Mafic alkalic magmatism in central Kachchh,India: a monogenetic volcanic field in the northwestern Deccan Traps

Magmatism in Kachchh, in the northwestern Deccan continental flood basalt province, is represented not only by typical tholeiitic flows and dikes, but also plug-like bodies, in Mesozoic sandstone, of alkali basalt, basanite, melanephelinite and nephelinite, containing mantle nodules. They form the base of the local Deccan stratigraphy and their volcanological context was poorly understood. Based on new and published field, petrographic and geochemical data, we identify this suite as an eroded monogenetic volcanic field. The plugs are shallow-level intrusions (necks, sills, dikes, sheets, laccoliths); one of them is known to have fed a lava flow. We have found local peperites reflecting mingling between magmas and soft sediment, and the remains of a pyroclastic vent composed of non-bedded lapilli tuff breccia, injected by mafic alkalic dikes. The lapilli tuff matrix contains basaltic fragments, glass shards, and detrital quartz and microcline, with secondary zeolites, and there are abundant lithic blocks of mafic alkalic rocks. We interpret this deposit as a maar-diatreme, formed due to phreatomagmatic explosions and associated wall rock fragmentation and collapse. This is one of few known hydrovolcanic vents in the Deccan Traps. The central Kachchh monogenetic volcanic field has >30 individual structures exposed over an area of ∼1,800 km² and possibly many more if compositionally identical igneous intrusions in northern Kachchh are proven by future dating work to be contemporaneous. The central Kachchh monogenetic volcanic field implies low-degree mantle melting and limited, periodic magma supply. Regional directed extension was absent or at best insignificant during its formation, in contrast to the contemporaneous significant directed extension and vigorous mantle melting under the main area of the Deccan flood basalts. The central Kachchh field demonstrates regional-scale volcanological, compositional, and tectonic variability within flood basalt provinces, and adds the Deccan Traps to the list of such provinces containing monogenetic- and/or hydrovolcanism, namely the Karoo-Ferrar and Emeishan flood basalts, and plateau basalts in Saudi Arabia, Libya, and Patagonia.     

Mineralogy and geothermometry of high-temperature rhyolites from the central and western Snake River Plain

Voluminous mid-Miocene rhyolitic ash-flow tuffs and lava flows are exposed along the northern and southern margins of the central and western Snake River Plain. These rhyolites are essentially anhydrous with the general mineral assemblage of plagioclase ±sanidine ± quartz + augite + pigeonite ± hypersthene ± fayalitic olivine + Fe-Ti oxides + apatite + zircon which provides an opportunity to compare feldspar, pyroxene, and Fe-Ti oxide equilibration temperatures for the same rocks. Estimated pyroxene equilibration temperatures (based on the geothermometers of Lindsley and coworkers) range from 850 to 1000°C, and these are well correlated with whole-rock compositions. With the exception of one sample, agreement between the two-pyroxene thermometers tested is well within 50°C. Fe-Ti oxide geothermometers applied to fresh magnetite and ilmenite generally yield temperatures about 50 to 100°C lower than the pyroxene temperatures, and erratic results are obtained if these minerals exhibit effects of subsolidus oxidation and exsolution. Results of feldspar thermometry are more complicated, and reflect uncertainties in the thermometer calibrations as well as in the degree of attainment of equilibrium between plagioclase and sanidine. In general, temperatures obtained using the Ghiorso (1984) and Green and Usdansky (1986) feldspar thermometers agree with the pyroxene temperatures within the respective uncertainties. However, uncertainties in the feldspar temperatures are the larger of the two (and exceed ±60°C for many samples). The feldspar thermometer of Fuhrman and Lindsley (1988) produces systematically lower temperatures for many of the samples studied. The estimated pyroxene temperatures are considered most representative of actual magmatic temperatures for these rhyolites. This range of temperatures is significantly higher than those for rhyolites from many other suites, and is consistent with the hypothesis that the Snake River Plain rhyolitic magmas formed by partial fusion of relatively dry (e.g. granulitic) crustal lithologies.     

