Sediment sources of northern Québec and Labrador glacial deposits and the northeastern sector of the Laurentide Ice Sheet during ice-rafting events of the last glacial cycle

Provenance studies of anomalously high-flux layers of ice-rafted detritus (IRD) in North Atlantic sediments of the last glacial cycle show evidence for massive iceberg discharges coming from the Hudson Strait region of the Laurentide Ice Sheet (LIS). Although these so-called Heinrich events (H events) are commonly thought to be associated with abrupt drawdown of the LIS interior, uncertainties remain regarding the sector(s) of this multi-domed ice sheet that conveyed ice through Hudson Strait. In Northern Québec and Labrador (NQL), large-scale patterns of glacial lineations indicate massive ice flows towards Ungava Bay and Hudson Strait that could reflect the participation of the Labrador–Québec ice dome in H events. Here we evaluate this hypothesis by constraining the source of NQL glacial deposits, which provide an estimate of the provenance characteristics of IRD originating from this sector. Specifically, we use ⁴⁰Ar/³⁹Ar ages of detrital hornblende grains in 25 till samples distributed along a latitudinal transect (lat. 58°) extending east and west of Ungava Bay. The data show that tills located west and southwest of the Ungava Bay region are largely dominated by hornblende grains with Archean ages (>2.6 Ga), while tills located east of Ungava Bay are characterized by grains with early Paleoproterozoic ages (2.0–1.8 Ga), although most samples contain a few Archean-age grains. IRD derived from the NQL region should thus be characterized by a large proportion of Archean-age detrital grains, which contrasts significantly with the predominant Paleoproterozoic ⁴⁰Ar/³⁹Ar ages (1.8–1.6 Ga) typically reported for the dominant age population of hornblende grains in H layers. Comparisons with IRD through the last glacial cycle from a western North Atlantic core off Newfoundland do not show evidence for any prominent ice-rafted event with the provenance characteristics of NQL glacial deposits, thereby suggesting that significant ice-calving event(s) from the Labrador–Québec sector may have been limited throughout that interval. Although these results tend to point towards a relative stability of this ice dome during H events, our study also indicates that further provenance work is required on IRD proximal to the Hudson Strait mouth in order to constrain with a greater confidence the sector(s) of the LIS that fed ice into Hudson Strait during H events. Alternatively, these results and other paleogeographic considerations tend to support models suggesting that part of the Ungava Bay glacial lineations could be associated with a Late-Glacial ice flow across Hudson Strait.     

Ice-rafted detritus evidence from 40Ar/39Ar ages of individual hornblende grains for evolution of the eastern margin of the Laurentide ice sheet since 43 14C ky

During the last glacial interval, the North Atlantic ice sheets expanded and contracted in approximate synchronicity with orbitally forced global climate change. Variation in ice rafted detritus content in North Atlantic marine sediment cores record the waxing and waning of glaciers, as well as the abrupt temperature changes at millennial time scales. The background variations of ice rafting are punctuated by Heinrich layers, which appear to record the catastrophic collapse of the Laurentide ice sheet through the Hudson Strait. The objective of this paper is to document the evolution of glaciation on Laurentia during the last 43 ¹⁴C kyr. We present a provenance study based on ⁴⁰Ar/³⁹Ar dates of individual hornblende grains from 57 samples taken at 2 cm spacing between 4 and 134 cm from core V23-14 (43.4°N, 45.25°W, 3177 m). Sedimentation rates outside of the Heinrich layers are very low in this core, but the Heinrich layers are easily identified. Laurentide glaciation did not extend into the ocean south of 55°N until about 26 ¹⁴C kyr, and retreated to the coastline or beyond by 14 ¹⁴C kyr. Documenting the history of this major ice sheet has significant implications for understanding ice rafting sources in more distal locations where mixing among different ice sheets is likely.     

