Petrology and Mineral Chemistry of Lower Crustal Intrusions: the Chilas Complex, Kohistan (NW Pakistan)

Mineral major and trace element data are presented for the mainrock units of the Chilas Complex, a series of lower crustalintrusions emplaced during initial rifting within the MesozoicKohistan (paleo)-island arc (NW Pakistan). Detailed field observationsand petrological analysis, together with geochemical data, indicatethat the two principal units, ultramafic rocks and gabbronoritesequences, originate from a common parental magma, but evolvedalong different mineral fractionation trends. Phase petrologyand mineral trace element data indicate that the fractionationsequence of the ultramafic rocks is dominated by the crystallizationof olivine and clinopyroxene prior to plagioclase, whereas plagioclaseprecedes clinopyroxene in the gabbronorites. Clinopyroxene inthe ultramafic rocks (with Mg-number [Mg/(Fe_tot + Mg] up to0·95) displays increasing Al₂O₃ with decreasing Mg-number.The light rare earth element depleted trace element pattern(Ce_N/Gd_N 0·5–0·3) of primitive clinopyroxenesdisplays no Eu anomaly. In contrast, clinopyroxenes from thegabbronorites contain plagioclase inclusions, and the traceelement pattern shows pronounced negative anomalies for Sr,Pb and Eu. Trace element modeling indicates that in situ crystallizationmay account for major and trace element variations in the gabbronoritesequence, whereas the olivine-dominated ultramafic rocks showcovariations between olivine Mg-number and Ni and Mn contents,pointing to the importance of crystal fractionation during theirformation. A modeled parental liquid for the Chilas Complexis explained in terms of mantle- and slab-derived components,where the latter component accounts for 99% of the highly incompatibleelements and between 30 and 80% of the middle rare earth elements.The geochemical characteristics of this component are similarto those of a low percentage melt or supercritical liquid derivedfrom subducted mafic crust. However, elevated Pb/Ce ratios arebest explained by additional involvement of hydrous fluids.In accordance with the crystallization sequence, the subsolidusmetamorphic reactions indicate pressures of 0·5–0·7GPa. Our data support a model of combined flux and decompressionmelting in the back-arc. KEY WORDS: Kohistan; Island arc; gabbro; trace element modelling; lower crustal intrusion     

Coronas and high-P veins in metagabbros of the Kohistan island arc, northern Pakistan: evidence for crustal thickening during cooling

Abstract The E-W-trending Kohistan terrane in the NW Himalaya is a sandwich of a magmatic arc between the collided Karakoram (Asian) and Indian plates. The southern part of the Kohistan arc is principally made up of amphibolites derived from volcanic and plutonic rocks of Early Cretaceous age. Gabbroic relics in the amphibolites display calc-alkaline character, and their mineralogy is similar to low-P plutonic rocks reported from modern and ancient island arcs. The largest of these relics, occurring along the southern margin of the amphibolite belt near Khwaza Khela, is subcircular in outline and is about 1 km across. It consists of cumulate gabbros and related rocks displaying a record of cooling and crustal thickening. Primary olivine and anorthite reacted to produce coronas consisting of two pyroxenes +Mg-Fe²⁺-Al spinel ± tschermakitic hornblende at about 800° C, 5.5–7.5 kbar. This thermotectonic event is of regional extent and may be related to the overthrusting of the Karakoram plate onto the Kohistan arc some 85 Ma ago, or even earlier. Later the gabbros were locally traversed by veins containing high-P assemblages: garnet, kyanite, zoisite, paragonite, oligoclase, calcite, scapolite and quartz ° Chlorite ° Corundum ± diopside. Formed in the range 510–600° C, and 10–12 kbar, these suggest further thickening and cooling of the crust before its uplift during the Tertiary. This paper presents microprobe data on the minerals, and discusses the tectonic implications of the coronitic and vein assemblages in the gabbros.     

