137Cs在滇西与黔中地区散落的差异——青藏隆起对滇西地区全球性扩散大气污染物散落屏蔽效应的推断

云贵高原是青藏隆起在南亚大陆形成的一个海拔梯度大、地势格局复杂的特异环境单元.该地域兼受东南季风与西南季风的交汇影响,是全球变化的敏感区之一.青藏隆起对云贵高原现代环境影响主要表现在1)全球性大气扩散污染物的屏蔽效应和局地性大气扩散污染物的滞留效应;2)区域化学风化的增强效应和物理侵蚀的梯级效应;3)地表环境地球化学过程的低纬度-高海拔效应.核素示踪模式分析表明滇西与黔中地区之间137Cs自大气散落差异明显[1986年以前,洱海和红枫湖沉积物中137Cs散落的累计值分别为(0.11±0.01)Bq/cm2及(0.37±0.01)Bq/cm2],而7Be的散落相近.这说明青藏隆起对滇西地区存在全球性扩散大气污染物散落的屏蔽效应.     

滇西和黔中表土及湖泊沉积物中7Be与137Cs对比

滇西和黔中地区位于喜马拉雅隆起东翼斜坡云贵高原,海拔高程不同但纬度相近,均不同程度地受东南季风和西南季风交汇影响。区内碳酸盐岩出露广泛,土壤类型相似。对滇西洱海、沪沽湖和黔中红枫(百花,下同)湖沉积物及其汇水区28个表土剖面的散落核素⁷Be和'¹³⁷Cs分布和蓄..     

现代沉积年分辨的137Cs计年──以云南洱海和贵州红枫湖为例

1964,1975及1986年三个¹³⁷CS时标计算出红枫湖和洱海沉积物平均堆积速率完全一致,说明1975年和1986年次级蓄积峰作为计年时标的可靠性。洱海沉积物平均堆积速率为0．047±0．002g／(cm²·a),与²¹⁰Pb方法所获得的结果一致;红枫湖为0．17±0．01g／(cm²·a),与其建湖以来沉积物实际堆积的观察结果吻合。洱海1964年沉积物中¹³⁷CS的比活度(校正到沉积年代)仅46．4Bq／kg,而红枫湖达145Bq／kg。由于红枫湖沉积物堆积速率约为洱海的3．7倍,所以其1964年层节沉积物中¹³⁷CS蓄积量比洱海大11.5倍。红枫湖沉积物中¹³⁷CS累计值的99．4％分配于1985年以前,而洱海的19．4％分配于1986年以后,显示出¹³⁷CS在洱海沉积物中的较大扩散能力。     

长江河口水下三角洲137Cs地球化学分布特征

文章通过对长江口水下三角洲采集的10个柱状样放射性核素¹³⁷Cs的分析可以得知,长江口水下三角洲¹³⁷Cs剖面中均存在清晰的最大蓄积峰,其峰值比活度介于5.68±1.03～21.74±1.39Bq/kg之间,平均值为14.11±1.10Bq/kg,最大蓄积峰所处的深度为55～117cm。剖面中¹³⁷Cs最大蓄积峰应该与1963年的¹³⁷Cs散落沉降相对应。长江口水下三角洲的表层沉积物中的¹³⁷Cs比活度范围介于0～9.19±1.12Bq/kg之间,并且与长江流域其他地区的表层¹³⁷Cs比活度相一致。长江口水下三角洲可探测到的¹³⁷Cs比活度的最大深度范围在88～160cm的范围内变化,¹³⁷Cs蓄积总量为2361.30±174.38～17714.94±262.14Bq/m²,平均值为9664.97±100.05Bq/m²,¹³⁷Cs比活度的最大深度及¹³⁷Cs蓄积总量均表现出从岸向海逐渐增加的趋势。实测的¹³⁷Cs总量均大于长江流域的¹³⁷Cs背景值,说明了长江口水下三角洲的¹³⁷Cs蓄积既有大气散落直接沉降的来源,又有流域侵蚀带来的¹³⁷Cs输入,并且主要以后者为主。通过放射性核素示踪模型分析长江口水下三角洲¹³⁷Cs散落蓄积特征可以得知,长江口水下三角洲¹³⁷Cs的蓄积以长江流域来源为主,说明了放射性核素¹³⁷Cs在长江口水下三角洲沉积物中的蓄积主要受流域侵蚀因素的影响。     