Intercalibration of the Hb3gr Ar/Ar dating standard

The ⁴⁰Ar/³⁹Ar dating technique is based on the knowledge of the age of neutron fluence monitors (standards). Recent investigations have improved the accuracy and precision of the ages of most of the Phanerozoic-aged standards (e.g. Fish Canyon Tuff sanidine (FCs), Alder Creek sanidine, GA1550 biotite and LP-6 biotite); however, no specific study has been undertaken on the older standards (i.e. Hb3gr hornblende and NL-25 hornblende) generally used to date Precambrian, high Ca/K, and/or meteoritic rocks.In this study, we show that Hb3gr hornblende is relatively homogenous in age, composition (Ca/K) and atmospheric contamination at the single grain level. The mean standard deviation of the ⁴⁰Ar^?/³⁹Ar_K (F-value) derived from this study is 0.49%, comparable to the most homogeneous standards. The intercalibration factor (which allows direct comparison between standards) between Hb3gr and FCs is R_FCs^Hb3gr = 51.945 ± 0.167. Using an age of 28.02 Ma for FCs, the age of Hb3gr derived from the R-value is 1073.6 ± 5.3 Ma (1σ; internal error only) and ± 8.8 Ma (including all sources of error). This age is indistinguishable within uncertainty from the K/Ar age previously reported at 1072 ± 11 Ma [Turner G., Huneke, J.C., Podosek, F.A., Wasserburg, G.J., 1971. ⁴⁰Ar-³⁹Ar ages and cosmic ray exposure ages of Apollo 14 samples. Earth Planet. Sci. Lett. 12, 19-35].The R-value determined in this study can also be used to intercalibrate FCs if we consider the K/Ar date of 1072 Ma as a reference age for Hb3gr. We derive an age of 27.95 ± 0.19 Ma (1σ; internal error only) for FCs which is in agreement with the previous determinations. Altogether, this shows that Hb3gr is a suitable standard for ⁴⁰Ar/³⁹Ar geochronology.     

The origin and flux of icebergs released into the Last Glacial Maximum Northern Hemisphere oceans: the impact of ice‐sheet topography

The precipitation fields of a palaeoatmospheric general circulation model are used to derive estimates of the geographical distribution, and flux, of icebergs from the Laurentide, Fennoscandinavian and eastern Siberian ice‐sheets at the Last Glacial Maximum (LGM). The atmospheric model fields from LGM simulations using CLIMAP or Peltier (ICE‐4G) ice orography were studied, to test the sensitivity of the predicted flux. The estimated Northern Hemispheric LGM iceberg flux is 3500–4000 km³ yr^?1, of which about 60% issued directly into the North Atlantic. The iceberg flux from the St Lawrence area is of similar significance to that issuing from Hudson Strait in all estimates. Both the North Pacific and the Arctic received substantial iceberg fluxes (ca. 700 km³ yr^?1), with relatively minor differences occurring between the two ice‐sheet reconstructions. Apparent discrepancies between Arctic deep‐sea core samples of ice‐rafted debris and our estimates of mean glacial iceberg flux may be ascribed to coastal trapping of bergs, the existence of floating ice tongues or a rapid exit of icebergs from the Arctic basin into the Greenland Sea through the Fram Strait. Copyright © 2001 John Wiley & Sons, Ltd.     

40Ar/39Ar ages and 40Ar* concentrations of fine-grained sediment fractions from North Atlantic Heinrich layers

New K/Ar ages based on ⁴⁰Ar/³⁹Ar incremental heating of <2- and 2–20-μm size fractions of the well-characterized, carbonate-bearing Heinrich layers of core V28-82 in the eastern North Atlantic are 846–1049 Ma, overlapping with conventional K/Ar ages from the same Heinrich layers on the Dreizack seamounts of 844–1074 Ma. This agreement suggests the equivalence of the methods in fine-grained terrigenous sediments. Additionally, Heinrich layer H2 yielded a ⁴⁰Ar/³⁹Ar-based K/Ar age of 970±4 from Orphan Knoll in the southern Labrador Sea, within the range found in eastern North Atlantic Heinrich layers. Thus, the K/Ar data are robust in their indication of a dominant Labrador Sea ice-rafted source to even the finest sediment fraction in the eastern North Atlantic during the massive detrital carbonate-bearing Heinrich events of the last glacial cycle (H1, H2, H4, H5). Close correspondence of the radiogenic argon concentration (⁴⁰Ar*) from the de-carbonated <63-μm fractions from V28-82 with the <2- and 2–16-μm fractions from the Driezack seamounts demonstrates that this measurement is a rapid and reliable method for correlating these layers within their belt of distribution.A ⁴⁰Ar/³⁹Ar-based K/Ar age of 433±5 million years for H11 in V28-82 is within the range of published data from background sediments in the eastern North Atlantic, and is consistent with published results across this interval in the Driezack seamounts. In contrast, the ⁴⁰Ar/³⁹Ar-based K/Ar age of H11 in the western Atlantic core EW9303-JPC37 is 614±5 million years. A brick red sample from approximately the interval of H3 of core EW9303-GGC40 yielded a ⁴⁰Ar/³⁹Ar-based K/Ar age of 567±1 million years, comparable to the published range of 523–543 Ma from the 2–16-μm fractions from that interval on the Dreizack seamounts. Both JPC37 and GGC40 are located in the path of the North Atlantic Drift. The older ages from western samples of H3 and H11 may result from dilution of a Hudson Strait source or an elevated age from southeastern Laurentide sources.     