The dynamics of the suture between the Kohistan island arc and the Indian plate in the Himalaya of Pakistan

ABSTRACT The pressure-temperature and temperature-time paths derived for rocks in the Kohistan arc and adjacent Nanga Parbat-Haramosh massif record the dynamics of the collision between the island arc and the Indian plate. Studies of P-T-t paths show that the Kohistan arc was thrust over the Nanga Parbat-Haramosh massif at least 25 Ma ago, but not more than 30–35 Ma ago. Rocks in the Kohistan arc followed decreasing pressure paths, with the early metamorphism beginning at high pressures (9.5 kbar) and later metamorphism occurring at 8.0 kbar. In contrast, rocks in the Nanga Parbat-Haramosh massif (Indian plate) experienced increasing pressure and temperature paths. Prior to thrusting, the massif was at low pressures (4.0 kbar) and low temperatures (450°c). Later, the pressure and temperature increased to 8 kbar and 580°c. The authors interpret the convergence (to approximately the same pressure and temperature) of the P-T paths in the two terranes as being the result of thrusting and thermal equilibration between the thrust sheets. ⁴⁰Ar/³⁹Ar cooling ages of hornblendes and other geochronological data suggest that the time of peak metamorphism and hence the completion of thickening was approximately 30–35 Ma ago. Temperature-time paths show that after thrusting, during the period 25–10 Ma, the Kohistan arc and Nanga Parbat-Haramosh massif were uplifted at similar rates (0.5 km Ma). However, in the past 10 Ma the Nanga Parbat-Haramosh massif has been uplifted more rapidly than the adjacent Kohistan arc. Rapid uplift has been accommodated by late faults along the edge of the massif.     

PALEOMAGNETIC STUDY OF IGNEOUS ROCKS OF GUPIS—SHAMRAN AREA,KOHISTAN ARC, PAKISTAN,NW HIMALAYA

Kohistan Sequence has been considered as island arc formed during the subduction of oceanic lithosphere at the leading edge of northward moving Indian continent.. Sedimentary sequences indicate that formation of the intra\|oceanic Kohistan arc began in early Cretaceous time. The isotopic data demonstrate the involvement of enriched, DUPAL type mantle, suggesting that Kohistan arc was formed at or south of the present equator (Khan et al., 1997). The Intra oceanic phase of Kohistan lasted until sometime between 102 and 85 Ma, when Kohistan collided with Asia. From this time until collision with India about 50 Ma ago, Kohistan existed as Andean\|type margin. This paleomagnetic study is from the volcanic and plutonic rocks exposed in Gupis\|Shamran area (west of Gilgit) in northern part of the Kohistan arc. According to geochronological data these rocks were formed 61～55Ma ago (Treloar et al., 1989), when Kohistan was existing as Andean\|type margin. Seven to nine samples were collected from nine sites of Shamran volcanics (58±1)Ma and from five sites of Pingal, Gupis, and Yasin plutons (Ar\|Ar hornblende ages ranges from 61～52Ma). On the basis of one Rb\|Sr age of (59±2)Ma from these plutons, the above\|mentioned Ar/Ar ages may be regarded as reasonable intrusion ages of these plutons (Searle, 1991).     

Petrogenesis of Mafic Garnet Granulite in the Lower Crust of the Kohistan Paleo-arc Complex (Northern Pakistan): Implications for Intra-crustal Differentiation of Island Arcs and Generation of Continental Crust

