Major- and trace-element systematics and isotope geochemistry of Cenozoic mafic volcanic rocks from the Vogelsberg (central Germany): Constraints on the origin of continental alkaline and tholeiitic basalts and their mantle sources

The Cenozoic basaltic province of the Vogelsberg area (central Germany) is mainly composed of intercalated olivine to quartz tholeiites and near-primary nephelinites to basanites. The inferred mantle source for the alkaline and tholeiitic rocks is asthenospheric metasomatized garnet peridotite containing some amphibole as the main hydrous phase. Trace element modelling indicates 2 to 3% partial melting for the alkaline rocks and 5 to 7% partial melting for the olivine tholeiites. Incompatible trace element abundances and ratios as well as Nd and Sr radiogenic isotope compositions lie between plume compositions and enriched mantle compositions and are similar to those measured in Ocean Island Basalts (OIB) and the Central European Volcanic Province elsewhere. The mafic olivine tholeiites have similar Ba/Nb, Ba/La and Nd–Sr isotope ratios to the alkaline rocks indicating derivation of both magma types from chemically comparable mantle sources. However, Zr/Nb ratios are slightly higher in olivine tholeiites than in basanites reflecting some fractionation of Zr relative to Nb during partial melting. Quartz tholeiites have higher Ba/Nb, Zr/Nb, La/Nb, but lower Ce/Pb ratios and lower Nd isotope compositions than the alkaline rocks which can be explained by interaction of the basaltic melt with lower (granulite facies) crustal material or partial melts thereof during stagnation within the lower crust. It appears most likely that upwelling of hot, asthenospheric material results in the generation of primitive alkaline rocks at the base of the lithosphere at depths of 75–90 km. Lithospheric extension together with minor plume activity and probably lower lithosphere erosion induced melting of shallower heterogenous upper mantle generating a spectrum of olivine tholeiitic melts. These olivine tholeiitic rocks evolved via crystal fractionation and probably limited contamination to quartz tholeiites.     

Origin of some calc-alkalic andesites in the Japanese Islands

Origin of calc-alkalic andesite in the Japanese Islands is reviewed on the basis of the recent trace element data and new experimental results. It is suggested that calc-alkalic andesites in the Japanese Islands have at least four different origins; (1) fractional crystallization with separation of magnetite of high-alumina basalt magma, (2) partial melting of hydrous upper mantle peridotite (for magnesian andesite), (3) fractional crystallization with separation of olivine and/or orthopyroxene of magnesian andesite magma and (4) mixing of dacitic and basaltic magmas. Emphasis is placed on the possible generation of primary magnesian calc-alkalic andesite magmas by direct partial melting of the upper mantle peridotite under hydrous conditions at depths between 40 and 60 km.     

The activation and cessation of Late Cenozoic extension in the lithosphere at the margin of the Baikal Rift Zone: Alternating sources of volcanism in the Vitim Upland

A comparative analysis of the concentrations of major oxides, trace elements, and the ¹⁴³Nd/¹⁴⁴Nd ratios in representative sequences of volcanic and subvolcanic rocks in the western and eastern Vitim Upland has revealed petrogenetic groups with different relationships among components from lithosphere and sublithosphere sources. It is hypothesized that the initial 16–14-Ma eruptions of picrobasalts and Mg basanites in the east of the upland resulted from high-temperature melting, hence, the melting of sublithospheric peridotite and lithospheric Mg-pyroxenite mantle material with mildly and strongly depleted isotope compositions of Nd relative to the value in the primitive mantle (0.512638). The broad range of varying lava compositions in the 14–9 Ma time span was caused by “passive” rifting in the west of the upland and by “active” rifting in the east. The “passive” rifting manifested itself in the melting of lithospheric material with some admixture of material from the underlying asthenosphere, while the “active” rifting lifted deep-lying mantle material. The structural rearrangement that has been occurring in the Baikal Rift System during the last 9 Ma resulted in stopping the rifting in the area of study. Relaxation, flattening and thinning of the lithosphere beneath the east part of the system during the 1.1–0.6 Ma time span caused magma effusion with values of ¹⁴³Nd/¹⁴⁴Nd that are typical of a moderately depleted asthenospheric source contaminated with deeper mildly depleted mantle material.     

