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1.
Soil erosion has been identified as a potential global carbon sink since eroded organic matter is replaced at source and eroded material is readily buried. However, this argument has relied on poor estimates of the total fate of in‐transit particulates and could erroneously imply soil erosion could be encouraged to generate carbon stores. These previous estimates have not considered that organic matter can also be released to the atmosphere as a range of greenhouse gases, not only carbon dioxide (CO2), but also the more powerful greenhouse gases methane (CH4) and nitrous oxide (N2O). As soil carbon lost by erosion is only replaced by uptake of CO2, this could represent a considerable imbalance in greenhouse gas warming potential, even if it is not significant in terms of overall carbon flux. This work therefore considers the flux of particulate organic matter through UK rivers with respect to both carbon fluxes and greenhouse gas emissions. The results show that, although emissions to the atmosphere are dominated by CO2, there are also considerable fluxes of CH4 and N2O. The results suggest that soil erosion is a net source of greenhouse gases with median emission factors of 5.5, 4.4 and 0.3 tonnes CO2eq/yr for one tonne of fluvial carbon, gross carbon erosion and gross soil erosion, respectively. This study concludes that gross soil erosion would therefore only be a net sink of both carbon and greenhouse gases if all the following criteria are met: the gross soil erosion rate were very low (<91 tonnes/km2/yr); the eroded carbon were completely replaced by new soil organic matter; and if less than half of the gross erosion made it into the stream network. By establishing the emission factor for soil erosion, it becomes possible to properly account for the benefits of good soil management in minimizing losses of greenhouse gases to the atmosphere as a by‐product of soil erosion. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

2.
Environmental dating tracers (3H, 3He, 4He, CFC-12, CFC-11, and SF6) and the natural spring response (hydrochemistry, water temperature, and hydrodynamics) were jointly used to assess mixing processes and to characterize groundwater flow in a relatively small carbonate aquifer with complex geology in southern Spain. Results evidence a marked karst behaviour of some temporary outlets, with sharp and rapid responses to precipitation events, while some perennial springs show buffer and delayed variations with respect to recharge periods. The general geochemical evolution shows a pattern, from higher to lower altitudes, in which mineralization and the Mg/Ca ratio rise, evidencing longer water–rock interaction. The large SF6 concentrations in groundwater suggest terrigenic production, whereas CFC-11 values are affected by sorption or degradation. The groundwater age in the perennial springs—as deduced from CFC-12 and 3H/3He—points to mean residence times of several decades, although the large amount of radiogenic 4He in samples indicate a contribution of old groundwater (free of 3H and CFC-12). Lumped parameter models and shape-free models were created based on 3H, tritiogenic 3He, CFC-12, and radiogenic 4He data in order to interpret the age distribution of the samples. Results evidence the existence of two mixing components, with an old fraction ranging between 160 and 220 years in age. The correlation of physicochemical parameters with some dating parameters, derived from the mixing models, serves to explain the hydrogeochemical processes occurring within the system. Altogether, long residence times are shown to be possible in small alpine systems with a clearly karst behaviour if the geological setting features highly tectonized media including units with diverse hydrogeological characteristics. These findings highlight the importance of applying different approaches, including groundwater dating techniques, when studying such groundwater flow regimes.  相似文献   

3.
Use of eddy covariance (EC) techniques to map the spatial distribution of diffuse volcanic CO2 fluxes and quantify CO2 emission rate was tested at the Horseshoe Lake tree-kill area on Mammoth Mountain, California, USA. EC measurements of CO2 flux were made during September–October 2010 and ranged from 85 to 1,766 g m−2 day−1. Comparative maps of soil CO2 flux were simulated and CO2 emission rates estimated from three accumulation chamber (AC) CO2 flux surveys. Least-squares inversion of measured eddy covariance CO2 fluxes and corresponding modeled source weight functions recovered 58–77% of the CO2 emission rates estimated based on simulated AC soil CO2 fluxes. Spatial distributions of modeled surface CO2 fluxes based on EC and AC observations showed moderate to good correspondence (R 2 = 0.36 to 0.70). Results provide a framework for automated monitoring of volcanic CO2 emissions over relatively large areas.  相似文献   