Ice‐rafting patterns on the western Svalbard slope 74–0 ka: interplay between ice‐sheet activity,climate and ocean circulation

The distribution of ice‐rafted detritus (IRD) is studied in three cores from the western Svalbard slope (1130–1880 m water depth, 76–78°N) covering the period 74–0 ka. The aim was to provide new insight into the dynamics of the Svalbard–Barents Sea Ice Sheet during Marine Isotope Stages (MIS) 4–1 to get a better understanding of ice‐sheet interactions with changes in ocean circulation and climate on orbital and millennial (Dansgaard–Oeschger events of stadial–interstadial) time scales. The results show that concentration, flux, composition and grain‐size of IRD vary with climate and ocean temperature on both orbital and millennial time scales. The IRD consists mainly of fragments of siltstones and mono‐crystalline transparent quartz (referred to as ‘quartz’). IRD dominated by siltstones has a local Svalbard–Barents Sea source, while IRD dominated by quartz is from distant sources. Local siltstone‐rich IRD predominates in warmer climatic phases (interstadials), while the proportion of allochthonous quartz‐rich IRD increases in cold phases (glacials and stadials/Heinrich events). During the Last Glacial Maximum and early deglaciation at 24–16.1 ka, the quartz content reached up to >90%. In warm climate, local iceberg calving apparently increased and the warmer ocean surface caused faster melting. During the glacial maxima (MIS 4 and MIS 2) and during cold stadials and Heinrich events, the local ice‐sheets must have been relatively stable with low ablation. During ice retreat phases of the MIS 4/3 and MIS 2/1 transitions, maxima in IRD deposition were dominated by local coarse‐grained IRD. These maxima correlate with episodes of climate warming, indicating a rapid, stepwise retreat of the Svalbard–Barents Sea Ice Sheet in phase with millennial‐scale climate oscillations.     

Compositional variability of ice‐rafted debris in Heinrich layers 1 and 2 on the northwest European continental slope identified by environmental magnetic analyses

The composition of ice‐rafted debris (IRD) within a sediment core from the European continental slope (core OMEX‐2K; 49° 5′ N, 13° 26′ W) has been examined using environmental magnetic analyses. The data demonstrate compositional variability of the IRD within Heinrich layers 2 (H2) and 1 (H1) and these differences are most readily explained by changes in the contribution of different IRD sources to the core site. Some IRD within the main Heinrich layers show magnetic signatures that are similar to IRD derived from the Laurentide ice sheet found in cores from within the main North Atlantic IRD‐belt. In contrast, other IRD‐rich layers, both prior to and within the main Heinrich layers, demonstrate different magnetic behaviour, suggesting a contribution from a non‐Laurentide sourced IRD, most likely derived from ice streams discharging from northeast Atlantic ice sheets such as the British and Fennoscandian ice sheets. These data are consistent with published compositional data from the same core and, given the rapid, highly sensitive and non‐destructive nature of the method, suggest that environmental magnetic analysis has considerable potential for characterising IRD materials within Heinrich layers for the purposes of defining provenance. Copyright © 2006 John Wiley & Sons, Ltd.     

