Geochemistry and mineralogy of the Al-rich shale from Baluti formation,Iraqi Kurdistan region: implications for weathering and provenance

The mineralogical and geochemical characteristics of the Upper Triassic Baluti shale from the Northern Thrust Zone (Sararu section) and High Folded Zone (Sarki section) Kurdistan Region, Iraq, have been investigated to constrain their paleoweathering, provenance, tectonic setting, and depositional redox conditions. The clay mineral assemblages are dominated by kaolinite, illite, mixed layers illite/smectite at Sararu section, and illite > smectite with traces of kaolinite at Sarki. Illite, to be noted, is within the zone of diagenesis. The non-clay minerals are dominated by calcite with minor amounts of quartz and muscovite in Sararu shale; and are dominated by dolomite with amounts of calcite and quartz in Sarki shale. Baluti shale is classified as Al-rich based on major and minor elements. The chemical index of alteration (CIA) is significantly higher in the Sararu than the Sarki shales, suggesting more intense weathering of the Sararu than the Sarki shales. The index of compositional variability (ICV) of the Sararu shale is less than 1 (suggesting it is compositionally mature and was deposited in a tectonically quiescent setting). More than 1 for Sarki shales (suggest it is less mature and deposited in a tectonically active setting). Most shale of the Baluti plot parallel and along the A-K line in A-CN-K plots suggest intense chemical weathering (high CIA) without any clear-cut evidence of K-metasomatism. Clay mineral data, Al enrichment, CIA values, and A-CN-K plot suggest that the source area experienced high degree of chemical weathering under warm and humid conditions, especially in Sararu. Elemental ratios critical of provenance (La/Sc, Th/Sc, Th/Cr, Th/Co, Ce/Ce*_PN, Eu/Eu*_PN, and Eu/Eu*_CN) shows slight difference between the Sararu and Sarki shales; and the ratios are similar to fine fractions derived from the weathering of mostly felsic rocks. The Eu/Eu^* _CN, Th/Sc, and low K₂O/Al₂O₃ ratios of most shales suggest weathering from mostly a granodiorite source rather than a granite source, consistent with a source from old upper continental crust. Discrimination diagrams based on major and trace element content point to a role of the felsic-intermediate sources for the deposition of Baluti Formation, and probably mixed with mafic source rocks at Sararu section. The chondrite-normalized rare earth elements (REE) patterns are similar to those of PAAS, with light REE enrichment, a negative Eu anomaly, and almost flat heavy REE pattern similar to those of a source rock with felsic components. The source of sediments for the Baluti Formation was likely the Rutba Uplift and/or the plutonic-metamorphic complexes of the Arabian Shield located to the southwest of the basin; whereas the Sararu shale was affected by the mafic rocks of the Bitlis-Avroman-Bisitoun Ridge to the northeast of Arabian Plate. The tectonic discrimination diagrams, as well as critical trace and REE characteristic parameters imply rift and active setting for the depositional basin of the shale of Baluti Formation. The geochemical parameters such as U/Th, V/Cr, V/Sc, and Cu/Zn ratios indicate that these shales were deposited under oxic environment and also show that Sarki shale was deposited under more oxic environment than Sararu.     

Characterization of the Lebanese Jurassic–Cretaceous carbonate stratigraphic sequence: a geochemical approach

