Determination of Fe,Ni, Cu,Zn, Cd and Pb in seawater by isotope dilution automatic solid-phase extraction—ICP-MS

A thorough understanding of the biogeochemical cycling of trace metals in the ocean is crucial because of the important role these elements play in regulating metabolism in marine biotas and thus, the climate. However, a precise and accurate analysis of trace metals in seawater is difficult because they are present at extremely low concentrations in a high salt matrix. In this study, we report an analytical method for the preconcentration and separation of six trace metals, Fe, Ni, Cu, Zn, Cd and Pb, in seawater using a seaFAST automatic solid-phase extraction device, analysis by a triple quadrupole collision/reaction technique with inductively coupled plasma mass spectrometry (ICP-MS), and quantification by the isotope dilution technique. A small volume (10 mL) of seawater sample was mixed with a multi-element isotope spike and subjected to seaFAST procedures. The preconcentrate solution was then analyzed using the optimized collision/reaction cell mode of ICP-MS, with NH₃ gas for Fe and Cd with a flow rate of 0.22 mL/min and He for Ni, Cu, Zn and Pb with a flow rate of 4.0 mL/min. The procedure blanks were 130 pmol/L, 3.0 pmol/L, 6.8 pmol/L, 37 pmol/L, 0.29 pmol/L and 0.42 pmol/L, for Fe, Ni, Cu, Zn, Cd and Pb, respectively. The method was validated using five reference materials (SLRs-6, SLEW-3, CASS-6, NASS-7 and GEOTRACE-GSC), and our results were consistent with the consensus values. The method was further validated by measuring full-water-column seawater samples from the subtropical Northwest Pacific Ocean, and our results demonstrated good oceanic consistency.     

Shifting sands? Coastal protection by sand banks,beaches and dunes

In a closely integrated system, (sub-) littoral sandy sediments, sandy beaches, and sand dunes offer natural coastal protection for a host of environmentally and economically important areas and activities inland. Flooding and coastal erosion pose a serious threat to these environments, a situation likely to be exacerbated by factors associated with climate change. Despite their importance, these sandy ‘soft’ defences have been lost from many European coasts through the proliferation of coastal development and associated hard-engineering and face further losses due to sea-level rise, subsidence, storm surge events, and coastal squeeze. As part of the EU-funded THESEUS project we investigated the critical drivers that determine the persistence and maintenance of sandy coastal habitats around Europe's coastline, taking particular interest in their close link with the biological communities that inhabit them. The successful management of sandy beaches to restore and sustain sand budgets (e.g. via nourishment), depends on the kind of mitigation undertaken, local beach characteristics, and on the source of ‘borrowed’ sediment. We found that inter-tidal invertebrates were good indicators of changes linked to different mitigation options. For sand dunes, field observations and manipulative experiments investigated different approaches to create new dune systems, in addition to measures employed to improve dune stabilisation. THESEUS provides a ‘toolbox’ of management strategies to aid the management, restoration, and creation of sandy habitats along our coastlines, but we note that future management must consider the connectivity of sub-littoral and supra-littoral sandy habitats in order to use this natural shoreline defence more effectively.     

Investigation of geotechnical and geochemical relationships by parameter cross‐correlation methods,oslofjorden and dramsfjorden,Norway

Abstract

A cross‐correlation matrix was computer developed to investigate the statistical dependence of geotechnical properties on other properties as an aid to learning why such dependence exists. Linear correlation coefficients, based on 10,000 data values from borings in four major basins along the axis of the Oslofjorden, and one boring at the south end of the Dramsfjorden, are presented for 17 measured or calculated geotechnical and geochemical parameters. Confidence levels of 99 percent and 99.99 percent were calculated for all parameters, and causative and fortuitous relationships or linkages were investigated using regrouped matrices showing correlations significant at the 99.99 percent confidence level. A table summarizes parameters correlating in both fjords, only in the Oslofjorden, only in the Dramsfjorden, and in neither fjord.

Generally, relationships were as expected. Examples of unexpected absence of correlations follow: In the Oslofjorden, the clay‐size fraction and the plastic limit correlated only with the activity and the liquid limit, respectively. The lack of correlation with other parameters may be related to the character of the clay‐size fraction. In the Dramsfjor‐den, the sensitivity did not correlate with any other parameter, which may be related to the anoxic soils found in this fjord.     