4.
K lauea Volcano, Hawai‘i, currently hosts the longest running SO2 emission-rate data set on the planet, starting with initial surveys done in 1975 by Stoiber and his colleagues. The 17.5-year record of summit emissions, starting in 1979, shows the effects of summit and east rift eruptive processes, which define seven distinctly different periods of SO2 release. Summit emissions jumped nearly 40% with the onset (3 January 1983) of the Pu‘u ‘ ‘ -K paianaha eruption on the east rift zone (ERZ). Summit SO2 emissions from K lauea showed a strong positive correlation with short-period, shallow, caldera events, rather than with long-period seismicity as in more silicious systems. This correlation suggests a maturation process in the summit magma-transport system from 1986 through 1993. During a steady-state throughput-equilibrium interval of the summit magma reservoir, integration of summit-caldera and ERZ SO2 emissions reveals an undegassed volume rate of effusion of 2.1×105 m3/d. This value corroborates the volume-rate determined by geophysical methods, demonstrating that, for K lauea, SO2 emission rates can be used to monitor effusion rate, supporting and supplementing other, more established geophysical methods. For the 17.5 years of continuous emission rate records at K lauea, the volcano has released 9.7×106 t (metric tonnes) of SO2, 1.7×106 t from the summit and 8.0×106 t from the east rift zone. On an annual basis, the average SO2 release from K lauea is 4.6×105 t/y, compared to the global annual volcanic emission rate of 1.2×107 t/y.  相似文献   

5.
Soils release more carbon, primarily as carbon dioxide (CO2), per annum than current global anthropogenic emissions. Soils emit CO2 through mineralization and decomposition of organic matter and respiration of roots and soil organisms. Given this, the evaluation of the effects of abiotic factors on microbial activity is of major importance when considering the mitigation of greenhouse gases emissions. Previous studies demonstrate that soil CO2 emission is significantly affected by temperature and soil water content. A limited number of studies have illustrated the importance of bulk density and soil surface characteristics as a result of exposure to rain on CO2 emission, however, none examine their relative importance. Therefore, this study investigated the effects of soil compaction and exposure of the soil surface to rainfall and their interaction on CO2 release. We conducted a factorial laboratory experiment with three soil types after sieving (clay, silt and sand soil), three different bulk densities (1·1 g cm–3, 1·3 g cm–3, 1·5 g cm–3) and three different exposures to rainfall (no rain, 30 minutes and 90 minutes of rainfall). The results demonstrated CO2 release varied significantly with bulk density, exposure to rain and time. The relationship between rain exposure and CO2 is positive: CO2 emission was 53% and 42% greater for the 90 minutes and 30 minutes rainfall exposure, respectively, compared to those not exposed to rain. Bulk density exhibited a negative relationship with CO2 emission: soil compacted to a bulk density of 1·1 g cm–3 emitted 32% more CO2 than soil compacted to 1·5 g cm–3. Furthermore we found that the magnitude of CO2 effluxes depended on the interaction of these two abiotic factors. Given these results, understanding the influence of soil compaction and raindrop impact on CO2 emission could lead to modified soil management practices which promote carbon sequestration. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

6.
当水流通过泄洪建筑物下泄时,水体中所溶解的温室气体(二氧化碳(CO2)、甲烷(CH4)等)会因为所受压力的瞬间改变而导致溶解度降低,从而造成气液之间传质的发生及水中温室气体的排放.然而,目前对于泄流条件下水中温室气体排放的研究还较为缺乏.鉴于原型观测与模型试验的局限性,本文建立了大坝泄流条件下温室气体排放速率的数学模型...  相似文献   

