Atmospheric circulation epochs and climate changes

The atmospheric circulation studies allow climate changes to be diagnosed and forecasted. Variations in occurrence frequencies of the atmospheric circulation forms W, E, and C (by the Vangengeim classification) and Z, M ₁, and M ₂ (by the Girs classification), which characterize climatic conditions in most of the Northern Hemisphere, are analyzed over a period of more than 100 years. It is shown that the occurrence frequency of the forms W, C, and M ₁ continually decreased, while that of the forms E and Z increased, which indicates a significant change in atmospheric circulation in the Northern Hemisphere during the last century. The occurrence frequency of the forms C and Z demonstrates specific features at inter-decade time scales. Correlations are found between accumulated sums of anomalies of occurrence frequencies of the atmospheric circulation forms C, (W + E), Z, and (M ₁ + M ₂) and inter-decade variations of the Earth’s rotation. The causes of these relationships are discussed along with possibilities of their use for diagnosis of climatic variations in the Northern Hemisphere.     

Comprehensive modeling of monthly mean soil temperature using multivariate adaptive regression splines and support vector machine

Soil temperature (T _s) and its thermal regime are the most important factors in plant growth, biological activities, and water movement in soil. Due to scarcity of the T _s data, estimation of soil temperature is an important issue in different fields of sciences. The main objective of the present study is to investigate the accuracy of multivariate adaptive regression splines (MARS) and support vector machine (SVM) methods for estimating the T _s. For this aim, the monthly mean data of the T _s (at depths of 5, 10, 50, and 100 cm) and meteorological parameters of 30 synoptic stations in Iran were utilized. To develop the MARS and SVM models, various combinations of minimum, maximum, and mean air temperatures (T _min, T _max, T); actual and maximum possible sunshine duration; sunshine duration ratio (n, N, n/N); actual, net, and extraterrestrial solar radiation data (R _s, R _n, R _a); precipitation (P); relative humidity (RH); wind speed at 2 m height (u ₂); and water vapor pressure (V_p) were used as input variables. Three error statistics including root-mean-square-error (RMSE), mean absolute error (MAE), and determination coefficient (R ²) were used to check the performance of MARS and SVM models. The results indicated that the MARS was superior to the SVM at different depths. In the test and validation phases, the most accurate estimations for the MARS were obtained at the depth of 10 cm for T _max, T _min, T inputs (RMSE = 0.71 °C, MAE = 0.54 °C, and R ² = 0.995) and for RH, V _p, P, and u ₂ inputs (RMSE = 0.80 °C, MAE = 0.61 °C, and R ² = 0.996), respectively.     

Multivariate drought frequency estimation using copula method in Southwest China

This study reveals the impacts of climatic variable trends on drought severity in Xinjiang, China. Four drought indices, including the self-calibrating Palmer drought severity index (sc-PDSI), Erinç’s index (I _m), Sahin’s index (I _sh), and UNEP aridity index (AI), were used to compare drought severity. The ensemble empirical mode decomposition and the modified Mann-Kendall trend test were applied to analyze the nonlinear components and trends of the climatic variable and drought indices. Four and six climatic scenarios were generated in sc-PDSI, I _m, I _sh, and AI with different combinations of the observed and detrended climatic variables, respectively. In Xinjiang, generally increasing trends in minimal, average, and maximal air temperature (T _min, T _ave, T _max) and precipitation (P) were found, whereas a decreasing trend in wind speed at 2 m height (U ₂) was observed. There were significantly increasing trends in all of the four studied drought indices. Drought relief was more obvious in northern Xinjiang than in southern Xinjiang. The strong influences of increased P on drought relief and the weak influences of increased T _min, T _ave, and T _max on drought aggravation were shown by comparing four drought indices under different climate scenarios. Decreased U ₂ had a weak influence on drought, as shown by the AI in different climate scenarios. The weak influences of T and U ₂ were considered to be masked by the strong influences of P on droughts. Droughts were expected to be more severe if P did not increase, but were likely milder without an increase in air temperature and with a decrease in U ₂.     

