中条山地区郭家沟基性-超基性岩体的岩石成因及地质意义

文章通过对中条山地区郭家沟基性-超基性岩体的岩石学、矿物学和岩石地球化学方面的分析研究,讨论了该岩体的形成时代、岩石成因、及其地质意义。郭家沟岩体侵入时代为元古代,可能与绛县群形成时代较为相近(2200Ma左右)。郭家沟岩体具有岩相分带现象,边缘相为辉长岩,向内渐变过渡为含长辉石岩、变余辉石岩(角闪石岩)等,在岩体的中心发育着磁铁透闪石岩;岩石中Mg O与其他主量元素线性相关,各类岩石地球化学特征较为相似,显示出岩石受分离结晶作用的影响,具有岩浆同源演化的趋势;岩石总体显示出低硅、低镁、高铁、高钛、高钙的特征,相对富集LREE和LILE,而亏损HREE和Nb、Ta、Zr、Y等高场强元素,轻重稀土分馏明显,具有较弱的Eu异常,V含量较高,具有阿拉斯加型侵入岩体和与火山弧相关的岩浆特征。从岩石组合及地球化学特征结合区域构造演化,认为岩体形成于大陆边缘弧的构造环境,从侧面也说明绛县群的形成环境应该是大陆边缘俯冲后的伸展环境,而非陆内裂谷。     

武山蛇绿岩的特征、同位素年代及其地质意义

武山蛇绿岩位于北秦岭西段、商丹断裂西延之北 ,岩石组成主要为超基性岩、变质的基性侵入岩、枕状玄武岩及大理岩。变玄武岩的岩石地球化学特征显示为钙碱性玄武岩 ,形成于大陆裂谷至初始洋盆环境 ,其Sm -Nd等时线年龄为 15 70Ma ,反映原始岩浆形成于中元古代 ,属大陆地壳演化早期的蛇绿岩     

大兴安岭中生代双峰式火山岩的地球化学特征

大兴安岭中生代火山岩的主要活动时期为晚侏罗世至早白垩世，由碱性系列玄武岩和亚碱性系列玄武岩以及伴生的中酸性火山岩组成。它们与邻区俄罗斯和蒙古同时期火山岩构成面形展布的巨型火山岩带。碱性系列玄武岩高度富集不相容元素，其富集程度类似于板内碱性系列玄武岩，但明显亏损Nb和Ta等高场强元素这一点又类似于活动大陆边缘火山弧或岛弧钙碱性玄武岩。亚碱性系列玄武岩适度富集不相容元素而强烈亏损高场强元素的特征类似于活动大陆边缘火山弧或岛弧火山岩，其中低钾玄武岩类似于拉斑玄武岩。大兴安岭酸性火山岩根据地球化学特征可划分为高Sr流纹岩类和低Sr流纹岩类。前者富集Ti、Ba、Sr、Co和Ni而贫Rb、Zr和Th等强不相容元素，类似于大陆溢流玄武岩省分异作用形成的流纹岩；后者明显富集不相容元素Rb、Zr和Th而亏损Ti、Ba、Sr和Co，它们与碱性系列玄武岩之间形成类似于大陆裂谷环境的双峰式火山岩组合。亚碱性系列玄武岩与高Sr流纹岩的成因关系类似于大陆伸张环境的双峰式火山岩，但前者形成从基性到酸性的连续演化系列，并没有形成Daly成分间断。这表明大兴安岭火山岩在源区及其原始岩浆的性质上明显区别于世界大陆溢流玄武岩省。也就是说，大陆溢流玄武岩省的双峰模式起源于干岩浆体系，这种岩浆分异形成的中性岩浆由于其教度大于玄武岩、挥发分含量低于流纹岩而未能喷出地表。大兴安岭富含水的原始岩浆使分异形成的中性熔岩被挥发分过饱和，导致中性熔岩的爆炸性喷发。     

武山蛇绿岩的特征、同位素年代及其地质意义

武山蛇绿岩位于北秦岭西段、商丹断裂西延之北，岩石组成主要为超基性岩、变质的基性侵入岩、枕状玄武岩及大理岩。变玄武岩的岩石地球化学特征显示为钙碱性玄武岩，形成于大陆裂谷至初始洋盆环境，其Sm-Nd等时线年龄为1570Ma，反映原始岩浆形成中元古代，属大陆地壳演化早期的蛇绿岩。     

新疆西天山查汗查哈花岗岩锆石U-Pb定年、岩石地球化学特征及其大地构造意义

查汗查哈岩体出露于新疆西天山东南段,位于中天山南缘断裂北缘的那拉提-中天山侵入岩带,岩性主要为片麻状花岗闪长岩和二长花岗岩。锆石U-Pb定年结果显示,查汗查哈岩体花岗质岩石形成于421.9±6.2 Ma。岩石地球化学特征表明其属于准铝质钙碱性Ⅰ型花岗岩,并具有较典型的大陆边缘弧侵入岩的特征。这一研究结果显示,南天山洋在晚志留世已经开始向北俯冲,并在中天山南缘形成大陆边缘弧环境。      

