The 1995–2002 Long-Term Monitoring of Comet C/1995 O1 (HALE–BOPP) at Radio Wavelength

The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH₃OH, H₂CO, H₂S, CS, CH₃CN and HNC) were monitored. CS, H₂S, H₂CO, CH₃CN were detected up to r_h= 3–4 AU from the Sun, while HCN and CH₃OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at r_h= 14 AU. The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as r_h ^-0.4 within 7 AU from the Sun, but remained close to 0.4 km s^-1 further away. The CO spectra obtained at large r_hare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about 10 K at 7 AU to 110 K around perihelion.     

C/1995 O1 (Hale-Bopp): Gas Production Curves And Their Interpretation

The discovery of C/1995 O1 (Hale-Bopp) at 7 AU from the Sun provided the first opportunity to follow the activity of a bright comet over a large range of heliocentric distances r_h. Production rates of a number of parent molecules and daughter species have been monitored both pre- and postperihelion. CO was found to be the major driver of the activity far from the Sun, surpassed by water within 3 AU whose production rate reached 10³¹ s⁻¹ at perihelion. Gas production curves obtained for various species show several behaviours with r_h. Gas production curves contain important information concerning the physical state of cometary ices, the structure of the nucleus and all the processes taking place inside the nucleus leading to outgassing. They are relevant to the study of several other phenomena such as the sublimation from icy grains, dust mantling or seasonal effects. For some species, such as H₂CO or HNC, they permit to constrain their origin in the coma. We discuss models of subsurface gas production in distant comets and predictions of how such a source may vary as the comet moves along its orbit, approaching perihelion and receding again. Features in the observed gas production curves of comet Hale-Bopp are generally interpretable in terms of either subsurface production (typical example: CO at large r_h) or free sublimation (typical example: H₂O). Possible implications for the vertical stratification of the cometary ices are reviewed, and preference is found for a model with crystallization of amorphous ice close to the nuclear surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spectroscopy of Comet Hale-Bopp in the infrared

High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH₄, C₂H₆, HCN, C₂H₂, CH₃OH, H₂O, CO, and OH were detected. The rotational temperature of CH₄ in the inner coma was T_rot=110±20 K. Spatial profiles of CH₄, C₂H₆, and H₂O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H₂O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H₂O (in percent) were 1.1±0.3 (CH₄), 0.39±0.10 (C₂H₆), 0.18±0.04 (HCN), 0.17±0.04 (C₂H₂), 1.7±0.5 (CH₃OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.     

Evidences for extended sources and temporal modulations in molecular observations of C/1995 O1 (Hale-Bopp) at the IRAM interferometer

Comet C/1995 O1 (Hale-Bopp) has been observed on October 5 and 25, 1996 and from March 6 to March 22, 1997 with the Institut de Radioastronomie Millimétrique (IRAM) interferometer at Plateau de Bure (France). Millimetre lines of HCN,HNC, CO, H₂CO, CH₃OH, H₂S, CS and SO were mapped with spatial resolutions of 1.5–3.5 arc sec. These observations allow us to investigate whether these species are released by the nucleus or produced in the coma by extended sources or photo-processes. The brightness distribution of the HCN J (1-0) line is consistent with release from the nucleus. The HNC J (1-0) distribution deviates from that of HCN in the innermost coma, and indicates production of HNC in the coma. This is in agreement with the heliocentric variation of the HNC/HCN ratio (Biver et al., 1997, Science 275, 1915; Irvine et al., 1998, this issue) and formation by chemical reactions (Rodgers and Charnley, 1998, Ap. J. 501, L227; Irvine et al., 1998, Nature 393, 547). There is clear evidence that SO is a photo dissociation product. The observations also confirm that H₂CO is mainly produced by an extended source, as first evidenced in comet P/Halley. The contribution of the nucleus to the total H₂CO production rate does not exceed 6%. The molecular lines have also been monitored hourly with the five antennas of the interferometer in single-dish mode. The line velocity shifts show aperiodic modulation linked to the nucleus rotation. The amplitude of the modulation differs from one species to another. The periodic modulation seen for the CO J (2-1) line on March 11 suggests that a significant fraction of CO is released continuously night and day by an active source situated at equatorial latitudes on the nucleus surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Lessons of Comet Hale-Bopp for Coma Chemistry: Observations and Theory