Origin of high-magnesian andesites in the Setouchi volcanic belt,southwest Japan,II. Melting phase relations at high pressures

Melting phase relations of an augite-olivine high-magnesian andesite and an augite-olivine basalt from the Miocene Setouchi volcanic belt in southwest Japan have been studied under water-saturated, water-undersaturated and under anhydrous conditions. Both the andesite and the basalt are characterized by low FeO*/MgO ratios (0.86 and 0.76 in weight, respectively) and qualify as primary magmas derived from the upper mantle.The andesite melt coexists with olivine, orthopyroxene and clinopyroxene at 15 kbar and 1030°C under water-saturated conditions, and at 10 kbar and 1070°C under water-undersaturated conditions (7 wt.% H₂O in the melt). The basalt-melt also coexists with the above three phases at 11 kbar and 1305°C under anhydrous conditions, and at 15 kbar and 1205°C in the presence of 4 wt.% water.Present studies indicate that high-magnesian andesite magmas may be produced even under water-undersaturated conditions by partial melting of mantle peridotite. It is suggested that two types of high-magnesian andesites in the Setouchi volcanic belt (augite-olivine and bronzite-olivine andesites) were produced by different degrees of partial melting; augite-olivine andesite magmas, whose mantle residual is lherzolite, were formed by lower degrees of partial melting than bronzite-olivine andesite magmas, which coexist with harzburgite. The basalt magmas, which were often extruded in close proximity to the high-magnesian andesite magmas, are not partial melting products of a mantle peridotite which had previously melted to yield high-magnesian andesite magmas.     

Petrology of arc volcanic rocks and their origin by mantle diapirs

Calc-alkalic chemical trends characteristic of arc volcanic rocks mainly result from three mechanisms which act additively: (1) fractional crystallization involving separation of titanomagnetite; (2) selective concentration of plagioclase phenocrysts and selective depletion of titanomagnetite phenocryst compared with the actually fractionated proportion; and (3) mixing of magmas on continuous fractionation trends. The association of calc-alkalic and tholeiitic trends in a single composite volcano may not represent different fractional crystallization processes or different chemistries of primary magmas, but the calc-alkalic chemical trend can be considered as a mixing trend resulting from mixing of various magmas on associated tholeiitic chemical trends. Chemical variations of most arc volcanic rocks, including calc-alkalic ones, can accordingly be essentially accounted for by the low-pressure fractional crystallization of phenocrystic phases from primary basaltic magmas.Crystallization sequences of arc magmas which are strongly dependent on water content in magmas are deduced from the phenocryst assemblages. The crystallization sequence changes laterally across-arc, suggesting increasing water contents in magmas toward the back-arc side, as is also seen for other incompatible elements such as K and Rb. Systematic differences in the characteristic crystallization sequence are also observed among arcs, roughly correlating with the crustal thickness. Water content in magma, like other incompatible elements, tends to increase with increasing crustal thickness. The variation of incompatible elements including water roughly represents that of the degree of partial melting of the upper mantle, which is broadly controlled by the crustal thickness.The variation of water content indicates that arc magmas are not saturated with water during differentiation to late differentiates such as dacite or rhyolite. This strongly constrains the maximum water contents in primary basaltic magma, at most 2.5 wt.%. This value suggests that magma generation beneath arcs is dependent on dry solidus of peridotite. Diapiric uprise of the hot deeper mantle and associated adiabatic decompression would be necessary for mantle peridotite to attain the temperature as high as dry solidus. Diapirs that begin to rise from the subduction zone may stop at or near the crust-mantle boundary because of the surrounding density change, and their degree of partial melting is roughly controlled by their stopped depth assuming their similar temperature. Across-arc variation is also explained by the stopped depth of diapirs, but is not controlled by crustal thickness.     

U-Pb isotopic geochemistry of the post-collisional mafic-ultramafic rocks from the Dabie Mountains——Crust-mantle interaction and LOMU component

Geochronological studies of mafic-ultramafic intrusions occurrence in the northern Dabie zone (NDZ) suggest that these pyroxenite-gabbro intrusions formed 120—130 Ma ago should be post-collisional magmatic rocks[1—4]. These mafic-ultramafic rocks provid…     

Geochemistry and tectonic setting of Tertiary volcanism in the Güvem area, Anatolia, Turkey

