Fission track ages of Hymalayan muscovites (Kathmandu Valley,Nepal)

Summary Himalayan muscovites from pegmatites of Kathmandu Valley, Nepal yield an age of 2–23 m. y. by fission track (f.t.) method. The uranium concentration is estimated to be 10^–10 atom/atom.     

Paleosecular variation and absolute geomagnetic paleointensity records retrieved from the Early Cretaceous Posadas Formation (Misiones,Argentina)

The Early Cretaceous may be considered a key period for understanding the evolution of the Earth’s magnetic field. Some still unsolved problems are related to the mode of paleosecular variation (PSV) of the Earth’s magnetic field before and during the Cretaceous Normal Superchron. We report here a detailed rock-magnetic, paleomagnetic and paleointensity investigation from 28 lava flows (331 standard paleomagnetic cores) collected in the Argentinean part of the Parana Flood Basalts (Formation Posadas) in order to contribute to the study of PSV during the early Cretaceous and to obtain precise Cretaceous paleomagnetic pole positions for stable South America. The average paleofield direction is precisely determined from 26 sites, which show small within-site dispersion and high directional stability. Five sites show evidences for the self-reversal of thermoremanent magnetization. 23 sites yielded normal polarity magnetization and only 3 are reversely magnetized. Moving windows averages were used to analyze the sequential variation of virtual geomagnetic pole’s (VGP) axial positions. Interestingly, the axial average VGP path traces an almost complete cycle around the geographical pole and passes near the location of all previously published Paraná Magmatic Province poles. Both paleomagnetic poles and average VGP paths are significantly different from the pole position suggested by fixed hotspot reconstructions, which may be due to true polar wander or the hotspot motion itself. Only 15 samples from 5 individual basaltic lava flows, yielded acceptable paleointensity estimates. The site mean paleointensities range from 25.2 ± 2.2 to 44.0 ± 2.2 μT. The virtual dipole moments (VDMs) range from 4.8 to 9.9 × 10²² Am². This correspond to a mean value of 7.7 ± 2.1 × 10²² Am² which is 96% of the present day geomagnetic field strength. These intensities agree with the relatively high values already reported for Early Cretaceous, which are consistent with some inferences from computer simulations previously published.     

Watershed modelling of hydrology and water quality in the Sacramento River watershed,California

Agricultural pollutant runoff is a major source of water contamination in California's Sacramento River watershed where 8500 km² of agricultural land influences water quality. The Soil and Water Assessment Tool (SWAT) hydrology, sediment, nitrate and pesticide transport components were assessed for the Sacramento River watershed. To represent flood conveyance in the area, the model was improved by implementing a flood routing algorithm. Sensitivity/uncertainty analyses and multi‐objective calibration were incorporated into the model application for predicting streamflow, sediment, nitrate and pesticides (chlorpyrifos and diazinon) at multiple watershed sites from 1992 to 2008. Most of the observed data were within the 95% uncertainty interval, indicating that the SWAT simulations were capturing the uncertainties that existed, such as model simplification, observed data errors and lack of agricultural management data. The monthly Nash–Sutcliffe coefficients at the watershed outlet ranged from 0.48 to 0.82, indicating that the model was able to successfully predict streamflow and agricultural pollutant transport after calibration. Predicted sediment loads were highly correlated to streamflow, whereas nitrate, chlorpyrifos and diazinon were moderately correlated to streamflow. This indicates that timing of agricultural management operations plays a role in agricultural pollutant runoff. Best management practices, such as pesticide use limits during wet seasons, could improve water quality in the Sacramento River watershed. The calibrated model establishes a modelling framework for further studies of hydrology, water quality and ecosystem protection in the study area. Copyright © 2012 John Wiley & Sons, Ltd.     