River Runoff Effects on the Coastal Water Transparency in the Western Black Sea

Using the data of long-term observations of the Secchi disk visibility depth and water salinity (1947-2000) and satellite monitoring of chlorophyll a concentration (1978-1986), their seasonal spatial distributions and intraannual variability in the coastal waters of the western Black Sea are considered. The estimates of seasonal variations are obtained for the coastal zone of the sea. A good agreement is demonstrated between intraannual variations in the salinity of transformed river water, chlorophyll a concentration, and transparency in the areas where these waters propagate. We studied the effects of the Danube River runoff and transformed river water on the phytoplankton development and chlorophyll a concentration which largely define water transparency.     

A compact form for the analytic description of temperature dependence of saturation vapor pressure over plane surfaces of water and ice

A possibility is studied of extending the range of action of the simple three-parameter formula (ITS-90 scale) proposed in the previous work of the author [2] for the dependence of saturation vapor pressure E on temperature T within the range of 250 to 490 K. The results demonstrated that the dependence ln[E(T)/E(T _bas)] = (T - T _bas)[A - B(T - T _bas) + C(T - T _bas)²]/T with four sets of coefficients A, B, and C obtained using one base temperature Tbas equal to the temperature of triple point of water T _t = 273.16 K and two additional base values T _bas2 = 473.16 K and T _bas3 = 623.16 K makes it possible to approximate rather accurately the initial experimental and computed data in the temperature range from the point of homogeneous freezing of 235 K to the critical temperature of 647 K for liquid water and from 193 K to T _t for ice. A procedure used for obtaining the inverse function T(E) by solving the third-degree algebraic equation is validated. A hypothesis is proposed for the physical substantiation of additional base points in the form of “a noticeable appearance of dimers at the point T _bas2 and their 100% concentration at the temperature T _bas3.”     

Characteristics of the precipitation recycling ratio and its relationship with regional precipitation in China

A dynamic recycling model (DRM) with an analytical moisture trajectory tracking method, together with Japan Meteorological Agency 25-year reanalysis data, is used to study the regional precipitation recycling process across China, by calculating the regional recycling ratio (ρ _r ) at the daily time scale during 1979–2010. The distribution of ρ _r shows that, in western China, especially the Tibetan Plateau and its surrounding areas, precipitation is strongly dependent on the recycling process associated with regional evaporation. In Southeast China, however, the contribution from the recycling processes is much smaller due to the influence of the summer monsoon. A precipitation threshold value of about 4 mm/day is obtained from detailed analysis of both extreme and all-range ρ _r years. According to this threshold, China is classified into three types of sub-regions: low-precipitation sub-regions (mainly in the northwest), high-precipitation sub-regions (mainly in the south), and medium-precipitation sub-regions (mainly in the northeast). It is found that ρ _r correlates positively with precipitation, as well as convective precipitation (P _CP) and large-scale precipitation (P _LP) in the low-precipitation sub-regions. However, negative ρ _r ?～?P _LP correlations are found in the high-precipitation sub-regions and nonsignificant correlations exist in the medium-precipitation sub-regions. As P _CP is mainly locally generated due to mid-latitude mesoscale systems and the cumulus parameterization used in producing the reanalysis, the recycling ratio positively correlates to the ratio P _CP/P _LP in almost all sub-regions, particularly in the Tibetan Plateau and its surrounding areas. The correlation between radiation flux and ρ _r suggests more net radiation supports more evaporation and higher ρ _r , especially in the high-precipitation sub-regions. The influence of clouds on shortwave radiation is crucial, since evaporation is suppressed when the amount of cloudiness increases, especially in the high-precipitation sub-regions. Together with the consideration of soil moisture, it can be inferred that limited soil moisture inhibits evaporation in the low-precipitation sub-regions, while the energy or radiation is the dominant factor controlling evaporation in the high-precipitation sub-regions.     

