The geochemistry of mafic metavolcanics: implications for the origin of the Devonian massive sulfide deposits at Zlaté Hory,Czechoslovakia

Mafic metavolcanic rocks in the area of the Zlaté Hory massive sulfide deposits are interpreted as convergent plate-margin basalts and basaltic andesites metamorphosed to the greenschist facies. According to the major- and trace-element compositions the metabasites exhibit island-arc tholeiitic to low-K, calc-alkaline composition.Approximately 50% of samples of maifc metavolcanics studied have a salient negative anomaly of Ce in chondrite-normalized REE patterns. The Ce-depleted greenschists are thought to represent hydrothermally altered equivalents of metabasites of island-arc tholeiitic composition. The alteration was accompanied by the sulfide mineralization. That is indicated by enrichment in Ba and S together with correlation of the Ce/Ce* values and CO₂ abundances in the Ce-depleted rocks. The Ce anomaly may be caused by alteraton of ore-forming, seawaterderived solutions. The occurrence of Ce-depleted greenschists supports the hypothesis of the volcanogenic origin of the ore deposits in the Zlaté Hory area.     

滇西北烂泥塘斑岩铜矿床原生晕异常结构研究

烂泥塘矿床是云南香格里拉地区典型的斑岩型铜矿床,主矿体产于在地表以下300～500米,地表矿化带仅见脉状铜矿体和铜矿化体.为研究云南香格里拉烂泥塘斑岩铜矿床的原生晕异常结构,本文以异常结构模式理论和方法为基础,对矿床地表和坑道岩矿石样品开展了元素组合、异常特征和水平分带规律研究.结果表明,烂泥塘铜矿床地球化学系统的结构...     

REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan

Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.     

Application of Bi-dimensional empirical mode decomposition (BEMD) modeling for extracting gravity anomaly indicating the ore-controlling geological architectures and granites in the Gejiu tin-copper polymetallic ore field,southwestern China

The Gejiu tin-copper polymetallic ore field, located at the westernmost end of the Cathaysia Block in South China, is one of the largest tin polymetallic ore fields in the world. It is associated with magmatic-hydrothermal ore-forming processes triggered by deeply seated structures and concealed granites. The Bi-dimensional empirical mode decomposition (BEMD) was used to decompose gravity data covering an area including the Gejiu tin-copper polymetallic ore field in the west and the Bozhushan silver-lead-zinc polymetallic ore field in the east, which yielded three two-dimensional intrinsic mode function (BIMFs) images and one residue (Res(m, n)) image that depict four layers of geological architectures at different wavelengths within the study area. The high-pass filtered gravity component image (BIMF₁) is interpreted to depict the shallow geological architecture, which indicates that the skarn alteration and tin-copper mineralization with positive gravity anomalies are distributed around the granites characterized by negative gravity anomalies. The band-pass filtered gravity component image (BIMF₂) is interpreted to depict the middle-shallow geological architecture, which indicates that the outcropped granites in the western Gejiu ore field bounded by the Gejiu fault may extend to the eastern Gejiu ore field to form one integrated granitic complex in the subsurface. The other band-pass filtered gravity component image (BIMF₃) is interpreted to depict the middle-lower geological architecture, which indicates that there may be an EW-trending granite zone with negative gravity anomaly at middle-lower depth connecting the Gejiu tin-copper polymetallic field to the Bozhushan silver-lead-zinc polymetallic field, displaying the existence of an EW-trending regional polymetallic ore-forming zone within the study area. The low-pass filtered gravity component image (Res(m, n)) is interpreted to depict the lowest geological architecture within the study area, which reflects that there may be a pair of the NW-trending uplift zone of the mantle and/or the basement with positive gravity anomaly and the depression zone of the mantle and/or the basement with negative gravity anomaly. The Gejiu tin-copper polymetallic deposits and the related granites are located at the transitional zone between the uplift and depression, whereas the Bozhushan silver-lead-zinc polymetallic deposits and the related granites are situated within the depression zone, which implies that the diversity of the Late Yanshanian granites and the related polymetallic deposits in the study area may be controlled by the complexity of the crust-mantle interaction at depth.     

