Dissociation constants of protonated cysteine species in seawater media

The dissociation constants (pK₁, pK₂ and pK₃) for cysteine have been measured in seawater as a function of temperature (5 to 45 °C) and salinity (S = 5 to 35). The seawater values were lower than the values in NaCl at the same ionic strength. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been compared to those calculated from the Pitzer ionic interaction model. The lower values of pK₃ in the Na–Mg–Cl solutions have been attributed to the formation of Mg²⁺ complexes with Cys²⁻ anions

Mg²⁺ + Cys²⁻ = MgCys

The stability constants have been fitted to

after corrections are made for the interaction of Mg²⁺ with H⁺.The pK₁ seawater measurements indicate that H₃Cys⁺ interacts with SO₄²⁻. The Pitzer parameters β⁰(H₃CysSO₄), β¹(H₃CysSO₄) and C(H₃CysSO₄) have been determined for this interaction. The formation of CaCys as well as MgCys are needed to account for the values of pK₂ and pK₃ in seawater.The consideration of the formation of MgCys and CaCys in seawater yields model calculated values of pK₁, pK₂ and pK₃ that agree with the measured values to within the experimental error of the measurements. This study shows that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids.     

Simulation of Seawater Intrusion Range in Coastal Aquifer Using the FEMWATER Model for Disaster Information

The FEMWATER model is a three-dimensional finite element model that can simulate both groundwater flow and mass transport at the same time, and so by using this FEMWATER model seawater intrusion was simulated and the results were compared to observation data. By using the observation data, a conceptual model was made of 3 layers based on the type of soil, and the hydrogeological parameter was selected. There are two types of dispersivities: longitudinal dispersivity and transverse dispersivity. Longitudinal dispersivity was calculated by Xu and Eckstein's method (1995 Xu , M. and Y. Eckstein . 1995 . Use of weighted least-squares method in evaluation of the relationship between dispersivity and field scale . Ground Water 33 ( 6 ): 905 – 908 .[Crossref], [Web of Science ®] , [Google Scholar]) and the transverse dispersivity was put at 3/10 of the longitudinal dispersivity for the simulation. The electrical conductivity suggested by Freeze and Cherry (1979 Freeze , R. A. and J. A. Cherry , J. A. 1979 . Groundwater . Eaglewood Cliffs , NJ : Prentice-Hall . [Google Scholar]) and the correlation with total dissolved solids, TDS, was used to classify the state of the water. Upon analyzing the depths at 15 m, 30 m, 60 m, and 90 m, occurrence of seawater intrusion near the ground surface was limited to the vicinity of the coastline, but as the depths became deeper, seawater intrusion expanded inland. From these results we can come to the conclusion that in order to prevent seawater intrusion there needs to be sufficient preliminary examination.     

Characterizing air–sea CO2 exchange dynamics during winter in the coastal water off the Hugli-Matla estuarine system in the northern Bay of Bengal, India

The distribution of the fugacity of CO₂ ( $ f_{{{\text{CO}}_{ 2} }} $ ) and air–sea CO₂ exchange were comprehensively investigated in the outer estuary to offshore shallow water region (lying adjacent to the Sundarban mangrove forest) covering an area of ~2,000 km² in the northern Bay of Bengal during the winter. A total of ten sampling surveys were conducted between 1 December, 2011 and 21 February, 2012. Physico-chemical variables like sea surface temperature (SST), salinity, pH, total alkalinity (TAlk), dissolved inorganic carbon (DIC) and in vivo chlorophyll-a along with atmospheric variables were measured in order to study their role in controlling the CO₂ flux. Surface water $ f_{{{\text{CO}}_{ 2} }} $ ranged between 111 and 459 μatm which correlated significantly with the SST (r = 0.71, p < 0.001, n = 62). Neither DIC nor TAlk showed any linear relationship with varying salinity in the estuarine mixing zone, demonstrating the significant presence of non-carbonate alkalinity. An overall net biological control on the surface $ f_{{{\text{CO}}_{ 2} }} $ distribution was established during the study, although no significant correlation was found between chlorophyll-a and $ f_{{{\text{CO}}_{ 2} }} $ (water). The shallow water region studied was mostly under-saturated with CO₂ and acted as a sink for atmospheric CO₂. The difference between surface water and atmospheric $ f_{{{\text{CO}}_{ 2} }} $ ( $ \Updelta f_{{{\text{CO}}_{ 2} }} $ ) ranged from ?274 to 69 μatm, with an average seaward flux of ?10.5 ± 12.6 μmol m^?2 h^?1. The $ \Updelta f_{{{\text{CO}}_{ 2} }} $ and hence the air–sea CO₂ exchange was primarily regulated by the variation in sea surface $ f_{{{\text{CO}}_{ 2} }} $ , since atmospheric $ f_{{{\text{CO}}_{ 2} }} $ varied over a comparatively narrow range of 361.23–399.05 μatm.     