We report the results of a geochemical study of the Jijal andSarangar complexes, which constitute the lower crust of theMesozoic Kohistan paleo-island arc (Northern Pakistan). TheJijal complex is composed of basal peridotites topped by a gabbroicsection made up of mafic garnet granulite with minor lensesof garnet hornblendite and granite, grading up-section to hornblendegabbronorite. The Sarangar complex is composed of metagabbro.The Sarangar gabbro and Jijal hornblende gabbronorite have melt-like,light rare earth element (LREE)-enriched REE patterns similarto those of island arc basalts. Together with the Jijal garnetgranulite, they define negative covariations of La_N, Yb_N and(La/Sm)_N with Eu^* [Eu^* = 2 x Eu_N/(Sm_N + Gd_N), where N indicateschondrite normalized], and positive covariations of (Yb/Gd)_Nwith Eu^*. REE modeling indicates that these covariations cannotbe accounted for by high-pressure crystal fractionation of hydrousprimitive or derivative andesites. They are consistent withformation of the garnet granulites as plagioclase–garnetassemblages with variable trapped melt fractions via eitherhigh-pressure crystallization of primitive island arc basaltsor dehydration-melting of hornblende gabbronorite, providedthat the amount of segregated or restitic garnet was low (<5wt %). Field, petrographic, geochemical and experimental evidenceis more consistent with formation of the Jijal garnet granuliteby dehydration-melting of Jijal hornblende gabbronorite. Similarly,the Jijal garnet-bearing hornblendite lenses were probably generatedby coeval dehydration-melting of hornblendites. Melting modelsand geochronological data point to intrusive leucogranites inthe overlying metaplutonic complex as the melts generated bydehydration-melting of the plutonic protoliths of the Jijalgarnet-bearing restites. Consistent with the metamorphic evolutionof the Kohistan lower arc crust, dehydration-melting occurredat the mature stage of this island arc when shallower hornblende-bearingplutonic rocks were buried to depths exceeding 25–30 kmand heated to temperatures above c. 900°C. Available experimentaldata on dehydration-melting of amphibolitic sources imply thatthickening of oceanic arcs to depths >30 km (equivalent toc. 1·0 GPa), together with the hot geotherms now postulatedfor lower island arc crust, should cause dehydration-meltingof amphibole-bearing plutonic rocks generating dense garnetgranulitic roots in island arcs. Dehydration-melting of hornblende-bearingplutonic rocks may, hence, be a common intracrustal chemicaland physical differentiation process in island arcs and a naturalconsequence of their maturation, leading to the addition ofgranitic partial melts to the middle–upper arc crust andformation of dense, unstable garnet granulite roots in the lowerarc crust. Addition of LREE-enriched granitic melts producedby this process to the middle–upper island arc crust maydrive its basaltic composition toward that of andesite, affordinga plausible solution to the ‘arc paradox’ of formationof andesitic continental-like crust in island arc settings. KEY WORDS: island arc crust; Kohistan complex; Jijal complex; amphibole dehydration-melting; garnet granulite; continental crustal growth     

巴基斯坦北部科希斯坦弧奇拉斯杂岩体的地质及地球化学特征

位于巴基斯坦北部西喜马拉雅的科希斯坦地体为夹持于亚洲板块与印度板块之间的倾斜的岛弧型壳体。科希斯坦岛弧北界为主地幔逆总断层（MMT），北界为北部缝合带（或喀啦昆仑主逆冲断层，MKT），可将其划分为几个地质单元。奇拉斯（Chilas)杂岩体为一长约300km、宽50km的巨型基性侵入岩体，与MMT和MKT近平行展布。它被认为是科希斯坦岛弧的岩浆房根区。奇拉斯杂岩体主要由辉长苏长岩和几个超镁铁质岩－镁铁质岩（简称UMA）岩体组成。前侵入后之中。奇拉斯杂岩体岩石普遍发生轻微变形，出现叶理化和韧性剪切带。UMA主要由橄榄石（含或不含单斜辉石）堆积岩（纯橄岩，异剥橄岩）和斜长石－单斜辉石－斜方辉石堆积岩（二辉辉长岩）组成，含有少量单斜辉石－斜方辉石堆积岩（辉石岩）。辉长苏长岩的地球化学特征表明其为岛弧环境下形成的非堆积岩，而UMA的地球化学特征表明其为岛弧环境下的堆积岩。辉长苏长岩和UMA的主元素地球化学特征在AFM图解上可用堆积和非堆积的模式来解释，辉长苏长岩的稀土和微量元素地球化学特征在100MgO/(MgO TFeO)图解上显示岛弧型特点，且UMA表明其堆积特性。     