The Lebanese crustal segment is part of a much larger carbonate platform deposited along the northwestern margin of the Arabian Plate, in the eastern Mediterranean region. It is made up mainly of Jurassic–Cretaceous carbonate rocks. Most of this stratigraphic sequence is exposed in the Nahr Ibrahim canyon and surrounding areas in central Lebanon. The various formations, from the oldest unit (the Lower Jurassic Kesrouane Formation) to the Upper Cretaceous Chekka Formation, are made up of different types of carbonate rocks including micritic limestone, medium‐ to coarse‐grained dolostone, biomicritic (chalk), biosparrudite limestone, micritic dolostone, pelmicrite, marl and marly limestone. Results of this first chemical investigation on the Lebanese carbonate platform show that the micritic limestone of the Kesrouane Formation is relatively enriched in Ca, Na and Sc, and has low rare‐earth element (REE) contents. The marl units of the Hammana Formation are enriched in Al, Fe, K, Ti, Rb, Ga, Nb, U, Th and REE. The chalk of the Chekka Formation shows the highest phosphorus content. A significant increase in P and Sr contents with time (from the Lower Jurassic to the Upper Cretaceous carbonate units) characterizes the Lebanese sequence; this is interpreted to be related to a possible increase in continental weathering rates during the Mesozoic. Enrichment in Ni, Ti and Nb in some formations is interpreted to be linked to Mesozoic volcanism in central Lebanon. The Cretaceous formations are subdivided according to their REE patterns into two distinct groups: limestones (Mdairej, Sannine and Maameltain formations) which are depleted in REE; and marl/chalk (Hammana and Chekka formations) which are significantly enriched in REE. On several geochemical variation diagrams, such as the K–Ti–P triangular plot, the Lebanese Mesozoic carbonate formations are found to occupy distinct compositional fields. Thus, carbonate geochemistry could prove to be a powerful tool (especially when combined with petrographic data) in characterizing and correlating carbonate formations (chemical stratigraphy), particularly in regions where field evidence may be limited. Results of this study have significant implications for the entire carbonate platform that covers a large part of the eastern Mediterranean region. Copyright © 2002 John Wiley & Sons, Ltd.     

云南鲁史三合洞组地层时代讨论

云南兰坪盆地三合洞组的时代存在争议,有早古生代和中生代两种观点。本文通过对云南鲁史上三叠统三合洞组和挖鲁八组岩石地层、古生物化石、微体化石及碎屑锆石U-Pb年代学研究,认为三合洞组时代为晚三叠世。本区三合洞组生物碎屑灰岩、泥晶灰岩及白云质灰岩与挖鲁八组炭质板岩呈整合接触关系,与歪古村组砂质板岩呈逆断层接触关系,整体表现为倒转地层。挖鲁八组炭质板岩中采获叉皱海燕蛤、虚海燕蛤等晚三叠世化石,而三合洞组灰岩中的小欣德牙形刺、奥泽克刺、滑梯螺、长卵形槽花介等微体化石时代也为晚三叠世。笔者从挖鲁八组粉砂岩中获得碎屑锆石U-Pb年龄,其最小年龄为218 Ma,指示挖鲁八组的最晚沉积时代为晚三叠世。综合生物化石和同位素年代学资料,认为兰坪盆地三合洞组的时代为晚三叠世。     

Palynofacies and hydrocarbon generation potential of the upper Triassic Kurrachine Formation and lower part of the Baluti Formation, Mosul Block, Northwestern Iraq

Three exploration wells were selected near Mosul city (Az-29, Bm-15, and Kd-1) to study the palynozones and hydrocarbon generation potential of the Upper Triassic Baluti and Kurrachine Formations. This study was completed in two phases: The first was a study of palynofacies and their paleoenvironmental indications, degree of preservation, diversity of palynomorphs, and organic maturity of the rocks according to palynomorphs’ color using a refracted light microscope. More than 80 slides of organic matter were used for this study. Four palynofacies were tentatively recognized. (1) The first palynofacies is diagnostic of the Baluti Formation in the Az-29 and Kd-1 wells; (2) The second palynofacies appeared at different depths in the Kurrachine Formation in three wells. (3) The third was only found between the depths of 4,534 to 4,685 m in the well Az-29. (4) The fourth was only found between 3,500- and 3590-m depth in the well Bm-15. A distal coastal marine environment is suggested for the Baluti Formation and restricted lagoonal environment for the Kurrachine Formation. The second phase used organic geochemical analyses to confirm the suggested paleoenvironmental and hydrocarbon generation material. Three techniques were used, namely total organic carbon, pyrolysis, and pyrolysis gas chromatography, on more than 35 samples from different depths in three wells. The analyses proved that a sufficient quantity of organic matter occurs that and has suitable maturity for hydrocarbon generation potential of oil and gas.     

