic–carbonate deposition is observed near the Barremian–Aptian boundary in many sections both within and outside the shallow‐marine Tethyan Realm. This important facies change in the Swiss Helvetic Alps is documented here and interpreted in the context of general palaeoenvironmental change. To achieve this, a detailed micropalaeontological, sedimentological, mineralogical and geochemical study has been carried out on six sections across the upper part of the lower Schrattenkalk Member (Late Barremian), the Rawil Member (formerly ‘Lower Orbitolina Beds’, earliest Aptian) and the lowermost part of the upper Schrattenkalk Member (Early Aptian). The sediments of the Rawil Member exhibit inner‐platform facies with rudists, miliolids, orbitolinids and dasycladals to outer‐platform facies characterized by small benthic foraminifera, orbitolinids, crinoids and bryozoans. Stratigraphic trends in microfacies environments and the composition of microfossil assemblages, indicate that the Rawil Member includes a transgressive systems tract and the base of a highstand systems tract which are composed of an increasing number of parasequences in distal directions (five to nine in the sections studied here). The sea‐level rise discerned in the Rawil Member is coeval with increased detrital input and phosphorus burial, with maximum values up to 80 times and 21 times the background values in the subjacent part of the lower Schrattenkalk Member, respectively. Furthermore, the Rawil Member records the appearance of kaolinite, indicating a change towards tropical and more humid climate conditions. This change may have led to an increase in continental weathering rates and an associated increase in detrital and nutrient fluxes towards the ocean. The phase of climate change observed near the Barremian–Aptian boundary may have been triggered by a phase of intensified volcanic activity linked with the onset of the Ontong Java large igneous province and the Rawil Member may be the expression of a precursor episode to Oceanic Anoxic Event 1a in the shallow‐marine environment.     

Ammonites (Phylloceratina,Lytoceratina and Ancyloceratina) and organic-walled dinoflagellate cysts from the Late Barremian in Boljetin,eastern Serbia

Late Barremian ammonite fauna from the epipelagic marlstone and marly limestone interbeds of Boljetin Hill (Boljetinsko Brdo) of Danubic Unit (eastern Serbia) is described. The ammonite fauna includes representatives of three suborders (Phylloceratina, Lytoceratina and Ancyloceratina), specifically Hypophylloceras danubiense n. sp., Lepeniceras lepense Rabrenović, Holcophylloceras avrami n. sp., Phyllopachyceras baborense (Coquand), Phyllopachyceras petkovici n. sp., Phyllopachyceras eichwaldi eichwaldi (Karakash), Phyllopachyceras ectocostatum Drushchits, Protetragonites crebrisulcatus (Uhlig), Macroscaphites perforatus Avram, Acantholytoceras cf. subcirculare (Avram), Dissimilites cf. trinodosus (d'Orbigny) and Argvethites? sp. The taxonomic composition and percent abundance of the identified ammonites indicate that their taxa are predominantly confined to the Tethyan realm. Ammonites with smooth and slightly sculptured shells predominate among the studied fauna. The ammonite-bearing succession from Boljetin represents the lower part of the Upper Barremian, ranging in ammonite zonation from the Toxancyloceras vandenheckei Zone to the lower part of the Imerites giraudi Zone. The associated organic-walled dinoflagellate cysts confirm the Late Barremian age of the ammonite-bearing levels.     

Latitudinally different responses of Tethyan shoal‐water carbonate systems to the Early Aptian oceanic anoxic event (OAE 1a)

