新疆托里别鲁阿嗄希地区花岗岩类的岩石学和成因

别鲁阿嘎希花岗闪长岩－石英闪长岩带与金矿化有十分密切的关系。锆石Ｕ－Ｐｂ法测得别鲁阿嘎希石英闪长岩年龄为３６９Ｍａ。斜长石环带成分振荡，与黑云母共生的角闪石成分显示为富镁。岩石地球化学特征表明，这些岩石为幔源的拉斑玄武岩岩浆和地壳部分熔融形成岩浆混合后的产物。     

西准噶尔别鲁阿嘎希花岗闪长岩年代学、地球化学特征及岩石成因

为更深入了解西准噶尔晚古生代岩浆活动和构造背景,对位于西准噶尔中部的别鲁阿嘎希岩体开展了年代学、地球化学以及Sr-Nd同位素研究,讨论了岩石成因、源区性质和构造背景.别鲁阿嘎希花岗闪长岩为钙碱性系列岩石,岩浆锆石结晶年龄为318.7±3.3 Ma.其具相对高的MgO(Mg#=49~59)、Ni、Cr含量,富集大离子亲石元素(如K、Rb、Sr和Ba)、亏损高强场元素(如Nb、Ta、Ti),轻重稀土元素分异不明显.Sr-Nd同位素特征显示,其有较低的初始Sr比值(0.704 297~0.704 399),较高的ε_Nd(t)值(5.8~6.5).通过综合分析,认为在晚石炭世早期,达尔布特洋壳(板片)俯冲至地幔楔下部,俯冲洋壳板片脱水所产生的流体在上升过程中与地幔楔共同作用,底侵加热由亏损地幔形成不久的年轻地壳(由洋壳和岛弧组成),使其部分熔融形成了别鲁阿嘎希分异I型花岗岩.      

Petrogenesis of the Mesozoic Intrusive Rocks From the Tongling Ore Cluster Region: The Metallogenic Significance

安徽铜陵矿集区是我国最著名的铜、金、铁产地之一,成矿与岩浆作用关系密切.本次对铜陵地区中生代侵入岩进行了系统的矿物学、岩石学和元素地球化学研究.结果表明:①本区岩浆岩主要为辉石(二长)闪长岩( SiO2≤55％)、石英(二长)闪长岩(SiO255％～65％)和花岗闪长岩(SiO2≥65％)三种岩石组合,其矿物成分主要为中长石、正长石、镁质黑云母和直闪石铝直闪石系列.②辉石(二长)闪长岩组合岩石主要为碱性和橄榄玄粗岩系列.带有古老俯冲洋壳成分的富集岩石圈地幔分离结晶作用可能是辉石(二长)闪长岩组合岩石产生的最主要原因.③花岗闪长岩、石英(二长)闪长岩组合岩石主要属于亚碱性和高钾钙碱性系列,其某些地球化学特征和埃达克岩的地球化学特征一致.幔源岩浆和壳源岩浆的混合可能是石英闪长岩组合和花岗闪长岩组合岩石的主要形成机制.④早白垩世岩浆活动及其相关的铜、金成矿作用可能与古太平洋板块俯冲及其演化过程密切相关.     

西昆仑加里东期花岗岩带的地质特征

西昆仑地区加里东期花岗岩极为发育,主要沿库地北构造带南侧成带分布,岩体数量多、规模大,不同测试方法获同位素年龄主要为４００￣４８０Ｍａ;岩石组合类型大致可分为石英闪长岩－花岗闪长岩－二长花岗岩组合－钾长花岗岩－二长花岗岩组合和石英闪长岩－花岗闪长岩－斜长花岗岩组合;岩石化学表明该区花岗岩主要为钙碱性系列;构造环境判别岩石为同造山和造山期前岩浆活动产物。结合区域地质资料及与之相伴生蛇绿岩带的地质特征     

