Adsorption capacity of iron oxide-coated gravel for landfill leachate: simultaneous study

Landfill leachate is a high-strength wastewater. If it is not managed properly, it can pollute surrounding environment. The aim of this study is to determine the simultaneous adsorption capacity of iron oxide-coated gravel for metals such as Cd(II), Cu(II), Fe(II), Ni(II) and Zn(II) in high-strength leachate sample. Different operating conditions such as pH, time, and dosages were investigated to determine the kinetics and mechanism of adsorption process. Coating with iron oxide changed the external surface of gravel. The adsorption capacities increased with increased pH, and the optimum pH was found to be 7. High removal rates were observed in a short period of time. The Freundlich model fitted reasonably well to the experimental data, indicating multilayer adsorption process and the heterogeneity of the surface (R ² ranging 0.57–0.94). The Temkin model fitted well to the experimental data as well (R ² ranging 0.67–0.98), indicating that the adsorption is an exothermic process. The adsorption of ions was found to obey second-order kinetics, indicating one-step, surface-only adsorption process. The degree of metal adsorption on iron oxide-coated gravel at pH 7 was in the order Cu(II) > Cd(II) > Fe(II) > Zn(II) > Ni(II).     

Co-management of landfill leachate concentrate with brick waste by solidification/stabilization treatment

The treatment of landfill leachate by reverse osmosis (RO) generates huge volumes of heavily polluted concentrate that has to be properly treated before its discharge into the environment. The aim of this work was to assess the solidification/stabilization (S/S) treatment of the leachate concentrate (LC) for chemical/physical immobilization of contaminants and for obtaining durable monolithic matrix suitable for storage, landfilling, or use. In addition, the possible use of brick waste as a partial replacement of natural aggregates used for S/S process was investigated. Concrete mixtures were prepared using local PC, sand, gravel, and tap water/LC. The substitution of coarse aggregate material by brick waste was examined for the replacement ratios 25, 50, and 75%. Hardened concrete specimens were subject to compressive test as well as flexural strength test at 7 and 28 days. Besides, a leaching test was performed, and the collected eluates were analyzed for pH, total dissolved solids, chemical oxygen demand, chlorides, sulfates, phosphorus, and heavy metals. The aggregate replacement with brick waste showed various trends according to the substituted fraction size and ratio. A 28-day compressive strength of more than 25 MPa was obtained even at 50% simultaneous substitution of PC, gravel, and sand. Leaching test analysis confirmed that S/S could be a successful treatment for RO LC decreasing most of the pollutants to comply with landfilling criteria, except for chromium known to be mobile at high pH. Furthermore, the substitution of natural aggregates with brick waste revealed the possibility to cast valuable masonry units. However, a long-term assessment is still needed to ensure the mechanical and chemical stability/durability of concrete.     

天然与改性膨润土组合处理难生物降解垃圾渗滤液的实验研究

以北京市阿苏卫垃圾填埋场中晚期渗滤液为研究对象,通过正交实验的方法分析了改性土、原土、明矾、改性土加明矾等的用量及搅拌速度、搅拌时间、静置时间等因素对垃圾渗滤液CODcr去除率的影响。通过对改性土、原土、明矾处理垃圾渗滤液的机理进行分析后,将改性土、原土分别用来处理垃圾渗滤液中可溶性物质中的疏水性物质和亲水性物质,并结合明矾的絮凝作用组合处理垃圾渗滤液。处理后垃圾渗滤液CODcr值从4700mg/L明显下降到839mg/L,CODcr去除率为82.15%,BOD5从700mg/L下降到263mg/L,BOD5去除率为62.43%。有机改性膨润土、明矾、原土组合处理是一种有效的处理垃圾渗滤液方法。     

Chemical composition of landfill leachate in a karst area with a Mediterranean climate (Marbella, southern Spain)

 Between March 1994 and April 1997, the physical and chemical parameters and chemical composition of the urban solid waste leachate of the Marbella landfill (southern Spain) were determined. The data obtained show an ammonium and sodium chloride and bicarbonate type, a pH>7 and high mineralization, effectively described by the following parameters: Na⁺, K⁺, NH₄ ⁺, Cl^– and alkalinity. The chemical composition depends on the rainfall: in dry years, the mineralization and component concentrations have values as much as double those found in normal rainfall years. After storm events, a major and rapid dilution (within several hours) is seen in the leachate. Received: 28 January 1998 · Accepted: 2 June 1998     