7.
The characteristics of dayside auroras during the large (16–24 nT) positive values of the IMF B z component, observed on January 14, 1988, during the interaction between the Earth’s magnetosphere and the body of the interplanetary magnetic cloud, have been studied based on the optical observations on Heiss Island. A wide band of diffuse red luminosity with an intensity of 1–2 kilorayleigh (kR) was observed during 6 h in the interval 1030–1630 MLT at latitudes higher than 75° CGL. Rayed auroral arcs, the brightness of which in the 557.7 nm emission sharply increased to 3–7 kR in the postnoon sector immediately after the polarity reversal of the IMF B y component from positive to negative, were continuously registered within the band. Bright auroral arcs were observed at the equatorward edge of red luminosity. It has been found out that the red auroral intensity increases and the band equatorward boundary shifts to lower latitudes with increasing solar wind dynamic pressure. However, a direct proportional dependence of the variations in the auroral features on the dynamic pressure variations has not been found. It has been concluded that the source of bright discrete auroras is located in the region of the low-latitude boundary layer (LLBL) on closed geomagnetic field lines. The estimated LLBL thickness is ∼3 R e . It has been concluded that the intensity of the dayside red band depends on the solar wind plasma density, whereas the position of the position equatorward boundary depends on the dynamic pressure value and its variations.  相似文献   

8.
A spectral imager specifically designed to measure the O+(2P-2D) emission in the thermosphere during twilight has been constructed and tested in Toronto (43.8°N, 79.3°W), and found to show promise for long-term and campaign-mode operations. A modification of the mesopause oxygen rotational temperature imager (MORTI), it consists basically of a narrow-band interference filter (0.14 nm bandwidth) to separate wavelengths as a function of off-axis angle, a lens to focus the spectrum into a series of concentric rings, and a focal plane array (CCD) to record the spectral images in digital form. The instrument was built with two fields of view, one for the zenith and one for 20° above the horizon, movable to track the azimuth of the Sun, in order to provide appropriate data for inversion. Data gathered during June 1991 provided measurements of the column-integrated emission rate with a precision of about 3%. An atomic oxygen profile was deduced that showed good agreement with that predicted by the MSIS-90 model atmosphere. Geomagnetically induced variations of the O+ lines, calcium spectra resulting from meteor showers, and OH nightglow were also observed.  相似文献   

9.
Airborne and ground-based (correlation spectrometer, cascade impactor, and photoelectric counter together with intake filter probes) measurements are described for the volcanic emissions from Popocatépetl volcano (Mexico) from December 23, 1994 to January 28, 1995. Measurements of SO2 restarted 48 h after the eruption onset of December 21, 1994. Maximum sulfur dioxide (4560 t d−1) plus 3.8×104 t d−1 of particulate matter were ejected on December 24, 1994. The maximum rate of ejection occurred coincidentally with the maximum amplitude of harmonic tremor and the maximum number of seismic type B events. Sulfur dioxide emission rates ranged from 1790 to 2070 t d−1 (December 23–24, 1994). Afterwards, sulfur dioxide emission rates clearly indicated a consistent decline. However, frequent gas and ash emission puffs exhibited SO2 fluxes reaching values as high as 3060 t d−1. The emission SO2 baseline for the period of study (February 1994–January 1995) was about 1000 t d−1. Ejection velocity of particulate matter was approximately 270 m s−1 reaching a height of about 2.5 km over the summit. The immediate aerosol dispersion area was estimated at 6.0×104 km2 maximum. The microscopic structure of particles (aerosol and tephra) showed a fragile material, probably coming from weathered crustal layers. X-ray fluorescence and neutron-activation analysis from the impactor samples found the following elements: Si, Al, Ca, S, P, Cl, K, Ni, Fe, Ti, Sc, Cu, Zn, Mn, Sr, Cr, Co, Y, Br, Se, Ga, Rb, Hg and Pb. Morphological analysis shows that ash samples might be from pulverized basaltic rock indicating that the Popocatépetl eruption of December 21, 1994 was at low temperature. The microscopic structure of puff material showed substance aggregates consisted of fragile rock, water and adsorbed SO2. These aggregates were observed within water droplets of approximately 1 mm and even larger. Sulfur transformations in the droplets occurred intensively. Volcanic ash contained 5–6% of sulfur during the first expulsion hours. Elemental relative concentrations with respect to Al show that both Si and S have relative concentrations >1, i.e., 13.73 and 2.17, respectively in agreement with the photoelectric counter and COSPEC measurements.  相似文献   

