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1.
Airborne measurements made during August 1985 over Greenland and its environs show that both accumulation-mode (0.1 m D2.0 m) and giant (D2 m) particles were present in relatively high concentrations in arctic haze layers and that the accumulation-mode particles dominated light scattering. Particles with diameters (D) between 1 and 4 m consisted predominately of mixed materials, small and dense inclusions, and probably organic compounds containing sulfur. Many of the particles from 0.1 to 1 m in diameter were also of mixed composition, with sulfuric acid, ammonium sulfate and organics probably the dominant constituents.  相似文献   

2.
On the determination of the height of the Ekman boundary layer   总被引:1,自引:1,他引:1  
The heighth of the Ekman turbulent boundary layer determined by the momentum flux profile is estimated with the aid of considerations of similarity and an analysis of the dynamic equations. Asymptotic formulae have been obtained showing that, with increasing instability,h increases as ¦¦1/2 (where is the non-dimensional stratification parameter); with increasing stability, on the other hand,h decreases as –1/2. For comparison, a simple estimate of the boundary-layer heighth u determined by the velocity profile is given. As is shown, in unstable stratification,h u behaves asymptotically as ¦¦–1, i.e., in a manner entirely different from that ofh .  相似文献   

3.
We present the first application of a multi-stage impactor to study volcanic particle emissions to the troposphere from Masaya volcano, Nicaragua. Concentrations of soluble SO4 2–,Cl, F, NO3 , K+, Na+,NH4 +, Ca2+ and Mg2+ were determined in 11 size bins from 0.07 m to >25.5 m. The near-source size distributions showed major modes at 0.5m (SO4 2–, H+,NH4 +); 0.2 m and 5.0 m (Cl) and 2.0–5.0 m(F). K+ and Na+ mirrored the SO4 2– size-resolvedconcentrations closely, suggesting that these were transported primarily asK2SO4 and Na2SO4 in acidic solution, while Mg2+ andCa2+ presented modes in both <1 m and >1 m particles. Changes in relative humidity were studied by comparing daytime (transparent plume) and night-time (condensed plume) results. Enhanced particle growth rates were observed in the night-time plume as well as preferential scavenging of soluble gases, such as HCl, by condensed water. Neutralisation of the acidic aerosol by background ammonia was observed at the crater rim and to a greater extent approximately 15 km downwind of the active crater. We report measurements of re-suspended near-source volcanic dust, which may form a component of the plume downwind. Elevated levels ofSO4 2–, Cl, F,H+, Na+, K+ and Mg2+ were observed around the 10 m particle diameter in this dust. The volcanic SO4 2– flux leaving the craterwas 0.07 kg s–1.  相似文献   

4.
A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO3 (0.01), N2O5 (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

5.
Weekly bulk aerosol samples collected at Funafuti, Tuvalu (8°30S, 179°12E), American Samoa (14°15S, 170°35W), and Rarotonga (21°15S, 159°45W), from 1983 through most of 1987 have been analyzed for nitrate and other constituents. The mean nitrate concentration is about 0.11 g m–3 at each of these stations: 0.107±0.011 g m–3 at Funafuti; 0.116±0.008 at American Samoa; and 0.117±0.010 at Rarotonga. Previous measurements of mineral aerosol and trace metal concentrations at American Samoa are among the lowest ever recorded for the near-surface troposphere and indicate that this region is minimally affected by transport of soil material and pollutants from the continents. Consequently, the nitrate concentration of 0.11 g m–3 can be regarded as the natural level for the remote marine boundary layer of the tropical South Pacific Ocean. In contrast, over the tropical North Pacific which is significantly impacted by the transport of material from Asia and North America, the mean nitrate concentrations are about three times higher, 0.29 and 0.36 g m–3 at Midway and Oahu, respectively. The major sources of the nitrate over the tropical South Pacific are still very uncertain. A very significant correlation between the nitrate concentrations at American Samoa and the concentrations of 210Pb suggests that transport from continental sources might be important. This continental source could be lightning, which occurs most frequently over the tropical continents. A near-zero correlation with 7Be indicates that the stratosphere and upper troposphere are probably not the major sources. A significant biogenic source would be consistent with the higher mean nitrate concentrations, 0.16 to 0.17 g m–3, found over the equatorial Pacific at Fanning Island (3°55N, 159°20W) and Nauru (0°32S, 166°57E). The lack of correlation between nitrate and nss sulfate at American Samoa does not necessarily preclude an important role for marine biogenic sources.  相似文献   