Detailed field mapping in the Güvem area in the Galatia province of NW Central Anatolia, Turkey, combined with K–Ar dating, has established the existence of two discrete Miocene volcanic phases, separated by a major unconformity. The magmas were erupted in a post-collisional tectonic setting and it is possible that the younger phase could be geodynamically linked to the onset of transtensional tectonics along the North Anatolian Fault zone. The Early Miocene phase (18–20 Ma; Burdigalian) is the most voluminous, comprising of over 1500 m of potassium-rich intermediate-acid magmas. In contrast, the Late Miocene volcanic phase (ca. 10 Ma; Tortonian) comprises a single 70-m-thick flow unit of alkali basalt. The major and trace element and Sr–Nd isotope compositions of the volcanics suggest that the Late Miocene basalts and the parental mafic magmas to the Early Miocene series were derived from different mantle sources. Despite showing some similarities to high-K calc-alkaline magma series from active continental margins, the Early Miocene volcanics are clearly alkaline with higher abundances of high field strength elements (Zr, Nb, Ti, Y). Crustal contamination appears to have enhanced the effects of crystal fractionation in the petrogensis of this series and some of the most silica-rich magmas may be crustal melts. The mantle source of the most primitive mafic magmas is considered to have been an asthenospheric mantle wedge modified by crustally-derived fluids rising from a Late Cretaceous–Early Tertiary Tethyan subduction zone dipping northwards beneath the Galatia province. The Late Miocene basalts, whilst still alkaline, have a Sr–Nd isotope composition indicating partial melting of a more depleted mantle source component, which most likely represents the average composition of the asthenosphere beneath the region.     

U-Pb isotopic geochemistry of the post-collisional mafic-ultramafic rocks from the Dabie Mountains

The U-Pb isotope geochemical study of the pyroxenite-gabbro intrusion in the Dabie Mountains shows that the post-collisional mafic-ultramafic rocks of the Dabie Mountains are characterized by relative high Pb contents, low U contents and low U/Pb ratios. These characters may be results of interaction between lithosphere or depleted asthenospheric mantle (DMM) and lower crust, but have nothing to do with mantle plume and subducted continental crust. It was first observed that some samples with lower ²⁰⁶Pb/²⁰⁴Pb and higher ²⁰⁷Pb/²⁰⁴Pb ratios show typical characters of the LOMU component. The Pb, Sr, and Nd isotopic tracing shows that three components are needed in the source of the Zhujiapu pyroxenite-gabbro intrusion. They could be old enriched sub-continental lithospheric mantle (LOMU component), lower crust and depleted asthenospheric mantle. The crust-mantle interaction process producing primitive magma of post-collisional mafic-ultramafic rocks in the Dabie Mountains could be described by a lithospheric delamination and magma underplating model. After continent-continent collision, delamination of the thickened lithosphere induced the upwelling of depleted asthenospheric mantle, which caused partial melting of asthenospheric mantle and residual sub-continental lithospheric mantle. The basaltic magma produced in this process underplated in the boundary between the crust and mantle and interacted with lower crust resulting in the geochemical characters of both enriched lithospheric mantle and lower crust.     

Geochemistry and origin of Archean volcanic rocks from the Upper Keewatin assemblage (ca 2.7 Ga), Lake of the Woods Greenstone Belt, Western Wabigoon Subprovince, Superior Province, Canada

Abstract   Volcanic rocks from the Upper Keewatin assemblage ( ca 2720 Ma) were geochemically classified into five groups; komatiites, tholeiitic rocks having near-flat primitive mantle-normalized abundance patterns, Nb-enriched basalts and andesites (NEBA) plus normal calc-alkaline (NCA) rocks, adakites and shoshonites. The adakites having [La/Yb]_N >30 and <30 were probably derived from felsic magmas formed by partial melting of a subducted slab at relatively greater and smaller depths, respectively. Ascending adakite magmas, by interaction with the overlying mantle wedge, decreased in Al₂O₃ / Y ratio and selectively lost high-field strength elements, thereby forming mantle sources for both NEBA + NCA and shoshonite magmas. Under the influence of a mantle plume, the source of komatiites, the NEBA + NCA magmas were generated from that part of the mantle wedge metasomatized by adakite magmas having [La / Yb]_N <30, and tholeiitic magmas from unmetasomatized part of the same mantle wedge. Magmas of both adakites having [La / Yb]_N >30 and shoshonites were generated in a normal Archean Arc system setting.     