Magnetic minerals in sediments at the Cretaceous/Paleogene boundary (the Gams Section,Eastern Alps)

The paper presents results of detailed magnetomineralogical and microprobe studies of sediments at the Cretaceous/Paleogene (K/T) boundary in two epicontinental sections in the Eastern Alps (Austria), where deposits, including the K/T boundary, outcrop along the Gams River and its tributaries. K/T boundary layers in these sections are similar in the set of such magnetic minerals as iron hydroxides, ferrospinels, hemoilmenite, titanomagnetite, magnetite, hematite, and metallic iron. However, the boundary layer in the Gams-1 section is distinguished by the presence of metallic nickel and its alloy with iron and by the absence of iron sulfides, whereas nickel has not been discovered in the Gams-2 section, which, however, contains iron sulfides of the pyrite type. Therefore, these minerals occur locally. It is suggested that enrichment in iron hydroxides of a common origin can be regarded as a global phenomenon inherent in the K/T boundary and unrelated to an impact event.     

Granulometric study of the Hanaupah Fan,Death Valley,California

We applied new granulometric techniques to the various surfaces of the Hanaupah Fan, Death Valley, California, namely the Q1 surface, with an estimated age of 800–490 ka, the younger Q2 (170–105 ka) and Q3 (50–14 ka) surfaces, the <14 ka deposits of the incised channel, and to a (c. 14 ka) Lake Manly shoreline deposit at the northern periphery of the fan. We used these techniques to generate quantitative information on surface clast grain-size distributions, clast sphericity, roundness, and clast orientation to provide a data set that could be used to define fan-segment surfaces, and to help interpret fan genesis. Grain-size analyses were carried out by photo-sieving of 139 surface pictures, by petrographic identification of samples taken in the incised channel, and by identification and measuring of the largest clasts (1452 measurements) on the Q3 surface. The results show that all fan-segment surfaces, regardless of age, have similar size distributions, with a well-defined gravel mode of −2·3 to −3·0 phi, and are poorly to moderately sorted. Samples from the incised channel have distributions that are very similar to each other, regardless of distance from the apex, but display reduced sorting compared to the fan surfaces (which largely lack fines, perhaps from winnowing by secondary overland flow). Only the shoreline deposit is different from the other elements, showing a much narrower, well-defined gravel mode (−3·0 phi), and is moderately well sorted. Sphericity and roundness of clasts on all surfaces show only minor differences, similar to the other sedimentary parameters, indicating a remarkable homogeneity of the surfaces of the sediment body. In addition, measurements of the largest clasts (>100 cm long axis) on the Q3 surface showed no discernible trend either with radial distance or with rock type. These data suggest large depositional episodes that produce extensive sedimentary units without differentiation relative to distance from the source. Of the examined parameters, clast orientation is the best predictor of relative age of fan surfaces. Clast orientation in the main channel is bimodal, i.e. the long axes of clasts are either at right angles or parallel to transport direction. This bimodality disappears with increasing age, and the preferred orientation becomes unimodal (long clast axes normal to transport direction) on the Q1 surface. Although the causes of this change are still in debate, use of this parameter as a relative-age dating tool seems possible. © 1998 John Wiley & Sons, Ltd.     

Catastrophic rock avalanche 3600 years BP from El Capitan,Yosemite Valley,California

Large rock slope failures from near‐vertical cliffs are an important geomorphic process driving the evolution of mountainous landscapes, particularly glacially steepened cliffs. The morphology and age of a 2·19 × 10⁶ m³ rock avalanche deposit beneath El Capitan in Yosemite Valley indicates a massive prehistoric failure of a large expanse of the southeast face. Geologic mapping of the deposit and the cliff face constrains the rock avalanche source to an area near the summit of ～8·5 × 10⁴ m². The rock mass free fell ～650 m, reaching a maximum velocity of 100 m s^?1, impacted the talus slope and spread across the valley floor, extending 670 m from the base of the cliff. Cosmogenic beryllium‐10 exposure ages from boulders in the deposit yield a mean age of 3·6 ± 0·2 ka. The ～13 kyr time lag between deglaciation and failure suggests that the rock avalanche did not occur as a direct result of glacial debuttressing. The ～3·6 ka age for the rock avalanche does coincide with estimated late Holocene rupture of the Owens Valley fault and/or White Mountain fault between 3·3 and 3·8 ka. The coincidence of ages, combined with the fact that the most recent (AD 1872) Owens Valley fault rupture triggered numerous large rock falls in Yosemite Valley, suggest that a large magnitude earthquake (≥M7.0) centered in the south‐eastern Sierra Nevada may have triggered the rock avalanche. If correct, the extreme hazard posed by rock avalanches in Yosemite Valley remains present and depends on local earthquake recurrence intervals. Published in 2010 by John Wiley & Sons, Ltd.     