佳木斯地块东部二叠纪方山花岗岩体的锆石U—Pb年代学、地球化学特征及其地质意义

本文报道了佳木斯地块东部方山花岗岩体的锆石LA--ICP--MS U--Pb定年结果、全岩地球化学特征,确定了花岗质岩石的形成时代以及大地构造背景。花岗岩的锆石主要呈自形-半自形晶,振荡环带发育,Th/U在0.26~1.16之间,显示其典型的岩浆成因;测年结果表明这些花岗岩形成于早二叠世(278 Ma,277 Ma)。方山花岗岩呈现出弱过铝质高钾钙碱性的地球化学特征,这些岩石轻稀土富集,重稀土亏损,具有Eu负异常,富集大离子亲石元素(Rb、K等),相对亏损高场强元素(Nb、Ta、P、Zr和Ti)。该区花岗岩地球化学特征与佳木斯东缘二叠纪的美作、青山、楚山、柴河、石场、锦山等岩体相似,体现出火山弧型花岗岩的特征。结合区域研究资料,我们认为佳木斯地块东缘在早二叠世期间为活动大陆边缘。     

内蒙古狼山地区早石炭世石英闪长岩U-Pb年龄、地球化学特征及其对古亚洲洋俯冲的指示

内蒙古狼山山脉西侧分布大面积的晚古生代岩浆岩,时代集中在早石炭世—晚二叠世,早石炭世石英闪长岩体出露于潮格温都尔镇西侧。该岩体岩性为石英闪长岩,LA-ICP-MS锆石U-Pb年龄显示,石英闪长岩的~(206)Pb/~(238)U年龄加权平均值为337.4±6.6 Ma。岩石暗色矿物以角闪石为主,黑云母次之,富铁,富钠,高钠钾比值,为钙碱性系列;富集大离子亲石元素Rb、K、Pb,不同程度的亏损高场强元素Nb、Ta、P、Ti的特点,稀土元素配分型式为轻稀土元素富集,重稀土元素亏损,弱的负Eu异常,总体反映岩浆弧的地球化学特征。构造环境判别图显示样品点落在大陆边缘弧范围,岩石地球化学特征表明狼山地区早石炭世处于大陆边缘弧构造背景,古亚洲洋石炭纪存在向南俯冲。对比北部造山带西乌旗地区的早石炭世石英闪长岩,两者地球化学特征基本相同。因此,早石炭世古亚洲洋发生了双向俯冲,形成了以石英闪长岩为主的岩石类型。     

内蒙古北山北缘蓬勃山一带古亚洲洋闭合时间制约——来自黑红山二长花岗岩的证据

黑红山二长花岗岩分布于红石山-百合山-蓬勃山蛇绿岩带北部,地球化学特征显示其属于准铝质-弱过铝质、中-高钾钙碱性系列,为高分异的I型花岗岩;轻稀土元素富集,轻、重稀土元素分馏明显,具弱负Eu异常,稀土元素曲线为右缓倾。微量元素相对富集Ba、K、Zr、Hf,亏损Ta、Nb、P、Ti,显示与俯冲有关的侵入岩特征,形成于碰撞前的火山弧环境。LA-ICP-MS锆石U-Pb定年获得~(206)Pb/~(238)U年龄加权平均值为315.2±2.5Ma。综合研究表明,黑红山地区在晚石炭世属于活动大陆边缘的火山弧,红石山-百合山-蓬勃山蛇绿岩带所代表的洋盆在此尚未消亡。     

内蒙古东升庙矿区变质火山岩的地质地球化学特征及其意义

为探讨东升庙矿区变质火山岩的地质地球化学特征及其意义,本文对其产出特征、岩石学、岩石化学、地球化学和同位素等方面进行了综合分析研究。结果表明,矿区变质火山岩为一套以玄武岩为主的双峰式火山岩,其原岩为基性的玄武岩和酸性的流纹岩。玄武岩属碱性玄武岩,流纹岩属钙碱性系列,它们具有与火山弧火山岩相似的地球化学特征。基性火山岩的稀土元素分配型式和Nd同位素特征表明其成岩物质来源于（亏损）地幔。构造环境分析表明,矿区变质火山岩的构造环境为大陆边缘火山弧造山带。     

南天山库米什南黄尖石山岩体的年代学、地球化学和Sr、Nd同位素组成及其成因意义

南天山北缘库米什地区铜花山南部黄尖石山岩体高 Na、Mg 和 Fe、准铝或过铝质(ACNK=0.91～1.35),它们相对富集 K、Rb、Th,贫 Zr、Hf 等 HFSE,略亏损 Nb、Ta 和 P,具典型岛弧钙碱性Ⅰ型花岗岩的元素地球化学特征。其锆石 U-Pb 年龄为423Ma,ε_(Nd)(t)=-3.70～-7.32,t_(2DM)=1.45～1.75Ga,表明它们是早古生代早志留纪晚期由先存中元古代幔源基性地壳物质熔融的产物。岩体的 Ba、Sr 和 P 等弱亏损,Nb 和 Y 丰度及 Rb/Zr 比值中等则指示是活动大陆边缘俯冲带岛弧演化到正常大陆弧环境的产物。因此,该岩体的形成标志着南天山洋盆于晚志留世时期已进入俯冲消减的活动大陆边缘演化阶段。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.