Long-term variation of rainfall erosivity in Calabria (Southern Italy)

The changes in rainfall erosivity have been investigated using the rainfall erosivity factor (R) proposed for USLE by Wischmeier and Smith (R _W-S ) and some simplified indexes (the Fournier index modified by Arnoldus, F, a regional index spatial independent, R _Fr , and a regional index spatial dependent, R _Fs ) estimated by indirect approaches. The analysis has been carried out over 48 rainfall stations located in Calabria (Southern Italy) using data collected in the period 1936–2012 and divided in three sub-periods. The series of the erosivity indexes and of some precipitation variables have been analyzed for evidence of trends using standard methods. The simplified indexes suggested a general underestimation of the rainfall erosivity with respect to R _W-S . The mean underestimation ranged between 23 and 54 % for R _Fr and from 10 to 15 % for R _Fs . Both the sign and the magnitude of the trends were different for the different stations depending on the variable and sub-period considered. In general, the erosivity increased during the period 1936–1955 (1^st sub-period) and during the more recent sub-period (1992–2012, 3^rd sub-period), whereas it decreased during 1958–1977 (2^nd sub-period). The evidence of trends was generally higher for R _W-S than for R _Fr and R _Fs . Focusing on the most recent sub-period (3^rd sub-period), all the variables analyzed showed mainly increasing trends but with different magnitude. More particularly, R _W-S showed a mean increment of 29 %; F, R _Fr and R _Fs increased by 11, 15 and 18 %, respectively; the maximum intensity of 0.5-h precipitation increased by 5 %; and the annual precipitation increased by 22 %. Consequently, it remains difficult to define which precipitation variable plays the dominant role in the temporal variation of rainfall erosivity in the region. However, the overall results suggest that the indexes estimated by indirect procedures (F, R _Fr , and R _Fs ) should be used with caution for climate change analysis, despite they are used for practical purposes considering they are based on easily available information.     

Relationship Between Fine-Particle Pollution and the Urban Heat Island in Beijing,China: Observational Evidence

Urbanization has led to a significant urban heat island (UHI) effect in Beijing in recent years. At the same time, air pollution caused by a large number of fine particles significantly influences the atmospheric environment, urban climate, and human health. The distribution of fine particulate matter (PM_2.5) concentration and its relationship with the UHI effect in the Beijing area are analyzed based on station-observed hourly data from 2012 to 2016. We conclude that, (1) in the last five years, the surface concentrations of PM_2.5 averaged for urban and rural sites in and around Beijing are 63.2 and 40.7 µg m^?3, respectively, with significant differences between urban and rural sites (ΔPM_2.5) at the seasonal, monthly and daily scales observed; (2) there is a large correlation between ΔPM_2.5 and the UHI intensity defined as the differences in the mean (ΔT_ave), minimum (ΔT_min), and maximum (ΔT_max) temperatures between urban and rural sites. The correlation between ΔPM_2.5 and ΔT_min (ΔT_max) is the highest (lowest); (3) a Granger causality analysis further shows that ΔPM_2.5 and ΔT_min are most correlated for a lag of 1–2 days, while the correlation between ΔPM_2.5 and ΔT_ave is lower; there is no causal relationship between ΔPM_2.5 and ΔT_max; (4) a case analysis shows that downwards shortwave radiation at the surface decreases with an increase in PM_2.5 concentration, leading to a weaker UHI intensity during the daytime. During the night, the outgoing longwave radiation from the surface decreases due to the presence of daytime pollutants, the net effect of which is a slower cooling rate during the night in cities than in the suburbs, leading to a larger ΔT_min.     

Semi-idealized modeling of lightning initiation related to vertical air motion and cloud microphysics