Oriented growth of garnet by topotactic reactions and epitaxy in high‐pressure,mafic garnet granulite formed by dehydration melting of metastable hornblende‐gabbronorite (Jijal Complex,Kohistan Complex,north Pakistan)

Garnet growth in high‐pressure, mafic garnet granulites formed by dehydration melting of hornblende‐gabbronorite protoliths in the Jijal complex (Kohistan palaeo‐island arc complex, north Pakistan) was investigated through a microstructural EBSD‐SEM and HRTEM study. Composite samples preserve a sharp transition in which the low‐pressure precursor is replaced by garnet through a millimetre‐sized reaction front. A magmatic foliation in the gabbronorite is defined by mafic‐rich layering, with an associated magmatic lineation defined by the shape‐preferred orientation (SPO) of mafic clusters composed of orthopyroxene (Opx), clinopyroxene (Cpx), amphibole (Amp) and oxides. The shape of the reaction front is convoluted and oblique to the magmatic layering. Opx, Amp and, to a lesser extent, Cpx show a strong lattice‐preferred orientation (LPO) characterized by an alignment of [001] axes parallel to the magmatic lineation in the precursor hornblende‐gabbronorite. Product garnet (Grt) also displays a strong LPO. Two of the four 〈111〉 axes are within the magmatic foliation plane and the density maximum is subparallel to the precursor magmatic lineation. The crystallographic relationship 〈111〉_Grt // [001]_Opx,Cpx,Amp deduced from the LPO was confirmed by TEM observations. The sharp and discontinuous modal and compositional variations observed at the reaction front attest to the kinetic inhibition of prograde solid‐state reactions predicted by equilibrium‐phase diagrams. The P–T field for the equilibration of Jijal garnet granulites shows that the reaction affinities are 5–10 kJ mol.^?1 for the Grt‐in reaction and 0–5 kJ mol.^?1 for the Opx‐out reaction. Petrographic and textural observations indicate that garnet first nucleated on amphibole at the rims of mafic clusters; this topotactic replacement resulted in a strong LPO of garnet. Once the amphibole was consumed in the reaction, the parallelism of [001] axes of the mafic‐phase reactants favoured the growth of garnet crystals with similar orientations over a pyroxene substrate. These aggregates eventually sintered into single‐crystal garnet. In the absence of deformation, the orientation of mafic precursor phases conditioned the nucleation site and the crystallographic orientation of garnet because of topotaxial transformation reactions and homoepitaxial growth of garnet during the formation of high‐pressure, mafic garnet‐granulite after low‐pressure mafic protoliths.     

A PETROLOGICAL OVERVIEW OF THE KOHISTAN MAGMATIC ARC, NW HIMALAYA, N. PAKISTAN

A PETROLOGICAL OVERVIEW OF THE KOHISTAN MAGMATIC ARC, NW HIMALAYA, N. PAKISTAN1　TahirkheliRAK ,MattauerM .ProustF ,etal.1979.In :GeodynamicsofPakistan[C].FarahA ,DeJongKA ,eds.GeolSurvPakistan ,Quetta ,1979.12 5～ 130 . 2　CowardMP ,WindleyBF ,BroughtonRD ,etal.In :CollisionTectonics[C]..CowardMP ,RiesAC ,eds.GeolSoc,London ,SpecPub ,1986 ,19:2 0 3～ 2 19. 3　BardJP ,MaluskiH ,MattePh ,etal.GeolBull ,PeshawarUniversity ,1980 ,13:87～ 93. …     

A Cretaceous dike swarm provides evidence of a spreading axis in the back-arc basin of the Kohistan paleo-island arc,northwestern Himalaya,Pakistan