Biostratigraphy,Microfacies and Depositional Environment of the Sarvak Formation at the Pyun Anticline (Zagros Basin,Southwest of Iran)

The Sarvak Formation is a carbonate sequence of Late Albian–Early Turonian age in Zagros Basin in Iran. In this investigation, the Sarvak Formation at the Pyun Anticline section (Izeh Zone) has been studied. It consists of 797 m thick limestone which overlies the Kazhdumi Formation conformably and underlies the Gurpi Formation unconformably at the Pyun Anticline. A very rich fossil association (85 genera and 132 species) characterizes the Pyun section. Based on the stratigraphic distribution of diagnosed foraminifera, five biozones are established: 1, Muricohedbergella-Globigerinelloides sp. assemblage zone (Late Albian); 2, Praealveolina iberica-Chrysalidina gradata interval zone (Early Cenomanian); 3, Chrysalidina gradata-Cisalveolina fraasi (fallax) and C. lehneri interval zone (Middle Cenomanian); 4, C. fraasi (fallax) and C. lehneri-Praetaberina bingistani assemblage zone (Late Cenomanian); 5, Nezzazatinella picardi-Mangashtia- Dicyclina assemblage zone (Early Turonian). Based on the petrographic and sedimentological analyses, some 13 carbonate microfacies were identified. The investigated microfacies confirm a ramp-type paleoenvironment. These microfacies, from distal to proximal environments, consist of: MF1: planktonic foraminifera wackestone-packstone; MF2: Oligostegina planktonic foraminifera wackestone to packstone; MF3: planktonic-benthic foraminifers sponge spicules wackestone-packstone; MF4: rudist floatstone; MF5: rudist rudstone; MF6: bioclast intraclast grainstone; MF7: peloid intraclast grainstone; MF8: benthic foraminifers rudist grainstone-packstone; MF9: peloid bioclast grainstone-packstone; MF10: bioclast (benthic foraminifers) wackestone-packstone; MF11: peloid bioclast packstone; MF12: dacycladacea benthic foraminifera packstone-wackestone; MF13: miliolids wackestone-packstone.     

Sedimentology of the Baluti Formation in the Galley Derash,Amadiya, North Iraq: insight on carbonate turbidite facies and their depositional environmental

The Baluti Formation is exposed succession of the Rhaetian age (Upper Triassic). These strata are interpreted herein for the first time to redeposit in a deep marine setting (distally steepened carbonate ramp/medial to distal slope) on the northwestern margin of the Neo-Tethys. The Galley Derash section is apparently continuous with no evidence for either subaerial exposure or submarine erosion. The absence of erosional scours in the study area confirms emplacement of these strata below both fair-weather and storm wave base. Event beds, particularly those resulting from sediment gravity flows, dominate the Rhaetian interval. The Upper Rhaetian strata are primarily assigned to the Galley Derash Valley. It records an upward transition from moderate-scale, olistolith-bearing debris flow deposits (debrite) to medium-/thin-bedded turbidites remobilized as sediment slumps/slides. The succession is dominated by medium- to thin-bedded calcareous turbidites and hemipelagic suspension deposits. Very low fossil assemblages, particularly stromatolite fragments, and planktonic bivalves occur within some intervals in the section. Rapid and relatively continuous sedimentation is attested to by the thickness of the section, the abundance of calcareous turbidites, and the thin nature of the intercalated hemipelagic beds. Low content of badly preserved fossils and evidence of continuous and rapid sedimentation refer to alteration by tectonic disturbances or diagenesis. This makes the Baluti Beds as a supplementary section for the Rhaetian successions in Iraq.     