Mafic enclaves in the rhyolitic products of Lipari historical eruptions; relationships with the coeval Vulcano magmas (Aeolian Islands, Italy)

The recent finding of mafic enclaves in the Rocche Rosse (RR) lava flow, the last magmatic product on Lipari (Aeolian Islands, Italy) (AD 1230 ± 40), opens the possibility to investigate in detail the most recent magmatic system of the island, an important issue for the volcanic hazard assessment of the area. The RR lava flow is an aphyric rhyolitic coulée consisting of grey and black pumice and black and grey obsidian. Enclaves have ellipsoidal to spheroidal shape and vary from mm-sized in the central portion of the flow, to cm-sized, at the top and in the flow front, where they are also more abundant. Enclaves are shoshonitic-latitic (group A) and trachytic (group B) in composition. The mineralogy of group A consists of dominant clinopyroxene crystals with minor abundance of feldspar (plagioclase > K-feldspar), olivine and biotite, while group B is composed of feldspar (K-feldspar > plagioclase) with minor clinopyroxene, olivine and biotite. Geochemical modeling suggests that the host rhyolitic rocks could be the product of AFC (Assimilation plus Fractional Crystallization) of a magma compositionally similar to the associated shoshonitic-latitic enclaves, which, in turn, could be obtained, through an AFC process, from the primitive melts erupted as olivine hosted melt inclusions during the last 15 ka at Vulcano. The already-known last 42 ka relationship between Lipari and Vulcano Islands is here reinforced until historical time, especially for the last 1 ka. The geochemical and petrological overlap between Lipari and Vulcano is interpreted to reflect the existence of a similar magmatic system underneath the two islands. The nearly aphyric RR rhyolites are interpreted to be the products of a superheated (temperature far above the liquidus) and initially water-undersaturated magma that underwent degassing close to the surface inhibiting microlite crystallization.     

Alkaline rocks of the deccan traps

Recent investigations on the Deccan Traps reveal many new findings of alkaline rocks more commonly occurring as minor intrusions than as lava flows. In comparison to the vast extent of the Deccan Traps, the alkaline rocks are negligible in their volume and are confined to tectonic belts in parts of Western India. The rocks exhibit no systematic variation in their petrographical and chemical characters thereby suggesting that they were not derived from a primary alkali olivine-basalt magma. The possibility of derivation of alkaline magma locally along the rift zones is proposed. Some of the alkaline rocks are shown to have been formed due to the effective role of volatiles in bringing dissociation of feldspar in certain cases, and alkali metasomatism in others. The syntexis of the pre-Deccan Trap carbonate rocks along the Narmada rift zone is also responsible for some occurrences.     

Enigmatic clastogenic rhyolitic volcanism: The Corral de Coquena spatter ring,North Chile

We report on the unusual occurrence of the products of lava fountaining in a Pliocene calc-alkaline rhyolitic monogenetic center from northern Chile. Corral de Coquena is a discontinuous ring of lava located in the moat of La Pacana caldera (23°27' S, 67°23.5' W), part of the Altiplano-Puna Volcanic Complex of the Central Andes. The volcanic structure is composed of a maar-like crater, with an associated pyroclastic (possibly phreatomagmatic) unit, that is overlain by rhyolitic glassy lava ramparts, in which evidence of spatter, agglutinate and clastogenic material is found. Typical explanations for the unusual textures in a rhyolitic lava, such as peralkaline composition, high volatile content, or superheated magma are untenable in this case. We propose that the most likely explanation for this extreme style of rhyolitic volcanism is a combination of moderately high eruption rate and efficient degassing prior to eruption. In the light of reports of several other bodies of fountain-fed silicic magma from the UK, US, and Japan, we propose that Corral de Coquena is a rhyolitic spatter ring superimposed upon a maar-like crater. We further propose that pyroclastic fountaining should be considered an end-member of the spectrum of eruptive styles of calc-alkaline silicic magmas, and that Corral de Coquena is a rare example, preserved because of the hyper-arid climate in the Altiplano-Puna Volcanic Complex.     