A 100–4000 m wide and 15 km long dike swarm, consisting of basalt and dolerite, occurs at the base of the Thelichi Formation in the Kohistan paleo-island arc terrane, north Pakistan. The dikes contain hornblende (altered from diopsidic-augite), diopsidic-augite (relics; ophitic to subophitic texture), chlorite, epidote, sphene, apatite, zircon, ilmenite, titanomagnetite and magnetite. The geochemistry reveals two groups of dikes: (1) Higher TiO₂ (2.74–3.50 wt%), Na₂O, Fe₂O₃ and lower Al₂O₃ (12.65–14.16 wt%) and MgO (3.73–5.04 wt%); (2) Lower TiO₂ (1.24–2.05 wt%), Na₂O, Fe₂O₃ and higher Al₂O₃ (14.02–16.52 wt%) and MgO (3.98–7.52 wt%). The MgO contents (3.73–7.52-wt%) show a variation in the dikes from relatively primitive to more evolved compositions. The dikes contain high amounts of both LILE and HFSE. The major, trace and rare-earth elements data confirm the MORB affinity and the back-arc basin origin of the dike swarm. The NW–SE orientation of the dike swarm and its 134 ± 3 Ma K–Ar age suggest the spreading axis of the back-arc basin in the Early Cretaceous.     

Geochemical modelling of the Chilas Complex in the Kohistan Terrane,northern Pakistan

The Chilas Complex in the Kohistan Terrane, Pakistan, is a huge basic intrusion, about 300 km long and up to 40 km wide, which is regarded as tilted island-arc type crust. It has been interpreted as the magma chamber root zone of the Kohistan Island Arc. The Chilas Complex is composed mainly of gabbronorite (main facies) and several masses of ultramafic–mafic–anorthosite (UMA) association. The UMA association consists mainly of olivine-dominant cumulate (dunite, wehrlite, lherzolite) and plagioclase-dominant cumulate (troctolite, olivine gabbro, gabbronorite, anorthosite), with minor amount of pyroxene-dominant cumulate (clinopyroxenite, websterite).The major element geochemistry of the gabbronorite (main facies) and rocks of the UMA association, plotted on Harker diagrams, are explained by a cumulate and a non-cumulate model, respectively. Namely, the UMA association is explained as variable crystal cumulates from a primary magma and the gabbronorite of the main facies is explained as due to the fractionation of the residual melt. Chemical variations of major, trace and rare earth elements for the gabbronorite of the main facies in the Chilas Complex are explained by fractional crystallization and accumulation of plagioclase, orthopyroxene and clinopyroxene from the residual melt of the primary magma.     

Tectonometamorphic evolution of the Neoproterozoic Delgo suture zone,Northern Sudan

In the area around Delgo in north-east Sudan a narrow NNE-trending Neoproterozoic belt of low grade volcanosedimentary rocks is fringed by high grade migmatitic basement blocks. The volcanosedimentary sequence is structurally overlain by a rock body of several kilometres length, which is composed of metamorphosed ultramafic and mafic rocks. This sequence is interpreted as an island arc-ophiolite association representing a suture zone.With respect to their degrees of metamorphism and their structural characteristics, the lithological units of the Delgo area are significantly different from the adjacent basement rocks in the east and west. The lithological contacts of the metavolcanic-metasedimentary rocks with the basement rocks are often marked by intermediate-dipping mylonites which are locally overprinted by ductile to brittle-ductile strike-slip faults.The Delgo suture evolved through the subduction-related closure of an oceanic basin and final collision of the island arc with the migmatitic basement blocks on either side of the oceanic basin. Peak metamorphism of deeply buried back-arc basin sequences occurred at around 700 Ma ago. During the collision stage, island arc rocks, passive margin sequences and ophiolitic rocks were thrust to the east and west over the basement blocks, causing limited crustal thickening and a minor isostatic rebound.Lithospheric extension associated with increasing heat flow caused migmatization in the basement between ca. 580 and 540 Ma ago. The development of numerous intermediate-dipping mylonitic shear zones at decreasing temperatures post-dates the migmatization. Lithospheric extension may explain the juxtaposition of rocks which were formed and/or metamorphosed at significantly different crustal levels.     