Hydrogeological characterization of a carbonate aquifer using geophysical and geochemical approach: case of the Krachoua Formation in Tataouine area,Southern Tunisia

An integrated hydrogeological investigation involving geological surface data, well data (lithostratigraphical and piezometric data) and the vertical electrical sounding (VES) method was carried out in Tataouine area, Southern Tunisia to characterize the hydrogeology and the geochemistry of the Krachoua Formation aquifer. The electrical data were used to differentiate lithostratigraphic units and characterize their hydrogeological potentialities. Major elements contents within groundwater samples were assessed and some plots and diagrams have been established in order to investigate the hydrochemical properties of this aquifer and the origin of its mineralization. The Krachoua aquifer exhibits a general drawdown of the piezometric level from 2004 to 2015 reflecting a dramatic decrease in groundwater resources due to increased groundwater abstraction during the last decades. Flow directions shows that the recharge of this aquifer considered as a free aquifer is directly ensured by rainfalls over the outcropping fractured limestones. The geometry of the Krachoua Formation aquifer is tectonically controlled and structured in horst and graben features that impacted greatly the hydrogeology and the hydrodynamics of the area. Subsequent thickness and facies variations within this aquifer influenced the reservoir quality and the groundwater flows. The increased values of salinity to the northwest of the study area seems to be mainly related to the dissolution of the Upper Liassic gypsum of Mestaoua Formation which outcrops widely and can be dissolute easily by meteoric water and contaminate the Krachoua aquifer. This fact is also supported by the sulfated and calci-magnesian chloride facies of this aquifer related to the dissolution of evaporitic rocks (gypsum, anhydrite, and halite). However low salinity values are recorded within the zone where these evaporitic rocks are relatively deep.     

Farmland expansion prediction at a pastoral village in northeastern China: a spatially explicit targeting approach

Farmland expansion is one of the main causes of steppe loss in northern China. However, an effective land-use change prediction approach has not been available. A spatially explicit approach designed for identifying the trend of farmland expansion at the village scale was provided here. The first probability estimate model was generated by indicator kriging to predict farmland expansion, and the second was generated using multilevel modeling techniques to identify the causal relationships of farmland expansion. The two models were integrated by using Bayesian inference to eliminate the disadvantages of the two modelings.     

西藏描勤——申扎地层分区二叠系敌布错组的建立及其特征

敌布错组为125万措勤区幅区域地质调查首次发现并建立的岩石地层单位.该组角度不整合于下二叠统下拉组之上,盛产冈瓦纳-华夏混合植物群化石,岩性组合呈现灰色复陆屑建造的特点,厚度大于830m.层型剖面位于西藏措勤县江让乡敌布错北缘(E84.46′,N30.51′).2001年夏经专家实地考查确认,该剖面已完全具备建组条件.此套岩石组合的发现为进一步完善冈底斯构造带古生代地层系统提供了新的资料.     

Hydrocarbon source rock potential evaluation of the Late Paleocene Patala Formation,Salt Range,Pakistan: Organic geochemical and palynofacies approach

Organic geochemical and palynofacies analyses were carried out on shale intervals of the Late Paleocene Patala Formation at Nammal Gorge Section, western Salt Range, Pakistan. The total organic carbon content and Rock-Eval pyrolysis results indicated that the formation is dominated by type II and type III kerogens. Rock-Eval \({T}_{\mathrm{max}}\) vs. hydrogen index (HI) and thermal alteration index indicated that the analysed shale intervals present in the formation are thermally mature. \(S_{1}\) and \(S_{2}\) yields showed poor source rock potential for the formation. Three palynofacies assemblages including palynofacies-1, palynofacies-2 and palynofacies-3 were identified, which are prone to dry gas, wet gas and oil generation, respectively. The palynofacies assessment revealed the presence of oil/gas and gas prone type II and type III kerogens in the formation and their deposition on proximal shelf with suboxic to anoxic conditions. The kerogen macerals are dominated by vitrinite and amorphinite with minor inertinite and liptinite. The kerogen macerals are of both marine and terrestrial origin, deposited on a shallow shelf. Overall, the dark black carbonaceous shales present within the formation act as a source rock for hydrocarbons with poor-to-moderate source rock quality, while the grey shales act as a poor source rock for hydrocarbon generation.     