Source,timing, frequency and flux of ice‐rafted detritus to the Northeast Atlantic margin, 30–12 ka: testing the Heinrich precursor hypothesis

Haapaniemi, A.I., Scourse, J.D., Peck, V.L., Kennedy, H., Kennedy, P., Hemming, S.R., Furze, M.F.A., Pieńkowski, A.J., Austin, W.E.N., Walden, J., Wadsworth, E. & Hall, I.R. 2010: Source, timing, frequency and flux of ice‐rafted detritus to the Northeast Atlantic margin, 30–12 ka: testing the Heinrich precursor hypothesis. Boreas, Vol. 39, pp. 576–591. 10.1111/j.1502‐3885.2010.00141.x. ISSN 0300‐9483. Increased fluxes of ice‐rafted detritus (IRD) from European ice sheets have been documented some 1000–1500 years before the arrival of Laurentide Ice Sheet (LIS)‐sourced IRD during Heinrich (H) events. These early fluxes have become known as ‘precursor events’, and it has been suggested that they have mechanistic significance in the propagation of H events. Here we present a re‐analysis of one of the main cores used to generate the precursor concept, OMEX‐2K from the Goban Spur covering the last 30 ka, in order to identify whether the British–Irish Ice Sheet (BIIS) IRD fluxes occur only as precursors before H layers. IRD characterization and planktonic foraminiferal δ¹⁸O measurements constrained by a new age model have enabled the generation of a continuous record of IRD sources, timing, frequency and flux, and of local contemporary hydrographic conditions. The evidence indicates that BIIS IRD precursors are not uniquely, or mechanistically, linked to H events, but are part of the pervasive millennial‐scale cyclicity. Our results support an LIS source for the IRD comprising H layers, but the ambient glacial sections are dominated by assemblages typical of the Irish Sea Ice Stream. Light isotope excursions associated with H events are interpreted as resulting from the melting of the BIIS, with ice‐sheet destabilization attributed to eustatic jumps generated by LIS discharge during H events. This positive‐feedback mechanism probably caused similar responses in all circum‐Atlantic ice‐sheet margins, and the resulting gross freshwater flux contributed to the perturbation of the Atlantic Meridional Overturning Circulation during H events.     

Geochemistry and Ar/Ar geochronology of pseudotachylyte associated with UHP whiteschists from the Dora Maira massif, Italy

In situ UV-laser ablation ⁴⁰Ar/³⁹Ar geochronological and geochemical data, together with rock and mineral compositional data, have been determined from pseudotachylyte and surrounding mylonitic gneiss associated with the UHP whiteschists of the Dora Maira Massif, Italy. Several generations of fresh pseudotachylyte occur as irregular veins up to a few cm thick both parallel and at high angles to the foliation. Whole rock XRF data collected from representative lithologies of mylonitic gneiss are uniformly consistent with a mildly alkalic granitic protolith. Minimal compositional variation is observed between the pseudotachylyte and its surrounding mylonitic gneiss. The pseudotachylyte contains newly crystallized grains of biotite and K-feldspar in a matrix of glass with partially fused grains of quartz, zircon, apatite, and titanite. Electron microprobe analyses of the glass show significant compositional variation that is probably strongly influenced by micrometer-scale changes in mineralogy. UV-laser ablation ICP-MS traverses across the mylonitic gneiss–pseudotachylyte contact are consistent with cataclastic communition of REE carriers such as epidote, monazite, allanite, zircon, and apatite before melting as an efficient mechanism of REE homogenization in the pseudotachylyte. The ⁴⁰Ar/³⁹Ar data from one band of pseudotachylyte indicate formation at 20.1 ± 0.5 Ma, when the mylonitic gneisses were already in a near surface position. The variable effects of top-to-the-west shear deformation within outcrops of the coesite-bearing unit are reflected in localized zones of protomylonite, cataclasite, ultracataclasite, and pseudotachylyte. Preservation of several generations of pseudotachylyte suggests that seismic events may have played a significant role in triggering late unroofing of the UHP rocks. It is speculated that deeper crustal seismic events potentially played a role in the unroofing of the UHP rocks at earlier stages in their exhumation history.     