6.
The rainwater composition in the vicinity of Mainz, FRG, has been investigated with special emphasis on insoluble constituents. The number size distribution was determined in the range from 0.1 m up to 100 m radius. For particles with r>0.5 m radius the shape of the size distribution of insoluble particles in rain follows the shape of the average urban and rural aerosol. In this particular size range no major size selective removal processes could be seen. For r<0.5 m the number size distribution tends to flatten compared to the average aerosol. This might be the indication of a size selective removal process (Greenfield Gap).  相似文献   

7.
Data collected during the french VOVES-1977 experiment are used for the determination of the functionsA() andB() of the stability parameter . It is found that, although pertaining to different geographic conditions, they lead to the same kind of dependency ofA andB upon as found previously considered data. The influence of baroclinicity onA andB is also studied and it is found in that, statistically, consideration of this parameter does not lead either to a decrease of the large scatter of experimental points or to a significant improvement of the similarity theory. It is also shown that a satisfactory estimation of the surface geostrophic wind can be made from the network of meteorological stations, to compute such functions.  相似文献   

8.
Rain and air of Florence have been collected in a continuous way andanalysed by flow analysis spectrofluorimetric methods for formaldehydeand hydrogen peroxide. Diurnal and seasonal variations were observed;the mean/maximum concentrations of all data (as gm–3) are 3.3/23.4 for HCHO and 0.4/4.93 forH2O2. The effect of external sources and ofphotochemical reactions produces periods of positive and negativecorrelations for these compounds. The mean/maximum rain concentration ofall data are 98/443 g l–1 for HCHO and 84/685 g l–1 for H2O2. Concentrationratios rain/air and discrepancies to Henry's Law equilibrium arediscussed.  相似文献   

9.
Eighteen soil samples from central Sudan were fractionated by dry sieving ina size fraction from <45 m to >300 m while aerosols generatedfrom these soils were fractionated in the particle size range from 0.25 mto >16 m. The elemental concentrations of soil samples were determinedby energy-dispersive X-ray fluorescence, while the elemental concentrationsof generated aerosols were analysed by particle-induced X-ray emission. Theelements Al, K and Rb show a slight positive fractionation with decreasingparticle size throughout the particle size range studied. The concentrationsof Ca, Mn, Fe, Sr and Y are maximum in the small soil size fraction (<45m) and decrease for the coarse soil size fractions, while in the mineralaerosol particle sizes (0.25– > 16 m) the concentrations remainmore or less constant. The size distributions for Cr, Ti and Zr show a maximumin the particle size range 45–100 m and the concentrations of theseelements decrease sharply in the aerosol fraction down to 16 m to remainconstant in the smaller aerosol fractions.Enrichment factors for the elements were calculated relative to five referencematerials: average crustal rock, average soil, the investigated Sahara bulksoil, the finest fraction of this soil and the aerosol generated from thissoil, and using four reference elements: Al, Si, Ti and Fe. The enrichmentfactors were found to vary significantly depending on the choice of thereference material or the reference element. The enrichment factors for theSudan mineral aerosol were almost identical to those for Khartoum atmosphericaerosol but different from those for Namib mineral aerosol and Israelatmospheric aerosol following dust storms. Multivariate display methods(cluster analysis, principal component analysis and linear discriminantanalysis) were applied to the element ratios in the mineral aerosol from theSahara and Namib and this showed that these mineral aerosol can bedifferentiated into different groups. An attempt was also made to relate themineral aerosol to its parent soil through the use of these multivariatetechniques and the elemental ratios in both the mineral aerosols and the bulksoils (Namib and Sahara). It was also possible using the elemental ratios andthe multivariate display methods to associate the crustal component to themineral aerosol generated from the Sahara.  相似文献   

10.
Radiative Heat Transfer and Hydrostatic Stability in Nocturnal Fog   总被引:1,自引:0,他引:1  
We have performed a one-dimensional and transient radiative heat transfer analysis in order to investigate interaction between atmospheric radiation and convective instability within a nocturnal fog. The radiation element method using the Ray Emission Model (REM2), which is a generalized numerical method, in conjunction with a line-by-line (LBL) method, is employed to attain high spectral resolution calculations for anisotropically scattering fog. The results show that the convective instability has a strong dependence on radiative properties of the fog. For the condition of a 20-m droplet diameter and liquid water content of 0.1 × 10–3 kg m–3;, the temperature profile within the fog becomes S shaped, and a convective instability layer forms in the middle or lower level of the fog. However, for the same water content and a 40-m diameter droplet, no strong convective instability layer forms, whereas for a 10-m diameter droplet a strong convective instability is observed.  相似文献   