华蓥山地区天青石矿稀土元素地球化学特征

华蓥山地区天青石矿各类型天青石的稀土总量(∑REE)均较低,为轻稀土富集型。巨晶天青石和条带状矿石之白色条带状天青石具铕的正异常,为热卤水成因,层状和条带状矿石之暗色条带天青石具δ Eu的负异常,与碳酸盐岩围岩一致,为沉积成因。区内天青石、碳酸盐岩表现为δ Ce的轻度负异常或无异常,与该区早三叠世嘉陵江组沉积时期所处的含膏泻湖相沉积环境有关。     

川西呷村黑矿型多金属矿床热液体系稀土元素组成特征

本文首次测定了呷村黑矿矿石中流体包裹体的ＲＥＥ组成,计算了与含矿流纹岩系熔体平衡的岩浆热液ＲＥＥ含量。主成矿期流体具有轻稀土富集、Ｅｕ明显正异常的特点,但岩浆热液却具有明显的Ｅｕ负异常特征,结合热液体系氧同位素及稀土元素交换反应模拟,表明岩浆热液不是直接的成矿热液。蚀变围岩具显著的Ｅｕ正异常,其它稀土元素出现亏损。蚀变反应水／岩比值较大,蚀变岩中的ＲＥＥ组成反映了成矿热液ＲＥＥ的特点,且ＲＥＥ亏损     

山东昌邑莲花山铁矿矿床地质与矿石稀土、微量元素特征

莲花山铁矿位于昌邑-安丘铁成矿带的中部,铁矿体赋存于古元古代粉子山群小宋组中。本文通过矿石地球化学特征及其与矽卡岩矿物组合和赋矿围岩结构特征的对比研究,证明了莲花山铁矿与条带状铁矿相似。莲花山铁矿矿石稀土元素含量较低,经页岩标准化的稀土元素配分模式呈现轻稀土元素亏损、重稀土元素富集的特征,具有明显的Eu、Y、La异常,为无明显Ce异常,Y/Ho比值反映了在其沉积时受到海水作用的影响,表明莲花山铁矿的稀土元素来源于火山热液和海水的混合溶液。微量元素中Ti、V、Co、Ni、Mn、Sr、Ba等含量较低,原始地幔标准化的微量元素配分曲线显示,U、La、Hf呈正异常,Ba、Nb、Ta、Sr呈负异常,SiO2/Al2O3、Ti/V、Ni/Co、和Sr/Ba的比值指示了莲花山铁矿成矿物质来源于火山物质的沉积。研究结果表明,莲花山铁矿成矿作用源于火山热液与海水的混合,成矿物质来自火山沉积物,其地质与地球化学特征与五台山铁矿一致,为火山沉积变质型铁矿床。     

西藏墨竹工卡县邦铺钼(铜)矿床辉钼矿稀土—微量元素特征及对成矿流体性质的指示

文章以西藏墨竹工卡县邦铺钼(铜)矿床辉钼矿为研究对象,采用高精度电感耦合等离子质谱( ICPMS)对辉钼矿进行了稀土和微量元素测试.测试结果显示辉钼矿具有轻稀土富集的右倾配分模式,轻重稀土内部分馏明显.辉钼矿稀土元素不同程度地出现铕负异常和铈负异常现象,分析得出其铕负异常可能是继承了成矿流体自身铕亏损的特征,而铈负异常...     

青海省都兰县热水乡温泉地区磁力异常特征及找矿远景

青海省都兰县热水乡温泉地区具有较好资源潜力,陆续发现铅、锌、银、钼等多金属矿化现象。本文基于在该区开展1∶1万高精度磁测工作,对磁异常进行处理,推断区内断裂分布,并预测铅锌矿、钼矿等有利区。结果表明：区内有一级断裂3条,二级断裂41条;一级断裂控制地层展布及岩体分布,二级断裂控制地层局部分布和部分岩体分布,并为岩脉侵入通道。该区北部等轴状低缓中等磁力异常区可能为较大规模隐伏花岗闪长岩,此岩体与围岩接触部位是寻找铅锌矿化的有利区。研究区南部已发现的钼矿化带位于侏罗纪钾长花岗岩之中,呈现明显高磁异常,沿NW向断裂带边部的6处异常区为钼矿远景区。研究区中部沿一级断裂F₁存在隐伏的侏罗纪钾长花岗岩,岩体侵入为热水提供热源,断裂为热水运移通道,靠近察汗乌苏河的隐伏岩体附近为地热有利区。     