10.
水库作为温室气体的重要来源,对区域气候变化有不可忽略的影响。然而,目前对水库溶存温室气体的空间异质性及垂向特征的认知仍然欠缺。为了揭示水库分层期和混合期溶存温室气体空间特征及排放通量,也为厘清水库温室气体产生和排放的关键过程提供重要支撑。研究选择东北地区大型水库——汤河水库为对象,于2021年7—9月和10月(分别代表水库分层期和混合期)对水库不同位置(坝前、库中和库尾)开展溶存温室气体垂向分层监测。研究结果显示,水库CH4排放通量变化范围为0.018~0.174 mmol/(m2·d),是大气CH4的源,空间分布为库尾>库中>坝前;CO2通量为-4.91~58.77 mmol/(m2·d),除分层期东支库尾,其余点位均表现为大气CO2的源,空间分布为坝前>库中>库尾。时间上,分层期CH4排放通量(0.071±0.044 mmol/(m2·d))高于混合期((0.027±0.008) mm...  相似文献   

11.
We report herein the first results of two soil CO2 efflux surveys carried out at Cuicocha lake-filled and Pululahua caldera volcanic systems, Ecuador. A total of 172 and 217 soil CO2 efflux measurements were taken at the surface environment of Pululahua and Cuicocha calderas respectively, by means of the “accumulation chamber” method during the summer of 2006 to constrain the total CO2 output from the studied area. Soil CO2 efflux values ranged from non-detectable up to 48.5 and 141.7 g m− 2 d− 1 for Cuicocha and Pululahua calderas respectively. In addition, probability graphs were used to distinguish the existence of different geochemical populations. Sequential Gaussian Simulation was used to construct an average map for 100 simulations and to compute the total CO2 emission at each studied area: 106 and 270 t d− 1 (metric tons per day) for Cuicocha (13.3 km2) and Pululahua (27.6 km2) volcanoes respectively.  相似文献   

12.
The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high pCO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol%) with an appreciable content of H2S (0.8–2%). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February–March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8–25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.  相似文献   

13.
三峡水库澎溪河水-气界面CO2、CH4扩散通量昼夜动态初探   总被引:6,自引:2,他引:4  
李哲  姚骁  何萍  王钦  郭劲松  陈永柏 《湖泊科学》2014,26(4):576-584
三峡水库温室气体效应近年来备受关注.为揭示三峡水库典型支流澎溪河水-气界面CO2和CH4通量的昼夜动态规律,明晰短时间尺度下该水域温室气体释放的影响因素,在2010年6月至2011年5月的一个完整水文周年内,选择4个具有代表性的时段(2010年8、11月和2011年2、5月)对澎溪河高阳平湖水域开展昼夜跟踪观测.结果表明:2010年8、11月和2011年2、5月4次采样的CO2日总通量值分别为-8.34、73.94、28.13和-20.12 mmol/(m2·d),相应的CH4日总通量值分别为2.22、0.11、0.32和7.16 mmol/(m2·d),不同时期昼夜变化明显.研究水域CO2和CH4通量过程不具同步性:CO2昼夜通量变化可能更显著地受到水柱光合/呼吸过程的影响,但瞬时气象过程(水汽温差、瞬时风速等)在高水位时期亦可对CO2通量产生显著影响;CH4昼夜通量变化与水温条件改变更为密切.  相似文献   