西藏措勤—申扎地层分区二叠系敌布错组的建立及其特征

敌布错组为1∶25万措勤区幅区域地质调查首次发现并建立的岩石地层单位。该组角度不整合于下二叠统下拉组之上,盛产冈瓦纳—华夏混合植物群化石,岩性组合呈现灰色复陆屑建造的特点,厚度大于830m。层型剖面位于西藏措勤县江让乡敌布错北缘(E84°46',N30°51')。2001年夏经专家实地考查确认,该剖面已完全具备建组条件。此套岩石组合的发现为进一步完善冈底斯构造带古生代地层系统提供了新的资料。     

Evaluating the impacts of watershed management on runoff storage and peak flow in Gav-Darreh watershed,Kurdistan, Iran

Recently, water and soil resource competition and environmental degradation due to inadequate management practices have been increased and pose difficult problems for resource managers. Numerous watershed practices currently being implemented for runoff storage and flood control purposes have improved hydrologic conditions in watersheds and enhanced the establishment of riparian vegetation. The assessment of proposed management options increases management efficiency. The purpose of this study is to assess the impact of watershed managements on runoff storage and peak flow, and determine the land use and cover dynamics that it has induced in Gav-Darreh watershed, Kurdistan, Iran. The watershed area is 6.27 km² which has been subjected to non-structural and structural measures. The implemented management practices and its impact on land use and cover were assessed by integrating field observation and geographic information systems (GIS). The data were used to derive the volume of retained water and determine reduction in peak flow. The hydrology of the watershed was modeled using the Hydrologic Engineering Center–Hydrologic Modeling System (HEC–HMS) model, and watershed changes were quantified through field work. Actual storms were used to calibrate and validate HEC–HMS rainfall–runoff model. The calibrated HEC–HMS model was used to simulate pre- and post-management conditions in the watershed. The results derived from field observation and HEC–HMS model showed that the practices had significant impacts on the runoff storage and peak flow reduction.     

Discussion: Structural and stratigraphic problems of the Argylla Formation near Mary Kathleen,Queensland

Circumstantial evidence indicates that Gaussberg, an isolated, 370 m high volcanic cone on the Antarctic coast at 57°S, 89°E, is the product of subglacial eruption. The vesicular, highly potassic leucitite, of which Gaussberg is composed, has been dated by K‐Ar and fission‐track methods, the former being applied to leucite concentrates, the latter to glassy leucitite from the ropy‐textured, outer rind of a pillow‐like structure. The K‐Ar geochronology yields an average date of 56 000 ± 5000 years, jwhich is interpreted as defining the time of Gaussberg's formation. The fission‐track work yields a less precise date, which supports the K‐Ar age estimate. These new age determinations indicate that previously published K‐Ar age determinations of 20 Ma and 9 Ma for Gaussberg should be rejected.     

孤北-桩海地区东营组层序地层对比及层序地层格架

笔者通过大量的钻井岩芯观察、地震剖面解释、测井资料分析,详细研究了东营组层序划分和特征,共划分出了两个长期旋回,4个中期旋回。在层序划分的基础上,进行了全区的地层对比,各层序在不同地区发育程度不同是由于当时的古地理背景不同以及后期构造抬升剥蚀程度不同所造成的。分别建立了东西和南北向的层序地层格架模型,不同时期各中期旋回在不同地区有不同的发育特征。     

Iron mineralization in the Garagu Formation of Gara Mountain,Duhok Governorate,Kurdistan, NE Iraq: geochemistry,mineralogy and origin

The iron mineralization is hosted in carbonate beds of the Garagu Formation (Early Cretaceous) at Gara Mountain, Duhok Governorate, Kurdistan Region, NE Iraq. The Garagu Formation is composed of a series of limestone and siltstone beds with iron-rich beds in the middle part. The iron-rich limestones are iron-rich oolitic grainstone and bioclastic wackestone with hematite and goethite minerals. Geochemical results drawn from this study indicate that the percentage of iron in these beds reaches 19.73 %. Moreover, petrographical investigation of thin and polished sections reveals the presence of different types of fossils, indicating an open marine interior platform depositional environment. Different iron minerals, including hematite, goethite, siderite, pyrite and magnetite, were identified in the sections, and their geneses were related to syngenetic and diagenetic processes. The geochemical distribution of major and trace elements, as well as the V/Ni, V/(V+Ni), V/Cr and Sr/Ba ratios, indicates a reducing environment during the precipitation of carbonate sediments and a subsequent oxidizing condition during the concentration of iron minerals via diagenesis.