Confirmation of beach accretion by grain-size trend analysis: Camposoto beach, Cádiz, SW Spain

An application of the grain size trend analysis (GSTA) is used in an exploratory approach to characterize sediment transport on Camposoto beach (Cádiz, SW Spain). In May 2009 the mesotidal beach showed a well-developed swash bar on the upper foreshore, which was associated with fair-weather conditions prevailing just before and during the field survey. The results were tested by means of an autocorrelation statistical test (index I of Moran). Two sedimentological trends were recognized, i.e. development towards finer, better sorted and more negatively skewed sediment (FB–), and towards finer, better sorted and less negatively or more positively skewed sediment (FB+). Both vector fields were compared with results obtained from more classical approaches (sand tracers, microtopography and current measurements). This revealed that both trends can be considered as realistic, the FB+ trend being identified for the first time in a beach environment. The data demonstrate that, on the well-developed swash bar, sediment transported onshore becomes both finer and better sorted towards the coast. On the lower foreshore, which exhibits a steeper slope produced by breaking waves, the higher-energy processes winnow out finer particles and thereby produce negatively skewed grain-size distributions. The upper foreshore, which has a flatter and smoother slope, is controlled by lower-energy swash-backwash and overwash processes. As a result, the skewness of the grain-size distributions evolves towards less negative or more positive values. The skewness parameter appears to be distributed as a function of the beach slope and, thus, reflects variations in hydrodynamic energy. This has novel implications for coastal management.

Seabird bycatch by tuna longline fisheries off southern Africa, 1998–2000

The incidental mortality of seabirds in tuna longline fisheries is estimated for the continental South African Exclusive Economic Zone (EEZ). Fishery observers accompanied 13 fishing trips and observed 108 sets (143 260 hooks) during the period 1998–2000. Despite most lines being set at night, seabird bycatch rates were high, with a mean of 1.6 birds killed per 1 000 hooks. Japanese vessels (1% effort observed) had a higher bycatch rate (2.6 birds per 1 000 hooks, range per trip 0.1–5.4) than South African vessels (0.8, range 0.0–4.3; 17% effort observed), possibly as a result of gear differences. Bird bycatch differed regionally in relation to the numbers of birds attending vessels. In international waters off the Northern Cape and southern Namibia, where there are few birds, only one bird was caught on 93 600 hooks (0.01 birds per 1 000 hooks). Shy Thalassarche cauta, black-browed T. melanophris and yellow-nosed T. chlororhynchos albatrosses, and white-chinned petrels Procellaria aequinoctialis were killed most frequently. Based on 1998–1999 fishing effort, simple extrapolation suggests that 19 000–30 000 seabirds are killed annually in South Africa's EEZ, of which 70% are albatrosses. Confidence in these estimates is low, given the small proportion of effort observed, but it is clear that urgent steps are needed to reduce seabird bycatch within South African waters.     

Direct Determination of Cd, Pb, Cu in marine Sediments and Suspended Matters by Graphite Furnace Atomic Absorption Spectrometry

A simple and rapid method has been proposed for direct determination of Cd, Pb, Cu in marine sediments and suspended matters by graphite furnace atomic absorption spectrometry, using the HNO_3-HClO_4-HF decomposition. The L'vov platform and matrix modiffer technique were used with peak-area measurement to effectively eliminate the matrix     

Atypical size selection of captive school prawns,Metapenaeus macleayi,by three recreational fishing gears in south‐eastern Australia

Three manipulative experiments were done to estimate the selectivity of conventional and new sizes and configurations of mesh for school prawns, Metapenaeus macleayi, in three south‐eastern Australian recreational fishing gears (haul, push, and scoop nets). The treatment meshes examined were: (1) conventional‐sized, diamond‐shaped mesh used in all gears (20 mm in scoop nets and 30 mm in push and haul nets); (2) 30 mm in scoop nets; and (3) 40‐mm diamond‐ and (4) 23‐mm square‐shaped mesh in all gears. In all experiments, known quantities of school prawns (6–24 mm carapace length (CL)) were placed in purpose‐built enclosures, monitored to ensure no experimental‐induced stress (as measured by changes in L‐lactate in their haemolymph) and the replicate treatments of the various gear configurations deployed. Escapees from the various treatment nets were collected from the enclosures using fine‐meshed nets. Logistic selection curves were derived for all treatment nets and specific comparisons made within and among gears. All nets had 50% retention lengths (L₅₀) comparable to other penaeid‐catching gears with similar mesh sizes, but most had selection ranges (SRs) that were atypically inflated. The large SRs were attributed to a combination of factors that included the mesh geometry and towing speed of the gears and the behaviour of school prawns. The 20‐mm scoop net had the smallest selection parameters, retaining >99% of individuals larger than 13 mm CL. Mesh size in this gear would need to be increased to at least 30 mm to allow some maturing prawns (>18 mm CL) to escape.     

Numerical simulation of sediment lifted by waves and transported by tidal currents

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