Ocean‐wide anoxic events represent intensively investigated anomalies in the global carbon cycle. Most previous research has focussed on hemipelagic and pelagic settings and on the relationship between black‐shale deposition and carbon‐isotope excursions. The study of ocean‐wide anoxic events and coeval shallow‐water settings is now increasingly seen as an interesting complementary approach, but one that is not without problems. Whereas platform drowning characterizes the Early Aptian of the northern Tethyan margin, Lithocodium–Bacinella‐rich facies and ongoing shoal‐water sedimentation at the southern Tethyan margin (Oman) bears important information on potential causes of carbon‐cycle perturbations. The present paper seeks to test the supra‐regional relevance of the Oman data by investigating coeval central Tethyan limestones. Three Lower Aptian shoal‐water sections in Istria (Croatia), deposited on the isolated Adriatic Carbonate Platform, are investigated applying chemostratigraphy (carbon and strontium) and detailed sedimentological analysis. The focus is on peritidal to lagoonal facies characterized by mass occurrences of Lithocodium–Bacinella, an enigmatic microencruster community. Lithocodium–Bacinella facies occurs predominantly in layers ranging from one to several centimetres in stratigraphic thickness, with several layers merging to metre‐thick packages. Growth fabrics within the layers include oncoidal morphotypes, lumps, interconnected patches and columns, layers and rare nodular to massive bindstone facies. These growth patterns show a remarkable regional extent and consistency over study sites distributed several kilometres apart. This widespread distribution suggests that specific Lithocodium–Bacinella morphotypes might serve as regional stratigraphic markers. The high‐resolution carbon‐isotope chemostratigraphy presented here is based on pristine rudist shells and matrix micrite samples and calibrated against strontium‐isotope data obtained from screened rudist low‐Mg calcite. The chemostratigraphic data are consistent with existing biostratigraphic data and place the studied strata at the onset of Early Aptian oceanic anoxic event 1a. Moreover, results indicate the near‐coeval nature of Lithocodium–Bacinella bloom facies in Istria and Oman. The outcomes of this study point to latitudinally different responses of Tethyan shoal‐water carbonate systems (platform drowning versus Lithocodium–Bacinella blooms) to the ocean‐wide anoxic event 1a.     

Aptian to Coniacian (Early–Late Cretaceous) palynostratigraphy of the Gustav Group, James Ross Basin, Antarctica

The Gustav Group of the James Ross Basin, Antarctic Peninsula, forms part of a major Southern Hemisphere Cretaceous reference section. Palynological data, chiefly from dinoflagellate cysts, integrated with macrofaunal evidence and strontium isotope stratigraphy, indicate that the Gustav Group, which is approximately 2.6 km thick, is Aptian–Coniacian in age. Aptian–Coniacian palynofloras in the James Ross Basin closely resemble coeval associations from Australia and New Zealand, and Australian palynological zonation schemes are applicable to the Gustav Group. The lowermost units, the coeval Pedersen and Lagrelius Point formations, have both yielded early Aptian dinoflagellate cysts. Because the overlying Kotick Point Formation is of early to mid Albian age, the Aptian/Albian boundary is placed, questionably, at the Lagrelius Point Formation–Kotick Point Formation boundary on James Ross Island, and this transition may be unconformable. Although the Kotick Point Formation is largely early Albian on dinoflagellate cyst evidence, the uppermost part of the formation appears to be of mid Albian age. This differentiation of the early and mid Albian has refined the age of the formation, previously considered to be Aptian–Albian, based on macrofaunal evidence. The Whisky Bay Formation is of late Albian to latest Turonian age on dinoflagellate cyst evidence and this supports the macrofaunal ages. Late Albian palynofloras have been recorded from the Gin Cove, lower Tumbledown Cliffs, Bibby Point and the lower–middle Lewis Hill members. However, the Cenomanian age of the upper Tumbledown Cliffs and Rum Cove members, based on molluscan evidence, is not supported by the dinoflagellate cyst floras and further work is required on this succession. The uppermost part of the Whisky Bay Formation in north-west James Ross Island is of mid to late Turonian age and this is confirmed by strontium isotope stratigraphy. The uppermost unit, the Hidden Lake Formation, is Coniacian in age on both palaeontological and strontium isotope evidence. The uppermost part of the formation appears to be early Santonian based on dinoflagellate cysts, but strontium isotope stratigraphy constrains this as being no younger than late Coniacian. This refined palynostratigraphy greatly improves the potential of the James Ross Basin as a major Cretaceous Southern Hemisphere reference section.     

The response of two Tethyan carbonate platforms to the early Toarcian (Jurassic) oceanic anoxic event: environmental change and differential subsidence