A three-dimensional charge–discharge numerical model is used, in a semi-idealized mode, to simulate a thunder-storm cell. Characteristics of the graupel microphysics and vertical air motion associated with the lightning initiation are revealed, which could be useful in retrieving charge strength during lightning when no charge–discharge model is available. The results show that the vertical air motion at the lightning initiation sites (W_ini) has a cubic polynomial correlation with the maximum updraft of the storm cell (W_cell-max), with the adjusted regression coefficient R² of approximately 0.97. Meanwhile, the graupel mixing ratio at the lightning initiation sites (q_g-ini) has a linear correlation with the maximum graupel mixing ratio of the storm cell (q_g-cell-max) and the initiation height (z_ini), with the coefficients being 0.86 and 0.85, respectively. These linear correlations are more significant during the middle and late stages of lightning activity. A zero-charge zone, namely, the area with very low net charge density between the main positive and negative charge layers, appears above the area of q_g-cell-max and below the upper edge of the graupel region, and is found to be an important area for lightning initiation. Inside the zero-charge zone, large electric intensity forms, and the ratio of q_ice (ice crystal mixing ratio) to q_g (graupel mixing ratio) illustrates an exponential relationship to q_g-ini. These relationships provide valuable clues to more accurately locating the high-risk area of lightning initiation in thunderstorms when only dual-polarization radar data or outputs from numerical models without charging/discharging schemes are available. The results can also help understand the environmental conditions at lightning initiation sites.     

Formulation of stability-dependent empirical relations for turbulent intensities from surface layer turbulence measurements for dispersion parameterization in a lagrangian particle dispersion model

Season- and stability-dependent turbulence intensity (σ _u /u _*, σ _v /u _*, σ _w /u _*) relationships are derived from experimental turbulence measurements following surface layer scaling and local stability at the tropical coastal site Kalpakkam, India for atmospheric dispersion parameterization. Turbulence wind components (u′, v′, w′) measured with fast response UltraSonic Anemometers during an intense observation campaign for wind field modeling called Round Robin Exercise are used to formulate the flux–profile relationships using surface layer similarity theory and Fast Fourier Transform technique. The new relationships (modified Hanna scheme) are incorporated in a Lagrangian Particle Dispersion model FLEXPART-WRF and tested by conducting simulations for a field tracer dispersion experiment at Kalpakkam. Plume dispersion analysis of a ground level hypothetical release indicated that the new turbulent intensity formulations provide slightly higher diffusivity across the plume relative to the original Hanna scheme. The new formulations for σ _u , σ _v , σ _w are found to give better agreement with observed turbulent intensities during both stable and unstable conditions under various seasonal meteorological conditions. The simulated concentrations using the two methods are compared with those obtained from a classical Gaussian model and the observed SF₆ concentration. It has been found that the new relationships provide comparatively higher diffusion across the plume relative to the model default Hanna scheme and provide downwind concentration results in better agreement with observations.     

Effect of solubility limitation on hygroscopic growth and cloud drop activation of SOA particles produced from traffic exhausts

Hygroscopicity measurements of secondary organic aerosol (SOA) particles often show inconsistent results between the supersaturated and subsaturated regimes, with higher activity as cloud condensation nucleus (CCN) than indicated by hygroscopic growth. In this study, we have investigated the discrepancy between the two regimes in the Lund University (LU) smog chamber. Various anthropogenic SOA were produced from mixtures of different precursors: anthropogenic light aromatic precursors (toluene and m-xylene), exhaust from a diesel passenger vehicle spiked with the light aromatic precursors, and exhaust from two different gasoline-powered passenger vehicles. Three types of seed particles were used: soot aggregates from a diesel vehicle, soot aggregates from a flame soot generator and ammonium sulphate (AS) particles. The hygroscopicity of seed particles with condensed, photochemically produced, anthropogenic SOA was investigated with respect to critical supersaturation (s_c) and hygroscopic growth factor (gf) at 90% relative humidity. The hygroscopicity parameter κ was calculated for the two regimes: κ_sc and κ_gf, from measurements of s_c and gf, respectively. The two κ showed significant discrepancies, with a κ_gf /κ_sc ratio closest to one for the gasoline experiments with ammonium sulphate seed and lower for the soot seed experiments. Empirical observations of s_c and gf were compared to theoretical predictions, using modified Köhler theory where water solubility limitations were taken into account. The results indicate that the inconsistency between measurements in the subsaturated and supersaturated regimes may be explained by part of the organic material in the particles produced from anthropogenic precursors having a limited solubility in water.     