Gravitational Sedimentation Behavior of Sensitive Marine Ariake Clays

It has been well documented that natural marine Ariake clays are sensitive clays. In this study, extensive data of marine Ariake clays are obtained to investigate the gravitational compression behavior for sensitive clays. Analysis results indicate that the compression behavior of remolded Ariake clays is not different from that of other remolded/reconstituted soils. But natural Ariake clays do not follow the gravitational compression pattern reported by Skempton (1970) Skempton, A. W. 1970. “The consolidation of clays by gravitational compaction”. In Q. J. Geol. Soc 373–411.  [Google Scholar] for natural sedimentary soils. At a given value of effective overburden pressure, the void ratios of natural Ariake clays are almost independent of liquid limits. Most natural Ariake clays lie above the sedimentation compression line proposed by Burland (1990) Burland, J. B. 1990. On the compressibility and shear strength of natural clays. Gèotechnique, 40: 329–378. [Crossref], [Web of Science ®] , [Google Scholar]. When the liquid limit is larger than 90% and the ratio of natural water content over liquid limit ranges 0.8–1.1, the natural Ariake clays lie around the sedimentation compression line. In addition, the natural Ariake clay with higher value of the ratio of natural water content over liquid limit lies above the natural Ariake clay with lower value of the ratio of natural water content over liquid limit. Salt removal is the most probable cause for such a phenomenon.     

Closure to “anisotropic hydraulic conductivity and critical hydraulic gradient of a crushed sandstone–mudstone particle mixture”

A closure is presented to the discussion of Anisotropic hydraulic conductivity and critical hydraulic gradient of a crushed sandstone–mudstone particle mixture by Salahou, Jiao, and Yousif (2017 Fener, M., and N. Yesiller. 2013. Vertical pore structure profile of a compacted clayey soil. Engineering Geology 166:204–15. doi:10.1016/j.enggeo.2013.08.001.[Crossref], [Web of Science ®] , [Google Scholar]). The relationship between the critical hydraulic gradient and the uniformity coefficient can be limited to two curves. The internal erosion mechanism of soils with different particle grade curves is different. The maximum diameter of fine particles of different particle grade curves can be calculated by a lot of methods. The density of the original paper is the average density. The anisotropic hydraulic conductivity is caused by uneven density distribution. The hydraulic conductivities are tested on the saturated soils. The saturated hydraulic conductivity can be regard as a constant value for a saturated soil.     

Large eddy simulation of stratified mixing in a three-dimensional lock-exchange system

Accurate and computationally-efficient modeling of stratified mixing processes are of paramount importance in both coastal and large-scale ocean circulation. In this study, our main objective is to investigate the feasibility and accuracy of large eddy simulation (LES) as a possible tool to study small-scale oceanic processes. To this end, LES is evaluated in a 3D lock-exchange problem, which contains shear-driven mixing, internal waves, interactions with boundaries and convective motions, while having a simple domain, initial and boundary conditions, and forcing.Two general classes of LES models are tested, namely eddy viscosity (EV) models based on constant–coefficient and dynamic Smagorinsky models, and an approximate deconvolution (AD) model. By noting that the dynamic Smagorinsky and AD models have different strengths in that the former is good in providing appropriate dissipation while the latter in preserving the detail of coherent structures on coarse resolution meshes, a hybrid approach combining EV and AD models is also evaluated. A direct numerical simulation (DNS) is performed as the benchmark solution, and all LES models are tested on three coarse meshes. The main measure of mixing is taken as the temporal evolution of background potential energy.It is found that constant-coefficient Smagorinsky models can only provide a marginal improvement over under-resolved simulations, while both dynamic Smagorinsky and AD models lead to significant improvements in mixing accuracy. The primary accomplishment of this study is that it is shown that the hybrid approach attains the best agreement with the mixing curve from DNS, while being computationally approximately a thousand times faster.     