Effusive eruption of viscous silicic magma triggered and driven by recharge: a case study of the Cerro Chascon-Runtu Jarita Dome Complex in Southwest Bolivia

 The Cerro Chascon-Runtu Jarita Complex is a group of ten Late Pleistocene (∼85 ka) lava domes located in the Andean Central Volcanic Zone of Bolivia. These domes display considerable macroscopic and microscopic evidence of magma mixing. Two groups of domes are defined chemically and geographically. A northern group, the Chascon, consists of four lava bodies of dominantly rhyodacite composition. These bodies contain 43–48% phenocrysts of plagioclase, quartz, sanidine, biotite, and amphibole in a microlite-poor, rhyolitic glass. Rare mafic enclaves and selvages are present. Mineral equilibria yield temperatures from 640 to 750  °C and log ƒO₂ of –16. Geochemical data indicate that the pre-eruption magma chamber was zoned from a dominant volume of 68% to minor amounts of 76% SiO₂. This zonation is best explained by fractional crystallization and some mixing between rhyodacite and more evolved compositions. The mafic enclaves represent magma that intruded but did not chemically interact much with the evolved magmas. A southern group, the Runtu Jarita, is a linear chain of six small domes (<1 km³ total volume) that probably is the surface expression of a dike. The five most northerly domes are composites of dacitic and rhyolitic compositions. The southernmost dome is dominantly rhyolite with rare mafic enclaves. The composite domes have lower flanks of porphyritic dacite with ∼35 vol.% phenocrysts of plagioclase, orthopyroxene, and hornblende in a microlite-rich, rhyodacitic glass. Sieve-textured plagioclase, mixed populations of disequilibrium plagioclase compositions, xenocrystic quartz, and sanidine with ternary composition reaction rims indicate that the dacite is a hybrid. The central cores of the composite domes are rhyolitic and contain up to 48 vol.% phenocrysts of plagioclase, quartz, sanidine, biotite, and amphibole. This is separated from the dacitic flanks by a banded zone of mingled lava. Macroscopic, microscopic, and petrologic evidence suggest scavenging of phenocrysts from the silicic lava. Mineral equilibria yield temperatures of 625–727  °C and log ƒO₂ of –16 for the rhyolite and 926–1000  °C and log ƒO₂ of –9.5 for the dacite. The rhyolite is zoned from 73 to 76% SiO₂, and fractionation within the rhyolite composition produced this variation. Most of the 63–73% SiO₂ compositional range of the lava in this group is the result of mixing between the hybrid dacite and the rhyolite. Eruption of both groups of lavas apparently was triggered by mafic recharge. A paucity of explosive activity suggests that volatile and thermal exchanges between reservoir and recharge magmas were less important than volume increase and the lubricating effects of recharge by mafic magmas. For the Runtu Jarita group, the eruption is best explained by intrusion of a dike of dacite into a chamber of crystal-rich rhyolite close to its solidus. The rhyolite was encapsulated and transported to the surface by the less-viscous dacite magma, which also acted as a lubricant. Simultaneous effusion of the lavas produced the composite domes, and their zonation reflects the subsurface zonation. The role of recharge by hotter, more fluid mafic magma appears to be critical to the eruption of some highly viscous silicic magmas. Received: 23 August 1998 / Accepted: 10 March 1999     

The age and tectonic environment of the rhyolitic rocks on the western side of Wuyi Mountain,South China