黔中气溶胶传输的210 Pb和7 Be示踪:Ⅱ.月及年时间尺度的剖析

自2001年12月连续逐周在贵阳观风山附近对近地面空气210Pb-7Be浓度和沉降量的观测表明:区域性降水和气温制约近地面空气210Pb具高浓度"U"型年分布;降水量和平流层向下输送影响近地面空气7Be月均浓度的季节性变化;210Pb/7Be月均浓度比率受控于210Pb变化和富7Be气团下沉的影响.观风山与瓦里关山之间因纬度和海拔的关系,7Be比率急剧震荡,显示出海洋性贫7Be气团入侵对观风山地区的明显影响.2002-2008年间贵阳观风山近地面空气210Pb的年均浓度(2.8±0.6)mBq/m3,约为全球若干站点中最高平均浓度值的4倍;而7Be的年均浓度(4.8±0.6)mBq/m3,与全球高海拔站点长期观测的平均值相当,大约为北半球中纬度对流层顶部附近7Be浓度值(18.0 mBq/m3)的1/3.8,显示出低纬度、较高海拔地区的预期水平.2003年,瓦里关山和观风山近地面空气7Be的年均浓度比为3.8,与预期的大气输送和混合作用基本一致.7Be月均浓度的增大趋势反映出受太阳黑子数减少的变化关系,其影响底线大约为4 mBq/m3;7Be年均浓度波动的增大趋势反映出受太阳黑子数降低的可能影响.贵阳观风山降水中7Be和210Pb的体积加权浓度分别为0.72 Bq/L和0.27 Bq/L;年沉降通量分别为0.080 Bq/(cm2·a)和0.031 Bq/(cm2·a).数值模拟显示出全球空气210Pb高浓度区和高沉降通量环带分布,印证了洱海和红枫湖沉积物7Be和157Cs蓄积的模拟结果.     

松花湖沉积物~(137)Cs和~(210)Pb分布及沉积速率

松花湖沉积物柱心中存在3个明显的137Cs蓄积峰,分别是37 cm处的1964年蓄积峰、27 cm处的1971年蓄积峰和23 cm处的1975年蓄积峰.利用137Cs核素1964年和1975年对应蓄积峰计算的沉积速率分别为0.86 cm/a和0.71 cm/a.采用210Pb计年的常量初始浓度模式(CIC)计算的平均沉积速率为0.71 cm/a,两者估算的沉积速率吻合.松花湖1964-1975年间的沉积速率明显高于1975-2006年间的沉积速率.137Cs和210Pb计年方法的结合有助于提高沉积速率估算的准确性.     

^137Cs法测算黄土高原土壤侵蚀速率的初步研究

核尘埃~(137)Cs降落到地表后,被土壤胶粒强烈吸附,集中分布于0—25cm的土壤表层。土壤剖面的~(137)Cs总量随土壤的流失而减少。根据黄土农耕地和非农耕地土壤的~(137)Cs流失模式,推导了它们的流失量和侵蚀速率的相关公式。根据陕西洛川黑木沟和山西离石羊道沟的13个土壤剖面的~(137)Cs含量测试结果,求得的黑木沟草坡覆盖的老谷坡和新谷坡的侵蚀速率分别为1400 t/km~2·a和5700t/km~2·a;羊道沟梁峁坡农耕地的侵蚀速率为3270—6030 t/km~2·a;裸露新谷坡的侵蚀速率大于8000 t/km~2·a。     

