A 300 year record of environmental change from Lake Tuborg, Ellesmere Island, Nunavut, Canada

Lamination thickness measurements in sediments from Lake Tuborg, northern Ellesmere Island, Canada document an increase in high-energy hydrologic discharge events from ∼1865 to 1962. The timing of these events corresponds with evidence for an increase in the amount of melt on the adjacent Agassiz Ice Cap, as recorded in ice cores. There appears to have been a non-linear change in depositional energy resulting from a dramatic increase in Agassiz meltwater discharge, particularly after ∼1908. A strong correlation between the Lake Tuborg varve thickness record, the amount of melting on the Agassiz Ice Cap and Eureka 900 mb air temperature records suggests that changes in the height of the freezing level in the atmosphere have affected the extent of summer melting on the Agassiz Ice Cap, leading to high volume discharge events and associated sediment flux to Lake Tuborg.     

A diatom record of recent environmental change in Lake Duluti, northern Tanzania

Lake Duluti is a small, topographically closed crater lake located on the flanks of Mt Meru, northern Tanzania. Analyses of diatoms in three short sediment cores and four modern samples from Lake Duluti were used to infer past environmental changes. ²¹⁰Pb and ¹³⁷Cs activity profiles combined with AMS ¹⁴C dates provide the chronological framework. Weak agreement between the ²¹⁰Pb and ¹⁴C records, together with dating uncertainty, precludes construction of precise age models. The modern diatom flora, from plankton and three periphytic habitats, is dominated by Aulacoseira ambigua (Grunow) Simonsen, Gomphonema parvulum (Kützing) Grunow and Nitzschia amphibia Grunow. All three cores display similar stratigraphic succession, but the relative ratio of habitats represented by the diatoms varies substantially between cores. Diatoms indicate that the oldest part of the record is characterized by relatively low lake level and swampy vegetation. In the late nineteenth or early twentieth century there was a rapid lake level rise and the swamp turned into an open-water lake. High lake levels have prevailed since that time.     

A multi-proxy holocene record of environmental change fromthe sediments of Skinny Lake, Iskut region, northern British Columbia,Canada

A stratigraphic record from a lake in the Central Plateau Regionof northern British Columbia reveals changes in environment and inferredclimate during the Holocene. Upon deglaciation (ca. 11500 BP), Skinny Lakebecame an embayment of an ice-dammed lake. High clastic sedimentationrates, an unstable landscape, and cool, possibly wet conditions likelypersisted until the early Holocene (ca. 9000 BP). From ca. 9000–8300 BPdeclining lake levels coupled with warm and dry conditions resulted in theformation of a prominent marl bed. A colonizing shrub and herb assemblagepersisted from 9000 BP until about 8300 BP when it was replaced by a spruce(Picea) and subalpine fir (Abieslasiocarpa) forest under slightly cooler and moister conditions. Themiddle Holocene was warmer-than-present, however, decreasingtemperature and increasing precipitation trends characterize the period fromca. 6000 BP–3000 BP. The transition to modern climate at 3000 BP isevident primarily in the lithostratigraphic record and corresponds with theinitiation of the Tiedemann glacial advance (ca. 3300 BP) in thesouth-coastal mountains of British Columbia. A significant change infossil pollen occurs at ca. 2400 BP and is characterised by an increase in pinepollen accompanied by decreases in alder (Alnus), spruceand fir. This also coincides with an increase in west-sourced exoticwestern hemlock (Tsuga heterophylla) and cedar type(Cupressaceae) pollen possibly transported by regional changes in air masscirculation patterns associated with Aleutian Low dynamics. This studydemonstrates that both lithostratigraphic and biotic proxies are helpful inreconstructing the timing and nature of climate change and that each may havevarying sensitivities to a particular type of change.     

