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1.
Room-temperature torsional-shear strengths of 1.27-cm-diameter × 0.25-cm-high disks of Nevada Test Site “Hardhat” granodiorite and a Mt. Burnette, Alaska, dunite were determined to about 90 kbar. Tests, for the most part, were run under linearly increasing pressure at constant rates of applied twist: about 3–30° at 5.73 · 10−4–10−2 degr./sec for granodiorite, and 18° at 5.73 · 10−3 and 10−2 degr./sec for dunite. Transitions are observed in the rate of shear-strength change for the granodiorite at about 15, 35 and 80 kbar. Minor and recoverable instabilities in strength occur over the pressure range 15–80 kbar. Beyond about 80 kbar, the shear strength increases sharply and is terminated with a strain-release of explosion-like violence. Strain rate showed some influence on strength and magnitude of energy-release at higher pressures. Residual microstructures showed that, below 15 kbar, intragranular extensional fracturing, intergranular sliding, and bulk consolidation mainly occur. Between 15 and 35 kbar, intragranular undulatory extinction, random and crystallographic ruptures, and initial intragranular slip are observed. The predominant mechanisms between 35 and 80 kbar are an increasing frequency of intragranular slip, and networks of short, irregular, intragranular ruptures. Bulk fracturing and faulting were not observed. Samples stressed to explosion-like failure showed extensive crystal fragmentation, and series of parallel bands. Alternate bands were birefringent and isotropic, respectively, and extended over a considerable part of the samples. Dunite showed a transition from diminishing to increasing shear strength at about 80 kbar, but no explosion-like release of strain energy to 95 kbar. Comparative data to 70 kbar also are given for a slightly serpentinized dunite, a granite, a gneiss, three extrusive porphyries, and a marble. X-ray diffraction powder patterns of all stressed samples revealed only a broadening of peaks and a reduction of intensities from higher levels of stress.  相似文献   

2.
Measurements of compressional wave velocity Vp were made in a gas apparatus to 500°C at 10 kbar in three cores of an anisotropic dunite specimen from Twin Sisters Mountain. The axial directions of the three chosen cores coincide with the preferred directions and concentration of olivine crystallographic axes (a [100], b [010], andc [001]).Measured (δVp/δT)p values at 10 kbar in the three cores (−6.7, −5.4 and −6.2 · 10−4 km/sec · deg, respectively), and the mean value for the dunite (−6.1 · 10−4 km/sec · deg) are larger than the Voigt-Reuss-Hill values calculated from single-crystal data. This discrepancy is explained by the presence of internal thermal stresses, due to anisotropic expansion of olivine grains, causing grain boundary cracks to widen.It is concluded that high negative values of (δVp/δT)p for rocks reported in the literature should be carefully evaluated in terms of the formation of new cracks or widening of cracks already present under high pressure-temperature environments.  相似文献   

3.
Diopside single-crystals, oriented favorably for twin gliding on both systems: (001) [100] and (100)[001] have been deformed in a Griggs apparatus using talc as pressure medium. The latter mechanism is dominant at temperatures (T) below 1050° C at strain rates () of 10−3 sec−1, and below 800° C at ; at higher temperatures translation gliding on (100)[001] accompanied by syntectonic recrystallization is dominant but other glide systems also operate. Tests at a single set of conditions, T- and -incremental tests and stress-relaxation experiments have been carried out on websterite (68% CPX, 32% OPX), both in talc (“wet”) and talc-AlSiMag (“dry”) assemblies. Most tests were performed in the high-T regime, where syntectonic recrystallization and “relatively nonselective” glide are dominant. The mean size of recrystallized clinopyroxenes (D, μm) appears to be related to stress (σ, kb) as D = 60σ−0.9. The mechanical data fit the power law exp(-Q/RT)σn, where for the “wet” experiments A = 105.9kb−nsec−1, Q = 91.2 kcal/mole, n = 5.3; for σ < 3.5 kb n appears to decrease to 3.3. For the “dry” experiments A = 102.2, Q = 77.9, and n = 4.3 for σ < 7.0 kb. Clinopyroxene in the upper mantle occurs as ca. 0–15% mixed phase in peridotites and websterites occur as thin layers. Stresses in these materials will then be near those in the olivine-rich matrix. At , the equivalent viscosity of dry websterite is less than that of dry dunite at depths to 60 km but it increases rapidly at higher pressures; at 240 km it is 106 greater than that of dunite. This may account for the low strains and passive behavior observed for clinopyroxene crystals in most peridotites and websterites, that presumably have formed at great depth. Attenuated folds of websterite in peridotite—evidence of more ductile behavior—may then have formed at shallower levels; alternatively they may have formed under “wet” conditions.  相似文献   