Many new cometary molecules — both parents and daughters — were detected in the exceptionally productive comet C/1995 O1 (Hale-Bopp).The space distribution of several of these species could be investigated from radio interferometry or from long-slit spectroscopy in the infrared. The distinction between parent species — directly sublimated from nucleus ices — and secondary species — resulting from chemical processing in the coma or produced by a secondary source — is not always clear. It is important to assess whether or not observed minor species (HCOOCH₃, HCOOH...) could be synthesized by chemical reactions favoured by the high density of the coma of comet Hale-Bopp. Chemical modelling by Rodgers and Charnley suggests that this is notthe case. CO and H₂CO are abundant cometary species which partly come from distributed sources. The nature of these sources is still a mystery. A special case, now well documented, is that of HNC, for which the abundance evolution with heliocentric distance could be observed in comet Hale-Bopp and which was observed in several much less productive comets.     

Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H2CO) extended source in Comet C/1995 O1 (Hale-Bopp)

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.     

The HNC/HCN Ratio in Comets

The abundance ratio of the isomers HCN and HNC has been investigated in comet Hale-Bopp (C/1995 O1) through observations of the J = 4−3 rotational transitions of both species for heliocentric distances 0.93 < r < 3 AU, both pre- and post-perihelion. After correcting for the optical depth of the stronger HCN line, we find that the column density ratio of HNC/HCN in our telescope beam increases significantly as the comet approaches the Sun. We compare this behavior to that predicted from an ion-molecule chemical model and conclude that the HNC is produced insignificant measure by chemical processes in the coma; i.e., for comet Hale-Bopp, HNC is not a parent molecule sublimating from the nucleus. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Molecular Survey of Comet C/1995 O1 (Hale-Bopp) at the IRAM Telescopes

Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first detections of HCOOH,SO₂, NH₂CHO and HCOOCH₃ in a comet. HDO was detected through its3₁₂–2₂₁ line at 225.897 GHz,complementing the observation of the 1₀₁–0₀₀ line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines are present in the spectra. Observations of HC₃N, HNCO, OCS, SO, CN, CO₊, HCO₊, in addition to more ‘classical’species CO, HCN, HNC, CH₃CN, CH₃OH, H₂CO, CS and H₂S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows, which are believed to reflect the composition of interstellar grains. This revised version was published online in July 2006 with corrections to the Cover Date.     

Chemical Composition Diversity Among 24 Comets Observed At Radio Wavelengths

We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH₃CN,CH₃OH, H₂CO, CO, CS, H₂S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets. From the sub-sample of comets for which contemporary H₂O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH₃OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H₂CO/HCN varies between 1.6 and 10; and H₂S/HCN varies between 1.5 and 7.6. This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.     

Infrared Spectroscopy of Comet Hale-Bopp

High resolution (λ/δλ ∼ 20,000) spectra of comet C/1995 O1 (Hale-Bopp) in the 2–5 μm region were obtained during UT 2–5 March 1997 using CSHELL at the NASA Infrared Telescope Facility (IRTF) on Mauna Kea. The heliocentric and geocentric distances of the comet were ∼1.1 AU and ∼1.5 AU,respectively. We detected emission lines of the gas-phase molecules H₂O, ₄, C₂H₆, C₂H₂, HCN, and CO and derived absolute production rates and relative abundances for all species. We also used the 2-dimensional nature of the CSHELL data to investigate the spatial distribution of the molecules and find evidence that CO was derived at least partly from an extended source in the coma. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spectroscopic Observations of Comet C/1996 B2 (Hyakutake) with the Caltech Submillimeter Observatory