During the geological survey of the metamorphic rocks in Xingning-Wuhua region on the western side of Wuyi Mountain, South China, we discovered the Neoproterozoic rhyolite and rhyolitic greywacke for the first time that outcrop in the Proterozoic metamorphic rocks near Jingnan Town of Xingning County, eastern Guangdong Province. A systematic research on petrology, geochemistry and geochronology of rhyolitic rocks was conducted to understand their tectonic setting and formation age. The Jingnan rhyolite is interbedded with a coeval greywacke, with a total thickness of 60 m; both rhyolite and greywacke display a similar folding and metamorphic pattern. Meta-rhyolite consists of groundmass and phenocrystals including sanidine, orthoclase, and quartz with distinct undulose extinction; the groundmass has been recrystallized into fine-grain feldspar, quartz and sericite aggregation. Meta-greywacke is composed of crystallinoclastic grains (sanidine, orthoclase, quartz and oligoclase) and clay groundmass. Zircon grains used for the SHRIMP U-Pb analysis are light brown-colored and euhedral or subeuhedral. Dating data suggest two age groups; eight grains of magmatype zircon with an idiomorphic form yield an age of 972±8 Ma, and the other seven weakly corroded grains of zircon with euhedral to subeuhedral shape construct an average age of 1097±11 Ma, which were captured from older rocks by an uplifting magma, implying that a late Mesoproterozoic basement exists in the Nanling region. In addition, one Paleoproterozoic age, 2035±11 Ma, is obtained from a rounded detrital zircon, indicating that a Paleoproterozoic thermal event took place in the South China. Geochemically, the Jingnan rhyolitic rocks are characterized by high K2O content, intermediate Al2O3 content, with the ACNK value 0.98―1.11, and belonging to high-K alkaline series. They are rich in ΣREE, Rb, Th and Ce, depleted in Ba, Sr, Eu, Ti, P and Nb-Ta, and with moderate negative Eu and Sr anomalies. These features indicate that the Jingnan volcanic rocks have an affinity of continental arc that is similar to those of acid volcanic rocks in the SE-China Coastal Region, in other words, a Neoproterozoic tectonomagma event might have taken place in the western Wuyi region, leading to an eruption of high-K calc-alkaline granitic magma.     

Remobilization of granitoid rocks through mafic recharge: evidence from basalt-trachyte mingling and hybridization in the Manori–Gorai area,Mumbai, Deccan Traps

Products of contrasting mingled magmas are widespread in volcanoes and intrusions. Subvolcanic trachyte intrusions hosting mafic enclaves crop out in the Manori–Gorai area of Mumbai in the Deccan Traps. The petrogenetic processes that produced these rocks are investigated here with field data, petrography, mineral chemistry, and whole rock major, trace, and Pb isotope chemistry. Local hybridization has occurred and has produced intermediate rocks such as a trachyandesitic dyke. Feldspar crystals have complex textures and an unusually wide range in chemical composition. Crystals from the trachytes cover the alkali feldspar compositional range and include plagioclase crystals with anorthite contents up to An₄₇. Crystals from the mafic enclaves are dominated by plagioclase An_72–90, but contain inclusions of orthoclase and other feldspars covering the entire compositional range sampled in the trachytes. Feldspars from the hybridized trachyandesitic dyke yield mineral compositions of An_80–86, An_47–54, Ab_94–99, Or_45–60, and Or_96–98, all sampled within individual phenocrysts. We show that these compositional features are consistent with partial melting of granitoid rocks by influx of mafic magmas, followed by magma mixing and hybridization of the partial melts with the mafic melts, which broadly explains the observed bulk rock major and trace element variations. However, heterogeneities in Pb isotopic compositions of trachytes are observed on the scale of individual outcrops, likely reflecting initial variations in the isotopic compositions of the involved source rocks. The combined data point to one or more shallow-level trachytic magma chambers disturbed by multiple injections of trachytic, porphyritic alkali basaltic, and variably hybridized magmas.     

Structure and emplacement of the Nandurbar–Dhule mafic dyke swarm,Deccan Traps,and the tectonomagmatic evolution of flood basalts

Flood basalts, such as the Deccan Traps of India, represent huge, typically fissure-fed volcanic provinces. We discuss the structural attributes and emplacement mechanics of a large, linear, tholeiitic dyke swarm exposed in the Nandurbar–Dhule area of the Deccan province. The swarm contains 210 dykes of dolerite and basalt >1 km in length, exposed over an area of 14,500 km². The dykes intrude an exclusively basaltic lava pile, largely composed of highly weathered and zeolitized compound pahoehoe flows. The dykes range in length from <1 km to 79 km, and in thickness from 3 to 62 m. Almost all dykes are vertical, with the others nearly so. They show a strong preferred orientation, with a mean strike of N88°. Because they are not emplaced along faults or fractures, they indicate the regional minimum horizontal compressive stress (σ ₃) to have been aligned ~N–S during swarm emplacement. The dykes have a negative power law length distribution but an irregular thickness distribution; the latter is uncommon among the other dyke swarms described worldwide. Dyke length is not correlated with dyke width. Using the aspect ratios (length/thickness) of several dykes, we calculate magmatic overpressures required for dyke emplacement, and depths to source magma chambers that are consistent with results of previous petrological and gravity modelling. The anomalously high source depths calculated for a few dykes may be an artifact of underestimated aspect ratios due to incomplete along-strike exposure. However, thermal erosion is a mechanism that can also explain this. Whereas several of the Nandurbar–Dhule dykes may be vertically injected dykes from shallow magma chambers, others, particularly the long ones, must have been formed by lateral injection from such chambers. The larger dykes could well have fed substantial (≥1,000 km³) and quickly emplaced (a few years) flood basalt lava flows. This work highlights some interesting and significant similarities, and contrasts, between the Nandurbar–Dhule dyke swarm and regional tholeiitic dyke swarms in Iceland, Sudan, and elsewhere. Editorial responsibility: J. White     

Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska

Compositional heterogeneity (56–64 wt% SiO₂ whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO₂) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.     

The basic instrusions at Chirha and Tikwa,Shahdol district,M.P.

While mapping parts of the Shahdol district, the author for the first time noticed a dolerite dyke at Tikwa and a basalt sill at Chirha intrusive into the Gondwanas (Supra-Barakars). Though the dolerite dyke shows no noteworthy features in the field, the sill encloses xenoliths of Supra-Barakar sandstone in its basal portion. The present paper gives an account of the mode of occurrence, petrography and age relationship of these intrusions. The presence of abundant xenocrysts of quartz in the basalt sill leads the author to term it a quartz-xenocryst-basalt. The occurrence of Deccan Trap flows in the close proximity of the intrusions suggest that they may be related to the period of Deccan Trap activity.     

Minerals produced during cooling and hydrothermal alteration of ash flow tuff from Yellowstone drill hole Y-5

A rhyolitic ash-flow tuff in a hydrothermally active area within the Yellowstone caldera was drilled in 1967, and cores were studied to determine the nature and distribution of primary and secondary mineral phases. The rocks have undergone a complex history of crystallization and hydrothermal alteration since their emplacement 600,000 years ago. During cooling from magmatic temperatures, the glassy groundmass underwent either devitrification to alkali feldspar + α-cristobalite ± tridymite or granophyric crystallization to alkali feldspar + quartz. Associated with the zones of granophyric crystallization are prismatic quartz crystals in cavities similar to those termed miarolitic in plutonic rocks. Vapor-phase alkali feldspar, tridymite, magnetite, and sporadic α-cristobalite were deposited in cavities and in void spaces of pumice fragments. Subsequently, some of the vapor-phase alkali feldspar crystals were replaced by microcrystalline quartz, and the vapor-phase minerals were frosted by a coating of saccharoidal quartz.Hydrothermal minerals occur primarily as linings and fillings of cavities and fractures and as altered mafic phenocrysts. Chalcedony is the dominant mineral related to the present hydrothermal regime and occurs as microcrystalline material mixed with various amounts of hematite and goethite. The chalcedony displays intricate layering and was apparently deposited as opal from silica-rich water. Hematite and goethite also replace both mafic phenocrysts and vapor-phase magnetite. Other conspicuous hydrothermal minerals include montmorillonite, pyrite, mordenite, calcite, and fluorite. Clinoptilolite, erionite, illite, kaolinite, and manganese oxides are sporadic. The hydrothermal minerals show little correlation with temperature, but bladed calcite is restricted to a zone of boiling in the tuff and clearly was deposited when CO₂ was lost during boiling.Fractures and breccias filled with chalcedony are common throughout Y-5 and may have been produced by rapid disruption of rock caused by sudden decrease of fluid pressure in fractures, most likely a result of fracturing during resurgent doming in this part of the Yellowstone caldera. The chalcedony probably was deposited as opal or β-cristobalite from a pre-existing silica floc that moved rapidly into the fractures and breccias immediately after the sudden pressure drop.     

