The geochemistry of monazite types from the Eastern Ghats granulite terrain,India

Summary Monazite occurs as an accessory mineral in a variety of rock types in the granulite belt of the Eastern Ghats, India. Five types of monazite paragenesis are distinguished based on the mode of occurrence. They include: 1) tiny inclusions in cordierite and garnet occurring in khondalites and charnockites, 2) distinct grains in charnockite, 3) associated with other phosphates (apatite and xenotime) in magnetite-spinel-sillimanite-sapphirine granulites, 4) well-developed grains in charnockites affected by shearing and 5) clustered grains in metasomatised pyroxenites. Microprobe analyses of these monazites show that they have some distinct chemical characteristics, mainly in terms of ELREE (La + Ce + Pr + Nd + Sm)/Actinides (U + Th) and ELREE/Y ratios. The chemistry of monazites supports the interpretation that actinides substitute for LREE, and implies other concomitant substitutions such as Ca for REE and Si for P. Among the five types of monazites, type 2 monazite is concentrated in greater abundance in some of the heavy mineral placer deposits along the east coast of India.

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Die Geochemie der Monazite aus dem östlichen Ghats Granulit-Terrain, Indien

Zusammenfassung Monazit tritt als akzessorisches Mineral in verschiedenen Gesteinstypen des Granulit-Gürtels der Ost-Ghats, Indien, auf. Aufgrund seines Vorkommens, können fünf verschiedene Monazit-Paragenesen unterschieden werden: 1) winzig kleine Einschlusse in Cordierit und Granat aus Khondaliten und Charnockiten, 2) Einzelkörner im Charnockit, 3) zusammen mit anderen Phosphaten (Apatit und Xenotim) in Magnetit-Spinel-Sillimanit-Saphir-Granuliten, 4) gut ausgebildete, jedoch zerscherte Körner im Charnockit und 5) verteilte Körner in metasomatisierten Pyroxeniten. Mikrosonden-Analysen zeigen, daB die Monazite durch ganz bestimmte LREE (La + Ce + Pr + Nd + Sm)/Aktividen (U + Th) und LREE/Y Verhältnisse charakterisiert sind. Der Chemismus der Monazite bestatigt den Ersatz der LREE durch die Aktiniden, und deutet gleichzeitige Substitution der REE durch Ca und des P durch Si an. Von den fünf verschiedenen Monazitarten, ist der Typ 2 in größerer Anzahl in einigen der Schweremineralseifen entlang der Ostküste Indiens konzetriert.

     

Intrusion age, geochemistry and metamorphic conditions of a quartz-monzosyenite intrusion at the craton–Eastern Ghats Belt contact near Jojuru, India

The boundary between the Archean cratons and the Eastern Ghats Belt in peninsular India represents a rifted Mesoproterozoic continental margin which was overprinted by a Pan-African collisional event associated with the westward thrusting of the Eastern Ghats granulites over the cratonic foreland. The contact zone contains a number of deformed and metamorphosed nepheline syenite complexes of rift-related geochemical affinities. In addition to the nepheline-bearing rocks, metamorphosed quartz-bearing monzosyenitic bodies can also be identified along the suture in the region between the Godavari-Pranhita graben and the Prakasam Igneous Province. One such occurrence at Jojuru near Kondapalle is geochemically comparable to the nepheline syenites and furnishes a weighted mean concordant U–Th–Pb SHRIMP zircon age of 1263 ± 23 Ma (2σ), which provides a lower age bracket for the rift-related magmatic activity. The original igneous mineral assemblage in the monzosyenite was partially replaced by the formation of coronitic garnet during the Pan-African metamorphism of the rocks. P–T estimates of garnet corona formation at the interface between clinopyroxene–orthopyroxene–ilmenite clusters and plagioclase indicate mid to upper amphibolite facies condition (5.5–7.0 kbar and 600–700 °C) during the thrust induced deformation and metamorphism associated with the Pan-African collisional tectonics.     