The apparition of Comet C/1996 B2 (Hyakutake) offered an unexpected and rare opportunity to probe the inner atmosphere of a comet with high spatial resolution and to investigate with unprecedented sensitivity its chemical composition. We present observations of over 30 submillimeter transitions of HCN, H¹³CN, HNC, HNCO, CO, CH₃OH, and H₂CO in Comet Hyakutake carried out between 1996 March 18 and April 9 at the Caltech Submillimeter Observatory. Detections of the H¹³CN (4–3) and HNCO (16_0,16–15_0,15) transitions represent the first observations of these species in a comet. In addition, several other transitions, including HCN (8–7), CO (4–3), and CO (6–5) are detected for the first time in a comet as is the hyperfine structure of the HCN (4–3) line. The observed intensities of the HCN (4–3) hyperfine components indicate a line center optical depth of 0.9 ± 0.2 on March 22.5 UT. The HCN/HNC abundance ratio in Comet Hyakutake at a heliocentric distance of 1 AU is similar to that measured in the Orion extended ridge— a warm, quiescent molecular cloud. The HCN/H¹³CN abundance ratio implied by our observations is 34 ± 12, similar to that measured in giant molecular clouds in the galactic disk but significantly lower than the Solar System¹²C/¹³C ratio. The low HCN/H¹³CN abundance ratio may be in part due to contamination by an SO₂line blended with the H¹³CN (4–3) line. In addition, chemical models suggest that the HCN/H¹³CN ratio can be affected by fractionation during the collapse phase of the protosolar nebula; hence a low HCN/H¹³CN ratio observed in a comet is not inconsistent with the solar system¹²C/¹³C isotopic ratio. The abundance of HNCO relative to water derived from our observations is (7 ± 3) × 10⁻⁴. The HCN/HNCO abundance ratio is similar to that measured in the core of Sagittarius B2 molecular cloud. Although a photo-dissociative channel of HNCO leads to CO, the CO produced by HNCO is a negligible component of cometary atmospheres. Production rates of HCN, CO, H₂CO, and CH₃OH are presented. Inferred molecular abundances relative to water are typical of those measured in comets at 1 AU from the Sun. The exception is CO, for which we derive a large relative abundance of 30%. The evolution of the HCN production rate between March 20 and March 30 suggests that the increased activity of the comet was the cause of the fragmentation of the nucleus. The time evolution of the H₂CO emission suggests production of this species from dust grains.     

Long- and Short-Term Photometric Behavior of Comet Hyakutake (1996 B2)

Narrowband filter photometry observations of Comet Hyakutake (1996 B2) were used to investigate this comet's short-term variability as well as its behavior for the apparition as a whole. Utilizing measurements obtained on a total of 13 nights between February 9, 1996, and April 14, 1996, we find that the heliocentric distance (r_H) dependence of the production rates of OH and NH were much shallower than those for either the carbon-bearing species or the visible dust. Based on the OH measurements, the derived water r_H-dependence was also significantly less steep than expected from a basic water vaporization model and required an effective active surface area of about 29 km² at r_H=1.8 AU, 16 km² at r_H=1 AU, and only 13 km² at r_H=0.6 AU. This decrease in active area may be due to seasonally induced variations of a heterogeneous surface, or due to a decreasing contribution of gas from icy grains in the innermost coma. The relative abundances of the minor gas species place Hyakutake into the “typical” category of comets in the A'Hearn et al. (1995, Icarus118, 223-270) taxonomic classification system. The spectrum is generally redder at shorter wavelengths throughout the apparition; however, the dust color progressively changes from being significantly reddened (37%/1000 Å) at large r_H to near-solar at small r_H. This change of color with distance implies a significant change in grain sizes or a changing proportion between two or more grain populations.A major outburst was initiated near March 19.9, just prior to the comet's close approach to Earth. The characteristic recovery from the outburst differed among the observed species, with OH recovering most rapidly, essentially returning to its baseline values by March 25. The spatial radial fall-off of OH throughout this interval was consistent with the expected nominal spatial distribution, while CN and C₂ displayed fall-offs consistent with a distributed source, and the dust fall-off was significantly less steep than 1/ρ, possibly due to fragmenting grains. Rotational lightcurve amplitudes were largest for the OH, NH, and dust, again consistent with the carbon-bearing species primarily originating from a distributed source. Significant variations were observed in the lightcurve amplitude and phase shifts as functions of aperture size. Finally, a refined value for the rotation period of 0.2614±0.0003 day was determined.     

Infrared Observations Of Volatile Molecules In Comet Hale-Bopp

Infrared observations of comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp) benefited from the high spectral resolution and sensitivity of échelle spectrometers now equipping ground-based telescopes and from the availability of the Infrared Space Observatory (ISO). From the ground, several hydrocarbons were unambiguously detected for the first time: CH₄, C₂H₂, C₂H₆. Water was observed through several of its hot vibrational bands, escaping telluric absorption. CO, HCN, NH₃ and OCS were also observed, as well as several radicals. This permitted the evaluation of molecular production rates, of rotational temperature, and — taking advantage of the 1-D imaging of long-slit spectroscopy — of the space distribution of these species. With ISO, carbon dioxide was directly observed for the second time in a comet (after its detection from the Vega probes in P/Halley). The spectrum of water was investigated in detail (several bands of vibration and far-infrared rotational lines), permitting the evaluation of the rotational temperature of water, and of it spin temperature from the ortho-to-para ratio. Water ice was identified in the grains of Hale-Bopp as far as 7 AU from the ground and possibly at 3 AU with ISO. The composition of cometary volatiles appears to be strikingly similar to that of interstellar ices. This revised version was published online in July 2006 with corrections to the Cover Date.     