西准噶尔成矿带晚古生代花岗岩类岩浆活动及其构造意义

中亚造山带是晚古生代地壳显著生长与大规模成矿的重要地区。本文采集了中亚造山带西部的西准噶尔成矿带哈图-别鲁阿嘎希及其附近地区11个岩体共33件花岗岩类样品,对其开展了岩石地球化学与同位素示踪等研究,厘定了该地区晚古生代岩浆活动的特点与大地构造环境,并与哈萨克斯坦境内的巴尔喀什成矿带晚古生代岩浆活动进行了对比。研究表明,哈图地区晚石炭世花岗岩类主要为后碰撞伸展构造环境的A型花岗岩类,别鲁阿嘎希等地区存在洋内俯冲与岛弧环境的埃达克岩,显示了西准噶尔晚古生代构造环境时空变化的复杂性。该地区花岗岩类εNd(t)值较高(+4.62~+7.53)、εSr(t)值为(-57.61~+18.21),具有中亚造山带花岗岩类的共同特征,为古生代增生的新生陆壳,其源区与亏损地幔组分具有亲缘关系,这与巴尔喀什成矿带东段的花岗岩类具有一致性。花岗岩的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb比值范围分别为18.2776~19.1677、15.5260~15.5796和38.2080~39.0821,为造山带花岗岩类。     

水泉沟杂岩体的地质学和岩石学研究

水泉沟岩体为岩浆成因，岩体的侵位深度２－３ｋｍ，侵位时代为印支期，划分为４种岩石组合１，水泉沟岩体是一个钾质－高钾质的钙碱性，弱碱性和碱性岩石共存的杂岩体。岩石化学成分变异图解证明岩浆存在两种演化趋势，一是酸性演化趋势；辉石闪长岩－角闪二长岩－石英碱长正长岩－碱长花岗岩；二是碱性演化趋势；正长岩－霓辉正长岩－碱长正长岩。     

塔里木板块北缘活动陆陆缘型侵入岩带的岩石学与地球化学

在塔里木板块北缘，断续出露一条侵入岩带，总长度800多公里。岩石组合是：橄榄辉长岩－辉长岩－辉长闪长岩－闪长岩－石英闪长岩－花岗岩。各种类型岩石的组成显示了清晰的钙碱性岩浆演化趋势。稀土元素配分曲线均为轻稀土富集型，而且，重稀土元素配分曲线相对平坦。Sr、K、Rb、Ba、Th等大离子亲石元素强烈富集，而Ta、Nb、Zr、Hf、Ti等高场强元素显著贫化。这些岩石学与地球化学特征均表明，该侵入岩带形成于活动大陆边缘。     

措勤盆地冈底斯构造带侵入岩岩石地球化学特征及构造成因分析

冈底斯构造带为措勤盆地－主要Ⅱ级构造单元。该带中、新生代岩浆活动异常强烈，形成从中性闪长岩到酸性花岗岩完整的中酸性花岗岩侵入岩带。通过对侵入岩体的岩石类型、岩石化学特征、岩石地球化学特征研究，认为该岩浆岩带侵入岩体主要为花岗闪长岩、二长花岗岩、石英二长岩等，属钙碱性岩石系列，具“Ⅰ”型花岗岩的特征，是新特提斯洋壳沿雅鲁藏布江断裂带向北俯冲引起下地壳物质熔融向上侵入所致，为燕山晚期－喜山早期岩浆活动的产物。     

东天山尾亚复式岩株形成时代讨论

尾亚复式岩株由尾亚超单元（外环）及环形山超单元（内环）组成。由完全不同成分、不同岩浆源的两个独立岩浆作用，沿同一通道就位的产物。外环为碱性辉长岩、石英正长岩、碱长花岗岩，内环为钙碱系列的石英闪长岩－花岗闪长岩－二长花岗岩－钾长花岗岩。北侧侵入于早石炭世卡拉火大山组及白尖山超单元中。依据同位素年龄测定，其生成年龄270.67-267.3Ma，为早二叠世；环形山超单元生成年龄230－250Ma，为晚二叠世。     

四川米仓山地区晋宁期中性侵入岩序列岩石地球化学特征及其演化

本文首次以同源岩浆演化等级体制单元、超单元研究法对四川南江米仓山地区中性侵入岩———寨坡超单元进行了有效解体和系统研究。寨坡超单元是一以石英闪长岩为主体的超单元，由５个侵入岩单元组成，具有明显的结构－成分演化特征。各单元岩石均为ＳｉＯ２过饱和的正常岩石类型，δ＝１．９～３．３，具钙碱系列岩浆演化趋势。稀土元素为具弱负铕异常的轻稀土富集型；微量元素指示岩浆遭受了一定的混染作用。本超单元岩石同位素年龄为９４２～８７０Ｍａ，为晋宁期末岩浆活动的产物，具明显Ⅰ型岩浆同源演化的特征。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.