黄河口新生湿地沉积物放射性核素及其对 沉积过程变化指示作用解析

为探讨放射性核素对沉积速率、沉积环境变化以及重大环境历史事件的指示作用,本文首次报道了用HPGeγ谱仪测定黄河口新生湿地柱状沉积物中6种放射性核素活度的结果,并根据137Cs的垂直分布估算了沉积速率,探讨了放射性核素与有机质的关系及其垂直变化与沉积过程变化的对应关系。结果表明,黄河口新生湿地柱状沉积物中6种放射性核素的平均比活度分别为40K(687.33±54.59)Bq/kg、137Cs(8.60±1.35)Bq/kg、226Ra(29.96±4.23)Bq/kg、228Ra(69.96±6.63)Bq/kg、228Th(45.35±4.58)Bq/kg和238U(60.52±15.37)Bq/kg,与其他区域相比,黄河口新生湿地137Cs、238U含量偏高。除137Cs外,其他5种核素均与TOC呈显著正相关,表明有机质有利于核素在沉积物中的保留。137Cs的垂直分布与黄河口净造陆速率的年际变化具有一致性,据此估算获得近20年该区域平均沉积速率为2.8cm/a,其中河口湿地形成初期沉积速率较高,而后逐渐减小并保持相对稳定。放射性核素比活度的垂直变化可反映沉积过程中黄河断流、黄河调沙以及大的洪水等重大环境事件,可以作为指示沉积变化特征的重要指标。     

DISCUSSION ON APPLYING 137Cs AND 210Pbex FOR LAKE SEDIMENT DATING IN CHINA

137Cs和210Pbex是湖泊沉积物断代常用的两种核素,沉积物中核素的深度分布,不但随核素的大气沉降量变化,也与流域环境变化和沉积后核素的再分布有关.我国环境复杂,人类活动强烈,137Cs和210Pbex深度分布的非理想曲线常见于我国一些湖泊的沉积物.本文简要介绍了湖泊沉积物137Cs和210Pbex深度分布理想曲线和断代基本原理,在参阅大量有关中国湖泊沉积物137Cs和210Pbex断代文献的基础上,讨论了137Cs和210Pbex非理想深度分布曲线的解泽和沉积物断代的几个常见问题.主要观点如下:1)我国湖泊沉积物不存在所谓的1974年和1986年蓄积峰;2)一些湖泊沉积出现的非单峰型137Cs深度分布曲线,可能与人类活动或湖流扰动湖泊底泥、流域侵蚀产沙环境变化和137Cs主要来源于冰川融水补给等因素有关;3)沉积物中的核素垂向运移,不改变剖面中1963年137Cs蓄积峰的位置,不影响其断代标志意义;4)流域环境突发事件引起的沉积剖面中的137Cs和210Pbex明显异常,是断代的可靠标志等.最后介绍了根据沉积剖面137Cs和210Pbex总量与本底值对比,求算沉积速率的核素质量平衡法.     

137Cs测年的东北兴凯湖现代沉积速率研究

对兴凯湖我国水域沉积物137Cs比活度及通量空间分布进行了研究,利用137Cs测年法建立年代框架,估算了兴凯湖的沉积速率,结合粒度C-M图分析了湖泊现代沉积环境。兴凯湖我国水域西岸白棱河河口区域137Cs剖面形态区别于典型的137Cs全球大气沉降模式,且137Cs沉积通量高、平均137Cs活度高,中部和东部区域137Cs沉积通量低、平均137Cs活度低;137Cs沉积通量的空间分布主要受流域输入、水动力条件以及沉积物粒径的影响。兴凯湖沉积环境多表现为静水沉积,受特殊的风浪条件和泄洪闸等人类活动的影响,1963—2019年平均沉积速率空间分布上呈现西部高,中、东部低的特点,XKH-1、XKH-2和XKH-3柱样1963—2019年的平均沉积速率分别为0.143 cm/a、0.080 cm/a和0.036 cm/a。     

Research on the carbon isotopic composition of organic matter from Lake Chenghai and Caohai Lake sediments

The carbon isotopic composition of organic matter from lake sediments has been extensively used to infer variations in productivity. In this paper, based on the study of the contents and δ13C values of organic matter in different types of lakes, it has been found that δ13C values of organic matter have different responses to lake productivity in different lakes. As to the lakes dominated by aqutic macrophytes such as Lake Caohai, organic matter becomes enriched in 13C with increasing productivity. As to the lakes dominated by aquatic algae such as Lake Chenghai, δ13C values of organic matter decrease with increasing productivity, and the degradation of aquatic algae is the main factor leading to the decrease of δ13C values of organic matter with increasing productivity. Therefore, we should be cautious to use the carbon isotopic composition of organic matter to deduce lake productivity.     