Chemostratigraphic analyses (⁸⁷Sr/⁸⁶Sr, δ¹³C_carb) of limestones from two Jurassic platform‐carbonate sequences in Italy (Trento and Campania–Lucania Platforms) illustrate previously established trends found in pelagic sediments and skeletal carbonates from biostratigraphically well‐calibrated sections elsewhere in Europe. Chemostratigraphic correlations between the platform‐carbonate successions and appropriate intervals from well‐dated reference sections allow the application of high‐resolution stratigraphy to these shallow‐water peritidal carbonates and, furthermore, elucidate the facies response to the Early Toarcian Oceanic Anoxic Event (OAE). Lower Jurassic (Toarcian) levels of the western Trento Platform (Southern Alps, Northern Italy) contain spiculitic cherts that appear where rising carbon‐isotope values characterize the onset of the OAE: a palaeoceanographic phenomenon interpreted as driven by increased nutrient levels in near‐surface waters. There is a facies change to more clay‐rich facies at the level of the abrupt negative carbon‐isotope excursion, also characteristic of the OAE, higher in the section. The Campania–Lucania Platform (Southern Apennines, Southern Italy) records a change to more clay‐rich facies where carbon‐isotope values begin to rise at the beginning of the OAE but the negative excursion, higher in the section, occurs within oolitic facies. Although, in both examples, the Early Toarcian OAE can be recognized by a change to more clay‐rich lithologies, this facies development is diachronous and in neither case did the platform drown. Although the Trento Platform, in the south‐west sector studied here, was adversely affected by the OAE, it did not drown definitively until Late Aalenian time; the Campania–Lucania Platform persisted throughout the Jurassic and Cretaceous. Differential subsidence rates, which can be calculated using comparative chemostratigraphy, are identified as a crucial factor in the divergent behaviour of these two carbonate platforms: relatively fast in the case of the Trento Platform; relatively slow in the case of the Campania–Lucania Platform. It is proposed that where water depths remained as shallow as a few metres during the OAE (Campania–Lucania Platform), dissolved oxygen levels remained high, nutrient levels relatively low and conditions for carbonate secretion and precipitation remained relatively favourable, whereas more poorly ventilated and/or more nutrient‐rich waters (Trento Platform) adversely influenced platform growth where depths were in the tens of metres range. The stage was thus set for drowning on the more rapidly subsiding western margin of the Trento Plateau and a pulse of oolite deposition post‐dating the OAE was insufficient to revitalize the carbonate factory.     

Palaeobiogeographic implications of Late Bajocian-Late Callovian (Middle Jurassic) dinoflagellate cysts from the Central Alborz Mountains, northern Iran

The Dalichai Formation with an age of Late Bajocian-Late Callovian was sampled in Central Alborz Mountains of northern Iran and studied for palynological, palaeobiogeographical and palynocorrelation purposes. Palynological studies revealed diverse and well-preserved dinoflagellate cyst assemblages and lead to identification of three zones i.e., Cribroperidiniumcrispum (Late Bajocian), Dichadogonyaulaxsellwoodii (Bathonian to Early Callovian) and Ctenidodiniumcontinuum (Early to Middle Callovian) Zones. Subzone a of the D. sellwoodii Zone (Early to Middle Bathonian) was also differentiated. This biozonation corresponds to those recognised in Northwest Europe. Furthermore, the ammonoid families recorded including Phylloceratidae, Oppeliidae, Reineckeiidae, Perisphinctidae, Haploceratidae, Parkinsoniidae and Sphaeroceratidae, which confirm the Late Bajocian to Late Callovian age, are quite similar to those of Northwest Europe and the northwestern Tethys. The close similarities of the dinoflagellate cyst assemblages and ammonite fauna of northern Iran with those of Northwest Europe and the northwestern Tethys during the Middle Jurassic indicate direct but episodic marine connection and faunal exchange between the two areas.     

A reassessment of large theropod dinosaur tracks from the mid-Cretaceous (late Albian-Cenomanian) Winton Formation of Lark Quarry, central-western Queensland, Australia: A case for mistaken identity

Multivariate analysis is used to differentiate shape variations between ichnites of theropod and ornithopod dinosaurs. Tracks of an alleged theropod cf. Tyrannosauropus from the mid-Cretaceous (late Albian-Cenomanian) Winton Formation of Lark Quarry, central-western Queensland, Australia were examined and foot shape ratios calculated. Multivariate analysis of these shape variables indicates this track-maker was an ornithopod dinosaur. A strong morphological similarity exists between the Lark Quarry ichnites and those of the iguanodontian ichnotaxon Amblydactylus gethingi. Considering the grade of ornithopod this ichnogenus is thought to represent (a non-hadrosaurid styracosternan) and the age and geography of Lark Quarry, we suggest that the track-maker may have been a dinosaur similar to Muttaburrasaurus langdoni.     