The submarine eruption of the Bombarda volcano,Milos Island,Cyclades, Greece

The Milos volcanic field includes a well-exposed volcaniclastic succession which records a long history of submarine explosive volcanism. The Bombarda volcano, a rhyolitic monogenetic center, erupted ∼1.7 Ma at a depth <200 m below sea level. The aphyric products are represented by a volcaniclastic apron (up to 50 m thick) and a lava dome. The apron is composed of pale gray juvenile fragments and accessory lithic clasts ranging from ash to blocks. The juvenile clasts are highly vesicular to non-vesicular; the vesicles are dominantly tube vesicles. The volcaniclastic apron is made up of three fades: massive to normally graded pumice-lithic breccia, stratified pumice-lithic breccia, and laminated ash with pumice blocks. We interpret the apron beds to be the result of water-supported, volcaniclastic mass-How emplacement, derived directly from the collapse of a small-volume, subaqueous eruption column and from syn-eruptive, down-slope resedimentation of volcaniclastic debris. During this eruptive phase, the activity could have involved a complex combination of phreatomagmatic explosions and minor submarine effusion. The lava dome, emplaced later in the source area, is made up of flow-banded lava and separated from the apron by an obsidian carapace a few meters thick. The near-vertical orientation of the carapace suggests that the dome was intruded within the apron. Remobilization of pyroclastic debris could have been triggered by seismic activity and the lava dome emplacement. Published online: 30 January 2003 Editorial responsibility: J. McPhie     

A tertiary silicic cauldron complex at the northern margin of the basin and range province,central Arizona,U.S.A.

The Superior volcanic field occupies approximately 8,000 square kilometers of central Arizona in the zone between the southern Basin and Range Province and the Colorado Plateaus Province. The primary structural elements of an eruptive center in the western part of this field are: 1) volcanic plateau, 2) ring fracture zone, and 3) resurgent caldera core. A northwest trending graben controls the location of three small subsided blocks, the Willow Springs cauldron (2 km diameter), the Black Mesa cauldron (4 km diameter), and the Florence Junction cauldron (8 km diameter), which were centers for rhyolite ash and lava eruption. These late features are superimposed on a much larger volcano-tectonic structure, the Superstition resurgent cauldron which subsided at an earlier stage following the extrusion of quartz latite welded tuff. The history of the volcanic center is as follows: An early ring of dacite domes of up to 900 meters in relief formed a semi-circular are 7 km in diameter on the western margin of the caldera. The last phases of dome building were contemporaneous with the extrusion of a vast quartz latite welded tuff (22.6 m.y.). The plateau formed by the welded tuff collapsed to a maximum depth of 800 meters along a northwest trending graben which is the locus of three small cauldrons. These late cauldrons were the source of rhyolitic magma which produced non-welded ash flows, lava (21 m.y.), and a thick sequence of epiclastic breccias. The rhyolitic volcanism was followed by intrusion of domes and extrusion of glassy lavas (20 m.y.) of quartz latite composition in a 270° are 16 km in diameter concentric to the arc of older dacite domes. Following deposition of the epiclastic breccia and intrusion of the ring fracture dikes was the extrusion of mafic lava (18 m.y.) into low places in the graben. The mafic lava composition ranges from basalt to basanite.     

Cristobalite in a rhyolitic lava dome: evolution of ash hazard

Prolonged and heavy exposure to particles of respirable, crystalline silica-rich volcanic ash could potentially cause chronic, fibrotic disease, such as silicosis, in individuals living in areas of frequent ash fall. Here, we show that the rhyolitic ash erupted from Chaitén volcano, Chile, in its dome-forming phase, contains increased levels of the silica polymorph cristobalite, compared to its initial plinian eruption. Ash erupted during the initial, explosive phase (2–5 May 2008) contained approximately 2 wt.% cristobalite, whereas ash generated after dome growth began (from 21 May 2008) contains 13–19 wt.%. The work suggests that active obsidian domes crystallise substantial quantities of cristobalite on time-scales of days to months, probably through vapour-phase crystallisation on the walls of degassing pathways, rather than through spherulitic growth in glassy obsidian. The ash is fine-grained (9.7–17.7 vol.% <4 μm in diameter, the respirable range) and the particles are mostly angular. Sparse, fibre-like particles were confirmed to be feldspar or glass.     