Last glacial ice‐rafted debris off southwestern Europe: the role of the British–Irish Ice Sheet

Ice‐rafted debris (IRD) seeded into the ocean from Northern Hemisphere ice sheets is found in ocean cores along the southwestern European margin through the last glacial period. It is known that the origin of this IRD, especially off Iberia, can vary between North America and western Europe during short‐lived episodes of greatly enhanced iceberg flux, known as Heinrich events, although in most Heinrich events the IRD has a North American source. During the longer times of much lower IRD fluxes between Heinrich events, use of an intermediate complexity climate model, coupled to an iceberg dynamic and thermodynamic model, shows that background levels of IRD most likely originate from western Europe, particularly the British–Irish Ice Sheet. Combining modelling with palaeoceanographic evidence supports reconstructions of a short‐lived, but substantial, Celtic and Irish Sea Ice Stream around 23 ka. Copyright © 2010 John Wiley & Sons, Ltd.     

Hornblende Ar/Ar geochronology across terrane boundaries in the Sveconorwegian Province of S. Norway

Hornblende incremental heating ⁴⁰Ar/³⁹Ar data were obtained from augen gneiss and amphibolite of the Sveconorwegian Province of S. Norway. In the Rogaland-Vest Agder and Telemark terranes, four pyroxene-rich samples, located close (≤ 10 km) to the anorthosite-charnockite Rogaland Igneous Complex, define an age group at 916 + 12/ − 14 Ma and six samples distributed in the two terranes yield another group at 871 + 8/ − 10 Ma. The first age group is close to the reported zircon U---Pb intrusion age of the igneous complex (931 ± 2 Ma) and the regional titanite U---Pb age (918 ± 2 Ma), whereas the second group overlaps reported regional mineral Rb---Sr ages (895-853 Ma) as well as biotite K---Ar ages (878-853 Ma). In the first group, the comparatively dry parageneses of low-P thermal metamorphism (M2) associated with the intrusion of the igneous complex are well developed, and hornblende ⁴⁰Ar/³⁹Ar ages probably record a drop in temperature shortly after this phase. In other hornblende + biotite-rich samples, with presumably a higher fluid content, the hornblende ages are probably a response to hornblende-fluid interaction during a late Sveconorwegian metamorphic or hydrothermal event. A ca 220 m.y. diachronism in hornblende ⁴⁰Ar/³⁹Ar ages is documented between S. Telemark (ca 870 Ma) and Bamble (ca 1090 Ma). Differential uplift between these terranes was mostly accommodated by shearing along the Kristiansand-Porsgrunn shear zone. The final stage of extension along this zone occurred after intrusion of the Herefoss post-kinematic granite at 926 ± 8 Ma. On the contrary, the southern part of the Rogaland-Vest Agder and Telemark terranes share a common cooling evolution as mineral ages are similar on both sides of the Mandal-Ustaoset Line the tectonic zone between them. The succession within 20 m.y. of a voluminous pulse of post-tectonic magmatism at 0.93 Ga, a phase of high-T-low-P metamorphism at 0.93-0.92 Ga, and fast cooling at a regional scale ca 0.92 Ga, suggests that the southern parts of Rogaland-Vest Agder and Telemark were affected by an event of post-thickening extension collapse at that time. This event is not recorded in Bamble.     

New U-Pb zircon and Ar/Ar muscovite age constraints on the emplacement of the Lizio syn-tectonic granite (Armorican Massif, France)

LA-ICP-MS U-Pb analyses performed on zircon grains from the Lizio granite yielded an emplacement age of 316 ± 6 Ma. Typical S-C structures show that the Lizio granite was emplaced contemporaneously with dextral shearing along the northern branch of the South Armorican Shear Zone and that it was therefore active at that time. ⁴⁰Ar/³⁹Ar analyses performed on muscovite grains yielded plateau dates ranging between 311.5 and 308.2 Ma. Muscovite chemistry is typical of primary magmatic muscovite, which precludes a late fluids-induced resetting of the K-Ar isotopic system. ⁴⁰Ar/³⁹Ar dates thus likely correspond to the cooling ages below the argon closure temperature. Considering the uncertainties on the measured ages, we can propose that either the Lizio granite cooled down quickly in less than a million of years or that it remained in a hot environment for several millions of years after its emplacement. This latter scenario could have been sustained by shear heating during dextral shearing along the northern branch of the South Armorican Shear Zone.     