川西呷村超大黑矿型矿床成矿流体烯土元素组成

本文用ＩＣＰ－ＭＳ首次测定了呷村银多金属黑矿型矿床矿石流体包裹体中的稀土元素含量,研究表明,主成矿期流体稀土元素配分模式均为轻稀土富集,Ｅｕ具明显正异常,通过初步对比,本区主成矿期流体与东太平洋脊、大西洋脊等现代高温酸性地热系统热液具有相似的稀土模式,反映了它们物化条件的相似性;但前者∑ＰＥＥ高于后者,且两者Ｅｕ／Ｅｕ＾＊值不同,经过分析,本区成矿流体Ｅｕ正异常主要为Ｔ、ｐＨ、ｆｏ２控制,另外,围     

西昆仑赞坎铁矿床地质特征、形成时代及高品位矿石的成因

新疆赞坎铁矿床位于西昆仑塔什库尔干地块西段,是近年新发现的一个大型沉积变质型磁铁矿床。赋矿岩系布伦阔勒群主要由黑云母石英片岩、斜长角闪片岩、变粒岩、硅质岩及磁铁石英岩等组成。目前探明工业矿体4条,单个矿体长度大于2.5km,矿体厚10~70m;局部见高品位铁矿段(mFe50%),长度达900m,厚度40m左右。矿石类型主要为2种,一种为原生的条纹-条带状磁铁矿(为主);另一种为热液改造形成的块状(高品位铁矿石)及浸染状磁铁矿。矿石稀土元素配分(PAAS)表明,原生条纹-条带状铁矿石Ce和Y元素异常不明显(~1.15、~0.94),Eu具正异常(~1.69),Y/Ho平均值为25,稀土配分模式与沉积变质型铁矿相似。而受改造的矿石中,浸染状矿石具有较高的稀土总量,明显富集轻稀土,La和Ce显示正异常(~1.46、~1.17),Y显示负异常(=0.66~0.72),Eu表现为强烈的正异常(~4.37),稀土配分模式明显不同于原生条纹-条带状铁矿石。矿体围岩斜长角闪片岩(变沉积岩)中的碎屑锆石U-Pb年龄为591±1Ma,结合前人对矿区内侵入体的年代学研究(霏细斑岩,533Ma),大致反映沉积铁矿的形成时代为新元古代至早寒武世。电子探针显示,条带状磁铁矿中的TiO_2、AL_2O_3、MgO、MnO含量较低,标型组分含量与沉积变质型磁铁矿颇为接近,在磁铁矿单矿物成因图解中,条带状磁铁矿整体显示磁铁矿为沉积变质型铁矿;浸染状矿石和块状矿石的组成与典型沉积变质型铁矿的偏离反映了后期岩浆-构造热事件对条带状铁矿石的改造;上述结果显示赞坎铁矿整体属于沉积变质型铁矿(BIF)。调查发现赞坎高品位铁矿体与早寒武世侵入的霏细斑岩联系密切,高品位矿石及其围岩发育一定程度的矽卡岩化,如阳起石化、碳酸盐化和黄铁矿化。本文推测高品位铁矿石的成因可能为霏细斑岩的岩浆热液溶解并运移早期沉积变质铁矿中的含铁物质,在构造发育处充填交代形成块状磁铁富矿石。在早寒武世侵入到矿区中部的霏细斑岩体中,同时发育有角砾状磁铁矿和脉状磁铁矿,因此,岩浆热液改造原生条带状铁矿石形成高品位铁矿石的时代应为早寒武世。     

福建紫金山陆相火山岩型Cu－Au矿田区域地质地球化学异常结构模式

矿床模式是目前国内外的研究热点之一。各种各样的地质找矿模型与模式层出不穷，也建立了一些地球化学找矿模型。但是它们基本上是建立在矿床原生晕基础上的，以区域地球化学资料为基础建立的矿床或矿田区域地球化学异常模式尚属少见。本文以矿田为基础研究单元，以１：２０万区域化探扫面资料为基础，从矿田的区域地质背景特征和３９种元素的正、负区域地球化学异常分布规律出发，研究了成矿的区域地质环境和地球化学环境。发现成矿元素异常组合、指示元素异常组合和成矿环境元素异常组合的空间分布，在矿田上具有独特的结构特征，提出了异常结构模式的概念。进而总结出了紫金山矿田的区域地质地球化学异常结构模式。     