Geometry of scour hole around, and the influence of the angle of attack on the burial of finite cylinders under combined flows

Experiments were conducted to investigate the geometry of the scour hole and flow structure around short cylinders under the action of waves alone (WA) and combined flows (CF). The study is aimed at better understanding the dynamics of isolated objects on a sandy floor under oscillatory flows as occurs in shallow water regions in coastal areas. Flow velocities within the fluid core were recorded and 3D mapping of the bottom was performed with sub-aquatic acoustic sensors. Experiments were conducted for cylinder Reynolds wave number and Keulegan-Carpenter number within the ranges 10⁴R_e1.7×10⁵ and 2KC71, respectively. The present experimental evidence shows that the geometric characteristics of the scour hole (length and width) depend primarily on the Keulegan-Carpenter number (KC) and the cylinder aspect ratio (a_r=L_c/D). The effect of variation in the angle of attack of the flow with respect to the cylinder main axis was also investigated. Initial orientations of zero and ninety degrees were found to be stable while cylinders with intermediate initial orientations tended to orientate their main axes perpendicular to the flow direction. The final angle of orientation was found to be primarily a function of the Shields parameter, θ, and the initial angle of attack, α_i.     

Parameterization of iron and manganese cycling in the Black Sea suboxic and anoxic environment

New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σ_t16.2) and anoxic layers (σ_t16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σ_t16.2±0.2 kg m⁻³. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σ_t16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.     

Effects of stratification and mesoscale eddies on Kuroshio path variation south of Japan

Bimodality of the Kuroshio current path south of Japan is investigated, focusing on the effects of stratification and mesoscale eddies. For this purpose, wind-driven numerical experiments are executed in barotropic and two-layered ocean models. Stratification has two effects on the path selection of the Kuroshio south of Japan. First, it makes an alongshore path stable at intermediate wind stress strength τ₀ by arresting an eddy southeast of Kyushu. This enables an alongshore path to appear in the entire experimental range of τ₀. Second, the upper limit of τ₀ which allows a meandering path decreases from ( in the Sverdrup transport at the Tokara Strait) to () as Δρ/ρ₀ increases from 2.0×10^-3 to 4.0×10^-3. While an anticyclonic eddy imposed upstream (southeast of Kyushu) can cause the transition from an alongshore to a meandering path, it occurs most easily when (). The transition from a meandering to an alongshore path requires an eddy imposed downstream (east of the meandering segment) which suppresses redevelopment of the meandering segment and breaks the balance between the advective and beta effects. Applicability of the results to previously observed path variations is discussed.     

Experimental study on the gap entrance profile affecting rudder gap cavitation

The unsteady cavity patterns around the gap of the conventional and newly developed semi-spade rudders for marine ships are visualized qualitatively using a high-speed CCD camera. Time-resolved PIV analysis is also performed with the bubble tracers to study the flow behavior over the rudder surface. In addition, pressure measurements are conducted on the rudder surface and inside the gap to find out the flow characteristics around the gap entrance of the rudder. Both the rudders are tested without a propeller wake at the various cavitation numbers and at the rudder deflection angle of −8°θ10°. The strong cavitation patterns around the conventional rudder gap are significantly reduced by adopting a newly developed entrance profile, and a time-resolved velocity field is found to be very effective in catching the vortical cavity flow around the rudder gap. The stagnation point near the gap entrance of the conventional rudder can cause unsteady cavity flow. However, the developed rudder has very stable pressure distribution along the horn surface and decreases the pressure inside the gap because of the modification of the gap entrance. The pressure distribution around the gap of the suction side is closely related to the variation of the rudder deflection angle. The cavitation inception speed is delayed by about 4 knots in the angle range of −5°θ5° by employing the developed profile of the gap entrance.     