Petrology of the Udayagiri anorthosite complex, Eastern Ghats Belt, India

The Eastern Ghats Belt (EGB), characterised by pervasive Grenvillian granulite facies metamorphism, is the host to several 950–1000 Ma old massif-type anorthosite complexes. The present work describes one such complex near Udayagiri from the northern margin of the EGB, reported for the first time as “Udayagiri anorthosite complex” (UAC). The ‘massif type’ UAC comprises mainly of anorthosite, leuconorite-olivine leuconorite and norite in the decreasing order of areal extent. Mineralogically, these rocks dominantly consist of cumulates of moderately calcic plagioclase (～An_50–60), moderately magnesian intercumulus olivine (X_Mg: ～0.6) and orthopyroxene (X_Mg: 0.47 to 0.70). Metamorphic garnet (Alm: ～50 mol%) is also common in these rocks. Anorthosite and leuconorite of the UAC exhibit a moderate ‘+ve’ Eu anomaly. Norite occurs locally as schlierens and is relatively rich in Fe, P, Rb, Sr, Th, Nb, Ta, Y and REE which could be a residual melt product. These rocks exhibit both relict magmatic mineralogy and textures with a metamorphic impress manifested by the development of multilayered corona involving olivine, orthopyroxene, garnet, phlogopite, ilmenite and plagioclase during cooling of the pluton. The corona development is a result of combination of significant magmatic and metamorphic reactions which have the potential to provide important clues for deciphering the magmatic and metamorphic evolution of such plutons in ambient granulite facies conditions.     

Sediment geochemistry of coastal environments,southern Kerala,India: implication for provenance

Late Quaternary sediments representing the floodplain, estuary and offshore environments of southern Kerala were investigated to infer provenance. The grain size reveals the dominance of sand to silty clay, clay to clayey silt and clayey silt in the floodplain, estuary and offshore sediments, respectively. The chemical index of alteration (CIA) values and A-CN-K plot attributes to high, moderate and low weathering in floodplain, estuary and offshore regions, respectively. The SiO₂/Al₂O₃ values lesser than Post-Archean Australian Shale indicate low to moderate maturity for the estuarine and offshore sediments. The geochemical immaturity indicates its derivation from low to moderately weathered source rocks. The major and trace elemental ratios and discriminant function diagrams attribute that the sediments were derived from intermediate to felsic source rocks. The enrichment of Cr and Ni concentration in the sediments compared to the upper continental crust, related to the contribution of orthopyroxenes, weathered from charnockite and garnets from the granulite terrain, respectively.     

Contrasting mineral parageneses in high-temperature calc-silicate granulites: examples from the Eastern Ghats, India

Abstract Three types of mineral associations are described from calc-silicate granulites from the Eastern Ghats, India, where geothermobarometry in associated rocks suggests extremely high P–T conditions of metamorphism ( c . 9 ± 1 kbar, 950° C). These mineral associations are: (i) calcite + quartz + scapolite + plagioclase, (ii) calcite + scapolite + wollastonite + porphyroblastic garnet + coronal garnet and (iii) calcite + quartz + wollastonite + scapolite + porphyroblastic garnet + coronal garnet, all coexisting with K-feldspar, titanite and clinopyroxene. The first two associations evolved through nearly isobaric cooling retrograde paths, whereas the third evolved through a nearly isothermal decompression path followed by an isobaric cooling retrograde path. Textural and compositional characteristics suggest the following mineral reactions in the calc-silicate granulites: calcite + quartz = wollastonite + CO₂, calcite + plagioclase = scapolite, calcite + scapolite + wollastonite = porphyroblastic garnet ± quartz + CO₂, CaTs + wollastonite = coronal garnet (association ii) and wollastonite + scapolite = coronal garnet (association iii) + quartz + CO₂. Andradite content in garnet was buffered by the redox equilibria wollastonite + hedenbergite + O₂= andradite + quartz (association iii) and wollastonite + andradite + CaTs + scapolite = hedenbergite + calcite + grossular + O₂ (association ii). The contrasting mineral parageneses have been ascribed to interplay of variables such as X _CO2, f _O2, f _HCl in the fluid, bulk Na content and the nature of the retrograde P–T–X _CO2 paths through which the rocks evolved.     