福建紫金山陆相火山岩型Cu－Au矿田区域地质地球化学异常结构模式

矿床模式是目前国内外的研究热点之一。各种各样的地质找矿模型与模式层出不穷,也建立了一些地球化学找矿模型。但是它们基本上是建立在矿床原生晕基础上的,以区域地球化学资料为基础建立的矿床或矿田区域地球化学异常模式尚属少见。本文以矿田为基础研究单元,以1:20万区域化探扫面资料为基础,从矿田的区域地质背景特征和39种元素的正、负区域地球化学异常分布规律出发,研究了成矿的区域地质环境和地球化学环境。发现成矿元素异常组合、指示元素异常组合和成矿环境元素异常组合的空间分布,在矿田上具有独特的结构特征,提出了异常结构模式的概念。进而总结出了紫金山矿田的区域地质地球化学异常结构模式。     

吉林放牛沟硫铁多金属矿床原生地球化学异常特征

放牛沟矿床主要成矿元素Zn、Pb并非由地层提供,而是来自岩体深部,通过岩体接触带构造向火山—沉积岩系运移而形成矿床及原生异常的。Zn、Pb、Cu、Ag等元素正异常与Cr、Sr等元素负异常的套合产出是矿床存在的重要标志.矿体、矿组、矿床异常有明显的分带规律,分带性指数从浅部到深部呈规律性变化.根据Ag/Bi可判别前缘、尾晕,利用PbZnAgBa/CuBi可判别矿组和矿床原生异常的剥蚀程度.     

滇西北香格里拉市红牛—红山铜矿勘查系统模型

滇西北红牛—红山铜矿床是义敦—沙鲁里岛弧上与晚白垩纪中酸性侵入体有关的典型的斑岩-矽卡岩-热液型铜矿床。本文通过对其成矿地质背景、矿床地质特征、矿化富集规律及成矿模式、矿床地球物理和地球化学特征的综合研究，建立了红牛—红山铜矿床的"大比例尺地质填图和综合研究+重力+激电和高精度磁测+土壤化探测+工程验证"组合勘查技术方法、"燕山晚期石英二长斑岩+接触带矽卡岩和层间破碎带矽卡岩+重力低异常+高磁异常+高视极化率和低视电阻率异常+Cu-Mo-Pb-Zn-Ag-Au等元素综合异常"组合勘查模型。地质调查研究确定矿床成矿地质体和找矿地质体、矿化类型及其空间分布规律，建立矿床"四位一体"的成矿模式和区域-矿区地质找矿模型。区域中小比例尺的土壤化探测量确定区域找矿靶区，大比例尺土壤化探测量进一步缩小找矿靶区，逼近矿体赋存部位。矿区处于1∶5万土壤测量圈定的Cu-Pb-Zn-Mo-Au-Ag元素综合高异常区，1∶2.5万土壤测量圈出Cu-Pb-Zn-Ag-W元素综合异常面积较大、强度高、浓集中心明显、元素套合好，与矿区铜（铁）矿体赋存区域异常相对应。区域重力低异常区和正磁异常强度高区域是重要的找矿靶区，矿区大比例尺磁异常和激电异常区确定了矿体的空间位置和产状；矿区铜（铁）矿体赋存区为低视电阻率、高视极化率异常区，高精度磁测表现为正负磁异常相伴。矿区地质-地球化学-地球物理综合勘查模型对矿区深边部找矿起到重要的指导作用。     

云南大平掌铜多金属矿床稀土元素地球化学特征

滇西大平掌铜多金属矿床具典型的“双层结构”。对上部盆地相的块状硫化物和下部通道相的细脉浸染状硫化物的稀土元素分析表明,前者具正Eu异常的球粒陨石标准化配分模式,后者具负Eu异常的配分模式。这种变化与成矿流体演化有关。通过与大西洋中脊TAG热液活动区表层沉积硫化物和黑烟囱流体等的稀土元素配分模式对比,可以认为成矿是火山喷流沉积作用的结果。     