Dinoflagellate cyst stratigraphy and palaeoenvironment of the marginal marine Middle and Upper Miocene of the eastern Campine area,northern Belgium (southern North Sea Basin)

A stratigraphical and palaeoenvironmental analysis with organic‐walled palynomorphs of the Bolderberg and Diest formations provides new insights in the depositional history during Miocene times at the southern border of the North Sea Basin. The Neogene transgression invaded Belgium from a north–northwestern direction and fully marine sediments were deposited in the northern part of Belgium. The age and the palaeoenvironment of the deposits at the very border of the southern North Sea Basin remained till a few decades ago incomplete. The recovered dinoflagellate cysts, acritarchs and green algae from the Bolderberg Formation in the Wijshagen Borehole indicate a marginal marine depositional environment during late Burdigalian and Langhian times in the eastern Campine area, in contrast to the deeper marine conditions prevailing to the north–northwest. The relative dating of the Bolderberg Formation confirms that maximum flooding occurred during Langhian to early Serravallian times. Deposition apparently took place during the Middle Miocene Climatic Optimum, and ended when the climatic deterioration set in at around 14 Ma. A hiatus spanning ca. 2 Ma separates the Middle Miocene Bolderberg Formation from the Upper Miocene Diest Formation in the eastern Campine area at the border of the North Sea Basin. Copyright © 2007 John Wiley & Sons, Ltd.     

Dinoflagellate cyst biostratigraphy of the Upper Miocene Deurne Sands (Diest Formation) of northern Belgium,southern North Sea Basin

Diverse and well‐preserved palynomorph assemblages recovered from the Deurne Sands, a local member of the Upper Miocene Diest Formation near Antwerp, allow the recognition of dinoflagellate cyst biozones defined in the North Atlantic realm (East Coast, USA) and the North Sea region (Nieder Ochtenhausen well, northern Germany). Based on the dinoflagellate cyst assemblages and the calcareous microfossils, the deposition of the Deurne Sands took place at some time during middle to late Tortonian (Late Miocene). These sands can be correlated biostratigraphically with the Dessel Sands in the Campine area of northern Belgium. This correlation demonstrates the existence of two separate and contemporary depositional areas in northern Belgium during early Late Miocene times. Copyright © 2002 John Wiley & Sons, Ltd.     

Hymenoptera (wasps,bees and ants) in mid-Cretaceous Burmese amber: A review of the fauna

The Burmese amber assemblage of Hymenoptera with its 47 constituent families is now the richest in Cretaceous. A collection of Burmite (Burmese amber) from the Hukawng Valley, Myanmar at the Nanjing Institute of Geology and Palaeontology, Chinese Academy of Sciences was examined, revealing that Burmite inclusions contain a very highly diverse hymenopteran fauna with as many as ten families found new for the Burmese fossil assemblage. The mid-Cretaceous hymenopteran fauna of Burmese amber is revised at the family level. A high level of the first family occurrences and endemism is demonstrated suggestive of an insular syndrome affected the mid-Cretaceous Burmese biome, as well as somewhat contradictory features in composition of the hymenopteran families there.     

Relations of petrographical and geochemical parameters in the middle Miocene Lavanttal lignite (Austria)