地球化学方法在化学风化作用和物源判别中的应用综述

元素和同位素地球化学方法除了常用于研究古气候、古生态和沉积环境,现也广泛应用于化学风化和物源研究.虽然分析风化和物源的方法有多种,但就原理及其应用条件等来说,元素和同位素地球化学方法具有更广阔的应用前景.因此,本文总结了主量元素(Al、Na、Fe、K、Si和Fe等)、微量和稀土元素(La、Th、Zr和Sc等),以及同位素(235U、238U、204Pb、206Pb、147Sm和144Nd等)方法在化学风化和物源判别中的运用指标及其所代表的意义.结果显示,由于影响沉积物化学成分的因素较多,不同指标指示的意义可能会有所不同.因此,沉积物的化学风化程度和物源判别需要根据沉积物实际的化学组成成分具体分析,通过多种指标参数、判别图解和同位素定年的综合研究和相互验证才能得到更加直观和明确的结论.     

The Banpur-Balugaon and Bolangir Anorthosite Diapirs of the Eastern Ghats,India: Implications for the Massif Anorthosite Problem

Two anorthosite massifs in the Eastern Ghats share similar structural constitutions, internal differentiation histories, and overall thermal-tectonic patterns of evolution. The (1) circular to near-circular structural patterns both inside and close-to-border outside of the plutons; (2) the merging of these structures with the straight to gently flowing, essentially unidirectional structural trend of the granulite basement within short distances from the border of the plutons; (3) the increase of strain intensity near the border of the plutons; (4) the small but recognizable differences in the dip of the anorthosite flow layers; and (5) the foliation of the granulites, all are strong indications that these anorthosites were emplaced as syntectonic diapirs. In both massifs, anorthosite is by far the dominant lithology, noritic varieties being subordinate and generally formed as narrow dike-like bodies and pods, pockets, and irregular patches near the border. The striking features of the whole-rock and mineral chemistries of these massifs are increasing Fe, Ti, Mg, P, and REE, and decreasing Si and Al from the leucoanorthosites to the noritic rocks and wide Mg-Fe variation in the pyroxenes, in contrast to a relatively uniform plagioclase composition. These variations may be the result of initial differentiation in a layered complex serving as a precursor to the anorthosites, through modal sorting, rhythmic layering and cryptic changes, and a subsequent mixing of the modally sorted and cryptically enriched layers at different stages of anorthosite diapirism. Diapiraureole structural relationships, petrology, and thermobarometry suggest a moderately steep, counterclockwise cooling and exhumation path for both massifs to the P-T range: 5 to 6 kbar and 600 to 700°C. Such considerations, supplemented by a conductive cooling model for anorthosite emplacement and its subsequent evolution, lead to a branched path as the essential topology of the P-T-time history of the anorthosite-granulite associations of the Eastern Ghats. An important corollary of this inference is that a cycle of prograde and retrograde metamorphism of the aureole rocks—before and after the anorthosite invasion, respectively—is an essential consequence of the anorthosite emplacement.     

Petrology of Granulites from Anakapalle--Evidence for Proterozoic Decompression in the Eastern Ghats, India