Effects of optimized root water uptake parameterization schemes on water and heat flux simulation in a maize agroecosystem

As root water uptake (RWU) is an important link in the water and heat exchange between plants and ambient air, improving its parameterization is key to enhancing the performance of land surface model simulations. Although different types of RWU functions have been adopted in land surface models, there is no evidence as to which scheme most applicable to maize farmland ecosystems. Based on the 2007–09 data collected at the farmland ecosystem field station in Jinzhou, the RWU function in the Common Land Model (CoLM) was optimized with scheme options in light of factors determining whether roots absorb water from a certain soil layer (W_x) and whether the baseline cumulative root efficiency required for maximum plant transpiration (W_c) is reached. The sensibility of the parameters of the optimization scheme was investigated, and then the effects of the optimized RWU function on water and heat flux simulation were evaluated. The results indicate that the model simulation was not sensitive to W_x but was significantly impacted by W_c. With the original model, soil humidity was somewhat underestimated for precipitation-free days; soil temperature was simulated with obvious interannual and seasonal differences and remarkable underestimations for the maize late-growth stage; and sensible and latent heat fluxes were overestimated and underestimated, respectively, for years with relatively less precipitation, and both were simulated with high accuracy for years with relatively more precipitation. The optimized RWU process resulted in a significant improvement of CoLM’s performance in simulating soil humidity, temperature, sensible heat, and latent heat, for dry years. In conclusion, the optimized RWU scheme available for the CoLM model is applicable to the simulation of water and heat flux for maize farmland ecosystems in arid areas.     

Analysis of photosynthetically active radiation and applied parameterization model for estimating of PAR in the North China Plain

As photosynthetically active radiation (PAR) variability and PAR estimating methods play an important role in climate change and ecological process research, PAR variation trends and broadband global solar radiation (R _s ) ratios (PAR/R _s ) in the North China Plain (NCP) are examined using in situ PAR and R _s observed data for 2005 to 2011. The annual average PAR value found in the NCP is 22.9 mol m^?2 d^?1. The highest and lowest values were recorded at Changwu and Luancheng sites, respectively. The highest PAR/R _s value was found in Jiaozhouwan due to large water vapor volumes present in this area. PAR/R _s levels have increased in the NCP due to a decrease in fine aerosols and increase in water vapor concentration. From these analysis results, a parameterization model that can be applied to all sky conditions was checked. Empirical estimation model comparisons for obtaining PAR values indicate that model was least accurate when R _s was used independently. When the model included R _s, the clearness index (K _s) and the solar zenith angle, the model estimated PAR values with acceptable accuracy. A parameterization model was constructed by considering K _s and attenuation factors of PAR under clear weather conditions (ρ _clear). The improved parameterization model more accurately predicts values for local sites and for various observation sites.     

On the problem of velocity of long continuous waves in overland flows

The velocity of one-dimensional long continuous wave is computed from the condition of continuity of water both with its variable and constant discharge along the way passing through the control volume of water moving with the velocity V _W . The wave stability on the free surface of an overland flow is analyzed.     

Raindrop Size Distribution Parameters Retrieved from Guangzhou S-band Polarimetric Radar Observations

According to the statistical shape–slope (μ–Λ) relationship observed for the first time by several 2D-Video-Distrometers (2DVD) in southern China, a constrained gamma (C-G) model was proposed for the retrieval of rain drop size distributions (DSDs) from Guangzhou S-band polarimetric radar observations. Two typical precipitation processes were selected to verify the accuracy of the retrieval scheme. The μ–Λ relationship: Λ = 0.0241μ² + 0.867μ + 2.453 was obtained based on the 2DVD observation results from at Huizhou Longmen station, which is a very representative location in the area. Relying on the Guangzhou polarimetric radar measurements of radar reflectivity (Z_HH) and differential reflectivity (Z_DR), the gamma (Γ) size distribution parameters (N₀, μ, and Λ) can be retrieved by the C-G model retrieval scheme. The results show that the Guangzhou polarimetric radar retrievals of DSDs were close to the 2DVD observations at Guangzhou Maofengshan station. The rain rate, mass mean diameter, and normalized intercept parameter of radar retrievals were in good agreement with the 2DVD observations, and the relative errors were less than 10%. The overall accuracy of the retrieval scheme was high. The retrieval scheme has established the relationship between the polarimetric radar measurements and gamma size distribution parameters. It will be helpful to in-depth research and application of the dual-polarization radar data in microphysical precipitation processes analysis, as well as convection-resolved numerical model data assimilation and prediction effect evaluation.     