Spatial and temporal variability of rainfall: case of Bizerte-Ichkeul Basin (Northern Tunisia)

This study examines spatial and temporal variability of rainfall in Bizerte-Ichkeul Watershed. The basin, located in the extreme north of Tunisia, covers an area of 3084 km². Thirteen rainfall stations, with continuous monthly precipitation records over the period (1970–2011), were considered in the analysis. Two methods were used. In the first, the dimensionless standardized precipitation ratio is applied to examine precipitation temporal variation. The second method is represented by continuous wavelet analysis for the precipitation spatial analysis and the identification of the origin of its variability. The study of temporal variability of annual rainfall showed severe persistent and recurrent drought episodes over the period (1977–2001). Wavelet analysis resulted in detecting the modes and origins of precipitation variability. Three energy bands were clearly identified: (1, 2–4, and 4–8 years) for the entire watershed. The visualization of the power distribution showed that the observed modes of variability are different in their power distributions from one station to another. The approach adopted allowed the identification of two groups with the same precipitation frequency and temporal variation. These groups were defined according to the difference in occurrence of the frequency band for each station.     

Biosorption with autochthonous and allochthonous fungal biomasses for bioremediation and detoxification of landfill leachate

Landfill leachates are not adequately treated in traditional wastewater treatment plants, on account of their problematic peculiarities: i.e., dark colour, high concentration of recalcitrant pollutants and COD, and high toxicity. In this work, 19 biomasses (15 autochthonous and 4 allochthonous) were exploited in biosorption treatment for the remediation of a leachate (influent) and the effluent coming from the biological oxidation with activated sludge and nitrification–denitrification treatment. The effects of the initial pH, the biomass amount, and the medium for the biomass pre-culture were considered. The best configuration was: pH 5, 5 g L^??1 biomass cultivated on STY medium. Eventually, the two most effective biomasses, Cunninghamella bertholletiae MUT 2861 and Aspergillus fumigatus MUT 4050, were used in consecutive 2 h cycles in a batch biosorption experiment. The effectiveness of the treatment decreased in subsequent cycles in terms of decolourisation (31–15%). COD, Cl^?, SO₄^2?, total N, and toxicity were removed mainly in the second cycle of treatment (up to ??36, ??12, ??15, ??17 and ??49%, respectively). The results suggest that the effluent toxicity was basically due to uncoloured substances, which were mainly removed after coloured molecules.     

Insights and participatory actions driven by a socio-hydrogeological approach for groundwater management: the Grombalia Basin case study (Tunisia)

Sustainable groundwater management strategies in water-scarce countries need to guide future decision-making processes pragmatically, by simultaneously considering local needs, environmental problems and economic development. The socio-hydrogeological approach named ‘Bir Al-Nas’ has been tested in the Grombalia region (Cap Bon Peninsula, Tunisia), to evaluate the effectiveness of complementing hydrogeochemical and hydrogeological investigations with the social dimension of the issue at stake (which, in this case, is the identification of groundwater pollution sources). Within this approach, the social appraisal, performed through social network analysis and public engagement of water end-users, allowed hydrogeologists to get acquainted with the institutional dimension of local groundwater management, identifying issues, potential gaps (such as weak knowledge transfer among concerned stakeholders), and the key actors likely to support the implementation of the new science-based management practices resulting from the ongoing hydrogeological investigation. Results, hence, go beyond the specific relevance for the Grombaila basin, showing the effectiveness of the proposed approach and the importance of including social assessment in any given hydrogeological research aimed at supporting local development through groundwater protection measures.     