Sulfur Chemistry at Millimeter Wavelengths in C/Hale-Bopp

The recent availability of bright comets has given us an excellent opportunity to study cometary chemistry. Comet Hale-Bopp (1995 O1)gave us the particularly rare opportunity to study a bright and active comet for almost two years. Our program concentrated on millimeter-wave observations of sulfur-bearing molecules in an effort to understand the total sulfur budget of the comet. Using the National Radio Astronomy Observatory 12-m telescope on Kitt Peak we monitored both the long and short-term variations in H₂S, CS, and OCS, as well as observing H₂CS and SO. This was the first observation of H₂CS in any comet (Figure 1). Additionally, we mapped CS with the BIMA interferometer. Variations in the line profiles and changes in line intensity as large as a factor of two were seen in day to day observations of both H₂S and CS. An example for H₂S is shown in Figure 2. This is the first time we can attempt to study the entire group of sulfur-bearing molecules. Models of the sulfur coma have thus far largely been based on observations of the daughter products CS and atomic sulfur made over the last 18 years using the International Ultraviolet Explorer (IUE) satellite, coupled with radio observations of CS and H₂S in several recent comets. Four new sulfur-bearing species have been observed in comets Hale-Bopp and Hyaku take, three of them parent species. The high resolution maps in CS will also allow spatial information to be included in the sulfur model for the first time. C/Hale-Bopp is the first comet in which so many sulfur species have been observed. Analysis of the abundances of these species in comparison to the total atomic sulfur observed should reveal whether or not we can now account for all of the primary sulfur sources in comets. Perhaps the most interesting question that these observations raised was why C/Hale-Bopp appeared to contain so much more SO and SO₂ (as observed by others) than any other comet. This spurred the discovery that the UV fluorescence models of these species were incorrect (S. J. Kim, this issue). Analysis of the data and modeling of the sulfur budget are still underway. This revised version was published online in July 2006 with corrections to the Cover Date.     

Infrared measurements of the chemical composition of C/2006 P1 McNaught

C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 10³¹ molecules s⁻¹. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H₂O, CH₄, C₂H₂, C₂H₆, HCN, CO, NH₃, H₂CO) and two daughter fragments (OH and NH₂) were detected, enabling the determination of a rotational temperature and production rate for H₂O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH₄ (relative to H₂O) are slightly depleted while C₂H₂, NH₂ and possibly NH₃ are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.     

The Infrared Spectrum of Comet Hele–Bopp as Seen by the Infrared Space Observatory

Spectra of comet C/1995 O1 (Hale-Bopp) were obtained with the Infrared Space Observatory (ISO) at medium resolution with the grating spectrometer in the photometer (PHT-S) and/or at high resolution with the short wavelength spectrometer (SWS) and long wavelength spectrometer (LWS) in April 1996 (Crovisier et al., 1996), September–October 1996 (Crovisier et al., 1997a, b) and December 1997, at distances from the Sun of 4.6, 2.9 and 3.9 AU, respectively. For the first time, high-resolution spectra of a comet covering the entire 2.4 to 200 μm spectral range were obtained. The vibrational bands of H₂O, CO₂ and CO are detected in emission with PHT-S. Relative production rates of 100:22:70 are derived for H₂O:CO₂:CO at 3 AU pre-perihelion. H₂O is observed at high spectral resolution in the ν₃ group of bands around 2.7 μm and the ν₂ group around 6 μm with SWS, and in several rotational lines in the 100–180 μm region with LWS. The high signal-to-noise ratio of the ν₃ band observed on September–October 1996 allows accurate determinations of the water rotational temperature (28 K) and of its ortho-to-para ratio(2.45 ± 0.10, which significantly differs from the high temperature limit and corresponds to a spin temperature of 25 K). Longward of 6 μm the spectrum is dominated by dust thermal continuum emission, upon which broad emission features are superimposed. The wavelengths of the emission peaks correspond to those of Mg-rich crystalline olivine (forsterite). In the September–October 1996 spectra, emission features at 45 and 65 μm and possible absorption at 2.9–3.2 μm suggest that grains of water ice were present at 3 AU from the Sun. The observations made post-perihelion in late December 1997 led to the detections of H₂O, CO₂ and CO at 3.9 AU from the Sun (Figures 1 and 2). The production rates were ≈3.0 × 10²⁸,3.5 × 10²⁸ and ≈1.5 × 10²⁹ s^-1, respectively. This corresponds to H₂O:CO₂:CO = 100:110:500 and confirms that at such distances from the Sun, cometary activity is dominated by sublimation of CO and CO₂ rather than by H₂O. This revised version was published online in July 2006 with corrections to the Cover Date.     