柴北缘乌兰北部三叠纪辉长岩的年代学和地球化学特征

柴北缘乌兰地区中生代岩浆岩分布广泛，主要出露辉长岩、闪长岩、花岗闪长岩和花岗岩。乌兰北部两件辉长岩样品的LA-ICP-MS锆石U-Pb测年显示其加权平均年龄分别为（241.9±0.9） Ma和（245.4±1.9） Ma，说明其形成于中三叠世早期。辉长岩的w（SiO₂）为47.94%和52.01%，全碱质量分数较低（ALK为1.25%和1.47%），里特曼指数为0.33和0.26，属钙碱性系列岩石；w（Cr）（1 661.00×10^-6和1 418.00×10^-6）、w（Ni）（394.00×10^-6和280.00×10^-6）和Mg^#值（81和79）极高，具幔源原生玄武岩浆特征。轻、重稀土元素分馏较弱，LREE/HREE为3.92和3.44，无明显负Eu异常，表明未发生明显的岩浆分异作用；富集K、Rb等大离子亲石元素，不同程度地亏损Nb、Ta、Ti等高场强元素，表现为与俯冲作用相关的弧岩浆岩特征。辉长岩的ε_Hf（t）值（-3.0~9.3）变化较大，暗示来自地幔的基性岩浆中有地壳组分的加入。结合区域地质演化特征研究成果，认为辉长岩形成于古特提斯洋向北俯冲背景下的大陆边缘弧环境，俯冲的洋壳板片脱水产生的流体导致上覆地幔楔部分熔融，形成玄武质岩浆，岩浆上升侵位过程中遭受地壳物质混染或与壳源岩浆发生混合作用。     

河南刘山岩铜锌矿区细碧-石英角斑质含矿火山岩系的构造环境

刘山岩铜锌矿含矿岩系属于早古生代二郎坪群海相细碧-石英角斑岩系。在SiO2-(K2O+Na2O)岩石分类图上,细碧岩属于玄武岩和粗面玄武岩,石英角斑岩和石英钠长斑岩属于酸性流纹岩类,岩石组合为双峰式类型。大多数细碧岩和超基性岩的FeO*/MgO比值为0.2～2.93。在SiO2-(FeO*/MgO)图解上,它们属于拉斑玄武岩和钙碱性系列。火山岩系的微量元素模式以亏损Rb,Th,Nb,Sr,P,Ti和富集Ba,K及LREE为特征。在微量元素构造判别图上,火山岩样品集中在火山岛弧和弧后盆地的范围内。该火山岩系底部超镁铁岩的REE分布模式为轻稀土富集型,有小的Eu正异常;细碧岩-石英角斑岩也是轻稀土强富集型,Ce和Eu有轻微的正异常;硅质岩也有Eu正异常,表明与火山喷发有关;本区硅质岩δCe值为0.87,显示不是深海硅质岩的特征。火山岩系的地球化学特征表明,其形成的大地构造环境为弧后盆地型。     

米仓山新民角闪辉长岩地球化学特征及其构造意义

扬子板块西北缘新元古代岩浆作用的研究对于探讨Rodinia超大陆的构造演化具有重要意义,对米仓山新民地区角闪辉长岩的岩石学和地球化学分析结果表明,岩石Si O2含量较低且变化范围较小,岩石富Al和Ca,低K、Ti、P,Mg#值中等,属于亚碱性低钾拉斑岩石系列。岩石具有稀土元素总量相对较低、相对富集轻稀土元素和轻重稀土元素分馏程度低的特征,具弱Eu正异常,δEu=1.03~2.36。岩石总体上富集大离子亲石元素(Rb、Ba、Sr),亏损高场强元素(Nb、Zr、Hf、Th等),87Sr/86Sr=0.703 858,143Nd/144Nd=0.512 617,εNd(t)=+3.1。综合区域地质、地球化学特征,该岩体岩浆起源于亏损地幔的部分熔融,在上升侵位过程中可能受到了地壳物质的混染。在这时期,扬子板块北缘处于汇聚环境,新民角闪辉长岩形成于弧后盆地的构造环境,是Rodinia超大陆在新元古代期间演化过程中岩浆作用的产物。     