南极拉斯曼丘陵莫愁湖和团结湖水中有机物剖析(英)

Information on the organic compounds in water of Mochou Lake and Heart Lake, Antarctica is given in this paper. 93 organic compounds were identified from 121 chemical constituents in lake water, including n-alkanes, lipidal isopentadienes, aromatic hydrocarbons, polycyclic aromatics, alcohols, aldehydes, ketones, esters, monocarboxylic acids and phthalic esters in the range of 0. 027～4. 97 μg/L. Organic compounds of global occurrence like BHC, DDT and PCBs were detected in the water,at the concentration of 0. 012～0. 356 μg/L.     

Late Pleistocene and late Holocene lake highstands in the Pyramid Lake subbasin of Lake Lahontan, Nevada, USA

Shoreline geomorphology, shoreline stratigraphy, and radiocarbon dates of organic material incorporated in constructional beach ridges record large lakes during the late Pleistocene and late Holocene in the Pyramid Lake subbasin of Lake Lahontan, Nevada, USA. During the late Holocene, a transgression began at or after 3595 ± 35 ¹⁴C yr B.P. and continued, perhaps in pulses, through 2635 ± 40 ¹⁴C yr B.P., resulting in a lake as high as 1199 m. During the latest Pleistocene and overlapping with the earliest part of the Younger Dryas interval, a lake stood at approximately 1212 m at 10,820 ± 35 ¹⁴C yr B.P. and a geomorphically and stratigraphically distinct suite of constructional shorelines associated with this lake can be traced to 1230 m. These two lake highstands correspond to periods of elevated regional wetness in the western Basin and Range that are not clearly represented in existing northern Sierra Nevada climate proxy records.     

Major and trace element geochemistry of Lake Bogoria and Lake Nakuru,Kenya, during extreme draught

The physico-chemical properties of water samples from the two athalassic endorheic lakes Bogoria and Nakuru in Kenya were analysed. Surface water samples were taken between July 2008 and October 2009 in weekly intervals from each lake. The following parameters were determined: pH, salinity, electric conductivity, dissolved organic carbon (DOC), the major cations (FAAS and ICP-OES) and the major anions (IC), as well as certain trace elements (ICP-OES). Samples of superficial sediments were taken in October 2009 and examined using Instrumental Neutron Activation Analysis (INAA) for their major and trace element content including rare earth elements (REE). Both lakes are highly alkaline with a dominance of Na > K > Si > Ca in cations and HCO₃ > CO₃ > Cl > F > SO₄ in anions. Both lakes also exhibited high concentrations of Mo, As and fluoride. Due to an extreme draught from March to October 2009, the water level of Lake Nakuru dropped significantly. This created drastic evapoconcentration, with the total salinity rising from about 20‰ up to 63‰. Most parameters (DOC, Na, K, Ca, F, Mo and As) increased with falling water levels. A clear change in the quality of DOC was observed, followed by an almost complete depletion of dissolved Fe from the water phase. In Lake Bogoria the evapoconcentration effects were less pronounced (total salinity changed from about 40‰ to 48‰). The distributions of REE in the superficial sediments of Lake Nakuru and Lake Bogoria are presented here for the first time. The results show a high abundance of the REE and a very distinct Eu depletion of Eu/Eu* = 0.33–0.45.     