Dykes around Dadiapada,broach district,Gujarat

The basaltic lava flows of the Deccan Traps in the Dadiapada area are traversed by abundant dykes trending mostly in ENE to WSW direction. The density of the dykes distribution is 2 to 3 per mile. They vary in size from a few feet to 300 feet in width and some can be traced for many miles. Some of the dolerites contain quartz in considerable amounts and it is significant to find micropegmatite texture in them indicating their tholetitic nature.     

Degassing during magma ascent in the Mule Creek vent (USA)

 The structures and textures of the rhyolite in the Mule Creek vent (New Mexico, USA) indicate mechanisms by which volatiles escape from silicic magma during eruption. The vent outcrop is a 300-m-high canyon wall comprising a section through the top of a feeder conduit, vent and the base of an extrusive lava dome. Field relations show that eruption began with an explosive phase and ended with lava extrusion. Analyses of glass inclusions in quartz phenocrysts from the lava indicate that the magma had a pre-eruptive dissolved water content of 2.5–3.0 wt% and, during eruption, the magma would have been water-saturated over the vertical extent of the present outcrop. However, the vesicularity of the rhyolite is substantially lower than that predicted from closed-system models of vesiculation under equilibrium conditions. At a given elevation in the vent, the volume fraction of primary vesicles in the rhyolite increases from zero close to the vent margin to values of 20–40 vol.% in the central part. In the centre the vesicularity increases upward from approximately 20 vol.% at 300 m below the canyon rim to approximately 40 vol.% at 200 m, above which it shows little increase. To account for the discrepancy between observed vesicularity and measured water content, we conclude that gas escaped during ascent, probably beginning at depths greater than exposed, by flow through the vesicular magma. Gas escape was most efficient near the vent margin, and we postulate that this is due both to the slow ascent of magma there, giving the most time for gas to escape, and to shear, favouring bubble coalescence. Such shear-related permeability in erupting magma is supported by the preserved distribution of textures and vesicularity in the rhyolite: Vesicles are flattened and overlapping near the dense margins and become progressively more isolated and less deformed toward the porous centre. Local zones have textures which suggest the coalescence of bubbles to form permeable, collapsing foams, implying the former existence of channels for gas migration. Local channelling of gas into the country rocks is suggested by the presence of sub-horizontal syn-eruptive rhyolitic tuffisite veins which depart from the vent margin and invade the adjacent country rock. In the central part of the vent, similar local channelling of gas is indicated by steep syn-eruption tuffisite veins which cut the rhyolite itself. We conclude that the suppression of explosive eruption resulted from gas separation from the ascending magma and vent structure by shear-related porous flow and channelling of gas through tuffisite veins. These mechanisms of gas loss may be responsible for the commonly observed transition from explosive to effusive behaviour during the eruption of silicic magma. Received: 24 May 1995 / Accepted: 13 March 1996     