11.
The carbon isotopic ratio of atmospheric carbon dioxide at Tsukuba,Japan   总被引:1,自引:0,他引:1  
To find out the secular and seasonal trends of the 13C value and CO2 concentration in the surface air and the determination of the 13C in the atmospheric CO2 collected at Tsukuba Science City was carried out during the period from July 1981 to October 1983. The monthly average of the 13C value of CO2 in the surface air collected at 1400 LMT ranged from -7.52 to \s-8.45 with an average of -7.96±0.25 and the CO2 concentration in the air varied from 334.5 l 1-1 to 359 l 1-1 with an average of 347.2±6.3 l 1-1. The 13C value is high in summer and low in winter and is negatively correlated with the CO2 concentration. In general, the relationship between the 13C and the CO2 concentration is explainable by a simple mixing model of two different constant carbon isotopic species but the relationship does not always follow the model. The correlation between the 13C value and the CO2 concentration is low during the plant growth season and high at other times. The observed negative deviation of the 13C value from the simple mixing model in the plant growth season is partly due to the isotopic fractionation process which takes place in the land biota.  相似文献   

12.
A previously published technique for using tethered spherical balloons as anemometers for measuring light low-level winds has been further developed. Earlier data on the relationship between the aerodynamic drag coefficient and the Reynolds number of spherical rubber balloons were combined with a large number of new data and re-analysed; and the errors in the relationship were estimated. The results allowed a more accurate calculation of wind speed from the deflection of a tethered balloon from the vertical. When combined with a new technique for calculating the effects of the tether, this enabled light to moderate low-level winds at fixed heights up to 600 m or more to be measured with simple, cheap, and readily mobile equipment; and a slight modification of the technique allowed measurement of winds in and above fog. Wind speeds measured by the ballon technique showed reasonably good agreement with measurements by an anemometer carried beneath the balloon.Glossary of Symbols a, b, c Coefficients in the relationship between lnC d and lnR - A Quantity under square root in solution for lnV whena0 - C d Wind drag coefficient for balloon - C dc Value ofC d given by calibration curve of Table I - D Dynamic wind pressure force on balloon - F Buoyant free lift of balloon with load - Re Reynold's number of balloon (sphere) - R = Re/105 - r Radius of sphere - T Tension in tether - V Wind speed - 83() =(lnC dc -lnC d ) when 83° , or 0 for other - Error in lnC d - Elevation of tether where attached to balloon - Elevation of balloon from ground tether point - Molecular viscosity of air - Ratio of circumference to diameter of circle - Density of air  相似文献   

13.
Summary During an expedition to the high Andes of Southern Peru in June–July 1977, measurements of direct solar radiation in four spectral bands (0.270–0.530–0.630–0.695–2.900 ) were conducted at six sites in elevations ranging from sea level to 5645 m. These measurements were evaluated in Langley plots to determine total optical depths () and irradiances at the top of the atmosphere. In addition, water vapor optical depths (wv) were calculated from the mean radiosounding over Lima during the expedition, and Rayleigh (ray) and ozone (oz) optical depths were obtained from published tabulations. Subtracting ray, oz, and wv from yielded estimates of aerosol optical depth aer. The components ray and oz decrease from the shorter towards the longer wavelength bands and from the lower towards the higher elevation sites; aer also decreases towards the higher elevations. Particularly pronounced is the decrease of aer and from the lowlands of the Pacific coast to the highlands of the interior, reflecting the effect of a persistent lower-tropospheric inversion and the contrast from the marine boundary layer to the clear atmosphere of the high Andes.With 4 Figures  相似文献   

14.
A method for determining the distribution of supermicrometer nitrate between size-segregated sea-salt and soil derived particles is presented. The analysis is based on field data from six measurements at a coastal site in southern Finland, and on a theoretical treatment taking into account the transfer of gaseous species onto particle surfaces and their subsequent reaction. Significant amounts of nitrate were found in both the particle types, with the fraction of nitrate associated with soil particles varying from 20–50% in the 1–2 m size to near 90% in particles larger than 10 m. Overall, the nitrate accumulation followed closely the relative abundances of these two particle types. Two overlapping modes in supermicron nitrate mass size distributions could be identified. The lower mode, associated with sea-salt, was located between the surface-area and volume distribution of sodium peaking at about 2–3 m of EAD. The upper mode peaked at 3–5 m and followed more closely the surface-area distribution of calcium in all samples. At our site, the accumulation of nitrate into both particle types was shown to be limited by an effective surface reaction rate rather than by gas-phase diffusion. This rate was estimated to be considerably larger for sea-salt particles. Strong evidence in support of the saturation of nitrate in sea-salt particles were obtained.  相似文献   