A high resolution proxy-climate record from an arctic lake with annually-laminated sediments on Devon Island, Nunavut, Canada

Sediments from a 3 ha lake (75 °34.34N, 89 °18.55W) from the coastal region of northern Devon Island, Nunavut, Canada, contain discrete laminations in the deepest part of the basin. The laminations are varves as indicated by the correspondence between counts and thickness measurements of the couplets and ²¹⁰Pb dating. A 14 cm core representing 150 years of sedimentation contained laminated couplets consisting of a lighter inorganic layer with a higher percentage of calcium and magnesium, alternating with fine darker bands, typically more cohesive, and comprising higher proportions of silica and carbon. A reddish oxidation zone with higher iron and aluminum frequently separates the laminations. The dark layer represents a biogenic component deposited in summer and is made cohesive by bacterial filaments among the other particles. The light inorganic layer represents clastic deposition from allochthonous sources. Deposition rates were relatively consistent through the core with an increase in varve thickness in the 1950s. Diatom concentrations in the sediments increased by two orders of magnitude in this century, with major increases in the 1920s and 1950s. The increase in varve thickness and diatom abundance coincides with an increase in summer melt percentage in an ice core from the Devon Island Ice Cap (Koerner, 1977). The relatively high sedimentation rate (0.15 cm yr^-1) coupled with the consistency of deposition makes this lake a significant indicator for recent climate changes of the Canadian Arctic Archipelago.     

A 2300-year record of environmental change from SW Anatolia, Lake Burdur, Turkey

This work deals with changes recorded by lacustrine sediments from SW Anatolia in Turkey in the context of increasing stress on the Mediterranean environment in relation to human-climate-environmental interactions. Paleolimnological investigations were carried out on Lake Burdur (Lake District geographical subregion of Turkey), which has been subject to rapid changes in its hydrological system that caused a ~10-m water-level drop in the last 30 years. Study of a 5-m-long sediment core, taken from the recently dried out part of the lake, shows significant variation in granulometry, clay mineralogy, nitrogen and organic carbon content and its isotopic composition (?¹³C_org) throughout the sedimentary sequence, which represents the last 2,300 years. Chronology is based on radiocarbon dates obtained from plant fragments. The results provide a record of environmental changes, including biological productivity and erosion intensity, in relation to changes in water level and humidity of the area. The lowest previous water level, which is the same as observed today, occurred at approximately 300 BC, after which time a water-level increase led to a maximum stage between AD 200 and 1200. From AD 1200 to the present, the climate became drier accompanied by an overall lowering of water level, with periods of water-level fluctuations superimposed. The lake never dried out as is observed today at the coring site. The present drop in the lake water level is attributed to human activity rather than to climate change. This record of climate and environmental change in the Lake Burdur area appears to be stratigraphically complete. This study provides rare data for the late Holocene in Anatolia as well as information about rapid climate changes during specific periods. The influence of both the Northern hemisphere atmospheric circulation and Indian monsoon on the east Mediterranean remains unclear. Nevertheless, the North Sea—Caspian atmospheric teleconnection could be an important factor that explains local differences in climatic evolution of Anatolia during the period considered.     

Sedimentary geochemical record of recent environmental changes around Lake Middle Marviken,Sweden

Geochemical properties of sediments deposited in Lake Middle Marviken over the last 185 years record the impacts of a succession of environmental changes that have occurred in the watershed. Clear-cutting of forests for wood and charcoal and extensive water harnessing to support the local iron mills from 1897 to 1957 is recorded by low C/N ratios, high black carbon, and low TOC and N_total accumulation rates. Larger δ¹³C and δ¹⁵N values in sediments deposited during this period imply higher productivity. Fluctuations in N_total and P_total accumulation rates show that the lake chemistry has varied between P or N-depleted systems that affected the δ¹⁵N values. Organic matter in the sediments is predominantly immature terrestrial material. Furthermore, hydrocarbon CPI, TAR, and P_aq values conform with the observed geochemical trends, variations in organic matter sources, and changes in the watershed. Accumulation rates of Cd, Pb, Zn, and S remained mostly unchanged throughout the period of mining, but an increase from 1957 to 1980 is most likely associated with air-borne industrial and fossil fuel emissions from regional urbanization. In situ microbial processes, such as iron and manganese reduction, also appear to be important in carbon cycling and in affecting the sediment and water chemistry of this lake.     