Samples from two lignite seams (Lower Seam, Upper Seam) of the Lavanttal basin (Austria) and additional xylite were investigated for variations in maceral composition, petrography-based facies indicators, bulk geochemical parameters, and molecular composition of hydrocarbons. Both seams originated in a topogenous mire and evolved within a transgressive setting. The final drowning of the mire is indicated by sapropelic shales. Whereas the sapropelic shale overlying the Lower Seam was deposited in a freshwater lake, the sapropelic shale above the Upper Seam represents a brackish lake.Numerous relationships are found between petrography-based facies indicators and the geochemical composition of organic matter. The contents of macerals of the liptinite group are positively correlated with soluble organic matter (SOM) yields and hydrogen index (HI). Consistent with maceral composition and high HI values, enhanced proportions of short-chain n-alkanes, which are predominantly found in algae and microorganisms, are obtained from samples of the sapropelic shales. The final drowning of the mire is reflected by decreasing pristane/phytane ratios, due to the rise in (ground)water table and the establishment of anaerobic conditions, as well as by decreasing ratios of diasterenes/sterenes, indicating increasing pH values in the mire. The degree of gelification of plant tissue (gelification index) is governed by the microbial activity in the mire, as indicated by the hopanes concentration. The differences in floral assemblage during the formation of the Lavanttal lignite seams are reflected by major differences in tissue preservation. Preservation of plant tissue (TPI) in the Lavanttal lignite is obviously controlled by the presence/absence of decay-resistant gymnosperms in the peat-forming vegetation, and additionally influenced by the relative contribution of wood to coal formation. The results provide evidence that valuable information for coal facies characterization could be obtained by petrography-based and geochemical facies indicators. An influence of the floral assemblage (gymnosperms/angiosperms ratio) and of the contribution of algal biomass on carbon isotopic composition of the organic matter (δ¹³C = − 24.2 to − 28.6‰) is proposed. Carbon cycling during biogeochemical decomposition of plant tissue by bacteria is suggested to affect the δ¹³C values of the coal. The chemotaxonomical classification of the xylites as gymnosperm remnants, based on the molecular composition of terpenoid biomarkers, is corroborated by the carbon isotopic composition of the xylites (mean δ¹³C = − 24.1‰) and the extracted cellulose (mean δ¹³C = − 20.2‰). The higher isotopic difference of about 3.9‰ between cellulose and total organic carbon of the xylites, compared to the difference between cellulose and wood found in modern trees, is explained by the smaller effect of decomposition on δ¹³C of cellulose.     

The Early and Middle Miocene transgression at the southern border of the North Sea Basin (northern Belgium)

The Lower–Middle Miocene Berchem Formation of northern Belgium is an essentially sandy sequence with a varying glauconite content and often abundant shelly intervals. The formation was deposited in a shallow marine environment and rests unconformably on stiff Rupelian clays or Chattian sands. The lithological recognition of the four members (Edegem Sands, Kiel Sands, Antwerpen Sands and Zonderschot Sands members) of the Berchem Formation solely based on lithological criteria proved to be difficult, especially in boreholes. The geometry of the Formation in the subsurface of northern Belgium remained largely unknown. Diverse and well preserved dinoflagellate cyst associations have been recovered from the four members in seven boreholes and two outcrops, and allow a refinement of the biostratigraphy of these deposits. A Miocene biozonation defined in mid‐latitude shallow marine deposits in the Atlantic Coastal Plain of the USA (Salisbury Embayment, Maryland) is readily applicable to this material, and has led to a detailed stratigraphic assessment of each member. Three detailed profiles depicting the distribution of the biozones in the subsurface of northern Belgium allow the reconstruction of the geometry and depositional history of the Berchem Formation. The oldest Miocene deposits are of early Burdigalian age and they testify to a transgression, which invaded Belgium from a north–northwestern direction. The maximum flooding took place during early Serravallian times. The upper boundary of the formation is a major erosional surface of late Serravallian or (slightly) younger age. Copyright © 2005 John Wiley & Sons, Ltd.     

New insight on the genus Nolaniceras Casey, 1961 (Ammonoidea,Cretaceous) and its consequences on the biostratigraphy of the Aptian Stage

Nolaniceras nolani ( Seunes, 1887) has been widely quoted in the Upper Aptian literature over the years. Re-examination of the holotype of the species shows that it has always been misidentified and that this taxon is represented by a single specimen, the holotype, of uncertain age. As a consequence, its use as an index species for the Upper Aptian should be reconsidered and abandoned.     

Multi-proxy record of orbital-scale changes in climate and sedimentation during the Weissert Event in the Valanginian Bersek Marl Formation (Gerecse Mts., Hungary)

The Valanginian positive carbon isotope excursion and associated environmental changes, known as the Weissert Event, is the first in the series of Cretaceous Earth system perturbations. Here, we develop a multiproxy cyclostratigraphy from a 31.2-m-thick Upper Valanginian to lowermost Hauterivian section of the Bersek Marl Formation in Gerecse Mountains, Hungary, comprising alternating marlstone layers of varying clay and carbonate content. The bulk carbonate δ¹³C signal shows sustained, elevated values (up to 2.7‰) up to 19.2 m, followed by a decreasing trend upsection. Together with biostratigraphic data, this suggests that the lower part of the section was deposited during the plateau phase of the Late Valanginian Weissert Event. Spectral analyses of the multiproxy dataset, including magnetic susceptibility measurements and gamma-ray spectroscopy on the lower part of the section, led to the identification of precession, obliquity, and long and short eccentricity signals. A mean sedimentation rate of 14 m/Myr was calculated based on astronomical tuning. The cyclicity in the proxy signals reflects dilution cycles induced by the fluctuating rate of detrital runoff into the basin. This supports the idea that orbitally-forced humid-arid cycles controlled the pelagic alternating sedimentation during the Early Cretaceous throughout the Tethyan area.     