Method for comparing fish growth curves

The method of comparing growth curves that is described in this paper consists of describing growth for the ith group by the equation Li(t) = ai + bi r^t, which is linear in the two parameters ai and bi, and subsequently using the analysis of variance to compare the curves. The advantages of the linear growth equation over the von Bertalanffy equation, l i (t) ⁼ ai + bi r^t i, are easier analysis and a much simpler interpretation of the differences in the parameters in terms of growth rate and maximum size. An example comparing the growth of male and female red gurnard Chelidonichthys kumu from four areas within the Hauraki Gulf is given.     

Organic biogeochemistry of the Darwin Mounds, a deep-water coral ecosystem, of the NE Atlantic

The Darwin Mounds are a series of small (5 m high, 75–100 m diameter) sandy features located in the northern Rockall Trough. They provide a habitat for communities of Lophelia pertusa and associated fauna. Suspended particulate organic matter (sPOM) reaching the deep-sea floor, which could potentially fuel this deep-water coral (DWC) ecosystem, was collected during summer 2000. This was relatively “fresh” (i.e. dominated by labile lipids such as polyunsaturated fatty acids) and was derived largely from phytoplankton remains and faecal pellets, with contributions from bacteria and microzooplankton. Labile sPOM components were enriched in the benthic boundary layer (10 m above bottom (mab)) relative to 150 mab. The action of certain benthic fauna that are exclusively associated with the DWC ecosystem (e.g. echiuran worms) leads to the subduction of fresh organic material into the sediments. The mound surface sediments are enriched in organic carbon, relative to off-mound sites. There is no evidence for hydrocarbon venting at this location.     

The influence of light on nitrogen cycling and the primary nitrite maximum in a seasonally stratified sea

In the seasonally stratified Gulf of Aqaba Red Sea, both release by phytoplankton and oxidation by nitrifying microbes contributed to the formation of a primary nitrite maximum (PNM) over different seasons and depths in the water column. In the winter and during the days immediately following spring stratification, formation was strongly correlated (R² = 0.99) with decreasing irradiance and chlorophyll, suggesting that incomplete reduction by light limited phytoplankton was a major source of . However, as stratification progressed, continued to be generated below the euphotic depth by microbial oxidation, likely due to differential photoinhibition of and oxidizing populations. Natural abundance stable nitrogen isotope analyses revealed a decoupling of the δ¹⁵N and δ¹⁸O in the combined and pool, suggesting that assimilation and nitrification were co-occurring in surface waters. As stratification progressed, the δ¹⁵N of particulate N below the euphotic depth increased from −5‰ to up to +20‰.N uptake rates were also influenced by light; based on ¹⁵N tracer experiments, assimilation of , , and urea was more rapid in the light (434 ± 24, 94 ± 17, and 1194 ± 48 nmol N L⁻¹ day⁻¹ respectively) than in the dark (58 ± 14, 29 ± 14, and 476 ± 31 nmol N L⁻¹ day⁻¹ respectively). Dark assimilation was 314 ± 31 nmol N L⁻¹ day⁻¹, while light assimilation was much faster, resulting in complete consumption of the ¹⁵N spike in less than 7 h from spike addition. The overall rate of coupled urea mineralization and oxidation (14.1 ± 7.6 nmol N L⁻¹ day⁻¹) was similar to that of oxidation alone (16.4 ± 8.1 nmol N L⁻¹ day⁻¹), suggesting that mineralization of labile dissolved organic N compounds like urea was not a rate limiting step for nitrification. Our results suggest that assimilation and nitrification compete for and that N transformation rates throughout the water column are influenced by light over diel and seasonal cycles, allowing phytoplankton and nitrifying microbes to contribute jointly to PNM formation. We identify important factors that influence the N cycle throughout the year, including light intensity, substrate availability, and microbial community structure. These processes could be relevant to other regions worldwide where seasonal variability in mixing depth and stratification influence the contributions of phytoplankton and non-photosynthetic microbes to the N cycle.     