4.
Previous experiments by Raleigh et al. (1971) have shown that at strain rates of 10−2.sec−1 to 10−7.sec−1 only slip occurs in dry enstatite at temperatures above 1300°C and 1000°C, respectively.The present experiments have been conducted on polycrystalline enstatite under wet conditions in this regime where enstatite only slips, polygonizes and recrystallizes. Slip occurs throughout the whole regime on the system (100)[001] and at strains greater than 40% the system (010)[001] is observed. Polygonization and intragranular recrystallization begin at about 1300°C and 10−4.sec−1 and the orientation of these neoblasts is host-controlled. At lower strain rates intergranular neoblasts develop and their fabric is one of [100] maximum parallel with σ1 and [010] and [001] girdles in the σ2 = σ3 plane, similar to those in natural enstatite tectonites.Dislocation substructures of experimentally deformed enstatite have been examined by transmission electron microscopy. The samples were deformed within the field in which slip polygonization and recrystallization are the dominant deformation mechanisms. Samples within this regime have microstructures that are characterized by stacking faults and partial dislocations. Under the conditions of steady-state flow in olivine, these microstructures inhibit the operation of recovery mechanisms in enstatite.Other samples deformed within the polygonization and recrystallization field have microstructures that confirm the optical observations of intragranular and intergranular growth of neoblasts. It is suggested that the former result from strain-induced tilt of subrains, whereas the latter may result from bulge nucleation into adjacent subgrains.Mechanical data from constant strain-rate experiments at steady state, stress relaxation and temperature-differential creep tests are best fit to a power-law creep equation with the stress exponent, n~3 and the apparent activation energy for creep, Q~65 kcal/mole. Extrapolation of this equation to a representative natural geologic strain rate of 10−4. sec−1, over the temperature interval 1000–2000°C, gives an effective viscosity range of 1020–1018 poise and stresses in the range of 7-0.1 bar, respectively. Comparison with corrected wet-olivine mechanical data (Carter, 1976) over the same environment indicates that olivine is consistently the weaker of the two minerals and will recrystallize whilst enstatite will only slip and kink, thus accounting for the different habits of olivine and enstatite in ultramafic tectonites.  相似文献   

5.
Artificially prepared specimens of bischofite (MgCl2-6H2O) have been experimentally deformed at temperatures between 20 and 100°C, strain rates between 10−4 and 10−88 s−1, and confining pressures between 0.1 and 28 MPa. Development of microstructure with strain was studied by in-situ deformation experiments, and results of these were correlated with observations made on thin sections of deformed samples.In a first series of experiments the effect of grain size, impurity content and water content on the flow behaviour was investigated. Addition of about 0.1 wt.% water to dry samples was found to decrease the flow stress by a factor of 5. This effect was found to be associated with the formation of a thin fluid film on grain boundaries, strongly enhancing dynamic recrystallization due to the movement of high-angle grain boundaries, and possibly also to enhanced intracrystalline plasticity due to excess water present in the lattice. In a second series of experiments the strain-rate sensitivity of the flow stress of selected samples was investigated. Two regimes could be distinguished: one with a stress exponent n = 4.5 in the power law creep equation for values of the differential stress above 2.0 MPa, and one with n = 1.5 for stresses below this value.The main deformation mechanisms were intracrystalline slip, twinning, and grain-boundary sliding. Recrystallization occurred by subgrain rotation and high-angle grain-boundary migration. The rates of grain-boundary migration fell into two different regimes, one regime being distinguished by extremely fast migration rates. The applicability of the experimentally found flow law to the behaviour of bischofite rocks in nature is discussed.  相似文献   