Basalt and tonalite from the Amami Plateau, northern West Philippine Basin: New Early Cretaceous ages and geochemical results, and their petrologic and tectonic implications

Abstract Basalts and tonalites dredged from the Amami Plateau in the northern West Philippine Basin have the geochemical characteristics of intraoceanic island arc rocks: low ⁸⁷Sr/⁸⁶Sr (0.70297–0.70310), intermediate ¹⁴³Nd/¹⁴⁴Nd (0.51288–0.51292), moderate light rare earth element (LREE) enrichment (La/Yb = 4.1–6.6) and high La/Nb (1.4–4.3). The incremental heating of hornblende from tonalites yielded well‐defined plateaus and ⁴⁰Ar/³⁹Ar isochron ages of 115.8 ± 0.5 Ma and 117.0 ± 1.1 Ma, while plagioclase yielded disturbed Ar release patterns, with ages ranging from 70 to 112 Ma. Taken together, these results show that the Amami Plateau was formed by subduction‐related magmatism in the Early Cretaceous period, earlier than indicated by prior K/Ar results. The results support tectonic models in which the West Philippine Basin was opened within a complex of Jurassic–Paleocene island arc terranes, which are now scattered in the northern West Philippine Basin, the Philippine Islands and Halmahera. The Amami Plateau tonalites and basalts have higher Sr/Y and lower Y and ⁸⁷Sr/⁸⁶Sr compared with younger tonalitic rocks from the northern Kyushu–Palau Ridge and the Tanzawa complex, which were formed by the subduction of the Pacific Plate beneath the Philippine Sea Plate. Based on the geochemical characteristics of the basalts, the Early Cretaceous subduction zone that formed the Amami Plateau may have been the site of slab melting, which suggests that a younger and hotter plate was being subducted at that time. However, the Amami tonalites were probably formed from basaltic magma by fractional crystallization or by partial melting of basaltic arc crust, rather than by melting of the subducted slab.     

Calcareous nannofossil biostratigraphic study of forearc basin sediments: Lower to Upper Cretaceous Budden Canyon Formation (Great Valley Group), northern California,USA

The results of a calcareous nannofossil biostratigraphic investigation of the North Fork Cottonwood Creek section of the Budden Canyon Formation (BCF; Hauterivian–Turonian) in northern California are summarized using the Boreal – cosmopolitan Boreal Nannofossil Biostratigraphy (BC) – Upper Cretaceous Nannofossil Biostratigraphy (UC) nannofossil zonal schemes of Bown et al. and Burnett et al. Sixteen intervals, ranging from the BC15 to UC8 zones, were established in the section. Combined biostratigraphic and magnetostratigraphic studies suggest a Hauterivian to mid‐Turonian age for the studied sequence. The Hauterivian–Barremian, Barremian–Aptian, Aptian–Albian, Albian–Cenomanian, and Cenomanian–Turonian stage boundaries were delineated near the top of the Ogo Member, below the Huling Sandstone Member, within the upper Chickabally Member, in the upper portion of the Bald Hills Member and within the Gas Point Member, respectively. Unconformities probably exist at the base of the Huling Sandstone Member and the upper part of the upper Chickabally Member. The nannofossil assemblage in the North Fork Cottonwood Creek suggests that the study area was under the influence of cold‐water conditions during the Barremian to Lower Aptian interval, shifting to tropical/warm‐water conditions during the Albian to Turonian interval as a result of the mid‐Cretaceous global warming. Although oceanic anoxic events have not yet been reported in the BCF, preliminary total organic carbon, along with nannofossil data, suggest the presence of the global Cenomanian–Turonian boundary oceanic anoxic event 2.     