Particulate organic carbon–Th relationships in particles separated by settling velocity in the northwest Mediterranean Sea

In order to better understand the relationship between the natural radionuclide ²³⁴Th and particulate organic carbon (POC), marine particles were collected in the northwestern Mediterranean Sea (spring/summer, 2003 and 2005) by sediment traps that separated them according to their in situ settling velocities. Particles also were collected in time-series sediment traps. Particles settling at rates of >100 m d⁻¹ carried 50% and 60% of the POC and ²³⁴Th fluxes, respectively, in both sampling years. The POC flux decreased with depth for all particle settling velocity intervals, with the greatest decrease (factor of 2.3) in the slowly settling intervals (0.68–49 m d⁻¹) over trap depths of 524–1918 m, likely due to dissolution and decomposition of material. In contrast the flux of ²³⁴Th associated with the slowly settling particles remained constant with depth, while ²³⁴Th fluxes on the rapidly settling particles increased. Taking into account decay of ²³⁴Th on the settling particles, the patterns of ²³⁴Th flux with depth suggest that either both slow and fast settling particles scavenge additional ²³⁴Th during their descent or there is significant exchange between the particle classes. The observed changes in POC and ²³⁴Th flux produce a general decrease in POC/²³⁴Th of the settling particles with depth. There is no consistent trend in POC/²³⁴Th with settling velocity, such as might be expected from surface area and volume considerations. Good correlations are observed between ²³⁴Th and POC, lithogenic material and CaCO₃ for all settling velocity intervals. Pseudo-K_ds calculated for ²³⁴Th in the shallow traps (2005) are ranked as lithogenic material opal <calcium carbonate <organic carbon. Organic carbon contributes 33% to the bulk K_d, and for lithogenic material, opal and CaCO₃, the fraction is 22% each. Decreases in POC/²³⁴Th with depth are accompanied by increases in the ratio of ²³⁴Th to lithogenic material and opal. No change in the relationship between ²³⁴Th and CaCO₃ was evident with depth. These patterns are consistent with loss of POC through decomposition, opal through dissolution and additional scavenging of ²³⁴Th onto lithogenic material as the particles sink.     

The self-thinning exponent in overcrowded stands of the mangrove, Kandelia obovata, on Okinawa Island, Japan