6.
Deformation mechanism maps for feldspar rocks   总被引:6,自引:0,他引:6  
Deformation mechanism maps for feldspar rocks were constructed based on recently published constitutive laws for dislocation and grain boundary diffusion creep of wet and dry plagioclase aggregates. The maps display constant temperature contours in stress-grain size space for strain rates ranging from 10−16 to 10−12 s−1.Two fields of dominance of grain boundary diffusion-controlled creep and dislocation creep are separated by a strongly grain size-sensitive transition zone. For wet rocks, diffusion-controlled creep dominates below a grain size of about 0.1–1 mm, depending on temperature, stress, strain rate and feldspar composition. Plagioclase aggregates containing up to 0.3 wt.% water as often found in natural feldspars are more than 2 orders of magnitude weaker than dry rocks. The strength of water-bearing feldspar rocks is moderately dependent on composition and water fugacity.For a grain size range of about 10–50 μm commonly observed in natural ultramylonites, the deformation maps predict that diffusion-controlled creep is dominant at greenschist to granulite facies conditions. Low viscosity estimates of 1018–1019 Pa·s from modeling postseismic stress relaxation and channel flow of the continental lower crust can only be reconciled with laboratory experiments assuming dislocation creep at high temperatures >900 °C or, at lower temperatures, diffusion creep of fine-grained rocks possibly localized in abundant high strain shear zones. For similar thermodynamic conditions and grain size, lower crustal rocks are predicted to be less than order of magnitude weaker than upper mantle rocks.  相似文献   

7.
Naturally deformed clinoamphiboles from the Selbu-Tydal and Forsbäck-Tärnaby areas of the Scandinavian Caledonides exhibit a well defined subgrain microstructure. From a transmission electron microscopy study (TEM), the subgrain boundaries are shown to consist of arrays of positive and negative screw dislocations with Burgers vector . Locally expanded loops are present having long screw segments. The subgrain boundaries are parallel to rational crystallographic planes of the type (hk0). The density of isolated dislocations within the subgrains is low. In addition planar defect structures parallel to (010) and bounded by screw dislocations with are observed. Based on metamorphic criteria the PT values at the time of the amphibole growth have been estimated at 450°–600°C and 4–6 kbar, and these represent maximum conditions for the deformation. The present results indicate that slip on (hk0) [001] is an operative deformation mechanism in naturally deformed clinoamphiboles.  相似文献   