西藏措勤晚白垩世英安岩的厘定与地球化学特征

野外地质调查和SHRIMP锆石U/Pb地质年代学研究表明,拉萨地块中带措勤地区发育一套形成于晚白垩世中期的英安岩(88.5±1.2 Ma)。该套火山岩具有岛弧火山岩的地球化学特征,为地壳深部岩浆岩部分熔融形成的Ⅰ型岩浆岩,经历了明显的斜长石分离结晶作用。与同时代的侵入岩相比,该套火山岩为高度演化的岩浆,Rb/Sr比值较高,但Sr/Y比值较低。在拉萨地块内部,广泛发育的90～85 Ma的岩浆作用与新特提斯洋的北向俯冲作用相关。     

北部湾涠洲岛及斜阳岛火山岩微量元素和同位素地球化学及其构造意义

本文在北部湾内一对姊妹火山岛即涠洲岛及斜阳岛火山地质研究基础上,进一步开展火山岩微量元素和Sr-Nd-Pb同位素,以及地幔橄榄岩Re-Os同位素地球化学研究.岛上早晚两期火山岩均为碱性玄武岩,分别属于碱性橄榄玄武岩和碧玄岩.碧玄岩为玻基斑状结构,舍地幔橄榄岩碎块(一般<1cm),表明为地幔岩浆快速喷出地表冷凝而成,岩浆上升过程中极少演化.火山岩微量元素和Sr-Nd-Pb同位素资料表明,涠洲岛及斜阳岛玄武岩与雷琼及北部湾周边、南海海盆玄武岩类似,具有亏损地幔的Sr、Nd同位素组成与Pb同位素显示的EMII富集地幔特征的Dupal异常,表明岩浆并非来自单一地幔源区,不可与OIB或MORB源区简单类比,也非地幔柱成因,而是由两个不同的地球化学组分混合而成.Re-OS同位素特征也指示地幔橄榄岩捕虏体来源于亏损的岩石圈地幔,而非核幔边界.推测涠洲岛及斜阳岛与雷琼及北部湾周边的岩浆可能是由于南海扩张后大陆裂解-软流圈地幔热物质上涌,与上覆薄而年轻的岩石圈地幔相互作用的产物.     

Hercynian plutonic rocks of Voras Mountain,Macedonia, Northern Greece: their structure,petrogenesis, and tectonic significance