Analysis of dynamic changes and influence factors of Lake Balkhash in the last twenty years

Lake Balkhash is the third largest inland lake in Central Asia after the Caspian Sea and the Aral Sea.The Ili River-Balkash Lake Basin resides in the southeastern part of the Republic of Kazakhstan and the western part of China's Ili Prefecture,which belongs to the arid and semi-arid region.In the middle to late 20^thcentury,the Ili River-Balkash Lake Basin was affected by climate change and human activities,and the problems of water ecology and water resources became increasingly prominent,which became the focus of attention for China and Kazakhstan.In this study,the water level derived from radar altimeter data,the water surface area extracted from Landsat data,and the temperature and precipitation data in the basin were comprehensively utilised.Data analysis of the time course and correlation of hydrological,meteorological elements in the lake basin,water dynamic changes,and influencing factors of Lake Balkhash was studied.The results show that the cyclical change of regional climate is the main factor affecting the change of lake water,and human activities in the short term can regulate the change of water volume in Lake Balkhash.The research results in this paper can provide a scientific basis for the solution of water disputes in cross-border rivers between China and Kazakhstan.     

青海扎陵湖和鄂陵湖盆地第四纪河湖相地层研究

通过对扎陵湖和鄂陵湖沿岸的湖积阶地中湖相沉积的野外地质调查和实测剖面,对分布于盆地内的第四纪早更新世-全新世湖相地层进行了详细的研究和划分、重新厘定了该区第四纪岩石地层单元,确立了生物地层和年代地层序列.建立了青海东南部地区第四纪早更新世-全新世湖相地层单位-黄河源群(QH),黄河源群是由第四系下更新统野生沟组(Qp~1γ)、中更新统鄂陵湖组(Qp~2e)、上更新统大野马岭组(Qp~3d)和全新统黑河乡组(Qhh)等4个组组成.为青藏高原湖泊演化、气候变化、古地理变迁研究,以及第四纪地层的划分与对比等提供了新资料.     

中国盐湖锂资源的产业化现状-以西台吉乃尔盐湖和扎布耶盐湖为例

锂对国民经济和国家安全具有重要意义, 是21世纪的能源金属。近10年, 中国主要从国外进口碳酸锂产品。中国是一个多盐湖的国家, 盐湖锂占锂资源工业总储量的85%。现代第四纪盐湖主要分布在我国西北的青海、西藏、新疆和内蒙古四省区, 具有很好的开发前景。经过多年科研后, 目前国内已经在西台吉乃尔和扎布耶两个盐湖建立了卤水提锂产业。本文对比研究了这两个盐湖资源状况和地理气候条件, 以及由此而决定的盐湖资源开发工艺流程, 探讨了其工艺优化方向。并指出这两个盐湖具有锂资源储量大, 品位高的优势, 但是受盐湖类型或地理气候条件限制, 工艺上有待改善。建议继续加强对盐湖开发技术优化和对盐湖提锂产业的扶持。     

山东东平湖的变迁与黄河改道的关系

根据历史文献以及巨野、梁山、戴庙钻孔剖面的分析与研究及对东平湖底沉积的调查,确定了大野泽、梁山泊、安山湖、东平湖的沉积记录,提出东平湖由大野泽、梁山泊、安山湖演化而来。通过对东平湖演化与黄河决口和改道关系的分析与对比,指出历史时期东平湖演化历程与黄河关系密切,经历了黄河决口注入和改道流经湖区,河水注入、湖面扩大,河徙水退、湖面萎缩。黄河第一次大改道期间注入和一次改道流经大野泽。黄河第二次大改道期间两次注入、其中一次改道流经大野泽,水面北侵形成梁山泊。黄河第三次大改道期间三次决口注入,两次改道流经梁山泊,湖面进一步扩大成“八百里梁山泊”,之后黄河仅数次决入,水源短缺,湖面萎缩。黄河第四次大改道期间未流入梁山泊,湖面进一步缩小。黄河第五次大改道期间曾两次注入梁山泊,湖面又扩大成为一片泽国,而后断绝黄河水源,被分成安山湖等北五湖,梁山泊岁久填淤,变湖为陆。黄河第六次大改道期间黄河水源断绝,北五湖水面北移,逐渐萎缩消失,仅安山湖经历一次黄河决入,并淤塞而成东平湖,黄河水断绝时湖底干涸,黄河大汛期曾倒灌入湖。