The geochronology and origin of mantle sources for late cenozoic intraplate volcanism in the frontal part of the Arabian plate in the Karacadağ neovolcanic area of Turkey. Part 2. The results of geochemical and isotope (Sr-Nd-Pb) studies

A geochemical and isotope-geochemical (Sr-Nd-Pb) study has been carried out for the Karacada? neovolcanic area, which is situated within the frontal part of the Arabian plate. The obtained data and the results of petrological modeling show that the petrogenesis of parental magmas in the Karacada? neovolcanic area involved two compositionally different mantle sources; one consisted of garnet-bearing peridotites of the asthenosphere mantle and the other was spinel-bearing peridotites of the enriched subcontinental lithosphere mantle. During early stages in the evolution of the magmatic system, deep-seated asthenospheric magmas were ascending to the surface while intensively interacting with the melts that had been generated at upper mantle depths. The interaction gradually diminished, so that the later effusive rocks mostly have compositions that are similar to those of the primitive asthenospheric magmas. It is shown that a significant (up to 17–18 wt % of the mantle melt) assimilation of crustal material could take place only during the initial phases of the magmatism. Periodic replenishment of the magma chambers by primitive magmas, which resulted in an observable high degree of homogeneity in the composition of young effusive rocks, was also of importance in the petrogenesis of lavas during the evolution of volcanic activity.     

Setouchi high-Mg andesites revisited: geochemical evidence for melting of subducting sediments

In order to evaluate the mechanism of production of unusual high-Mg andesite (HMA) magmas, Pb–Nd–Sr isotopic compositions were determined for HMAs and basalts from the Miocene Setouchi volcanic belt in the SW Japan arc. The isotopic compositions of Setouchi rocks form mixing lines between local oceanic sediments and Japan Sea backarc basin basalts, suggesting a significant contribution of the subducting sediment component to the HMA magma generation. Mixing calculations using compositions of an inferred original mantle and local oceanic sediments suggest that a sediment-derived melt, neither an H₂O-rich fluid nor an amphibolite/eclogite-derived melt, could have been produced first and served as a plausible metasomatic agent for the HMA magma source. The unusual tectonic setting, including subduction of a newly-borne hence hot plate, may be responsible for melting of subducting sediments.     

Subduction of mantle wedge peridotites: Evidence from the Higashi-akaishi ultramafic body in the Sanbagawa metamorphic belt

The Higashi-akaishi garnet-bearing ultramafic body in the Sanbagawa metamorphic belt, Southwest Japan, represents a rare example of oceanic-type ultrahigh-pressure metamorphism. The body of 2 km × 5 km is composed mostly of anhydrous dunite with volumetrically minor lenses of clinopyroxene-rich rocks. Dunite samples contain high Ir-type platinum group elements (PGE) and Cr in bulk rocks, high Mg and Ni in olivine, and high Cr in spinel. On the other hand, clinopyroxene-rich rocks contain low concentrations of Ir-type PGE and Cr, high concentrations of fluid-mobile elements in bulk rocks, and low Ni and Mg in olivine. Clinopyroxene is diopsidic with low Al₂O₃. The compositions of bulk rocks and mineral chemistry of spinel, olivine, and clinopyroxene suggest that the olivine-dominated rocks are residual mantle peridotites after high degrees of influx partial melting, and that the clinopyroxene-rich rocks are cumulates of subduction-related melts. Thus, the Higashi-akaishi ultramafic body originated from the interior of the mantle wedge, most likely the forearc upper mantle. It was then incorporated into the Sanbagawa subduction channel by a mantle flow, and underwent high pressure metamorphism to a depth greater than 100 km. Such a strong active flow in the mantle wedge is likely facilitated by the lack of serpentinites along the interface between the slab and the overlying mantle, as it was too hot for serpentine. These unusually hot conditions and strong active mantle flow may reflect conditions in the earliest stage of development of subduction, and may have been maintained by massive upwelling and subsequent eastward flow of asthenospheric mantle in the northeastern Asian continent in Cretaceous time when the Sanbagawa belt began to form.     