We studied the structural, petrological, and geochemical characteristics, as well as the geotectonic setting, of the Hercynian (300 ± 3 Ma) Voras plutonic rocks intrusive into the lower part of the Pelagonian nappe pile (East Pelagonian Zone, EPZ). These rocks are compared with the neighbouring Hercynian Varnountas and Kastoria plutons intruding the tectonic upper Pelagonian part (Korabi West Pelagonian Zone, KoWPZ). Based on modal and chemical compositions, four rock-types can be distinguished for the Voras ploutonic rocks: (1) hornblende-biotite granodiorite to granite (HbBtGrd), (2) biotite granite (BtGr), (3) leucogranite (LGr), and (4) mafic microgranular enclaves (MMEs) occurring typically in HbBtGrd and BtGr. Aplites intrude HbBtGrd and BtGr whereas xenoliths are rare. The MMEs are metaluminous, while all the other rock-types are slightly peraluminous. Crystallization pressures range from 2.4 to 2.9 kbar for the HbBtGrd and 3.0 kbar for the MME. Field observations, chemical, mineralogical, and petrographical data suggest that theMME and HbBtGrd + BtGr formed as a result of a two-step evolution process. In the first step, a mantle-sourced basic magma with composition similar to the more basic MMEs fractionated (F = 0.40, 60% crystallization) and concurrently mixed with an acid magma, of composition similar to the more acid BtGr. The crystallized mineral assemblage is Qtz_38.27Pl_27.83Hb_14.84Bt_10.61Kf_6.13Ap_2.30Zrn_0.02. The process evolved with a low r-value (r = 0.3) giving the more basic HbBtGrd. In the second step, evolved magma (more basic HbBtGrd) fractionated, while simultaneously mixing with the same acid magma, but with higher r-value (r = 0.8), giving the more evolved HbBtGrd and the BtGr after 50% crystallization (F = 0.50) to the phase assemblage Qtz_30.07Pl_27.75Hb_5.59Bt_3.33Kf_23.26Tit_5.86Ap_1.91Zrn_0.04Mt_2.19. We interpret the evolution of the LGr through fractional crystallization; it formed by partial melting of gneisses or felsic charnokites and granoulites. The less evolved MME (basic end-member) had a mantle origin, whereas for the more evolved BtGr (acid end-member) we favour partial melting of gneisses or mafic charnokites. Detailed structural analysis shows a strong, polyphase Alpine deformation which affected the Hercynian Voras ploutonic rocks and is thoroughly imprinted on the host Pelagonian metamorphic basement rocks. No evidence of relict Hercynian structures has been recognized, possibly due to intense reworking by the younger Alpine deformation. We have identified five tectonic events (D1–D5) from the Late Jurassic to recent, that evolved progressively from ductile, synmetamorphic (D1, D2) to semi-ductile (D3), and finally brittle (D4, D5) conditions. Voras plutonic rocks in the EPZ, and Varnountas and Kastoria plutons in the KoWPZ, have similar major and trace element geochemistries, as well as structural evolution; they coevally intruded (Carboniferous) the Pelagonian continent as a single unit. They show similar crystallization pressures and mantle contributions for their genesis; both are related to a volcanic arc geotectonic setting, associated with the subduction of the Palaeotethys Ocean beneath the Pelagonian continental fragment, the latter possibly of Gondwana origin.     

西藏冈底斯带洛巴堆组火山岩地球化学及构造意义

冈底斯带中-新生代火山岩的成因和地质演化是青藏高原地质研究的热点领域,但是对晚古生代火山岩的性质及其形成的构造背景仍缺乏研究.冈底斯带二叠系显示缓慢的海退过程,并伴随基性和中酸性两期火山活动,具有活动大陆边缘特征.笔者对墨竹工卡县唐家乡和林周县勒青拉地区二叠纪洛巴堆组火山岩进行了常量、微量元素和St、Nd、Pb同位素地球化学测试.研究认为二叠纪是冈底斯岛弧的形成和演化时期.洛巴堆组玄武岩从下部(可能为早二叠世)到上部(中二叠世),MgO含量从7.43%降到3.99%,Al2O3含量从15.54%上升到17.57%,后者类似于岛弧高铝玄武岩;稀土总量∑REE从54.12(10-6)上升到108.82(10-6),LREE/HREE比值从3.00上升到5.40.洛巴堆组玄武岩均具有明显的Nb、Ta负异常,但中二叠世更显著.岩石地球化学示踪表明,冈底斯洛巴堆组玄武岩代表二叠纪初始岛弧环境.早期玄武岩形成于略亏损地幔和下地壳成分的混合源区,地壳相对较薄,源区或岩浆的壳源成分比例较低.到中二叠世地壳逐渐加厚.壳源成分在源区或岩浆中所占比例增大,代表向陆缘弧的演化过程.冈底斯带二叠纪岛弧是古特提斯洋向南的俯冲、消减的产物.     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.