Infrared study of ion-irradiated N2-dominated ices relevant to Triton and Pluto: formation of HCN and HNC

Infrared spectra and radiation chemical behavior of N₂-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N₂-rich ices containing CH₄ and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH₂N₂) form in the solid phase, along with several radicals. NH₃ is also identified in irradiated N₂ + CH₄ and N₂ + CH₄ + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N₂/CH₄ ratios from 100 to 4, and in three-component mixtures have an initial N₂/(CH₄ + CO) ratio of 50. HCN and HNC are not detected in N₂-dominated ices when CH₄ is replaced with C₂H₆, C₂H₂, or CH₃OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N₂ + CH₄ and N₂ + CH₄ + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N₂-rich ices containing CH₄.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH₃) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN⁻, CN⁻, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH₃, NH₄OCN, and NH₄CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides.     

Chemical and physical properties of gas jets in comets: I. Monte Carlo model of an inner cometary coma

We describe a 3-dimensional, time-dependent Monte Carlo model developed to analyze the chemical and physical nature of a cometary gas coma. Our model includes the necessary physics and chemistry to recreate the conditions applicable to Comet Hale-Bopp when the comet was near 1 AU from the Sun. Two base models were designed and are described here. The first is an isotropic model that emits particles (parents of the observed gases) from the entire nucleus; the second is a jet model that ejects parent particles solely from discrete active areas on the surface of the comet nucleus, resulting in coma jets. The two models are combined to produce the final model, which is compared with observations. The physical processes incorporated in both base models include: (1) isotropic ejection of daughter molecules (the observed gases) in the parent's frame of reference, (2) solar radiation pressure, (3) solar insolation effects, (4) collisions of daughter products with other molecules in the coma, and (5) acceleration of the gas in the coma. The observed daughter molecules are produced when a parent decays, which is represented by either an exponential decay distribution (photodissociation of the parent gas) or a triangular distribution (production from a grain extended source). Application of this model to the analysis the OH, C₂ and CN gas jets observed in the coma of Comet Hale-Bopp is the focus of the accompanying paper [Lederer, S.M., Campins, H., Osip, D.J., 2008. Icarus, in press (this issue)].     

The organic composition of Comet C/2001 A2 (LINEAR): I. Evidence for an unusual organic chemistry

We used the NIRSPEC instrument on the Keck-2 telescope atop Mauna Kea, HI to observe Comet C/2001 A2 (LINEAR) in a Target of Opportunity campaign on UT 2001 July 9.5, 10.5 August 4.4, 10.5. We measured seven organic parent volatiles (C₂H₆, C₂H₂, HCN, CH₄, CO, CH₃OH, H₂CO) simultaneously with H₂O. We obtained absolute production rates and relative abundances for parent volatiles, and also measured rotational temperatures for several of these species. The chemical composition of C/2001 A2 differs substantially from any comet we have observed to date. The abundances we measure (relative to H₂O) for C₂H₆, C₂H₂, HCN, and CH₃OH are enriched by a factor of ∼2 to 3 in C/2001 A2 compared with most comets in our database. Other molecular species were detected within the typical range of measured abundances. C/2001 A2 presented a unique opportunity to study the chemistry of a fragmenting comet where pristine areas are exposed to the Sun.     

Shock waves and the chemical structure of interstellar clouds

In this paper we study the effect of shock waves on the chemical structure of the interstellar clouds. A model of molecular cloud has been assumed. The chemistry is investigated in a time dependent model. Our chemical network contains 56 species in 251 reactions to including molecules of the elements H, O, C, N, S, and Si.The results indicate that the calculated fractional abundance of the molecules NS, H₂O, CN, NH, CO, and SO agrees well with the observations. The molecules OH, H₂S, CS, H₂CS, HS, NO, SiO, CH, CH₂, CH₃, HCO, C₂, and HCN reach high post-shock abundances.