14.
Glacier meltwater change in the north‐eastern edge of the Tibetan Plateau is greatly important for the projection of the impact of future climate change on local water resource management. Although the glaciated area is only approximately 4% of the Upper Reach of the Shule River Basin (URSRB), the average glacier meltwater contribution to river run‐off was approximately 23.6% during the periods 1971/1972 to 2012/2013. A new glacier melting module coupled with the macroscale hydrologic Variable Infiltration Capacity model (VIC‐CAS) was adopted to simulate and project changes in the glacier meltwater and river run‐off of the URSRB forced by downscaled output of the BCC‐CSM1.1(m), CANESM2, GFDL‐CM3, and IPSL‐CM5A‐MR models. Comparisons between the observed and simulated river run‐offs and glacier area changes during the periods 2000/2001, 2004/2006, 2008/2009, and 2012/2013 suggest that the simulation is reasonable. Due to increases in precipitation, the annual total run‐off is projected to increase by approximately 2.58–2.73 × 108 m3 in the 2050s and 0.28–1.87 × 108 m3 in the 2100s compared with run‐off in the 2010s based on the RCP2.6 (low greenhouse gas emission) and RCP4.5 (moderate greenhouse gas emission) scenarios, respectively. The contribution of glacier meltwater to river run‐off will more likely decrease to approximately 10% and less than 5% during the 2050s and 2100s, respectively.  相似文献   

15.
Based on observations of electromagnetic radiation, a concept of thermal solar flares has been proposed. The absence of hard X-ray emission implies no accelerated electrons. This fact is the basis of the proposed concept of thermal flares. Since the acceleration rate should not exceed the electron energy loss rate, plasma density in the acceleration range must be at least 1011 cm?3. The temperature of plasma emitting in the soft X-ray range is of the order of 107 K. In the simplified problem of heated plasma hydrodynamics, we calculated the temperature profiles and their changes over time and by coordinate. The emission measure values determined from observations of the soft X-ray emission of flares is of the order of 1045 cm?3. The geometry of the source is an axial symmetric straight cylinder with a section of 1016 cm2 and an axial coordinate determined by the depth of plasma heating. Time profiles of soft X-ray emission were calculated for different sources of plasma heating, which were simulated using the Gaussian distribution law with respect to the coordinate and time. We have considered two modes of plasma heating: single (in time) and multipulse modes with different pulse intervals. The dynamics of plasma heating and cooling was shown to control the experimentally observed time profiles of soft X-ray emission. A comparison of numerical results with observational data allows us to confirm the implications of the proposed concept of thermal flares and, in addition, to perform diagnostics of plasma parameters in the emission source.  相似文献   

16.
The seasonal dependences of the response of the hydroxyl ((6–2) band) and molecular oxygen O2(b 1Σ g + ) ((0–1) band) emission intensities, temperature, and density indicator in the region of the hydroxyl emission maximum (87 km) to solar activity have been obtained based on the spectral observations of the mesopause emissions at Zvenigorod observatory during 2000–2007. The ratio of the OH (7–3) and (9–4) band intensities, characterizing the behavior of the vibrational temperature, has been used as an indicator of density. It has been established that the response of the studied mesopause characteristics to solar activity is positive in all seasons. In winter the response is maximal in the intensities and temperature and is minimal in the density indicator. The main mechanisms by which solar activity affects the mesopause characteristics have been considered. The behavior of the internal gravity waves with periods of 0.33–7 h depending on solar activity has been studied. It has been noted that these waves become more active at a minimum of the 11-year solar cycle.  相似文献   

17.
植被类型及淹水带来的干湿交替过程是影响温室气体排放的重要因素.本文通过原状土柱模拟实验,模拟西洞庭湖水文节律变化对不同土壤—植被系统温室气体排放的影响.利用静态箱—气相色谱法研究不同植被—土壤类型(芦苇湿地、灰化苔草湿地和刚砍伐的杨树林湿地)在季节性淹水条件下的CO_2、CH_4和N_2O的排放通量变化,并探讨了在水位变化的情况下,不同植被—土壤类型对全球增温潜势的贡献.结果表明:在不同的水文条件下,芦苇湿地的CO_2排放通量均显著高于苔草和杨树林湿地;淹水过程导致3种植被类型覆盖湿地CO_2排放通量显著降低,甲烷排放通量升高,其中芦苇湿地CH_4排放通量升高显著,苔草和杨树林湿地CH_4排放通量升高不明显;水文变化及植被类型对N_2O排放通量的影响不显著;不同植被类型湿地对全球增温潜势的贡献为:芦苇杨树林苔草,分别为16191.3、3405.6和1883.1 kg/hm~2.本研究结果表明在西洞庭湖湿地恢复过程中,不再人为增大芦苇湿地面积,将杨树林湿地恢复为苔草湿地,更有利于降低湿地恢复过程中温室气体的排放.  相似文献   