8.
It is often observed that dynamic recrystallization results in a recrystallized grain size distribution with a mean grain size that is inversely related to the flow stress. However, it is still open to discussion if theoretical models that underpin recrystallized grain size–stress relations offer a satisfactorily microphysical basis. The temperature dependence of recrystallized grain size, predicted by most of these models, is rarely observed, possibly because it is usually not systematically investigated. In this study, samples of wet halite containing >10 ppm water (by weight) were deformed in axial compression at 50 MPa confining pressure. The evolution of the recrystallized grain size distribution with strain was investigated using experiments achieving natural strains of 0.07, 0.12 and 0.25 at a strain rate of 5×10−7 s−1 and a temperature of 125 °C. The stress and temperature dependence of recrystallized grain size was systematically investigated using experiments achieving fixed strains of 0.29–0.46 (and one to a strain of 0.68) at constant strain rates of 5×10−7–1×10−4 s−1 and temperatures of 75–240 °C, yielding stresses of 7–22 MPa. The microstructures and full grain size distributions of all samples were analyzed. The results showed that deformation occurred by a combination of dislocation creep and solution-precipitation creep. Dynamic recrystallization occurred in all samples and was dominated by fluid assisted grain boundary migration. During deformation, grain boundary migration results in a competition between grain growth due to the removal of grains with high internal strain energy and grain size reduction due to grain dissection (i.e. moving boundaries that crosscut or consume parts of neighbouring grains). At steady state, grain growth and grain size reduction processes balance, yielding constant flow stress and recrystallized grain size that is inversely related to stress and temperature. Evaluation of the recrystallized grain size data against the different models for the development of mean steady state recrystallized grain size revealed that the data are best described by a model based on the hypothesis that recrystallized grain size organizes itself in the boundary between the (grain size sensitive) solution-precipitation and (grain size insensitive) dislocation creep fields. Application of a piezometer, calibrated using the recrystallized grain size data, to natural halite rock revealed that paleostresses can vary significantly with temperature (up to a factor of 2.5 for T=50–200 °C) and that the existing temperature independent recrystallized grain size–stress piezometer may significantly underestimate flow stresses in natural halite rock.  相似文献   

9.
The densification curves for the hot-pressing of pure olivine powders were obtained as a function of grain size (5 μ–2000 μ), temperature (1000–1600°C), and compacting stress (166–298 bars). This range of variables was found to straddle two fields of hot-pressing behavior, one dominated by power-law creep, one by Coble creep. The time required to density a powder to 99% of the single crystal density could be represented by the shorter of the two times: t1 = 2.2 · 103σ−3.4exp(85,000/RT)t2 = 1.3 · 104σ−1.5(G)+3exp(85,000/RT) where the compacting stress or pressure, σ, is given in bars and the grain size, G, in centimeters. It was also possible to estimate the parameters appropriate to Coble creep in a solid polycrystalline aggregate from the hot-pressing data; and these were:
The strain rates computed from this formula are close to those predicted by Stocker and Ashby (1973) and those found by Twiss (1976).  相似文献   

10.
Batch wet grinding of zeolite was studied with emphasis on a kinetic study in a laboratory size steel ball mill of 200 mm diameter. The breakage parameters were determined by using the single sized feed fractions of − 850 + 600 µm, − 600 + 425 µm and − 425 + 300 µm for the zeolite samples. The Si (specific rate of breakage) and Bi,j (primary breakage distribution) values were obtained for those feed size fractions in order to predict the product size distributions by simulation for comparison to the experimental data. The specific rates of breakage values for wet grinding in the first-order breakage region were higher than the dry values reported previously by a factor 1.7 at the same experimental conditions, but the primary breakage distribution (Bi,j) values were approximately the same. The simulations of the product size distributions of zeolite were in good agreement with the experimental data using a standard ball mill simulation program. The wet grinding of zeolite was subjected to slowing-down effect in the mill at 2 min of grinding, corresponding to an 80% passing size of about 400 µm. On the other hand, the slowing down effect in the dry grinding of zeolite was also seen at 4 min of grinding. In addition, effects of some operational parameters on dry and wet grinding of zeolite were determined by simulation using the breakage parameters obtained experimentally.  相似文献   