The granulite complex at Anakapalle, which was metamorphosedat 1000 Ma, comprises orthopyroxene granulites, leptynite, khondalite,mafic granulites, calc-silicate rock, spinel granulites, andtwo types of sapphirine granulites—one quartz-bearingand migmatitic and the other devoid of quartz and massive. Reactiontextures in conjunction with mineral-chemical data suggest severalcontinuous and discontinuous equilibria in these rocks. In orthopyroxenegranulites, dehydration-melting of biotite in the presence ofquartz occurred according to the reaction biotite+quartz= garnet (Py₃₇)+K-feldspar+orthopyroxene + liquid. Later, this garnet broke down by the reaction garnet (Py₃₇)+quartz= orthopyroxene + plagioclase. Subsequently, coronal garnet (Py₃₀) and quartz were producedby the same reaction but proceeding in the opposite direction.In spinel granulites, garnet (Py₄₂) and sillimanite were producedby the breakdown of spinel in the presence of quartz. In thetwo types of sapphirine granulites, garnet with variable pyropecontent broke down according to the reaction garnet = sapphirine + sillimanite + orthopyroxene. The highest pyrope content (59 mol %) was noted in garnets fromquartz-free sapphirine granulites compared with the quartz-bearingone (53 mol % pyrope). The calculated positions of the mineralreactions and diserete P-T points obtained by thermobarometrydefine a retrograde P-T trajectory during which a steep decompressionof 1.5 kbar from P-T_max of 8 kbar and 900C was followed bynear-isobaric cooling of 300C. During this decompression, garnetwith variable pyrope contents in different rocks broke downon intersection with various divariant equilibria. Near-isobariccooling resulted in the formation of coronal garnet around second-generationorthopyroxene and plagioclase replacing earlier porphyroblasticgarnet in orthopyroxene granulites. It has been argued thatthe deduced P-T trajectory originated in an extensional regimeinvolving either a crust of near-normal thickness of a slightlyoverthickened crust owing to magmatic underaccretion.     

Contrasting magmatic signatures in the Rairakhol and Koraput alkaline complexes,Eastern Ghats belt,India

The relation between alkaline magmatism and tectonism has been a contentious issue, particularly for the Precambrian continental regions. Alkaline complexes at the southwestern margin of Eastern Ghats belt, India, have been interpreted as rift-valley magmatism. However, those complexes occurring in granulite ensemble in the interior segments of the Eastern Ghats belt could not possibly be related to the rift-system, assumed for the western margin of the Eastern Ghats belt. Koraput complex was emplaced in a pull-apart structure, dominated by magmatic fabrics and geochemically similar to a fractionated alkaline complex, compatible with an alkalibasalt series. Rairakhol complex, on the other hand, shows dominantly solid-state deformation fabrics and geochemically similar to a fractionated calc-alkaline suite. Isotopic data for the Koraput complex indicate ca. 917 Ma alkaline magmatism from a depleted mantle source and postcrystalline thermal overprint at ca. 745 Ma, also recorded from sheared metapelitic country rocks. The calc-alkaline magmatism of the Rairakhol complex occurred around 938 Ma, from an enriched mantle source, closely following Grenvillian granulite facies imprint in the charnockitic country rocks.     

Petro-tectonic Imprints in the Sapphirine Granulites from Anantagiri, Eastern Ghats Mobile Belt, India

Sapphirine granulite occurring as lenses in charnockite at Anantagiri,Eastern Ghat, India, displays an array of minerals which developedunder different P-T-X conditions. Reaction textures in conjunctionwith mineral chemical data attest to several Fe-Mg continuousreactions, such as

1. spinel+rutile+quartz+MgFe_–1=sapphirine+ilmenite
2. cordierite=sapphirine+quartz+MgFe_–1
3. sapphirine+quartz=orthopyroxene+sillimanite+MgFe_–1
4. orthopyroxene+sapphirine+quartz=garnet+MgFe_–1
5. orthopyroxene+sillimanite=garnet+quartz+MgFe_–1
6. orthopyroxene+sillimanite+quartz+MgFe_–1=cordierite.

Calculated positions of the reaction curves in P-T space, togetherwith discrete P-T points obtained through geothermobarometryin sapphirine granulite and the closely associated charnockiteand mafic granulite, define an anticlockwise P-T trajectory.This comprises a high-T/P prograde metamorphic path which culminatedin a pressure regime of 8?3 kb above 950?C, a nearly isobariccooling (IBC) path (from 950?C, 8?3 kb, to 675?C, 7?5kb) anda terminal decompressive path (from 7?5 to 4?5 kb). Spinel,quartz, high-Mg cordierite, and sapphirine were stabilized duringthe prograde high-T/P metamorphism, followed by the developmentof orthopyroxene, sillimanite, and garnet during the IBC. Retrogradelow-Mg cordierite appeared as a consequence of decompressionin the sapphirine granulite. Deformational structures, reportedfrom the Eastern Ghat granulites, and the available geochronologicaldata indicate that prograde metamorphism could have occurredat 30001?00 and 2500?100 Ma during a compressive orogeny thatwas associated with high heat influx through mafic magmatism. IBC ensued from P_max and was thus a direct consequence of progrademetamorphism. However, in the absence of sufficient study onthe spatial variation in P-T paths and the strain historiesin relation to time, the linkage between IBC and isothermaldecompression (ITD) has remained obscure. A prolonged IBC followedby ITD could be the consequence of one extensional mechanismwhich had an insufficient acceleration at the early stage, orITD separately could be caused by an unrelated extensional tectonism.The complex cooled nearly isobarically from 2500 Ma. It sufferedrapid decompression accompanied by anorthosite and alkalinemagmatism at 1400–1000 Ma.     