庐枞火山岩盆地北部马鞭山铁矿床磁异常特征及找矿预测

马鞭山铁矿处于庐枞火山岩盆地北部边缘,其赋矿层位为东马鞍山(T2d)含铁质、钙质泥质粉砂岩。航磁为梯度带上叠加局部异常、局部异常形态规则,其走向与梯度带大致平行;地磁与航磁对应较好,异常未分解;地磁异常剖面曲线连续完整且正负伴生、具低缓特征。小波变换较好地分离出了矿致异常。盆地西侧和北侧二条航磁梯度带上局部低缓磁异常系寻找该类铁矿的重要指示信息。     

鞍本地区EW向深大断裂地质特征

在“鞍本地区沉积变质型铁矿控矿条件及找矿模型研究”工作中,尝试在GIS平台上对鞍本地区进行区域地质、航磁、重力、化探、地热泉等资料进行综合分析,发现该区存在一条近EW向展布的航磁和重力水平一阶导数负值异常带,该带南北两侧的地磁场、重力场和地球化学场具有明显的差异.研究成果显示,这条EW向断裂带具有控岩、控矿作用.该断裂自新太古代以来一直有活动迹象,新太古代时,可能是火山喷发的重要通道,已知大型或特大型沉积变质型（鞍山式）铁矿床均分布在断裂北侧长约90 km、宽约20 km的带状区域内;元古宙—古生代时,断裂带对沉积环境具有明显的制约,断裂带两侧的沉积环境不尽相同;中生代时,一系列中酸性侵入岩沿该断裂侵入（局部为隐伏岩体）;新生代沿该断裂出露有一系列平行带状展布的地热泉.     

New Evidence for Hydrothermal Sedimentary Genesis of the Ni‐Mo Deposits in Black Rock Series of the Basal Cambrian,Guizhou Province: Discovery of Coarse‐Grained Limestones and its Geochemical Characteristics

The molybdenum-nickel deposits in Shuidong District of Nayong County (Guizhou Province, Southwest China) are found mainly in black shale series of Lower Cambrian Niutitang Formation, which is another Mo-Ni-rich region besides Zunyi District (Guizhou province). Our systematic study on the Mo-Ni deposits in Tangjiaba of Nayong reveals that layered coarse-grained limestones, spherical beaded limestones concretions are hosted at the lower seam of the Mo-Ni deposits. Its strong negative carbon isotope anomaly (the carbon isotope value of the coarse-grained limestones varies from ?2.148‰ to 8.223‰) is similar to that in the modern submarine black smoker chimney. The carbon in the coarse-grained limestones from black rock series of Nayong County might be deep source inorganic carbon. The seams, coarse-grained limestones, ore-bearing coarse-grained limestones and the roof and floor of the deposits are characterized by co-variation on the trace element spider diagram, showing good homology. The extraordinary enrichment of Ag, As and Sb resembles hydrothermal sedimentation. Pro-Earth's core elements Se is strongly enriched in Ni-Mo ore-bearing coarse-grained limestones. The ore-bearing rock series has an extremely low Th/U value (0.012–0.19); in the logU-logTh Cartesian Coordinates, the samples of the roof and floor of the deposits and ore-bearing coarse-grained limestones are found in the East Pacific tise; and the samples of coarse-grained limestones are found between the paleo-hydrothermal dedimentary area and the East Pacific tise. The chondrite-normalized rare earth element patterns of the Ni-Mo deposits show LREE enrichment, Ce negative anomaly, and Eu negative anomaly (which is supposed to be influenced by the deep magmatic processes in an extensional environment) resembles the rare earth element distribution patterns of the fluid and its sediments in modern submarine hydrothermal system. It proves that coarse-grained limestones is characterized by typical hydrothermal limestones, being closely related with the genesis of Mo-Ni deposits in Nayong County, which provides new evidence for hydrothermal sedimentary genesis of Mo-Ni deposit and negative carbon anomaly in the basal Cambrian on a global scale.     

成矿系统及综合地质异常

矿床综合异常是成矿预测的重要标志。在概述成矿系统特征的基础上,论述了地质异常与成矿系统的关系,提出矿源场异常、矿液通道异常、矿石圈闭异常（储矿场异常）等概念,建立了成矿系统与综合异常的相关性模型框架。提出了矿床综合异常的研究方法,并依据对胶东金矿和赣西北铜矿地质异常的实际研究,提出对找寻热液金属矿床有重要意义的４种异常带：①异常浓集带;②异常急变带;③异常复合带;④异常叠加带。并强调指出,对控矿地质因素和矿化类型的详细研究是评价异常和成矿预测的关键问题。