15.
Zusammenfassung Auf dem Feldberg (1493 m NN) im südlichen Schwarzwald wurden von Januar 1953 bis Mai 1953 und von September 1954 bis Februar 1955 Messungen von Tropfengröße, Wassergehalt und Sichtweite in Wolken durchgeführt. Die Tropfen der einzelnen Spektren haben einen mittleren Durchmesser zwischen 6 und 30 ; die Durchmesser der größten gemessenen Tropfen liegen zwischen 50 und 60 . Der Wassergehalt hat Werte zwischen 0,003 und 1,54 g/m3, wobei über 90% aller Messungen einen Wassergehalt unter 0,50 g/m3 zeigen. Ein einfacher Zusammenhang zwischen Sichtweite, Tropfengröße und Wassergehalt nach derTrabertschen Formel besteht nicht.Eine enge beziehung wurde zwischen der Form der Spektren und dem Niederschlag gefunden. In Zeiten ohne Niederschlag und bei geringfügigem Niederschlag überwiegen schmale ( < 12,0 ), in Zeiten mit länger andauerndem Niederschlag breite Spektren ( > 12,0 ). Eine Ausnahme machen alle Messungen in Hochnebel, die breite Spektren mit zwischen 13 und 17 zeigen, ohne daß Niederschlag fällt.Das gleichzeitige Vorhandensein der drei Phasen Wasserdampf, flüssiges Wasser und Eisteilchen über längere Zeiträume hinweg wurde festgestellt; somit kann die Eiskristall-Niederschlagstheorie vonBergeron und vonFindeisen für den Mechanismus der Niederschlagsbildung nicht im allgemein angenommenen Ausmaß zutreffen. Es erscheint notwendig, die Frage der Wolkenphysik nicht nur thermodynamisch, sondern auch in vermehrtem maß kolloidphysikalisch im Sinne vonSchmauss zu untersuchen.
Summary Measurements of drop size, water content and visibility in clouds have been carried out from January till May 1953 and from September 1954 to February 1955 on the Feldberg (1493 m. a. s. 1.) in the southern Black Forest. The drops of the different spectra have a mean diameter between 6 and 30 ; the diameters of the largest measured drops lie between 50 and 60 . The water content shows values between 0.003 and 1.54g/m3 whereby more than 90 per cent of all measurements lead to a water content below 0.50 g/m3. A simple relation between visibility, drop size and water content according to the formula ofTrabert does not exist.A closed connection between the form of the spectra and the precipitations has been found. In periods without or with only slight precipitation narrow spectra ( < 12.0 ) prevail, in periods with persistent precipitation broad ones ( > 12.0 ). All measurements in elevanted fog make an exception, showing broad spectra with between 13 and 17 without any precipitation.The simultaneous existance of the 3 phases: water vapour, liquid water and ice particles over alonger periods has been stated; the ice crystall precipitation theory ofBergeron andFindeisen for the mechanism of precipitation can therefore not hold in the generally accepted extent. The examination of the problems of cloud physics appears to be necessary, not only in thermodynamical respect, but also in the sense of coloid physics according toSchmauss.

Résumé On a effectué de janvier à mai 1953 et de septembre 1954 à février 1955 au Feldberg (1493 m.) en Forêt-Noire des mesures de grosseur de gouttelettes, de teneur en eau et de visibilité dans les nuages. Les gouttelettes ont und diamètre moyen compris entre 6 et 30 ; les plus grosses mesurent 50 à 60 . La teneur en eau varie de 0,003 à 1,54 g/m3; dans plus de 90% des mesures, elle reste inférieure a 0,5g/m3. Il n'y a pas de relation simple, qui suivrait la formula deTrabert, entre visibilité, grosseur des gouttelettes et teneur en eau.Il existe par contre une relation étroite entre la forme du spectre de fréquence et les précipitations. Lorsque celles-ci sont nulles ou très faibles ce sont les spectres étroit ( < 12,0 ) qui dominent; par précipitations durables, ce sont les spectres larges ( > ). Dans le stratus, sans pluie, les spectres larges ( entre 13 et 17 ) prédominent.On a constaté l'existence simultanée des trois phases solide, liquide et gazeuse pendant d'assez longs intervalles de temps, de sorte que le théorie deBergeron et deFindeisen concernant la genène des précipitations n'a pas la généralité qu'on lui prête. Il apparaît nécessaire d'aborder les problèmes de la physique des nuages non seulement du point de vue thermodynamique, mais aussi de celui de l'état colloïdal au sens deSchmauss.