Rainfall erosivity and erosivity density in Eastern Ghats Highland of east India

The rainfall erosivity (R-factor in USLE) is the long-term average of the sum of the product of rainfall kinetic energy and its maximum 30-min intensity. Therefore, at most 30-min time intervals pluviograph records are required to calculate R-factor. But, such high-resolution data are scarce in many parts of the world and require lengthy processing period. In this study, R-factor was correlated with daily, monthly and annual rainfall, and its spatial variability in Eastern Ghats Highland of east India was mapped. The result showed that power regression models predicted satisfactorily the daily, monthly and annual R-factor, of which annual R-factor model performed best (model efficiency 0.93). Mean monsoon season R-factor was 15.6 and 10.0 times higher than the pre- and post-monsoon season R-factor, and thus remained highly critical with respect to erosion. Annual R-factor values ranged from 3040 to 10,127 MJ mm ha^?1 h^?1 year^?1, with standard deviation of 1981 MJ mm ha^?1 h^?1 year^?1. Rainfall intensity was positively correlated with erosivity density, and numerical value of rainfall intensity was almost double of the erosivity density value. The combination of rainfall and erosivity density was used to identify flood, erosion and landslide-prone areas. The developed iso-erosivity, erosivity density and risk maps can be opted as a tool for policy makers to take suitable measures against natural hazards in Eastern Ghats Highland of east India and elsewhere with similar rainfall characteristics.

     

Neoproterozoic evolution and Cambrian reworking of ultrahigh temperature granulites in the Eastern Ghats Province,India

The time‐scales and P–T conditions recorded by granulite facies metamorphic rocks permit inferences about the geodynamic regime in which they formed. Two compositionally heterogeneous cordierite–spinel‐bearing granulites from Vizianagaram, Eastern Ghats Province (EGP), India, were investigated to provide P–T–time constraints using petrography, phase equilibrium modelling, U–Pb geochronology, the rare earth element composition of zircon and monazite, and Ti‐in‐zircon thermometry. These ultrahigh temperature (UHT) granulites preserve discrete compositional layering in which different inferred peak assemblages are developed, including layers bearing garnet–sillimanite–spinel, and others bearing orthopyroxene–sillimanite–spinel. These mineral associations cannot be reproduced by phase equilibrium modelling of whole‐rock compositions, indicating that the samples became domainal on a scale less than that of a thin section, even at UHT conditions. Calculation of the P–T stability fields for six compositional domains within which the main rock‐forming minerals are considered to have attained equilibrium suggests peak metamorphic conditions of ~6.8–8.3 kbar at ~1,000°C. In most of these domains, the subsequent evolution resulted in the growth of cordierite and final crystallization of melt at an elevated (residual) H₂O‐undersaturated solidus, consistent with <1 kbar of decompression. Concordant U–Pb ages obtained by SHRIMP from zircon (spread 1,050–800 Ma) and monazite (spread 950–800 Ma) demonstrate that crystallization of these minerals occurred during an interval of c. 250 Ma. By combining LA‐ICP‐MS U–Pb zircon ages with Ti‐in‐zircon temperatures from the same analysis sites, we show that the crust may have remained above 900°C for a minimum of c. 120 Ma between c. 1,000 and c. 880 Ma. Overall, the results suggest that, in the interval 1,050 to 800 Ma, the evolution of the Vizianagaram granulites culminated with UHT conditions from c. 1,000 Ma to c. 880 Ma, associated with minor decompression, before further zircon crystallization at c. 880–800 Ma during cooling to the solidus. However, these rocks are adjacent to the Paderu–Anantagiri–Salur crustal block to the NW that experienced counterclockwise P–T–t paths, and records similar UHT peak metamorphic conditions (7–8 kbar, ~950°C) followed by near‐isobaric cooling, and has a similar chronology during the Neoproterozoic. The limited decompression inferred at Vizianagaram may be explained by partial exhumation due to thrusting of this crustal block over the adjacent Paderu–Anantagiri–Salur crustal block. The residual granulites in both blocks have high concentrations of heat‐producing elements and likely remained hot at mid‐crustal depths throughout a period of relative tectonic quiescence in the interval 800–550 Ma. During the Cambrian Period, the EGP was located in the hinterland of the Denman–Pinjarra–Prydz orogen. A later concordant population of zircon dated at 511 ± 6 Ma records crystallization at temperatures of ~810°C. This age may record a low‐degree of melting due to limited influx of fluid into hot, weak crust in response to convergence of the Crohn craton with a composite orogenic hinterland comprising the Rayner terrane, EGP, and cratonic India.     