A sediment record of recent nutrient loading and trophic state change in Lake Norrviken,Sweden

Human-induced perturbations in the Lake Norrviken catchment, Sweden, over the last 100+ years have left distinctive geochemical imprints in the sediments. Disposal of sewage, industrial, and agricultural run-off into the lake since the end of the nineteenth century changed the trophic status from eutrophic to hyper-eutrophic. The primary organic matter (OM) source in the lake is in situ algal material. Total organic carbon (TOC) concentrations increased near the mid-section of a short sediment core collected from the deepest part of the lake, reflecting elevated epilimnetic productivity and consequent hypolimnetic anoxia. Accompanying shifts to lighter stable organic C and total N isotopic compositions suggest that cyanobacterial productivity increased during this period. The distribution of pigments in the core indicates a shift in the phytoplankton community to a cyanobacteria-dominated system. Moreover, pigments confirm that N₂-fixing versus non-N₂-fixing phytoplankton varied depending upon the external inputs of N and P. Conditions in the lake improved after sewage input was diverted and the lake is currently mesotrophic.     

Rapid 20th century environmental change on northeastern Baffin Island,Arctic Canada inferred from a multi-proxy lacustrine record

The Arctic has a disproportionately large response to changes in radiative forcing of climate, and arctic lacustrine ecosystems respond sensitively to these changes. The goal of this research is to generate high-resolution climate records for the past two millennia using multiple proxies in order to place 20th and 21st century climate and environmental change into a long-term context. We use a ¹⁴C- and ²¹⁰Pb-dated surface core from Lake CF8 on northeastern Baffin Island, Arctic Canada to generate a high-resolution multiproxy reconstruction of climate and environmental change. Throughout the late Holocene, primary productivity in Lake CF8 was low, but increased almost 20-fold in the past 200 years. Insect (Chironomidae) assemblages also show dramatic changes since 1950 AD, with cold stenothermous chironomid taxa disappearing from the record altogether. These changes in productivity and chironomid assemblages are unprecedented in the past 5,000 years. The dramatic ecological shifts that occurred at Lake CF8 have also been observed elsewhere in the Arctic, and will likely continue at ever-increasing rates as anthropogenic inputs of green house gases continue to cause climate warming and enhanced lacustrine primary production.     

A 27-kyr record of environmental change in central Asia inferred from the sediment record of Lake Hovsgol,northwest Mongolia

Geochemistry of a sediment core from Lake Hovsgol, northwest Mongolia provides a continuous, 27-kyr history of the response of the lake and the surrounding catchment to climate change. Principle component (PC) analysis of 19 major and trace elements, total inorganic carbon (TIC), and total organic carbon (TOC) in the bulk sediment samples revealed that the 21 chemical components can be grouped into four assemblages—group-1: Na, Mg, Ca, Sr, and TIC, hosted in carbonate minerals (calcite, dolomite, and magnesian calcite); group-2: Ni, Cu, and Zn, recognized as biophilic trace metals, and TOC; group-3: Al, K, Ti, V, Fe, Rb, Cs, Ba, and Pb, composed of rock-forming minerals; and group-4: Cr, Mn, and As, sensitive to the redox condition of the sediment. The four element assemblages originated from three relevant processes. Group-1 and group-2 components are authigenic products and comprise the end member on the PC-1 score, whose variation reflects changes in the water volume, i.e. the balance between precipitation and evaporation (P/E). Group-3 components from detrital materials of the catchment contribute to the PC-2 score, whose variability indicates erosion/weathering intensity in the drainage basin, which might be controlled by the amount of vegetation cover associated with moisture change. The group-4 components of redox-sensitive elements contribute to the PC-3 score and are not an end member because of their small amount. The first two PC scores suggest a sequential record of paleo-moisture evolution in central Asia. The P/E balance in the Lake Hovsgol region, inferred from the PC-1 score, gradually increased during the glacial/interglacial transition. This resembles climate change of the North Atlantic region on the glacial–interglacial scale, but does not reflect the abrupt climate shifts such as the warm Bølling-Allerød and the cold Younger Dryas of the North Atlantic on the millennial scale. A periodic variation of ~8.7 kyr was observed in the PC-2 score profile of detrital input to Lake Hovsgol over the last glacial and Holocene. The decrease in detrital input coincided with the copious supply of moisture from the Asian monsoon regime and the North Atlantic westerly winds to the Baikal drainage basin, which includes Lake Hovsgol. Our geochemical records from Lake Hovsgol demonstrate that the climate system of interior continental Asia was strongly influenced by change on both Milankovitch and sub-Milankovitch scales.     