Geochemistry of adakitic quartz diorite in the Yamizo Mountains, central Japan: Implications for Early Cretaceous adakitic magmatism in the inner zone of southwest Japan

Abstract   Small-volume plutons of Early to Late Cretaceous ages are widely distributed in the Yamizo Mountains, central Japan. These plutons consist predominantly of granitoids, classified into hornblende gabbro, quartz diorite, hornblende–biotite granodiorite and coarse-grained biotite granite. The quartz diorite (52–64 wt% of SiO₂) is characterized by a high Sr content (606–769 p.p.m.) associated with a low Y (13–27 p.p.m.) and heavy rare earth element content (Yb content of 1.19–2.13 p.p.m.). On the Sr/Y versus Y diagram, this rock type mainly plots in the adakite and Archean high-Al tonalite, trondhjemite and granodiorite (TTG) field. Together with its initial Sr isotopic ratios, which range from 0.7038 to 0.7046, these data suggest that quartz diorite originated as slab melts. However, geochemical calculations assuming either eclogite or garnet amphibolite as the source material do not support this suggestion. Instead, the chemical compositions of quartz diorite are better explained by the fractional crystallization of hornblende, plagioclase and biotite from a primitive, basaltic melt in a magma chamber. In this case, the formation of the associated hornblende gabbro can also be explained by the accumulation of hornblende and plagioclase. Adakitic rocks of Early Cretaceous ages have also been reported in the Tamba Belt of the inner zone of southwest Japan, located ca 500 km west of the Yamizo Mountains. These rocks can be correlated to the adakitic rocks in the Yamizo Mountains based on the geology, petrography, geochemistry and radiometric ages. Therefore, we propose the possibility that the Early Cretaceous adakitic rocks in the inner zone of southwest Japan were produced by fractional crystallization from basaltic arc magmas generated by a partial melting of metasomatized wedge mantle peridotite.     

Adakitic magmas in the Ecuadorian Volcanic Front: Petrogenesis of the Iliniza Volcanic Complex (Ecuador)

The Iliniza Volcanic Complex (IVC) is a poorly known volcanic complex located 60 km SSW of Quito in the Western Cordillera of Ecuador. It comprises twin peaks, North Iliniza and South Iliniza, and two satellite domes, Pilongo and Tishigcuchi. The study of the IVC was undertaken in order to better constrain the role of adakitic magmas in the Ecuadorian arc evolution. The presence of volcanic rocks with an adakitic imprint or even pristine adakites in the Ecuadorian volcanic arc is known since the late 1990s. Adakitic magmas are produced by the partial melting of a basaltic source leaving a garnet rich residue. This process can be related to the melting of an overthickened crust or a subducting oceanic crust. For the last case a special geodynamic context is required, like the subduction of a young lithosphere or when the subduction angle is not very steep; both cases are possible in Ecuador. The products of the IVC, made up of medium-K basaltic andesites, andesites and dacites, have been divided in different geochemical series whose origin requires various interactions between the different magma sources involved in this subduction zone. North Iliniza is a classic calc-alkaline series that we interpret as resulting from the partial melting of the mantle wedge. For South Iliniza, a simple evolution with fractional crystallization of amphibole, plagioclase, clinopyroxene, magnetite, apatite and zircon from a parental magma, being itself the product of the mixing of 36% adakitic and 64% calc-alkaline magma, has been quantified. For the Santa Rosa rhyolites, a slab melting origin with little mantle interactions during the ascent of magmas has been established. The Pilongo series magma is the product of a moderate to high degree (26%) of partial melting of the subducting oceanic crust, which reached the surface without interaction with the mantle wedge. The Tishigcuchi series shows two stages of evolution: (1) metasomatism of the mantle wedge peridotite by slab melts, and (2) partial melting (10%) of this metasomatized source. Therefore, the relative ages of the edifices show a geochemical evolution from calc-alkaline to adakitic magmas, as is observed for several volcanoes of the Ecuadorian arc.     

Geochronological Significance of the Post-Orogenic Mafic- Ultramafic Rocks in the Hongqiling Area of Jilin Province, Northeast China

INTRODUCTIONThe mafic-ultramafic complexesinthe Hongqilingarea were emplacedintothe metamorphic rocksof the Hulan Group. Age determination of the intrusion and metamorphism of the Hulan Groupmetamorphic rocks is crucial for the study of petrogenesis and evolution, orogenesis and itsdevelopment of the region. However ,so far it has been difficult to determine the geochronology ofmafic-ultramafic rocks inthe area ,thusthe age obtainedfromprevious data hadto be used.Inrecentyears ,withthe …     

Silicic arc volcanism in Central Luzon, the Philippines: Characterization of its space, time and geochemical relationship