Emplacement History of Pasupugallu Gabbro Pluton, Eastern Ghats Belt, India: a Structural Study

Structural mapping of the Pasupugallu pluton, an elliptical intrusive gabbro-anorthosite body, emplaced into the western contact zone between the Eastern Ghats Mobile Belt and the Archaean East Dharwar Craton, along the east coast of India, reveals concentric, helicoidal and inward dipping magmatic and/or tectonic foliations. We identify a <1 km-wide structural aureole characterized by pronounced deflection of regional structures into margin parallel direction, mylonitic foliations with S-C fabrics, sigmoidal clasts, moderately plunging stretching lineations, non-cylindrical intrafolial folds, and stretched elliptical mafic enclaves in the aureole rocks. Our results suggest that the pluton emplacement is syn-tectonic with respect to the regional ductile deformation associated with the terrane boundary shear zone at the western margin of the Eastern Ghats. We present a tectonic model for the emplacement of the pluton invoking shear-related ductile deformation, rotation and a minor component of lateral expansion of magma. The intrusive activity (1450-800 Ma) along the western margin of the Eastern Ghats can be correlated with the significant event of recurring mafic, alkaline and granitic magmatism throughout the global Grenvillian orogens associated with the continent-continent collision tectonics possibly related to the amalgamation and the breakup of the supercontinent Rodinia.     

Geology,geochemistry and age of the Hukeng tungsten deposit,Southern China

The Hukeng tungsten deposit, located in the Wugongshan area in central part of Jiangxi province, South China, is a large-scale quartz-vein wolframite deposit. It is hosted in the Hukeng granitic intrusion. Based on the mineral assemblage and crosscutting relationship of the veins, three mineralization stages are identified, including: (1) quartz–wolframite stage, (2) quartz–fluorite–wolframite stage, and (3) quartz–pyrite–sphalerite–wolframite stage.The homogenization temperatures of fluid inclusions in vein quartz vary from 220 to 320 °C, and the salinities are from 0 to 10 wt.% NaCl equiv.; corresponding densities range from 0.7 to 1 g/cm³. These features indicated that the ore-forming fluids in the Hukeng tungsten deposit have medium temperature, low density and low salinity.The δ¹⁸OSMOW values of quartz range from 10.8‰ to 14.4‰, with corresponding δ¹⁸O_fluid values of 3.7‰ to 7.7‰, and δD values of fluid inclusions of between ? 70‰ and ? 55‰. The combined isotopic data indicate that the ore-forming fluids of the Hukeng tungsten deposit were mainly derived from magmatic water, with some minor input from meteoric water.We have carried out molybdenite Re–Os and muscovite ⁴⁰Ar/³⁹Ar dating to constrain the timing of mineralization. Re–Os dating of six molybdenite samples yielded model ages ranging from 149.1 ± 2.0 to 150.7 ± 3.7 Ma, with an average of 150.0 Ma. The Re–Os analyses give a well-defined ¹⁸⁷Re/¹⁸⁷Os isochron with an age of 150.2 ± 2.2 Ma (MSWD = 0.60). Hydrothermal muscovite yields a plateau ⁴⁰Ar/³⁹Ar age of 147.2 ± 1.4 Ma. ⁴⁰Ar/³⁹Ar age is in good agreement with the Re–Os age. These ages show that the timing of tungsten mineralization occurred at about 150 Ma. Our new data, when combined with published geochronological results from the other major deposits in this region, suggest that widespread W mineralization occurred in the Late Jurassic throughout South China.     