A multi-proxy study of Holocene environmental change in the Maya Lowlands of Peten, Guatemala

We used multiple variables in a sediment core from Lake Peten-Itza, Peten, Guatemala, to infer Holocene climate change and human influence on the regional environment. Multiple proxies including pollen, stable isotope geochemistry, elemental composition, and magnetic susceptibility in samples from the same core allow differentiation of natural versus anthropogenic environmental changes. Core chronology is based on AMS ¹⁴C measurement of terrestrial wood and charcoal and thus avoids the vagaries of hard-water-lake error. During the earliest Holocene, prior to 9000 ¹⁴C yr BP, the coring site was not covered by water and all proxies suggest that climatic conditions were relatively dry. Water covered the coring site by 9000 ¹⁴C yr BP, coinciding with filling of other lakes in Peten and farther north on the Yucatan Peninsula. During the early Holocene (9000 to 6800 ¹⁴C yr BP), pollen data suggest moist conditions, but high ¹⁸O values are indicative of relatively high E/P. This apparent discrepancy may be due to a greater fractional loss of the lake's water budget to evaporation during the early stages of lake filling. Nonetheless, conditions were moist enough to support semi-deciduous lowland forest. Decrease in ¹⁸O values and associated change in ostracod species at 6800 ¹⁴C yr BP suggest a transition to even moister conditions. Decline in lowland forest taxa beginning 5780 ¹⁴C yr BP may indicate early human disturbance. By 2800 ¹⁴C yr BP, Maya impact on the environment is documented by accelerated forest clearance and associated soil erosion. Multiple proxies indicate forest recovery and soil stabilization beginning 1100 to 1000 ¹⁴C yr BP, following the collapse of Classic Maya civilization.     

A multi-proxy lake-sediment record of middle through late Holocene hydroclimate change in southern British Columbia,Canada

Journal of Paleolimnology - Analysis of the oxygen isotopic composition (δ18O) of sedimentary carbonates in Turquoise Lake (N50.83°, W121.69°, 807 m), southwestern British...     

Paleolimnological assessment of recent environmental change in Lake Baikal: sediment chronology

Sediment cores collected from six sites in Lake Baikal as part of an extensive investigation of sediment records of recent environmental change were dated radiometrically by ²¹⁰Pb. Although the results obtained were in some respects comparable to those obtained by previous ²¹⁰Pb studies, there were some significant differences. Most notably, a core from abyssal depths in the centre of the middle basin appeared to record at least wo major episodes of rapid sedimentation, possibly caused by turbidity currents. All cores, including those from the North Basin, contained significant records of weapons test fallout ¹³⁷Cs, though these were of little chronological value due to the long residence time of ¹³⁷Cs in the water column. Models and budgets for sediment and radionuclide transport through Baikal are presented and used to help validate the ²¹⁰Pb results.     

A late Holocene pollen record of deforestation and environmental change from the Lake Tauanui catchment, Northland, New Zealand

Late Holocene pollen and sediment records from the Lake Tauanui catchment, northern New Zealand, indicate that the lake formed about 5500 years ago following a series of volcanic events in the Tauanui Volcanic Centre. These volcanic events initiated a volcanosere resulting in a mixed conifer-hardwood forest. Dacrydium cupressinum was the dominant tree. Agathis australis was always present. Changes similar to those registered in other Northland pollen diagrams are apparent. At ca 4000 yr B.P., when the climate became cooler and drier than before, a fire occurred in the catchment area causing erosion of the surrounding slopes and some destruction of forest. Fluctuations in abundance of many forest species, including Ascarina lucida, A. australis and D. cupressinum, from ca 3500 yr B.P. indicate repeated disturbance, increasingly so after 1600 yr B.P. Summer droughts and increased frequency of cyclonic winds are suggested as the cause. Major anthropogenic deforestation events defined by palynology occurred across many parts of the New Zealand landscape at ca 700 yr B.P. At Lake Tauanui anthropogenic forest disturbance, radiocarbon dated to ca 1000 yr B.P., is indicated by significant decline in all tree and shrub elements with concomitant increase in pteridophytes, especially Pteridium esculentum. Charcoal concentration increases steadily from the onset of disturbance, and in the final phase after the arrival of Europeans, major clearance of vegetation is indicated. Herbs increase markedly in this period, in diversity and abundance.     