Lower Aptian Subbetic organic-rich facies, radiolarites, and associated deposits: the local expression of Oceanic Anoxic Event 1a (Carbonero Formation, southern Spain)

The Carbonero Formation represents a scarce, well documented example of Aptian anoxic facies in the Betic Cordillera. Generally, the Aptian record in the pelagic Subbetic basin is both very discontinuous and affected by frequent hiatuses, but in some subsident areas controlled by extensional faults (as in the Carbonero trough) an interesting record is preserved. The Carbonero Formation is characterised by a thick pelagic succession composed of marls with intercalations of calcareous turbidites and a thick interval of anoxic facies. This interval, dated as early Aptian, most likely represents the local expression of Ocean Anoxic Event 1a in the Subbetic basin. A multidisciplinary study including lithostratigraphy, biostratigraphy, and sedimentology has been carried out in the Carbonero Formation, with special attention to the anoxic interval. A collection of facies and sedimentary features has been characterised and interpreted, including barite concretions, calcareous concretions, black shales, siliceous marls and radiolarites, and calcareous turbidites. All these facies seem to have been deposited under oxygen-depleted conditions on a fault-bounded depression with a high subsidence rate. The accumulation and burial of sediments and the preservation of organic matter were controlled by both local and regional factors, such as the physiography of the basin and tectonic setting, as well as by global factors, such as palaeoceanographic and climatic changes.     

New Albian macro- and palynoflora from the Negev (Israel) with description of a new gymnosperm morphotaxon

New plant macrofossil localities are found in the middle-upper part of the Albian Upper Hatira Formation of Makhtesh Qatan, an erosion crater in the northern Negev. These are so far the only outcrop localities in the Negev containing plant compressions and well-preserved sporomorphs. Their age assignments are controlled by the ammonite Knemiceras records below and above the plant-bearing sequence in the adjacent Makhtesh Hatira. The macrofossil assemblages are strikingly different in the sandy fluvial and shaly lacustrine facies, the former being dominated by Araucaria, Athrotaxopsis, Brachyphyllum and pinnatifid Sapindopsis, comparable at the plant assemblage and leaf morphological levels to the early to early late Albian assemblage of the North American Potomac flora. The lacustrine shale macrofossil assemblages appear archaic on account of their diverse pteridophyte component and sparse angiosperm remains. A new supposedly gnetophytic genus and species Qataniaria noae Krassilov, gen. et sp. nov. is dominant in the shale horizon. The sporomorph assemblages are strongly dominated by psilate trilete spores (87-93%). In the absence of elaterate forms, the angiosperm pollen Afropollis jardinus, Pennipollis, Tricolpites spp. and Walkeripollis sp. is consistent with the early Albian age. The abundance and diversity of conifers and the prominence of the fern bog assemblage suggest a relatively humid phase of the regional Albian climates.     

Paleoceanographic evolution and chronostratigraphy of the Aptian Oceanic Anoxic Event 1a (OAE1a) to oceanic red bed 1 (ORB1) in the Gorgo a Cerbara section (central Italy)