Paleointensity of the geomagnetic field in the Cretaceous (from Cretaceous rocks of Mongolia)

A representative collection of Cretaceous rocks of Mongolia is used for the study of the magnetic properties of the rocks and for determination of the paleodirections and paleointensities H _anc of the geomagnetic field. The characteristic NRM component in the samples is recognized in the temperature interval from 200 to 620–660°C. The values of H _anc are determined by the Thellier-Coe method with observance of all present-day requirements regarding the reliability of such kind of results. Comparison of data in the literature on paleointensity in the Cretaceous superchron and in the Miocene supports the hypothesis of the inverse correlation between the average intensity of the paleofield and the frequency of geomagnetic reversals. The increase in the average intensities is accompanied by an appreciable increase in the variance of the virtual dipole moment (VDM). We suggest that the visible increase in the average VDM value in the superchron is due to the greater variability of VDM in this period compared to the Miocene.     

Curie Point Depth Estimates from Aeromagnetic Data from Death Valley and Surrounding Regions, California

Aeromagnetic data were analyzed to determine the Curie point depth (CPD) by power density spectral and three-dimensional inversion methods within and surrounding Death Valley in southern California. We calculated the CPD for 0.5° regions using 2D power density spectral methods and found that the CPDs varied between 8 and 17 km. However, the 0.5° region may average areas that include shallow and deep CPDs, and because of this limitation, we used the 3D inversion method to determine if this method may provide better resolution of the CPDs. The final 3D model indicates that the depth to the bottom of the magnetic susceptible bodies varies between 5 and 23 km. Even though both methods produced roughly similar results, the 3D inversion method produced a higher lateral resolution of the CPDs. The shallowest CPDs occur within the central and southern Death Valley, Panamint Valley, Coso geothermal field and the Tecopa hot springs region. Deeper (>15 km) CPDs occur over outcropping granitic and Precambrian lithologies in the Panamint Range, Grapevine Mountains, Black Mountains and the Argus Range. The shallowest CPD occurs within the central Death Valley over a possible seismically imaged magma body and slightly deeper values occur within the Panamint Valley, southern Death Valley and Tecopa Hot Springs. The shallow CPD values suggest that partially molten material may also be found in these latter regions. The CPD computed heat flow values for the region suggest that the entire area has high heat flow values (>100 mW m^?2), on the other hand, locally extremely high values (>200 mW m^?2) occur within the Panamint Valley, the southern and central Death Valley and Tecopa Hot Springs region. These locally high heat flow values may be related to midcrustal magma bodies; but additional geophysical experiments are needed to determine if the magma bodies exist.     

Magnetostratigraphy across the Berriasian-Valanginian stage boundary (Early Cretaceous), at Cehegin (Murcia Province, southern Spain)

The Berriasian-Valanginian stage boundary near the town of Cehegin in the eastern Subbetic Cordillera of Spain is documented by a detailed ammonite zonation in pelagic limestones. Two magnetostratigraphic sections spanning the uppermost ammonite subzone of the Berriasian and the lower two zones of the Valanginian yielded identical magnetic polarity patterns. Remanent magnetization is predominantly carried by magnetite, and characteristic directions were obtained by thermal demagnetization. The mean characteristic directions from both sites have an inclination of 48°; however, the site declinations are divergent (030° and 074°) due to the tectonic disturbance of the region. The Cehegin polarity pattern can be correlated by means of ammonite and calpionellid zonation to the magnetostratigraphies of the Berriasian stratotype and several Italian sections, thereby enabling a unique correlation to the M-sequence magnetic polarity time scale. The Berriasian-Valanginian stage boundary is in the middle of normal-polarity chron M15n.     