Geodetic and GIS tools for dam safety: case of Sidi Salem dam (northern Tunisia)

The dams are one of the important engineering structures used for water supply and different other important purposes. In order to provide safety, well-planned and implemented geodetic monitoring is very essential for such engineering structures, which constitute the aim of this study. In fact, micro-geodetic data can be exploited and used to survey the displacement of dam by measuring the horizontal and vertical coordinates at different dates from fixed positions (pillars) to other positions (targets). As a result, the superposition of the geodetic auscultation charts and the factors which can affect the stability of dams such as water level, hydrostatic pressure, and seismic state show a net correlation between these parameters and the auscultation variation at different periods. Geographical information system (GIS) techniques are used for mapping spatial variation of auscultation measures. These synthetic documents can help managers and decision makers in hydraulic management and water system protection.     

Interaction of phenanthrene with dissolved organic matter and its fractions from leachate of different landfill ages

Dissolved organic matter (DOM) in leachate from landfills of three different ages (0, 5, and 10?year) was partitioned into hydrophobic acid, hydrophobic neutral, and hydrophilic matter fractions using the fractionation method employing XAD-8 resin. The spectroscopic characteristics of these fractions were determined through constant-wavelength synchronous fluorescence spectrometry (CWSFS). The interaction characteristic of phenanthrene with these fractions was determined through the fluorescence quenching method and CWSFS. The results revealed that the composition of DOM became complex with the increase in landfill age. The partition coefficients (K _doc) for the three DOM samples of different landfill ages are in the order 10?a DOM?>?5?a DOM?>?0?a DOM. The hydrophobic fraction showed the highest K _doc value among the DOM fractions. Lower linearity Stern?CVolmer plots were observed in 10?a DOM and its hydrophobic fractions. CWSFS spectra showed that a special site was fully occupied with the addition of the quencher. Desorption was found in some fractions. Therefore, CWSFS is a sensitive tool for the detection of DOM-polycyclic aromatic hydrocarbon interaction.     

Micropaleontological study (foraminifera, ostracods) and characterization of the paleoenvironment of middle Cretaceous deposits (Djebel Chemla area, north-eastern Algeria)

The Djebel Chemla section is situated in the north-east of Algeria, close to the town of Tébessa and just a few kilometers from the Tunisian border. This section is composed mainly of a sequence of marl and marly limestone levels, alternating with recurring oyster levels which range in age from Vraconnian to the Early Turonian. Firstly, the micropaleontological study of the content (counting of foraminifera and ostracods, thin sections) allows the subdivision of the section into four biozones, with Rotalipora appenninica, Rotalipora globotruncanoides, Rotalipora cushmani, and Whiteinella archaeocretacea as bio-indicators; and, secondly, it provides the opportunity to specify the paleoenvironment. The supposed depositional environment is rather calm and deep, of an external platform type, with a maximum depth of 200 m. Bottom waters seem to be commonly poorly oxygenated. The end-Cenomanian anoxic crisis was also characterized by the presence of Bahloul facies levels, rich in TOC, in filaments and of globulous planktic foraminifera, including a considerable proportion of Heterohelix. The genus Rotalipora has disappeared a few levels lower down.     

Geochemistry and quality assessment of groundwater using graphical and multivariate statistical methods. A case study: Grombalia phreatic aquifer (Northeastern Tunisia)

The Grombalia coastal aquifer, situated in Northeastern Tunisia, is a water source for public, agricultural, and industrial supplies in the region. The overexploitation of this aquifer, since 1959, and the agriculture activities led to the degradation, by places, of the water quality. The present study implemented graphical, modeling, and multivariate statistical tools to investigate natural and anthropogenic processes controlling Grombalia groundwater mineralization and water quality for promoting sustainable development. To attempt this goal, groundwater was collected from 33 observation wells in January 2004, and samples were analyzed for 10 physicochemical parameters (temperature, pH, salinity, Na⁺, Ca²⁺, K⁺, Mg²⁺, Cl^?, HCO^3?, and SO ₄ ^2? ). Hydrochemical facies using Piper diagram indicates a predominance of a mixed facies, of the Na-Cl-HCO₃ type, or Na-Ca-Cl-SO₄ type, and, with less expansion, Na Cl type. The main factors controlling Grombalia groundwater mineralization seem to be mineral dissolution of highly soluble salts especially, the halite dissolution existing in the surface salty deposits and, with less importance, the ion exchange and reverse ion exchange process with clay minerals existing in the aquifer. The comparison of the major ions of the Grombalia groundwater, with the World Health Organization norms of potability (WHO 2004), reveals that these waters cannot be used for human consumption without any treatment. Most waters of the Grombalia aquifer, with a relatively high salinity, are not suitable for irrigation, in ordinary conditions. Nevertheless, they can be used for permeable soils, with an adequate drainage and applying an excess of leaching water.     