11.
Finite-element folds of similar geometry   总被引:3,自引:0,他引:3  
Model folds of similar geometry have been produced by using the finite-element method and the constitutive relations of a layer of wet quartzite embedded in a marble matrix with an initially sinusoidal configuration and a 10° limb dip. The power law for steady-state flow of Yule Marble (Heard and Raleigh, 1972) is used for the matrix and our new law for Canyon Creek quartzite deformed in the presence of water is used for the layer. The equiv- alent viscosity of the wet quartzite is highly temperature-sensitive, giving rise to a strong temperature dependence of the quartzite: marble viscosity ratio which, at a strain rate of 10−14/sec, drops from 543 at 200° to 0.13 at 800°C. At 375°C (ηq/ηm = 10), concentric folds develop at all strains to 80% natural shortening and stress, finite strain and viscosity distributions are somewhat similar to those found previously. Raising the temperature to 550° C (ηq/ηm = 1), at any stage of prior amplification, causes the folds to flatten with increasing strain, accompanied by attenuation of limbs and thickening of hinges, leading to folds with similar geometries and isoclinal folds at extreme strains. The effects are more pronounced at higher temperatures and at 700° C (ηq/ηm = 0.3) limb attenuation is so severe as to give rise to unrealistic geometries. At temperatures below about 600° C (ηq/ηm = 2), similar folds do not form. It thus appears as if a viscosity contrast near unity is required to produce similar folds in rocks, under the conditions simulated and different temperature dependencies of viscosities of materials in layered sequences is one important means of reducing viscosity contrasts.  相似文献   

12.
Long-term creep tests of gabbro which have been performed with a maximum bending stress (20 bar) under a high confining pressure (1 kbar) and various temperatures, are described. Methods and techniques used in the experiment are mainly similar to those reported previously by the same authors (Itô and Sasajima, 1980) except for the application of high pressure and temperature. The techniques include the bending system, size and preparation of the sample, and the determination of its deformation by use of interference fringes of Na-D light. In order to measure a very small deformation of creep, intermittent breaks of the application of loading, confining pressure and temperature are necessary, and the creep curve is constructed from the intermittent advance of permanent deformation.The experiment has revealed two strange phenomena : one is a sinuous progress of the creep curve, and the other is that the deformation recovery shows strange behavior after the unloading. These results are discussed in close connection with the mechanism of the “turn back of creep” denoted by Itô and Sasajima (1980). The mean creep curves, at 25°C. 95°C and 150°C, obtained so far lead to viscosities of 1.6 · 1020, 1.9 · 1019 and 4.8 · 1018 poise, respectively and the maximum strain rates employed in the samples were 4.2 · 10−14, 3.6 · 10−13 and 1.4 · 10−12/sec, respectively, which cover the geological strain rate. Although we have only three data points, the logarithm of viscosity is linearly related to the reciprocal of absolute temperature (see Fig. 7), and an activation energy for creep of gabbro is found to be 7.6 kcal/mol. It should be noted that viscosities obtained are considerably smaller than those estimated for the crust and mantle, and that the activation energy is surprisingly smaller than those obtained by high-pressure experiments of rock deformation, which have been carried out under a strain rate larger than 10−8/sec.  相似文献   

13.
The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na3AlF6] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO2, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO2 and H2O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ13C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ18O of CO2 (+ 21 to + 42‰ VSMOW) and δ18O of H2O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H2O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid.  相似文献   

14.
The isotopic composition of Fe was determined in water, Fe-oxides and sulfides from the Tinto and Odiel Basins (South West Spain). As a consequence of sulfide oxidation in mine tailings both rivers are acidic (1.45 < pH < 3.85) and display high concentrations of dissolved Fe (up to 420 mmol l− 1) and sulphates (up to 1190 mmol l− 1).The δ56Fe of pyrite-rich samples from the Rio Tinto and from the Tharsis mine ranged from − 0.56 ± 0.08‰ to + 0.25 ± 0.1‰. δ56Fe values for Fe-oxides precipitates that currently form in the riverbed varied from − 1.98 ± 0.10‰ to 1.57 ± 0.08‰. Comparatively narrower ranges of values (− 0.18 ± 0.08‰ and + 0.21 ± 0.14‰) were observed in their fossil analogues from the Pliocene–Pleistocene and in samples from the Gossan (the oxidized layer that formed through exposure to oxygen of the massive sulfide deposits) (− 0.36 ± 0.12‰ to 0.82 ± 0.07‰). In water, δ56Fe values ranged from − 1.76 ± 0.10‰ to + 0.43 ± 0.05‰.At the source of the Tinto River, fractionation between aqueous Fe(III) and pyrite from the tailings was less than would be expected from a simple pyrite oxidation process. Similarly, the isotopic composition of Gossan oxides and that of pyrite was different from what would be expected from pyrite oxidation. In rivers, the precipitation of Fe-oxides (mainly jarosite and schwertmannite and lesser amounts of goethite) from water containing mainly (more than 99%) Fe(III) with concentrations up to 372 mmol l− 1 causes variable fractionation between the solid and the aqueous phase (− 0.98‰ < Δ56Fesolid–water < 2.25‰). The significant magnitude of the positive fractionation factor observed in several Fe(III) dominated water may be related to the precipitation of Fe(III) sulphates containing phases.  相似文献   