Mit 9 Textabbildungen.

Hinsichtlich der Wiedergabe von Tabellen und Tropfenspektren stark verkürzte Fassung einer bei der Technischen Hochschule in Karlsruhe eingereichten und genehmigten Dissertation; die hier weggelssene Dokumentation kann zur Einsichtnahme bezogen werden bei den Bibliotheken der Technischen Hochschule Karlsruhe und des Deutschen Wetterdienstes, Offenbach (Main).  相似文献   

16.
E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c 2 /e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c 2 = 1.92, = 1.3, e = 1). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and e to 1.1 and 1.6, respectively, giving, with c 2 = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.  相似文献   

17.
Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both SO and AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m3. In the case of aerosol carbon, we obtained a more gradual increase of AC up to an LWC of 0.5 g/m3. At higher LWCs, _ remained relatively constant at 0.60. As the differences between SO and A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.  相似文献   

18.
Moments, up to order six, of the velocity derivative have been measured in both the atmospheric surface layer and in turbulent jet flows in the laboratory. The exponent which characterises the behaviour of dissipation fluctuations was determined from the autocorrelation of these fluctuations and found to be constant (0.20), independent of Reynolds number. Using this value of , the lognormal model satisfactorily represents the experimental variation with Reynolds number of the measured moments. When moments of ordern are plotted against those of ordern + 1, the scatter in the data is reduced considerably and the adequacy of the lognormal model vis-à-vis other models is more convincingly established.  相似文献   

19.
Summary Interannual modes are described in terms of three-month running mean anomaly winds (u,v), outgoing longwave radiation (OLR), and sea surface temperature (T * ). Normal atmospheric monsoon circulations are defined by long-term average winds (u n,v n) computed every month from January to December. Daily winds are grouped into three frequency bands, i.e., 30–60 day filtered winds (u L,v L); 7–20 day filtered winds (u M,v M); and 2–6 day filtered winds (u S,v S). Three-month running mean anomaly kinetic energy (signified asK L , K M , andK S , respectively) is then introduced as a measure of interannual variation of equatorial disturbance activity. Interestingly, all of theseK L , K M , andK S perturbations propagate slowly eastward with same phase speed (0.3 ms–1) as ENSO modes. Associated with this eastward propagation is a positive (negative) correlation between interannual disturbance activity (K L , K M , K S ) and interannualu (OLR) modes. Namely, (K L , K M , K S ) becomes more pronounced than usual nearly simultaneously with the arrival of westerlyu and negativeOLR (above normal convection) perturbutions. In these disturbed areas with (K L , K M , K S >0), upper ocean mixing tends to increase, resulting in decreased sea surface temperature, i.e.T * 0. Thus, groups (not individual) of equatorial disturbances appear to play an important role in determiningT * variations on interannual time scales. HighestT * occurs about 3 months prior to the lowestOLR (convection) due primarily to radiational effects. This favors the eastward propagation of ENSO modes. The interannualT * variations are also controlled by the prevailing monsoonal zonal windsu n, as well as the zonal advection of sea surface temperature on interannual time scales. Over the central Pacific, all of the above mentioned physical processes contribute to the intensification of eastward propagating ENSO modes. Over the Indian Ocean, on the other hand, some of the physical processes become insignificant, or even compensated for by other processes. This results in less pronounced ENSO modes over the Indian Ocean.With 10 FiguresContribution No. 89-6, Department of Meteorology, University of Hawaii, Honolulu, Hawaii.  相似文献   

20.
An expression is derived for the height of the stationary boundary layer during stable lapse rate conditions. It satisfies the conventional limits for neutral conditions and for large values of stability. Comparison with acoustic sounder observations near the meteorological mast at Cabauw (the Netherlands) shows that the steady-state height is not attained for large stability values. The observations are also used to investigate how the similarity functions A and B in the resistance laws depend on the stability parameters 0 = u */f L and = h/L. The function B shows a clear trend as a function of stability, which can be described in terms of . The dependence of A is masked by scatter in the data points. The general conclusion leads to the concept of a non-steady boundary layer during stable lapse rate conditions.  相似文献   

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