Cyclostratigraphy of the Induan (Early Triassic) in West Pingdingshan Section, Chaohu, Anhui Province

The Induan sequence in the West Pingdingshan Section, Chaohu, Anhui Province, displays a series of superimposed mudstone/limestone cycles. The lithological character of the cycles, combined with power spectral and wavelet analysis of magnetic susceptibility readings, reveals 12 short eccentricity and 56 precession Milankovitch cycles - obliquity cycles are not apparent. The uniformity of cycle thicknesses indicates a stable depositional setting making this section ideal to perform various geo-logical studies. Accordingly, the Induan Stage is estimated to have lasted 1.1 Ma, and the depositional rate for this part of the section is about 3.7 cm/ka. This places the Induan-Olenekian boundary in the West Pingdingshan Section at about 251.5 Ma based on an age of 252.6 Ma for the Permian-Triassic boundary.     

Mercury in soils of the Long Valley, California, geothermal system

An evaluation of the Hg distribution in soils of the Long Valley, California, geothermal area, was made. A₁-horizon soil samples were collected utilizing a grid system from the resurgent dome area and the Long Valley area. In addition, samples were collected in five traverses across three fault systems and four traverses across east-west-oriented gullies to measure the importance of aspect. Additional samples were collected in an analysis of variance design to evaluate natural variability in soil composition with sampling interval distance.The primary objectives of this study were to further evaluate the applicability of anomalously high Hg concentration in soils to exploration for geothermal systems and the importance of secondary controls on Hg concentration in soils above geothermal systems.Statistical analysis indicates that there are two populations of Hg concentrations in soils; one affected by geothermal activity and the other unaffected. Samples from the resurgent dome are shown to be statistically different from the samples collected in Long Valley proper with respect to Hg, organic carbon, and pH. This suggests that secondary influences may be important in controlling Hg distribution in soils.Organic carbon in soils is shown by stepwise multiple regression to be the most important secondary parameter controlling Hg concentration. For the most part, the secondary controls of Hg are overwhelmed in an area of prominent geothermal activity. Some faults exhibit prominent anomalies in total Hg concentration and others do not, indicating the possibility of low levels of hydrothermal activity or effective sealing of faults to gas leakage.The analysis of variance results indicate that there is a regional trend in Hg concentration across the resurgent dome. Soils can be sampled for Hg by utilizing a grid of about 0.4 km spacing. However, some local irregularities appear in this pattern and anomalous areas should be prospected at intervals of 100 m or less.     

Radon-222 in groundwater of the Long Valley caldera,California

In the Long Valley caldera, where seismicity has continued essentially uninterrupted since mid-1980 and uplift is documented, samples of water from hot, warm, and cold springs have been collected since September, 1982, and their²²²Rn concentrations analyzed. Concurrently, rocks encompassing the hydrologic systems feeding the springs were analyzed for their radioelement contents, because their uranium is the ultimate source of the²²²Rn in the water.The²²²Rn concentration in the springs varies inversely with their temperature and specific conductance. High concentrations (1500 to 2500 picocuries per liter) occur in dilute cold springs on the margins of the caldera, while low contents (12 to 25 pCi/l) occur in hot to boiling springs. Springwater radon concentrations also correlate slightly with the uranium content of the encompassing rocks.A continuous monitoring system was installed in August, 1983, at a spring issuing from basalt, to provide hourly records of radon concentration. A gamma detector is submerged in a natural pool, and we have observed that the radioactivity measured in this manner is due almost entirely to the²²²Rn concentration of the water. Initial operation shows diurnal and semidiurnal variations in the²²²Rn concentration of the springwater that are ascribed to earth tides, suggesting that those variations are responding to small changes in stress in the rocks encompassing the hydrologic system.     