15.
Experimental study of syntectonic recrystallization of fine-grained quartz aggregates was carried out in order to simulate the development of some natural microstructures of quartz tectonites and to understand their formation condition. Agate was axially compressed with a constant-strain-rate apparatus. Experiments were conducted at 4 kbar solid confining pressure, 700–1000°C and 10−4-10−6 sec−1 to 10%–45% strain. In all runs, deformation has proceeded under wet condition caused by dehydration of pyrophyllite used as pressure medium.Two different types of microstructure were distinguished in the deformed specimens. One is P-type which is characterized by equant, equidimensional, and polygonal grains. The other is S-type which is characterized by the highly oblate grains with the largest dimension perpendicular to the compression axis. The P-type microstructure is developed at higher temperatures and slower strain rates, while the S-type developed at lower temperatures and faster strain rates. The transition between the S- and P-types is found to be very sharp.  相似文献   

16.
The genesis of Lower Eocene calcite-cemented columns, “pisoid”-covered structures and horizontal interbeds, clustered in dispersed outcrops in the Pobiti Kamani area (Varna, Bulgaria) is related to fossil processes of hydrocarbon migration. Field observations, petrography and stable isotope geochemistry of the cemented structures and associated early-diagenetic veins, revealed that varying seepage rates of a single, warm hydrocarbon-bearing fluid, probably ascending along active faults, controlled the type of structure formed and its geochemical signature. Slow seepage allowed methane to oxidize within the sediment under ambient seafloor conditions (δ18O = − 1 ± 0.5‰ V-PDB), explaining columns' depleted δ13C ratios of − 43‰. Increasing seepage rates caused methane to emanate into the water column (δ13C = − 8‰) and raised precipitation temperatures (δ18O = − 8‰). Calcite-cemented conduits formed and upward migrating fluids also affected interbed cementation. Even higher-energy fluid flow and temperatures likely controlled the formation of “pisoids”, whereby sediment was whirled up and cemented.  相似文献   

17.
Post-deformational annealing of calcite rocks   总被引:3,自引:3,他引:3  
The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10 4 s 1 to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.  相似文献   

18.
Reaction-induced weakening of plagioclase–olivine composites   总被引:1,自引:0,他引:1  
The localisation of strain into natural ductile shear zones is often associated with the occurrence of metamorphic reactions. In order to study the effects of solid–solid mineral reactions on plastic deformation of rocks, we have investigated the shear deformation of plagioclase–olivine composites during the reaction plagioclase + olivine → orthopyroxene + clinopyroxene + spinel (± garnet). Microstructures of plagioclase–olivine composites were studied after shear deformation experiments in a Griggs apparatus. Experiments were performed on anorthite–forsterite (An–Fo) and labradorite–forsterite (Lab–Fo) composites at 900 °C, confining pressures between 1000–1600 MPa and with constant shear strain rates of 5 × 10−5 s−1.In absence of reaction, Lab–Fo composites are stronger than pure olivine and labradorite end-members that deform with a high temperature plasticity mechanism. Lab–Fo composites strain–harden due to the inhibition of extensive recrystallisation by interphase boundaries.In An–Fo composites, the reaction induces strain weakening by a switch from dislocation creep to grain size sensitive deformation mechanisms through the development of fine-grained (size < 0.5 μm) polyphase reaction products. Interconnecting layers of reaction products accommodate most of the applied strain by grain size sensitive creep. Recovery processes are pronounced during syndeformational reaction: original anorthite and olivine dynamically recrystallise by subgrain rotation and bulging recrystallisation. Presumably, the dynamic recrystallisation is caused by reduced stress conditions and partitioning of strain and strain rates between the new reaction products and the relict An–Fo grains. The results of our experiments are in good agreement with natural observations of shear localisation in the lower crust and upper mantle, and imply that anhydrous mineral reactions can be important causes for localisation of deformation.  相似文献   