We performed a detailed study of the stratigraphic transition of Oceanic Anoxic Event 1a (OAE1a) to oceanic red bed 1 (ORB1) from the classic Gorgo a Cerbara section in the Umbria region of central Italy. We focused on a 25.5-m-thick stratigraphic succession, from which we analyzed 305 samples for total organic carbon (TOC), CaCO₃, magnetic susceptibility, diffuse reflectance spectrophotometry and the stable carbon and oxygen isotopic composition of both bulk samples and organic matter. In the Gorgo a Cerbara section, the Selli Level of OAE1a (∼1.81 m thick) consists of laminated to bioturbated dark gray to black mudstones and shales with medium to dark gray radiolarian-rich silty to sandy layers and a maximum TOC content of 20.22%. The carbon isotopic values show a negative excursion (C3 stage, ∼0.14 m) at the base of the Selli Level, followed by a stepwise positive excursion (C4–C6 stages, ∼1.67 m) in the upper part of the Selli Level. The transition from OAE1a to ORB1 (∼3.19 m thick) is characterized by bioturbated greenish gray cherty limestones and marly limestones with subordinate marls, corresponding to stable carbon isotopic C7 stage and lasts for ∼0.75 Ma. The ORB1 interval (∼13.15 m) consists of reddish marly claystones, dark-red marlstones, red marly limestones and red calcareous shales which indicate a highly oxic environment. Our results reveal a stepwise transition from a predominantly mesotrophic and dysoxic to anoxic environment at the time that the OAE1a black shales were deposited to an oligotrophic and oxic environment during the transitional interval and finally to highly oxic conditions during the ORB1 interval. The nannoconid crisis occurs at the top of the C2 stage, just 0.34 m below the negative excursion in δ¹³C isotopic values. The massive CaCO₃ dissolution phase occurs 0.25 m above the negative excursion; it persisted for 0.85 Ma and probably resulted from excess CO₂, ocean acidification, and carbonate compensation depth (CCD) shoaling. Deposition of massive black shales occurs at the base of the C6 stage and lasted for 0.4 Ma.     

Biostratigraphy,palaeoenvironments and sequence stratigraphy of the Aptian sedimentary succession at Jebel Bir Oum Ali (Northern Chain of Chotts,South Tunisia): Comparison with contemporaneous Tethyan series

The Aptian sedimentary succession of the Chott region in southern Tunisia was deposited on the margin of the Saharan shield, and is punctuated by numerous hiatuses that separate seven 3rd-order depositional sequences. Early Aptian deposits correspond to the Berrani Member (early Bedoulian), which was deposited contemporaneously with the large carbonate platforms with rudists that developed under oligo-mesotrophic, tropical environmental conditions on both margins of the Tethys. Late Bedoulian sediments were deposited under mesotrophic conditions characterized by seagrass, algae, abundant orbitolinids and aragonite-producing organisms. The early to late Aptian transition was marked by the temporary disappearance of carbonate platforms and an important renewal of the microfauna, whose tests and skeletons became less and less aragonite-rich and more and more calcite-rich and arenaceous. This episode is reported from both Tethyan margins. The platform was subsequently flooded, and dysoxic environments with annelids marked the end of the early Aptian carbonate platform development. An arid and probably colder episode (earliest late Aptian) induced the deposition of gypsum in an intrashelf basin. Following on top, the return to more humid conditions triggered an enhanced input of detrital material in fluvio-deltaic environments (late Aptian). Finally, the return to oligo-mesotrophic, marine conditions allowed the temporary installation of wide lagoons with rudists in the latest Aptian and probably in the earliest Albian. Long-distance correlations have been established by means of benthic foraminiferal occurrences. They highlight the importance of stratigraphic gaps linked to low sea levels, which have been tentatively estimated.     

Determination of carbon fractionation factor between aqueous carbonate and CO2(g) in two-direction isotope equilibration

The experiments were conducted in the open CO₂ system to find out the equilibrium fractionation between the carbonate ion and CO₂(g). The existence of isotopic equilibrium was checked using the two-direction approach by passing the CO₂−N₂ gases with different δ¹³C compositions (− 1.5‰ and − 23‰) through the carbonate solution with δ¹³C = − 4.2‰. The Δ_{CO3T²⁻−CO2(g)} equilibrium fractionation is given as 6.03 ± 0.17‰ at 25 °C. Discussion is provided about the significance of carbonate complexing in determination of Δ_{CO3T²⁻−CO2(g)} and Δ_{HCO3T⁻−CO2(g)} fractionations. Finally, an isotope numerical model of flow and kinetics of hydration and dehydroxylation is built to predict the isotopic behaviour of the system with time.     

Microbiostratigraphy of Kazhdumi Formation in the Northwestern Shiraz (Southwest Iran) on the Basis of Foraminifera and Calcareous Algae

The middle Cretaceous Kazhdumi Formation,with a thickness of 222 m,belongs to the Bangestan Group and occurs in the Zagros folded zone in southwest Iran.The lower boundary with the Dariyan Formation is disconformable,which is recognized by iron oxides and glauconite.The recognized microfossils are Valvulammina sp.,Scandonea sp.,Daxia cenomana,Choffatela sp., Pseudolituonella reicheli and calcareous algae-Lithocodium aggregation(which belongs to the Sarvak Formation),representing the beginning of Cenomani...