Palaeoenvironments of the Continental Intercalaire fossil from the Late Cretaceous (Barremian-Albian) in North Africa: a case study of southern Tunisia

Through the Late Cretaceous, the southern shore of the Tethys Ocean migrated north and south over short distances. These vicissitudes are documented in the Continental Intercalaire, a long series of mainly non-marine sediments deposited in which dinosaur or other reptiles tracks and floral fossils are common across southern Tunisia (North Africa). A combined taxonomic, climatological, and palaentological studies provides independent lines of evidence for reconstruction of palaeoenvironments. The Bou Hedma/Boulouha and Sidi Aïch/Douiret Formations from southern Tunisia span the later part of the Late Cretaceous. During the Late Cretaceous the Tunisian territory was an archipelago, thus a particularly suitable area for a more detailed study. We investigated the area’s plant palaeo-biogeography, using fossil wood, with information from both a literature survey and investigation of new samples. The presence of fossils at great depths and distances from the present coastline, without signs of abrasion and far from areas of fluvial discharges does indicate that these remains have not been transported from the continent to the shelf, but have been preserved directly on the area that today correspond to the continental shelf. The climate during the accumulation of Barremian-Albian deposits in this region is inferred to have been warm and humid.     

Environmental problems associated with the development and operation of a lined and unlined landfill site: a case study demonstrating two landfill sites in Patra,Greece

The present work demonstrates the environmental problems associated with the development and operation of a lined and unlined landfill site, both used for municipal solid waste landfilling, that are situated next to the city of Patra, Greece. Findings from a detailed site investigation as well calculations on hydrologic evaluation of landfill’s performance and measurements on leachate composition proved that the lined landfill site is more secure and environmental friendly compared with the unlined landfill site. Even though, until today, there is no evidence from near boreholes for severe contamination problems generated by any of the two landfills, in the forthcoming future several environmental problems are expected to occur from the unlined site. In addition the prevailing hydrogeotechnical conditions indicated that the unlined site is a potential source of contamination; hence extra remedial measures should be received by the local authorities to prevent severe contamination in soil and groundwater.     

Municipal solid waste landfill siting by using GIS and analytical hierarchy process (AHP): a case study in Qom city,Iran

Qom is the eighth most populated city in center of Iran, and its population growth rate is among the highest in this country. Th presence of a Great Salt Lake, petroleum potential and tourism attractions in this city sheds light on the importance of how solid waste landfill locations should be disposed, located and managed as an environmental issue. Considering the key parameters in landfill site selection, in this study a series of location analysis have been conducted to locate optimum regions for municipal solid waste disposal, using analytical hierarchy process (AHP) and geographical information system (GIS). The main factors in selecting the suitable location for waste disposal include geomorphology–hydrography, environmental–social factors and design criteria, each of which are subdivided into several categories. Criteria are selected according to the regional condition; therefore, important factors such as distance from sea and forested areas were not considered. In the next step, digital layers are weighted and classified according to the available standards and expert judgment. Then, analytical multi-criteria decision-making algorithms as AHP and weighted linear combination are applied upon existing layers in GIS. The results show that by implementing the AHP method in this region only 7% of the study area has a very good and appropriate condition for landfill location and the field observation confirms them. Finally, considering the environmental effects of landfill, appropriate locations are suggested.     