Weller??s allometric model assumes that the allometric relationships of mean area occupied by a tree $ \bar{s} $ , i.e., the reciprocal of population density $ \rho $ , $ \bar{s}\left( { = {1 \mathord{\left/ {\vphantom {1 {\rho = g_{\varphi } \cdot \bar{w}^{\varphi } }}} \right. \kern-0em} {\rho = g_{\varphi } \cdot \bar{w}^{\varphi } }}} \right) $ , mean tree height $ \bar{H}\left( { = g_{\theta } \cdot \bar{w}^{\theta } } \right) $ , and mean aboveground mass density $ \bar{d}\left( { = g_{\delta } \cdot \bar{w}^{\delta } } \right) $ to mean aboveground mass $ \bar{w} $ hold. Using the model, the self-thinning line $ \left( {\bar{w} = K \cdot \rho^{ - \alpha } } \right) $ of overcrowded Kandelia obovata stands in Okinawa, Japan, was studied over 8?years. Mean tree height increased with increasing $ \bar{w} $ . The values of the allometric constant $ \theta $ and the multiplying factor $ g_{\theta } $ are 0.3857 and 2.157?m?kg^???, respectively. The allometric constant $ \delta $ and the multiplying factor $ g_{\delta } $ are ?0.01673 and 2.685?m^?3?kg^1???, respectively. The $ \delta $ value was not significantly different from zero, showing that $ \bar{d} $ remains constant regardless of any increase in $ \bar{w} $ . The average of $ \bar{d} $ , i.e., biomass density $ \left( {{{\bar{w} \cdot \rho } \mathord{\left/ {\vphantom {{\bar{w} \cdot \rho } {\bar{H}}}} \right. \kern-0em} {\bar{H}}}} \right) $ , was 2.641?±?0.022?kg?m^?3, which was considerably higher than 1.3?C1.5?kg?m^?3 of most terrestrial forests. The self-thinning exponent $ \alpha \left( { = {1 \mathord{\left/ {\vphantom {1 {\varphi = }}} \right. \kern-0em} {\varphi = }}{1 \mathord{\left/ {\vphantom {1 {\left\{ {1 - \left( {\theta + \delta } \right)} \right\}}}} \right. \kern-0em} {\left\{ {1 - \left( {\theta + \delta } \right)} \right\}}}} \right) $ and the multiplying factor $ K\left( { = \left( {g_{\theta } \cdot g_{\delta } } \right)^{\alpha } } \right) $ were estimated to be 1.585 and 16.18?kg?m^?2??, respectively. The estimators $ \theta $ and $ \delta $ are dependent on each other. Therefore, the observed value of $ \theta + \delta $ cannot be used for the test of the hypothesis that the expectation of the estimator $ \theta + \delta $ equals 1/3, i.e., $ \alpha = {3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-0em} 2} $ , or 1/4, i.e., $ \alpha = {4 \mathord{\left/ {\vphantom {4 3}} \right. \kern-0em} 3} $ . The $ \varphi $ value was 0.6310, which is the same as the reciprocal of the self-thinning exponent of 1.585, and was not significantly different from 2/3 (t?=?1.860, df?=?191, p?=?0.06429), i.e., $ \alpha = {3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-0em} 2} $ . Thus the self-thinning exponent is not significantly different from 3/2 based on the simple geometric model. On the other hand, the self-thinning exponent was significantly different from 3/4 (t?=?6.213, df?=?191, p?=?3.182?×?10^?9), i.e., $ \alpha = {4 \mathord{\left/ {\vphantom {4 3}} \right. \kern-0em} 3} $ . Therefore, the self-thinning exponent is significantly different from 4/3 based on the metabolic model.     

Artificial neural network modeling of cross-shore profile on sand beaches: The coast of the province of Valencia (Spain)

The paper describes the training, validation, testing, and application of models of artificial neural networks (ANN) for computing the cross-shore beach profile of the sand beaches of the province of Valencia (Spain). Sixty ANN models were generated by modifying both the input variables as the number of neurons in the hidden layer. The input variables consist of wave data and sedimentological data. To select and evaluate the performance of the optimal model, the following parameters were used: R², absolute error, mean absolute percentage error, and percentage relative error. Finally, the results are compared with the numerical model proposed by Aragonés et al. (2016b Aragonés, L., Y. Villacampa, F. J. Navarro-González, and I. López. 2016b. Numerical modelling of the equilibrium profile in Valencia (Spain). Ocean Engineering, 123:164–73. doi:10.1016/j.oceaneng.2016.07.036[Crossref], [Web of Science ®] , [Google Scholar]) for the equilibrium profile in the study area. The results show a mean absolute error of 0.21?m compared to 0.33?m Aragones’ model, significantly improving the results of the numerical model in the bar area around de Valencia Port. In addition, when comparing the results with other methods currently used (Dean’s or Vellinga formulation), the errors of these compared to ANN are of the order of 167 and 1538% higher, respectively.     

Physical dynamics and biological implications of a mesoscale eddy in the lee of Hawai’i: Cyclone Opal observations during E-Flux III