A 40,000-year record of environmental change from ancient Lake Ohrid (Albania and Macedonia)

Lake Ohrid is considered to be of Pliocene origin and is the oldest extant lake in Europe. A 1,075-cm-long sediment core was recovered from the southeastern part of the lake, from a water depth of 105 m. The core was investigated using geophysical, granulometric, biogeochemical, diatom, ostracod, and pollen analyses. Tephrochronology and AMS radiocarbon dating of plant macrofossils reveals that the sediment sequence spans the past ca. 39,500 years and features a hiatus between ca. 14,600 and 9,400 cal. year BP. The Pleistocene sequence indicates relatively stable and cold conditions, with steppe vegetation in the catchment, at least partial winter ice-cover of the lake, and oxygenated bottom waters at the coring site. The Holocene sequence indicates that the catchment vegetation had changed to forest dominated by pine and summer-green oak. Several of the proxies suggest the impact of abrupt climate oscillations such as the 8.2 or 4.0 ka event. The observed changes, however, cannot be related clearly to a change in temperature or humidity. Human impact started about 5,000 cal. year BP and increased significantly during the past 2,400 years. Water column mixing conditions, inflow from subaquatic springs, and human impact are the most important parameters influencing internal lake processes, notably affecting the composition and characteristics of the sediments.     

The ostracode record from Harris Lake, southwestern Saskatchewan: 9200 years of local environmental change

Holocene paleoenvironments of Harris Lake, southwestern Saskatchewan, are reconstructed from the ostracode stratigraphy of a 10.4 m sediment core. Twenty three taxa, representing nine genera, were identified and counted from 113 samples. At each depth, a theoretical faunal assemblage was derived from the raw counts. The mean and variance of chemical, climatic and physical variables were inferred from modern analogues of the fossil assemblages, using existing autecological data from 6720 sites, mostly in western Canada. These data suggest four paleoenvironments: an early-Holocene (9240–6400 years BP) variable climate supporting aspen parkland vegetation; the warm dry hypsithermal (6400–4500 years BP); a short transitional period of ameliorating climate and expanding subboreal forest (4500–3600 years BP); and the present environment since 3600 years BP. A change in regional climate with the draining of Glacial Lake Agassiz (ca. 8500 years BP) and landsliding in the watershed (ca. 4000 years BP) caused relatively rapid environmental change. The ostracode record generally corroborates the interpretations of other proxy data previously published for Harris Lake. Most of the discrepancy involves the timing and severity of maximum Holocene warmth and aridity. Peak aridity interpreted from the pollen data is earlier than in the other proxy records. Both the diatoms and ostracodes indicate highest paleosalinity between ca. 6500 and 5000 years BP, but maximum salinity in the diatom record occurs between ca. 6000–5700 years BP, whereas the ostracode-inferred salinity is relatively low at this time and peaks later at ca. 5000 years. Neither of these reconstructions suggests the short episodes of hypersalinity interpreted from the mineralogy.     

A 17,900-year multi-proxy lacustrine record of Lago Puyehue (Chilean Lake District): introduction

This paper introduces the background and main results of a research project aimed at unravelling the paleolimnological and paleoclimatological history of Lago Puyehue (40° S, Lake District, Chile) since the Last Glacial Maximum (LGM), based on the study of several sediment cores from the lake and on extensive fieldwork in the lake catchment. The longest record was obtained in an 11-m-long piston core. An age-depth model was established by AMS ¹⁴C dating, ²¹⁰Pb and ²³⁷Cs measurements, identification of event-deposits, and varve-counting for the past 600 years. The core extends back to 17,915 cal. yr. BP, and the seismic data indicate that an open-lake sedimentary environment already existed several thousands of years before that. The core was submitted to a multi-proxy analysis, including sedimentology, mineralogy, grain-size, major geochemistry and organic geochemistry (C/N ratio, δ¹³C), loss-on-ignition, magnetic susceptibility, diatom analysis and palynology. Along-core variations in sediment composition reveal that the area of Lago Puyehue was characterized since the LGM by a series of rapid climate fluctuations superimposed on a long-term warming trend. Identified climate fluctuations confirm a.o. the existence of a Late-Glacial cold reversal predating the northern-hemisphere Younger Dryas cold period by 500–1,000 years, as well as the existence of an early southern-hemisphere Holocene climatic optimum. Varve-thickness analyses over the past 600 years reveal periodicities similar to those associated with the El Niño Southern Oscillation and the Pacific Decadal Oscillation, as well as intervals with increased precipitation, related to an intensification of the El Niño impact during the southern-hemisphere equivalent of the Little Ice Age.     