Estimation of ground heat flux from soil temperature over a bare soil

Ground soil heat flux, G ₀, is a difficult-to-measure but important component of the surface energy budget. Over the past years, many methods were proposed to estimate G ₀; however, the application of these methods was seldom validated and assessed under different weather conditions. In this study, three popular models (force-restore, conduction-convection, and harmonic) and one widely used method (plate calorimetric), which had well performance in publications, were investigated using field data to estimate daily G ₀ on clear, cloudy, and rainy days, while the gradient calorimetric method was regarded as the reference for assessing the accuracy. The results showed that harmonic model was well reproducing the G ₀ curve for clear days, but it yielded large errors on cloudy and rainy days. The force-restore model worked well only under rainfall condition, but it was poor to estimate G ₀ under rain-free conditions. On the contrary, the conduction-convection model was acceptable to determine G ₀ under rain-free conditions, but it generated large errors on rainfall days. More importantly, the plate calorimetric method was the best to estimate G ₀ under different weather conditions compared with the three models, but the performance of this method is affected by the placement depth of the heat flux plate. As a result, the heat flux plate was recommended to be buried as close as possible to the surface under clear condition. But under cloudy and rainy conditions, the plate placed at depth of around 0.075 m yielded G ₀ well. Overall, the findings of this paper provide guidelines to acquire more accurate estimation of G ₀ under different weather conditions, which could improve the surface energy balance in field.     

New alternatives for reference evapotranspiration estimation in West Africa using limited weather data and ancillary data supply strategies.

Accurate estimation of reference evapotranspiration (ET ₀ ) is essential for the computation of crop water requirements, irrigation scheduling, and water resources management. In this context, having a battery of alternative local calibrated ET ₀ estimation methods is of great interest for any irrigation advisory service. The development of irrigation advisory services will be a major breakthrough for West African agriculture. In the case of many West African countries, the high number of meteorological inputs required by the Penman-Monteith equation has been indicated as constraining. The present paper investigates for the first time in Ghana, the estimation ability of artificial intelligence-based models (Artificial Neural Networks (ANNs) and Gene Expression Programing (GEPs)), and ancillary/external approaches for modeling reference evapotranspiration (ET ₀ ) using limited weather data. According to the results of this study, GEPs have emerged as a very interesting alternative for ET ₀ estimation at all the locations of Ghana which have been evaluated in this study under different scenarios of meteorological data availability. The adoption of ancillary/external approaches has been also successful, moreover in the southern locations. The interesting results obtained in this study using GEPs and some ancillary approaches could be a reference for future studies about ET ₀ estimation in West Africa.     

Modeling monthly meteorological and agronomic frost days,based on minimum air temperature,in Center-Southern Brazil