Abstract   The silicic volcanic rocks in Central Luzon show a temporal and spatial relationship with its geochemistry. Volcanic centers dated to approximately 5 Ma are silicic in geochemical composition whereas those between <5–1 Ma expose basaltic to andesitic rocks. Volcanic centers dated <1 Ma are characterized by a wide range of geochemistry encompassing basaltic through andesitic to dacitic signatures. Aside from changes in geochemistry through time, the areas (i.e. fore-arc to back-arc region) where the volcanic centers are formed also vary. The shift in the location of the volcanic centers in Central Luzon is attributed to changes in the dip of subduction of the South China Sea crust along the Manila Trench. Flat subduction resulted from the subduction of the Scarborough Seamount Chain, an oceanic bathymetric high along the Manila Trench west of northern Luzon. However, collision of Luzon with Taiwan in the north and Palawan in the south resulted in steepening of the subduction angle. The silicic volcanic centers in the forearc (Ce/Yb = 20–140) and back-arc (Ce/Yb = 20–60) regions are generally characterized by higher Ce/Yb compared to the basaltic-andesitic volcanic rocks in the main volcanic arc (Ce/Yb = 20) and back-arc (Ce/Yb = 20–30) regions. This across-arc geochemical variation highlights the contributions from the slab, mantle and crust coupled with the effects of geochemical processes that include partial melting, fractionation, magma mixing and mantle–melt interaction.     

Characteristics of subcontinental lithospheric mantle beneath Baegryeong Island, Korea: Spinel peridotite xenoliths

Abstract   Geochemical data on Baegryeong Island spinel peridotites found in Miocene alkali basalt provide the information for lithosphere composition, chemical processes, equilibrium pressure and temperature conditions. Spinel peridotite xenoliths, showing transitional textures between protogranular and porpyroclastic textures, were accidentally trapped by the ascending alkali basalt magma. The xenoliths originate at depths from 50 to 70 km with a temperature range from 800 to 1100°C. The variations of modal and mineral compositions of the spinel peridotite xenoliths indicate that the xenoliths have undergone 1–10% fractional melting. The spinel peridotites from Baegryeong Island have undergone cryptic mantle metasomatism subsequent to melt extraction. Metasomatic agent of enriched spinel peridotite xenoliths was carbonatite melt.     

Melilite-derived mineral inclusions in chromite from the Gaositai complex: Implications for an extensional tectonic setting in Early Permian at the north North China Craton

The Early Permian mafic-ultramafic concentrically zoned Gaositai intrusion at Chengde, on the northern margin of the North China Craton (NCC), is a cumulative complex emplaced along a giant fracture that penetrates deeply into the continental lithosphere. Melt inclusions are present in chromite crystals from the inner dunite and chromitite zones of the Gaositai complex. The melt inclusions have experienced post-trap crystallization and resulted in multiple mineral phases, including melilite, garnet, phlogopite, magnesite and apatite, which can indicate the liquidus minerals of the primitive magma. The characteristics of the melilite+melanite+clinopyxene assemblage indicate that the primary parental magma was highly undersaturated and derived from an alkali-rich mantle source. The crystallization of phlogopite, magnesite and apatite suggests a primary magma rich in K, H₂O and CO₂. When compared with experimental data, the primary magma of the Gaositai intrusion is concordant with a kamafugite magma originating from partial melting of enriched mantle with H₂O and CO₂ at pressures greater than 2.7 GPa. This magmatic process would have been related to extensional thinning of the continental lithosphere. The Gaositai primary magmas have high Nb/La ratios, which are similar to those of ocean island basalts, but different from arc-related magmas. This suggests that the northern margin of the NCC was not an active continental margin of the Paleo-Asian Ocean subduction zone during the Early Permian: an extensional tectonic setting during the emplacement of the Gaositai intrusion is more likely.     