E-Flux III (March 10–28, 2005) was the third and last field experiment of the E-Flux project. The main goal of the project was to investigate the physical, biological and chemical characteristics of mesoscale eddies that form in the lee of Maui and the Island of Hawai’i, focusing on the physical–biogeochemical interactions. The primary focus of E-Flux III was the cyclonic cold-core eddy Opal, which first appeared in the NOAA GOES sea-surface temperature (SST) imagery during the second half of February 2005. During the experiment, Cyclone Opal moved over 160 km, generally southward. Thus, the sampling design had to be constantly adjusted in order to obtain quasi-synoptic observations of the eddy. Analyses of ship transect-depth profiles of CTD, optical and acoustic Doppler current profiler (ADCP) data revealed a well-developed feature characterized by a fairly symmetric circular shape with a radius of about 80 km. Depth profiles of temperature, salinity and density were characterized by an intense doming of isothermal, isohaline and isopycnal surfaces. Isopleths of nutrient concentrations were roughly parallel to isopycnals, indicating the upwelling of deep nutrient-rich water. The deep chlorophyll maximum layer (DCML) shoaled from a depth of about 130 m in the outer regions of the eddy to about 60 m in the center. Chlorophyll concentrations reached their maximum values in Opal's core region (about 40 km in diameter), where nutrients were upwelled into the euphotic layer. ADCP velocity data clearly showed the cyclonic circulation associated with Opal. Vertical sections of tangential velocities were characterized by values that increased linearly with radial distance from near zero close to the center to a maximum of about at roughly 25 km from the center, and then slowly decayed. The vertical extent of the cyclonic circulation was primarily limited to the upper mixed layer, as tangential velocities decayed quite rapidly within a depth range of 90–130 m. Potential vorticity analysis suggests that only a relatively small (about 50 km in diameter) and shallow (to a depth of approximately 70 m) portion of the eddy is isolated from the surrounding waters. Radial movements of water can occur between the center of the eddy and the outer regions along density surfaces within an isopycnal range of σ–t_23.6 () and σ–t_24.4 (). Thus the biogeochemistry of the system might have been greatly influenced by these lateral exchanges of water at depth, especially during Opal's southward migration. While the eddy was translating, deep water in front of the eddy might have been upwelled into the core region, leading to an additional injection of nutrients into the euphotic zone. At the same time, part of the chlorophyll-rich waters in the core region might have remained behind the translating eddy and, thus contributed to the formation of an eddy wake characterized by relatively high chlorophyll concentrations.     

Offshore Absolute Calibration of Space-Borne Radar Altimeters

Absolute calibration of sea level measurements collected from space-borne radar altimeters is usually performed with respect to collocated sea level in situ records from tide gauges or GPS buoys (Ménard et al. 1994 Ménard, Y., Jeansou, E. and Vincent, P. 1994. Calibration of the TOPEX-Poseidon altimeters at Lampedusa: Additional results at Harves. J. Geophys Res., 99(C12): 24487–24504. http://dx.doi.org/10.1029%2F94JC01300 [Google Scholar]; Haines et al. 1996 Haines, B. J., Christensen, E. J., Norman, R. A., Parke, M. E., Born, G. H. and Gill, S. K. 1996. Altimeter calibration and geophysical monitoring from collocated measurements at the Harvest oil platform. EOS Trans. Suppl., 77(22): W16 [Google Scholar]; Bonnefond et al. 2003; Haines et al. 2003 Haines, B. J., Dong, D., Born, G. H. and Gill, S. K. 2003. The Harvest experiment: Monitoring Jason-1 and TOPEX/Poseidon from a California offshore platform. Mar. Geod., 26: 239–259. [Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]; Schum et al. 2003 Schum, C. K., Yi, Y., Cheng, K., Kuo, C., Braun, A., Calmant, S. and Chambers, D. 2003. Calibration of Jason-1 Altimeter over Lake Erie. Mar. Geod., 26: 335–354.  [Google Scholar]; Watson et al. 2003 Watson, C., Coleman, R., White, N., Church, J. and Govind, R. 2003. Absolute calibration of TOPEX/ Poseidon and Jason-1 using GPS buoys in Bass Strait, Australia. Mar. Geod., 26: 285–304. [Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]; Watson et al. 2004 Watson, C., White, N., Coleman, R., Church, J., Morgan, P. and Govind, R. 2004. TOPEX/Poseidon and Jason-1: Absolute calibration in Bass Strait, Australia. Mar. Geod., 27: 107–131. http://dx.doi.org/10.1080%2F01490410490465373[Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]). Such a method allows regular and long-term control of altimetric systems with independent records. However, this approach is based on a single, geographically dependent point. In order to obtain more significant and accurate bias and drift estimates, there is a strong interest in multiplying the number of calibration opportunities. This article describes a method, called the “offshore method” that was developed to extend the single-point approach to a wider regional scale. The principle is to compare altimeter and tide gauge sea level data not only at the point of closest approach of an overflying pass, but also at distant points along adjacent satellite passes. However, connecting sea level satellite measurements with more distant in situ data requires a more accurate determination of the geoid and mean ocean dynamic topography slopes, and also of the ocean dynamical changes. In this demonstration experiment, 10 years of averaged TOPEX/Poseidon mean sea level profiles are used to precisely determine the geoid and the mean ocean circulation slope. The Mog2d barotropic ocean model (Carerre et Lyard 2003 Carrère, L. and Lyard, F. 2003. Modelling the barotropic response of the global ocean to atmospheric wind and pressure forcing-comparisons with observations. GRL, 30(6): 1275 [Google Scholar]) is used to improve our estimate of the ocean dynamics term. The method is first validated with Jason-1 data, off Corsica, where the dedicated calibration site of Senetosa provides independent reference data. The method is then applied to TOPEX/Poseidon on its new orbit and to Geosat Follow On. The results demonstrate that it is feasible to make altimeter calibrations a few tens to hundreds of kilometers away from a dedicated site, as long as accurate mean sea level altimeter profiles can be used to ensure the connection with reference tide gauges.     