GIS-based analysis of the Stream Length-Gradient Index for evaluating effects of active tectonics: a case study of Enfidha (North-East of Tunisia)

Our study aims at calculating morphometric indices through the recourse to the Digital Elevation Model (DEM) and its attributes (hydrographic networks, watersheds, and reliefs). This quantitative measurement is used for the morphotectonical analysis of the Enfidha area (North-East of Tunisia) in the GIS environment and statistical platform. The Enfidha area is selected to analyze and identify neotectonic morphostructures on basis of the morphological evolution of the landscape. The coastal Enfidha plain is part of the Tunisian Sahel that is marked by its instability and frequent earthquakes that prove the presence of the recent deformation and active subsurface faults. This morphometric modeling in the geological investigation area reflects the morphotectonic spatial evolution in the Quaternary basins areas. Stream length (SL) proposed by Hack (1973) and denominated by Etchebehere et al. (2004) Revista do Instituto de Geociências USP, Série Científica, São Paulo 4(2):43–56 as the RDE index (Relation Declivity Extension) was used for application in the studies of neotectonic approach. RDE index is one of the morphotectonical indices that designates the tectonics anomalies in rivers. The variability in (RDE) values can indicate both a lithology resistance towards erosion and major active subsurface faults or low slope. Our geostatistical method is required to obtain RDE index maps based on lithological filtrations and value interpolations which are calculated in a drainage line network. This method calculates, measures, and validates spatial distribution of hack RDE index through a high statistical accuracy in a quantitative anomalies study. The RDE anomaly maps of the study area mirror the concurrence between anomaly zones, major active subsurface E-W faults, and local geological discontinuities related to neotectonical activities that affect the hydrographic network. This study proves that the RDE index can be especially used to detect the influence of active large-scale faults on the landscape evolution.     

Ground calcium carbonate (GCC) from the Barre de Ghomrassene in Southeast Tunisia: a suitable raw material for paint industry

The main scope of the present work is to investigate the potential of using ground calcium carbonate (GCC) from the Barre de Ghomrassene (BDG) in Southeast Tunisia in paint industry. In order to evaluate the performance of the material and the formulated paint films, representative raw specimens of main deposits of naturel GCCs in the Mediterranean basin and Middle East countries such as extra-white limestone from the Abiod Formation (Feriana region in West-Central Tunisia), A??gedi?i Formation (Ni?de Group, South Central Turkey), and Samalut Formation (Elminea, South Cairo, Egypt) were considered. Samples were ground to specific surface of about 3000 cm²/g and were subjected to detailed characterization including chemical and mineral composition, physical, and chromaticity characteristics. Results show that the GCC from the lower part of the Barre de Ghomrassene is, in most, dark and grainstone in texture, which limit its use in paint and coating application. Elsewhere, it is marked by high purity degree (generally more than 97% calcite); high lightness (more than 86.5, 95.2 in average) with relatively low chromaticity (a*?<?3.3, b*?<?9.1); low oil intake (17.4 g/100 GCC); very low electrolyte levels; good pH buffering (close to 9); accepted ranges of density and abrasion (2.65–2.7 and 10–18, respectively); good grindability; low levels of harmful components such as MgO, SiO₂, Fe₂O₃, and acid insoluble residue (less than 0.1% each); and improved rheological properties. The BDG seems to be a suitable filler for paint when mixed with water, styrene acrylic, and common additives. The formulated paint films meet all standard requirements, in that they have very good opacity, matt visual dualgloss 20/60°, high luminescence (L*?=?96.4), suitable hardness (145 s), good adhesion (B5), and sufficient impact resistance (1.5 kg m). The performances of these films are analogous to those based on Abiod and Samalut formations (natural carbonate), but they are slightly less lighter than those based on A??gedi?i Formation (metamorphic carbonate). Hence, the studied GCC can be used to substitute them in particular for local GCCs from the Abiod Formation, which are limited and over exploited.     

Identification of hazardous waste landfill site: a case study from Zanjan province, Iran

The study of landfill sites is one of the most important studies in landfill engineering, and the landfill site selection involves combination of engineering, science, and politics. This paper describes a comprehensive hazardous waste landfill site selection methodology with the combined utilization of geographic information system and multiple criteria analysis methods, as applied to the Zanjan province in Iran. The six main data categories that were used are geological/engineering geological, geomorphological, hydrological/hydrogeological, climatological, pedological, and social/economical criteria, which included 31 input layers in total. A suitability map for hazardous waste landfilling was prepared for study area with five classes from most suitable to completely unsuitable. Finally, out of the three sites, one site was selected which was chosen by the local authorities. Our work offers a comprehensive methodology and provides essential support for decision-makers in the assessment of hazardous waste management problems in Zanjan province in I.R. Iran and other developing cities in other countries.