Petrology and geochemistry of late archaean granitoids in the northern part of Eastern Dharwar Craton,Southern India: Implications for transitional geodynamic setting

The results of field, petrographic and geochemical work of the granitoids of Hutti-Gurgunta area in the northern part of Eastern Dharwar Craton (EDC) is presented in this paper. This crustal section comprises polyphase banded to foliated TTG gneisses, middle amphibolite facies Gurgunta schist belt and upper greenschist facies Hutti schist belt and abundant granite plutons. The focus of the present study is mainly on basement TTG gneisses and a granite pluton (∼ 240 sq km areal extent), to discuss crustal accretion processes including changing petrogenetic mechanism and geodynamic setting. The TTGs contain quartz, plagioclase, lesser K-feldspar and hornblende with minor biotite while the granite contain quartz, plagioclase, K-feldspar and hornblende. Late stage alteration (chloritisation, sericitisation and epidotisation) is wide spread in the entire area. A huge synplutonic mafic body which is dioritic to meladioritic in composition injects the granite and displays all stages of progressive mixing and hybridization. The studied TTGs and granite show distinct major and trace element patterns. The TTGs are characterized by higher SiO₂, high Al₂O₃, and Na₂O, low TiO₂, Mg#, CaO, K₂O and LILE, and HFS elements compared to granite. TTGs define strong trondhjemite trend whilst granite shows calc-alkaline trend. However, both TTGs and granite show characteristics of Phanerozoic high-silica adakites. The granite also shows characteristics of transitional TTGs in its high LILE, and progressive increase in K₂O with differentiation. Both TTGs and granite define linear to sub-linear trends on variation diagrams. The TTGs show moderate total REE contents with fractionated REE patterns (La/Yb_N =17.73–61.73) and slight positive or without any significant Eu anomaly implying little amount of amphibole or plagioclase in residual liquid. On the other hand, the granite displays poor to moderate fractionation of REE patterns (La/Yb_N = 9.06–67.21) without any significant Eu anomaly. The TTGs have been interpreted to be produced by low-K basaltic slab melting at shallow depth, whereas the granite pluton has been formed by slab melting at depth and these melts interacted with peridotite mantle wedge. Such changing petrogenetic mechanisms and geodynamic conditions explain increase in the contents of MgO, CaO, Ni and Cr from 2700 Ma to 2500 Ma granitoids in the EDC.     

西藏措勤地区则弄群火山岩源区——地球化学及Sr-Nd同位素制约

西藏中冈底斯带出露大面积早白垩世则弄群火山岩。措勤地区则弄群火山岩具有较高的SiO2含量(61.91%~74.28%),轻稀土元素相对富集,富集大离子亲石元素Rb、Ba、Th、U,亏损高场强元素Nb、Ta等,并具Sr负异常,同时具有高的初始Sr同位素(0.707 89~0.710 17)和低的Nd的同位素(-3.4~-9.3)特征,与壳源岩浆的地球化学特征类似。在εNd(t)-(87Sr/86Sr)i图解上,措勤地区则弄群火山岩所有样品均投于第四象限,而且都分布在上地壳与雅鲁藏布江MORB型亏损地幔混合线附近。微量元素构造环境判别图解显示,则弄群火山岩形成于岛弧环境。综合已有研究成果以及最新1∶25万区域地质调查资料,认为措勤地区则弄群长英质火山岩很可能是幔源基性岩浆的热量促使地壳物质脱水发生重熔的产物,其形成的大地构造背景很可能与班公湖-怒江特提斯洋南向的俯冲作用有关。