The rhyolitic–andesitic eruptive history of Cotopaxi volcano,Ecuador

At Cotopaxi volcano, Ecuador, rhyolitic and andesitic bimodal magmatism has occurred periodically during the past 0.5 Ma. The sequential eruption of rhyolitic (70–75% SiO₂) and andesitic (56–62% SiO₂) magmas from the same volcanic vent over short time spans and without significant intermingling is characteristic of Cotopaxi’s Holocene behavior. This study documents the eruptive history of Cotopaxi volcano, presenting its stratigraphy and geologic field relations, along with the relevant mineralogical and chemical nature of the eruptive products, in order to determine the temporal and spatial relations of this bimodal alternation. Cotopaxi’s history begins with the Barrancas rhyolite series, dominated by pumiceous ash flows and regional ash falls between 0.4 and 0.5 Ma, which was followed by occasional andesitic activity, the most important being the ample andesitic lava flows (∼4.1 km³) that descended the N and NW sides of the edifice. Following a ∼400 ka long repose without silicic activity, Cotopaxi began a new eruptive phase about 13 ka ago that consisted of seven rhyolitic episodes belonging to the Holocene F and Colorado Canyon series; the onset of each episode occurred at intervals of 300–3,600 years and each produced ash flows and regional tephra falls with DRE volumes of 0.2–3.6 km³. Andesitic tephras and lavas are interbedded in the rhyolite sequence. The Colorado Canyon episode (4,500 years BP) also witnessed dome and sector collapses on Cotopaxi’s NE flank which, with associated ash flows, generated one of the largest cohesive debris flows on record, the Chillos Valley lahar. A thin pumice lapilli fall represents the final rhyolitic outburst which occurred at 2,100 years BP. The pumices of these Holocene rhyolitic eruptions are chemically similar to those of older rhyolites of the Barrancas series, with the exception of the initial eruptive products of the Colorado Canyon series whose chemistry is similar to that of the 211 ka ignimbrite of neighboring Chalupas volcano. Since the Colorado Canyon episode, andesitic magmatism has dominated Cotopaxi’s last 4,400 years, characterized by scoria bomb and lithic-rich pyroclastic flows, infrequent lava flows that reached the base of the cone, andesitic lapilli and ash falls that were carried chiefly to the W, and large debris flows. Andesitic magma emission rates are estimated at 1.65 km³ (DRE)/ka for the period from 4,200 to 2,100 years BP and 1.85 km³ (DRE)/ka for the past 2,100 years, resulting in the present large stratocone.     

Hydrothermal alteration associated with rift zones at Fangataufa atoll (French Polynesia)

 The Mururoa and Fangataufa atoll basement consists of superimposed submarine and subaerial lava flows which have been intruded by late volcanics. The intrusions have developed large hydrothermal alteration haloes throughout the basaltic wall rock. The cuttings of the Natice-1 and Mitre-1 holes, drilled into the submarine volcanic pile at Fangataufa atoll, show a vertical zonation of clay minerals ranging from 270 to 850 m depth. The newly formed clay minerals occurring from top to bottom of the altered pile are: dioctahedral aluminous smectites, saponite, an intimate assemblage of saponite with two random chlorite/saponite mixed layers and an intimate assemblage of one random chlorite/saponite mixed-layer with one ordered chlorite/saponite mixed layer and one chlorite below 816 m depth. These clay mineral assemblages indicate a general increase in the chloritic component with depth. They are associated throughout the pile with secondary carbonates and quartz. The ∂¹⁸O and ∂¹³C of calcite and ∂¹⁸O of clay minerals, on the one hand, and the intimate mixtures of trioctahedral species, on the other, suggest a general cooling with the evolution of a paleogeothermal gradient from approximately 300  °C/km during the crystallization of chlorite to 150  °C/km for the late calcite precipitation. Received: 2 October 1995 / Accepted: 14 January 1997     

The influence of trace amounts of water on the viscosity of rhyolites

 As a major volatile in volcanic systems, water has a significant influence on the rheological properties of silicic magmas. This is especially so at minor water contents relevant to the emplacement of silicic lavas. To investigate the influence of water on the viscosity of natural rhyolitic obsidians, a novel strategy has been adopted employing parallel-plate and micropenetration techniques. Viscosities have been determined on three types of material: (a) raw water-bearing obsidians; (b) remelted (1650  °C, 1 atm) degassed glasses of the obsidians; and (c) hydrothermally hydrated (1300  °C, 3 kbar) obsidians. Ten natural rhyolitic obsidians (peraluminous, calc-alkaline and peralkaline) were employed: seven originated from lava flows and contained <0.2 wt.% H₂O, two samples were F-rich from pyroclastic successions, and one was an obsidian cobble with 1.5 wt.% water also associated with pyroclastic units. Melt compositions and water contents were stable during viscometry. The measured decreases in activation energies of viscous flow and viscosity with small amounts of water are much greater than the Shaw calculation scheme predicts. In addition, a marked non-linear decrease in η exists with increasing water content. In contrast to the case for peralkaline rhyolites, 0.1–0.2 wt.% water decreases activation energies significantly (up to 30%) for calc-alkaline compositions. These results have important implications for the ease of near-surface degassing of silicic magmas during emplacement and permit the testing of calculational models for viscosity, largely based on synthetic systems. Received: 7 July 1997 / Accepted: 6 April 1998