Deltaic soil behavior classification using CPTu records—Proposed approach and applied to fifty-four case histories

For the past four decades, the CPT has played a key role in onshore and offshore soil investigations. One of the main applications of cone penetration test (CPT) is the soil behavioral classification. Most of the developed methods for soil identification using CPT and CPTu (piezocone) data are well categorized for common soils, such as clays, silts, and sands. Soils with low resistance or more compressibility generally involve problems in geotechnical engineering practice and construction projects. Consequently, these unusual deposits require further evaluation and more detailed data. Five major groups of problematic soils including: liquefiable, sensitive, peaty, collapsible, and expansive soils have been considered in this study. One hundred and forty CPT and CPTu test records were collected from fifteen countries. Sixty-one of the records are related to difficult soils. A brief comparison is performed for currently used soil behavioral classification charts, such as by Campanella et al. (1985 Campanella, R. G., P. K. Robertson, D. Gillespie, and J. Greig. 1985. Recent developments in in-situ testing of soils. Proceedings of 11th International Conference on Soil Mechanics and Foundation Engineering, ICSMFE, San Francisco, Vol. 2, 849–54. [Google Scholar]), Robertson (1990 Robertson, P. K. 1990. Soil classification using the cone penetration test. Canadian Geotechnical Journal 27 (1):151–58. doi:10.1139/t90–014[Crossref], [Web of Science ®] , [Google Scholar]), Jefferies and Davies (1991 Jefferies, M. G., and M. P. Davies. 1991. Soil classification using the cone penetration test: Discussion. Canadian Geotechnical Journal 28 (1):173–76. doi:10.1139/t91–023[Crossref], [Web of Science ®] , [Google Scholar]) and Eslami and Fellenius (1997 Eslami, A., and B. H. Fellenius. 1997. Pile capacity by direct CPT and CPTu methods applied to 102 case histories. Canadian Geotechnical Journal 34 (6):886–904. doi:10.1139/cgj-34–6-886[Crossref], [Web of Science ®] , [Google Scholar]). Analysis based on CPT data indicates that a few commonly used charts recognize relatively well problematic deposits. However, further studies are needed to increase the accuracy and capability of methods. Existing charts have some problems due to the limitations of the nature of rectangular charts based on two axes. A new format of classification chart, i.e., triangular form containing cone tip resistance (q_c), sleeve friction (f_s), and pore pressure (u₂) is proposed for soil identification which can be realized in practice. The proposed chart with more accuracy and less scattering of data than the previous charts is able to identify soil types particularly for deltaic soils.     

Chromium(VI) reduction by sulphur(IV) in aqueous solutions

The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔH_app of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression

−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]²