19.
In order to determine the effect of water on deformation in the brittle-ductile transition region of crustal rocks, experiments have been conducted on Westerly granite and a polycrystalline albite rock, comparing samples dried at 160°C for 12 h (‘dry’) and samples with about 0.2 wt% water added (‘wet’). The deformation mechanisms and style of deformation of the wet and dry samples, determined using optical and transmission electron microscopy, have been found to depend on temperature, pressure, strain rate, and strain. At 15 kb and 10−6, the added water reduces the temperature of the transition between microcracking and dislocation glide and climb by about 150–200°C for both quartz and feldspar. However, the penetration of ‘water’ into the grains is slow compared with the time of the experiments and many of the wet samples show evidence of initial microcracking and later dislocation creep. Wet samples deformed at 10 kb show less hydrolytic weakening than wet samples deformed at 15 kb. Because the deformation mechanism and strength of silicates depend so sensitively on trace amounts of water, and because the water content of experimental samples varies with temperature and pressure and thus with time, flow laws for any samples are only meaningful if the water content has been carefully controlled or characterized.  相似文献   

20.
A ‘soft’ carbon-based high-volatile bituminous (Ro max=0.68%) coal and a ‘hard’ carbon-based Pennsylvania anthracite (Ro max=5.27%) were deformed in the steady state at high temperatures and pressures in a series of coaxial and simple shear deformation experiments designed to constrain the role of shear strain and strain energy in the graphitization process. Tests were carried out in a Griggs-t type solid (NaCl) medium apparatus at T=400–900°C, constant displacement rates of 10-5−10-6 s−1, at confining pressures of 0.6 GPa (coaxial) or 0.8 and 1.0 GPa (simple shear). Coaxial samples were shortened up to 50%, whereas shear strains up to 4.9 were attained in simple shear tests. Experiments lasted up to 118 h. Deformed, high-volatile bituminous coal was extensively coked and no correlation between strain and Ro max, bireflectance or coal texture was observed in any samples. With increasing temperature, Ro max and bireflectance increase in highly anisotropic, coarse mosaic units, but remain essentially constant in the fine granular mosaic, which becomes more abundant at higher temperatures. Graphite-like reflectances are observed locally only in highly reactive macerals and in pyrolytic carbon veins. The degree of molecular ordering attained in deformed bituminous coal samples appears to be determined by the heating-pressurization path rather than by subsequent deformation.Graphitization did not occur in coaxially deformed anthracite. Nonetheless, dramatic molecular ordering occurs at T>700°C, with average bireflectance values increasing from 1.68% at 700°C to 6.36% at 900°C. Anisotropy is greatest in zones of high strain at all temperatures. In anthracite samples deformed in simple shear over the 600–900°C range at 1.0 GPa, the average Ro max values increase up to 11.9%, whereas average bireflectance values increase up to 10.7%. Bireflectance increases with progressive bedding rotation and, thus, with increasing shear strain. Graphitization occurs in several anthracite samples deformed in simple shear at 900°C. X-ray diffraction and transmission electron microscopy of highly anisotropic material in one sample confirms the presence of graphite with d002=0.3363 nm. These data strongly suggest that shear strain, through its tendency to align basic structural units, is the factor responsible for the natural transformation of anthracite to graphite at temperatures far below the 2200°C required in hydrostatic heating experiments at ambient pressure.  相似文献   

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