碳酸岩是大陆岩石圈构造背景和地幔交代作用的指示岩石

根据已知碳酸岩的地质产状、岩石学特征、Nd-Sr-Pb同位素及痕量元素地球化学特征,结合高温高压实验岩石学资料,论述了其地幔源区的物质成分、交代过程、软流圈地幔部分熔融机制和碳酸岩岩浆的演化模型碳酸岩既可以产生于裂谷环境,由起源于软流圈地幔的霞石质超基性-基性岩浆经液态不混溶作用而形成,与硅酸不饱和过碱性杂岩构成环状碳酸岩-碱性杂岩;也能够产生于碰撞造山过程中派生的引张岩石圈断裂带,直接导源于岩石圈地幔的低程度部分熔融作用,形成单一的透镜状、条带状和似层状碳酸岩体     

Mesozoic mafic magmatism in North China: Implications for thinning and destruction of cratonic lithosphere

The North China Craton (NCC) has been thinned from >200 km to <100 km in its eastern part. The ancient subcontinental lithospheric mantle (SCLM) has been replaced by the juvenile SCLM in the Meoszoic. During this period, the NCC was destructed as indicated by extensive magmatism in the Early Cretaceous. While there is a consensus on the thinning and destruction of cratonic lithosphere in North China, it has been hotly debated about the mechanism of cartonic destruction. This study attempts to provide a resolution to current debates in the view of Mesozoic mafic magmatism in North China. We made a compilation of geochemical data available for Mesozoic mafic igneous rocks in the NCC. The results indicate that these mafic igneous rocks can be categorized into two series, manifesting a dramatic change in the nature of mantle sources at ~121 Ma. Mafic igneous rocks emplaced at this age start to show both oceanic island basalts (OIB)-like trace element distribution patterns and depleted to weakly enriched Sr-Nd isotope compositions. In contrast, mafic igneous rocks emplaced before and after this age exhibit both island arc basalts (IAB)-like trace element distribution patterns and enriched Sr-Nd isotope compositions. This difference indicates a geochemical mutation in the SCLM of North China at ~121 Ma. Although mafic magmatism also took place in the Late Triassic, it was related to exhumation of the deeply subducted South China continental crust because the subduction of Paleo-Pacific slab was not operated at that time. Paleo-Pacific slab started to subduct beneath the eastern margin of Eruasian continent since the Jurrasic. The subducting slab and its overlying SCLM wedge were coupled in the Jurassic, and slab dehydration resulted in hydration and weakening of the cratonic mantle. The mantle sources of ancient IAB-like mafic igneous rocks are a kind of ultramafic metasomatites that were generated by reaction of the cratonic mantle wedge peridotite not only with aqueous solutions derived from dehydration of the subducting Paleo-Pacific oceanic crust in the Jurassic but also with hydrous melts derived from partial melting of the subducting South China continental crust in the Triassic. On the other hand, the mantle sources of juvenile OIB-like mafic igneous rocks are also a kind of ultramafic metasomatites that were generated by reaction of the asthenospheric mantle underneath the North China lithosphere with hydrous felsic melts derived from partial melting of the subducting Paleo-Pacific oceanic crust. The subducting Paleo-Pacific slab became rollback at ~144 Ma. Afterwards the SCLM base was heated by laterally filled asthenospheric mantle, leading to thinning of the hydrated and weakened cratonic mantle. There was extensive bimodal magmatism at 130 to 120 Ma, marking intensive destruction of the cratonic lithosphere. Not only the ultramafic metasomatites in the lower part of the cratonic mantle wedge underwent partial melting to produce mafic igneous rocks showing negative ε_Nd(t) values, depletion in Nb and Ta but enrichment in Pb, but also the lower continent crust overlying the cratonic mantle wedge was heated for extensive felsic magmatism. At the same time, the rollback slab surface was heated by the laterally filled asthenospheric mantle, resulting in partial melting of the previously dehydrated rocks beyond rutile stability on the slab surface. This produce still hydrous felsic melts, which metasomatized the overlying asthenospheric mantle peridotite to generate the ultramafic metasomatites that show positive ε_Nd(t) values, no depletion or even enrichment in Nb and Ta but depletion in Pb. Partial melting of such metasomatites started at ~121 Ma, giving rise to the mafic igneous rocks with juvenile OIB-like geochemical signatures. In this context, the age of ~121 Ma may terminate replacement of the ancient SCLM by the juvenile SCLM in North China. Paleo-Pacific slab was not subducted to the mantle transition zone in the Mesozoic as revealed by modern seismic tomography, and it was subducted at a low angle since the Jurassic, like the subduction of Nazca Plate beneath American continent. This flat subduction would not only chemically metasomatize the cratonic mantle but also physically erode the cratonic mantle. Therefore, the interaction between Paleo-Pacific slab and the cratonic mantle is the first-order geodynamic mechanism for the thinning and destruction of cratonic lithosphere in North China.