A high resolution record of storm-induced erosion from lake sediments,New Zealand

The sustainable management of erodible pastoral hill country is a major focus of land use research in New Zealand. A multi-disciplinary study, using a high resolution lake sedimentation record, is being conducted to determine the role that cyclonic storms and natural and human-induced vegetation changes play in the erosion history of a landslide-prone hill country watershed.Sediment cores from Lakes Tutira and Waikopiro in northern Hawke's Bay were analysed to construct the magnitude-frequency history of storm-induced erosion since European settlement. Pulses of sediment representing individual storms can be clearly identified and are correlated to a storm history derived from analysis of a 93 year daily rainfall record. Correlation and dating are confirmed by pollen and diatom analysis,¹³⁷Cs distribution, tephrochronology and reference to a well documented land use history. Annually laminated, organic rich deposits, which occur in the uppermost sediments and represent the annual decomposition of biogenic material associated with eutrophication, are also used to confirm the chronology.A high correlation was found between storm sediment thickness and total storm rainfall (R²=0.8). Although sediment producing storms (>150 mm) occur on a near annual basis, the two largest storms (>600 mm) contributed 54% of the total sediment thickness.The presence of well defined storm sediment pulses has enabled the lake storage component of a sediment budget to be calculated for Cyclone Bola (1988), the most recent and largest rainstorm on record. The integration of this budget with the storm-magnitude-frequency history will be used to develop watershed-based models to predict the impacts of land use changes and the erosion response to climate scenarios.This is the third paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Palaeolimnological Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.     

Tracking recent recovery from eutrophication in a high arctic lake (Meretta Lake, Cornwallis Island, Nunavut, Canada) using fossil diatom assemblages

Meretta Lake (Resolute Bay, Cornwallis Island, Nunavut, Canada) is a high arctic lake that received raw sewage for almost 50 years from the Canadian Department of Transport Base. The lake was sampled from 1968–72 during the International Biological Programme, as part of the Char Lake Project. As the number of users at the Transport Base declined throughout the 1990s, so too did the lake's nutrient levels, and Meretta Lake is now classified as oligotrophic. A previous diatom-based paleolimnological study revealed marked species assemblage shifts coincident with sewage inputs beginning in the late 1940s; however, because the core was taken at a time when nutrient levels were still relatively high (i.e., 1993), the diatom record did not yet track any signs of recovery. In this present study, we examined fossil diatom assemblages from a sediment core taken in 2001. Our results indicate a shift to the pre-impact diatom assemblages in the most recent sediments, indicating that the paleolimnological record is tracking the decreased nutrient inputs to this high arctic lake, and confirms that no significant lags exist in these largely ice-covered lakes.     

Organic geochemical record of environmental changes in Lake Dianchi,China

In order to investigate the natural ecosystem of Lake Dianchi and to assess its anthropogenic impacts, a stratigraphic study of bulk and molecular compositions of organic matter was conducted using a 63-cm long sediment core. The results show that two apparent environmental changes occurred during the evolution of Lake Dianchi: (1) the first change occurred in the 43–63 cm sediment depth, and was revealed by the amount and the composition of organic matter in the stage. Natural changes were possibly major factors responsible for triggering the environmental change, but the influence of human activities could not be excluded. Subsequently, the lake entered into a relatively stable and oligotrophic stage, which maintained until 20-cm sediment depth. (2) Eutrophication started in the upper 20 cm depth. Human activities became a major factor influencing environmental changes in this stage. Vertical profiles of various organic geochemical variables in the upper 20-cm sediments show evidence that primary productivity of the lake increased progressively and that the lake started eutrophic. Especially in the uppermost 10 cm, notable excursions to less negative δ¹³C_org and δ¹⁵N_total and high TOC concentrations have recorded an abrupt change in the lacustrine environment, suggesting that the lake entered a hypereutrophic stage. In addition, enhancement of αβ-hopanes reflects the contribution of fossil fuels to the lake sediments.