Pesticide residues in ground water of the San Joaquin Valley, California

A regional assessment of non-point-source contamination of pesticide residues in ground water was made of the San Joaquin Valley, an intensively farmed and irrigated structural trough in central California. About 10% of the total pesticide use in the USA is in the San Joaquin Valley. Pesticides detected include atrazine, bromacil, 2.4-DP, diazinon, dibromochloropropane, 1,2-dibromoethane, dicamba, 1,2-dichloropropane, diuron, prometon, prometryn, propazine and simazine. All are soil applied except diazinon.

Pesticide leaching is dependent on use patterns, soil texture, total organic carbon in soil, pesticide half-life and depth to water table. Leaching is enhanced by flood-irrigation methods except where the pesticide is foliar applied such as diazinon. Soils in the western San Joaquin Valley are fine grained and are derived primarily from marine shales of the Coast Ranges. Although shallow ground water is present, the fewest number of pesticides were detected in this region. The fine-grained soil inhibits pesticide leaching because of either low vertical permeability or high surface area; both enhance adsorption on to solid phases. Soils of the valley floor tend to be fine grained and have low vertical permeability. Soils in the eastern part of the valley are coarse grained with low total organic carbon and are derived from Sierra Nevada granites. Most pesticide leaching is in these alluvial soils, particularly in areas where depth to ground water is less than 30m. The areas currently most susceptible to pesticide leaching are eastern Fresno and Tulare Counties.

Tritium in water molecules is an indicator of aquifer recharge with water of recent origin. Pesticide residues transported as dissolved species were not detected in non-tritiated water. Although pesticides were not detected in all samples containing high tritium, these samples are indicative of the presence of recharge water that interacted with agricultural soils.     

Late Jurassic/Early Cretaceous magnetic stratigraphy from the sümeg section,Hungary

The pelagic limestones exposed at Sümeg appear to represent continuous deposition from Kimmeridgian through Berriasian. Detrital magnetite and haematite pigment are the carriers of remanence in the red and non-red limestones in the lower part, while magnetite becomes predominant in the upper half of the section. Thermal demagnetization has succesfully removed overprint magnetizations, and a well-defined magnetic stratigraphy has been obtained. The Late Jurassic/Early Cretaceous mixed polarity interval is correlated with the sequence of geomagnetic reversals derived from oceanic magnetic anomalies.     

The Upper Valanginian (Early Cretaceous) positive carbon-isotope event recorded in terrestrial plants

Our understanding of the ancient ocean-atmosphere system has focused on oceanic proxies. However, the study of terrestrial proxies is equally necessary to constrain our understanding of ancient climates and linkages between the terrestrial and oceanic carbon reservoirs. We have analyzed carbon-isotope ratios from fossil plant material through the Valanginian and Lower Hauterivian from a shallow-marine, ammonite-constrained succession in the Crimean Peninsula of the southern Ukraine in order to determine if the Upper Valanginian positive carbon-isotope excursion is expressed in the atmosphere. δ¹³C_plant values fluctuate around − 23‰ to − 22‰ for the Valanginian-Hauterivian, except during the Upper Valanginian where δ¹³C_plant values record a positive excursion to ∼− 18‰. Based upon ammonite biostratigraphy from Crimea, and in conjunction with a composite Tethyan marine δ¹³C_carb curve, several conclusions can be drawn: (1) the δ¹³C_plant record indicates that the atmospheric carbon reservoir was affected; (2) the defined ammonite correlations between Europe and Crimea are synchronous; and (3) a change in photosynthetic carbon-isotope fractionation, caused by a decrease in atmospheric pCO₂, occurred during the Upper Valanginian positive δ¹³C excursion. Our new data, combined with other paleoenvironmental and paleoclimatic information, indicate that the Upper Valanginian was a cool period (icehouse) and highlights that the Cretaceous period was interrupted by periods of cooling and was not an equable climate as previously thought.