Although Brazil is predominantly a tropical country, frosts are observed with relative high frequency in the Center-Southern states of the country, affecting mainly agriculture, forestry, and human activities. Therefore, information about the frost climatology is of high importance for planning of these activities. Based on that, the aims of the present study were to develop monthly meteorological (F _MET) and agronomic (F _AGR) frost day models, based on minimum shelter air temperature (T _MN), in order to characterize the temporal and spatial frost days variability in Center-Southern Brazil. Daily minimum air temperature data from 244 weather stations distributed across the study area were used, being 195 for developing the models and 49 for validating them. Multivariate regression models were obtained to estimate the monthly T _MN, once the frost day models were based on this variable. All T _MN regression models were statistically significant (p < 0.001), presenting adjusted R ² between 0.69 and 0.90. Center-Southern Brazil is mainly hit by frosts from mid-fall (April) to mid-spring (October). The period from November to March is considered as frost-free, being very rare a frost day within that period. Monthly F _MET and F _AGR presented significant sigmoidal relationships with T _MN (p < 0.0001), with adjusted R ² above of 0.82. The residuals of the frost day models were random, which means that the sigmoidal models performed quite well for interpreting the frost day variability throughout the study area. The highlands of Santa Catarina, Rio Grande do Sul, São Paulo, and Minas Gerais had in average more than 25 and 13 frosts per year, respectively, for F _MET and F _AGR. The F _MET and F _AGR maps developed in this study for Center-Southern Brazil is a useful tool for farmers, foresters, and researchers, since they contribute to reduce frost spatial and temporal uncertainty, helping in planning project for strategic purposes. Furthermore, the monthly F _MET and F _AGR maps for this Brazilian region are the first zoning of these variables for the country.     

Uncertainty of global summer precipitation in the CMIP5 models: a comparison between high-resolution and low-resolution models

Worldwide, the majority of rapidly growing neighborhoods are found in the Global South. They often exhibit different building construction and development patterns than the Global North, and urban climate research in many such neighborhoods has to date been sparse. This study presents local-scale observations of net radiation (Q _* ) and sensible heat flux (Q _H ) from a lightweight low-rise neighborhood in the desert climate of Andacollo, Chile, and compares observations with results from a process-based urban energy-balance model (TUF3D) and a local-scale empirical model (LUMPS) for a 14-day period in autumn 2009. This is a unique neighborhood-climate combination in the urban energy-balance literature, and results show good agreement between observations and models for Q _* and Q _H . The unmeasured latent heat flux (Q _E ) is modeled with an updated version of TUF3D and two versions of LUMPS (a forward and inverse application). Both LUMPS implementations predict slightly higher Q _E than TUF3D, which may indicate a bias in LUMPS parameters towards mid-latitude, non-desert climates. Overall, the energy balance is dominated by sensible and storage heat fluxes with mean daytime Bowen ratios of 2.57 (observed Q _H /LUMPS Q _E )–3.46 (TUF3D). Storage heat flux (ΔQ _S ) is modeled with TUF3D, the empirical objective hysteresis model (OHM), and the inverse LUMPS implementation. Agreement between models is generally good; the OHM-predicted diurnal cycle deviates somewhat relative to the other two models, likely because OHM coefficients are not specified for the roof and wall construction materials found in this neighborhood. New facet-scale and local-scale OHM coefficients are developed based on modeled ΔQ _S and observed Q _* . Coefficients in the empirical models OHM and LUMPS are derived from observations in primarily non-desert climates in European/North American neighborhoods and must be updated as measurements in lightweight low-rise (and other) neighborhoods in various climates become available.     

Detection of nitric acid (HNO<Subscript>3</Subscript>) in the atmosphere using the LOPAP technique

A new instrument (LOPAP: LOng Path liquid Absorption Photometer) for the sensitive detection of nitric acid (HNO₃) in the atmosphere is described. HNO₃ is sampled in a temperature controlled stripping coil mounted in an external sampling module to minimize sampling artefacts in sampling lines. After conversion into a strongly absorbing dye, HNO₃ is detected in long path absorption in special Teflon® AF 2400 tubes used as liquid core wave guides. For the correction of some interferences, due to for example HONO and particle nitrate, two channels are used in series. The interferences from several potential interfering compounds including particle nitrate were quantified in the laboratory and in a large outdoor simulation chamber. With the exception of the interference caused by N₂O₅, which is quantitatively measured by the instrument, all tested interferences can be corrected under atmospheric conditions. Thus, in the instrument only the sum of N(V) from HNO₃ and N₂O₅ is determined, which is expected to be a common problem of wet chemical HNO₃ instruments. The instrument has a detection limit of 5–30 pptv for a time response of 6–2 min, respectively and was validated against the FTIR technique in a large outdoor simulation chamber. In addition, the applicability of the instrument was demonstrated in a field campaign.