18.
Representation of dust sources remains a key challenge in quantifying the dust cycle and its environmental and climatic impacts. Direct measurements of dust fluxes from different landform types are useful in understanding the nature of dust emission and characterizing the dynamics of soil erodibility. In this study we used the PI-SWERL® instrument over a seasonal cycle to quantify the potential for PM10 (particles with diameter ≤10 μm) emission from several typical landform types across the Tengger Desert and Mu Us Sandy Land, northern China. Our results indicate that sparse grasslands and coppice dunes showed relatively high emission potentials, with emitted fluxes ranging from 10−1 to 101 mg m−2 s−1. These values were up to five times those emitted from sand dunes, and one to two orders of magnitude greater than the emissions from dry lake beds, stone pavements and dense grasslands. Generally, PM10 emission fluxes were seen to peak in the spring months, with significant reductions in summer and autumn (by up to 95%), and in winter (by up to 98%). Variations in soil moisture were likely a primary controlling factor responsible for this seasonality in PM10 emission. Our data provide a relative quantification of differences in dust emission potential from several key landform types. Such data allow for the evaluation of current dust source schemes proposed by prior researchers. Moreover, our data will allow improvements in properly characterizing the erodibility of dust source regions and hence refine the parameterization of dust emission in climate models. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.  相似文献   

19.
Meteor radar measurements of winds near 95 km in four azimuth directions from the geographic South Pole are analyzed to reveal characteristics of the 12-h oscillation with zonal wavenumber one (s = 1). The wind measurements are confined to the periods from 19 January 1995 through 26 January 1996 and from 21 November 1996 through 27 January 1997. The 12-h s = 1 oscillation is found to be a predominantly summertime phenomenon, and is replaced in winter by a spectrum of oscillations with periods between 6 and 11.5 h. Both summers are characterized by minimum amplitudes (5–10 ms–1) during early January and maxima (15–20 ms–1) in November and late January. For 10-day means of the 12-h oscillation, smooth evolutions of phase of order 4–6 h occur during the course of the summer. In addition, there is considerable day-to-day variability (±5–10 ms–1 in amplitude) with distinct periods (i.e., 5 days and 8 days) which suggests modulation by planetary-scale disturbances. A comparison of climatological data from Scott Base, Molodezhnaya, and Mawson stations suggests that the 12-h oscillation near 78°S is s = 1, but that at 68°S there is probably a mixture between s = 1 and other zonal wavenumber oscillations (most probably s = 2). The mechanism responsible for the existence of the 12-h s = 1 oscillation has not yet been identified. Possible origins discussed herein include in situ excitation, nonlinear interaction between the migrating semidiurnal tide and a stationary s = 1 feature, and thermal excitation in the troposphere.  相似文献   

20.
Popocatépetl volcano in central Mexico has been erupting explosively and effusively for almost 4 years. SO2 emission rates from this volcano have been the largest ever measured using a COSPEC. Pre-eruptive average SO2 emission rates (2–3 kt/d) were similar to the emission rates measured during the first part of the eruption (up to August 1995) in contrast with the effusive–explosive periods (March 1996–January 1998) during which SO2 emission rates were higher by a factor of four (9–13 kt/d). Based on a chronology of the eruption and the average SO2 emission rates per period, the total SO2 emissions (up to 1 January 1998) are estimated to be about 9 Mt, roughly half as much as the SO2 emissions from Mount Pinatubo in a shorter period. Popocatépetl volcano is thus considered as a high-emission rate, passively degassing eruptive volcano. SO2 emission rates and SO2 emissions are used here to make a mass balance of the erupted magma and related gases. Identified excess SO2 is explained in terms of continuous degassing of unerupted magma and magma mixing. Fluctuations in SO2 emission rate may be a result of convection and crystallization in the chamber or the conduits, cleaning and sealing of the plumbing system, and/or SO2 scrubbing by the hydrothermal system.  相似文献   

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