The relationship of Heinrich events and their European precursors over the past 60 ka BP: a multi-proxy ice-rafted debris provenance study in the North East Atlantic

High resolution, multi-proxy records of ice-rafted debris (IRD) flux and provenance in the NE Atlantic detail the development, variability and decline of marine margins of the last glacial circum-North Atlantic ice sheets. Coupled lithological identification, Sr and Nd isotopic composition and ⁴⁰Ar/³⁹Ar ages of individual hornblende grains reduce ambiguity as to IRD potential source region, allowing clear differentiation between Laurentide (LIS), Icelandic and British (BIS) ice sheet sources (the Icelandic and BIS are collectively referred to as the NW European ice sheet, NWEIS). A step-wise increase in the flux of IRD to the core site at ∼26.5 ka BP documents BIS advance and glaciation of Ireland. Millennial-scale variability of the BIS at a ∼2 ka periodicity is inferred through clusters of pulsed IRD fluxes throughout the late glacial (26.5–10 ka BP). Combination of these European IRD events and the ∼7 ka periodicity of LIS instability is thought to account for quasi-synchronicity of the NWEIS and LIS IRD pulses at Heinrich event (H) 2 and H1, previously suggested to represent the possible involvement of the NWEIS in the initiation of H events. Furthermore, the lack of extensive NWEIS marine margin is inferred prior to H3 (31.5 ka BP), such that no ‘European precursor’ event is associated with either H5 or H4. This suggests that ‘precursor events’ were not directly implicated in the collapse of the LIS, and the persistent instabilities of the BIS that are clustered at a 2 ka periodicity are incompatible with the concept that both H events and their ‘precursors’ are independent responses to a common underlying trigger.     

Ar/Ar geochronology of gold mineralization in Brasiliano strike-slip shear zones in the Borborema province, NE Brazil

⁴⁰Ar/³⁹Ar geochronology of muscovite and biotite grains genetically related to gold and Be–Ta–Li pegmatites from the Seridó Belt (Borborema province, NE Brazil) yield well-defined, reliable plateau ages. This information, combined with data about paragenetic and field relationships, reveals Cambro-Ordovician mineralization ages (520 and 500–506 Ma) for the orogenic gold deposits in the Seridó Belt. Biotite ages of 525±2 Ma, which represent the mean weighted results of the incremental heating analysis of six biotite single crystals, record the time of pegmatite emplacement and reactivation of Brasiliano/Pan-African strike-slip shear zones. These results, along with previous structural evolution studies, suggest that shear zones formed during the Brasiliano/Pan-African event were reactivated in the Upper Cambrian–Lower Ordovician. Mineralization occurs late in the history of the orogen.     

Growth,dynamics and deglaciation of the last British–Irish ice sheet: the deep-sea ice-rafted detritus record

The evolution and dynamics of the last British–Irish Ice Sheet (BIIS) have hitherto largely been reconstructed from onshore and shallow marine glacial geological and geomorphological data. This reconstruction has been problematic because these sequences and data are spatially and temporally incomplete and fragmentary. In order to enhance BIIS reconstruction, we present a compilation of new and previously published ice-rafted detritus (IRD) flux and concentration data from high-resolution sediment cores recovered from the NE Atlantic deep-sea continental slope adjacent to the last BIIS. These cores are situated adjacent to the full latitudinal extent of the last BIIS and cover Marine Isotope Stages (MIS) 2 and 3. Age models are based on radiocarbon dating and graphical tuning of abundances of the polar planktonic foraminifera Neogloboquadrina pachyderma sinistral (% Nps) to the Greenland GISP2 ice core record. Multiple IRD fingerprinting techniques indicate that, at the selected locations, most IRD are sourced from adjacent BIIS ice streams except in the centre of Heinrich (H) layers in which IRD shows a prominent Laurentide Ice Sheet provenance. IRD flux data are interpreted with reference to a conceptual model explaining the relations between flux, North Atlantic hydrography and ice dynamics. Both positive and rapid negative mass balance can cause increases, and prominent peaks, in IRD flux. First-order interpretation of the IRD record indicates the timing of the presence of the BIIS with an actively calving marine margin. The records show a coherent latitudinal, but partly phased, signal during MIS 3 and 2. Published data indicate that the last BIIS initiated during the MIS 5/4 cooling transition; renewed growth just before H5 (46 ka) was succeeded by very strong millennial-scale variability apparently corresponding with Dansgaard–Oeschger (DO) cycles closely coupled to millennial-scale climate variability in the North Atlantic region involving latitudinal migration of the North Atlantic Polar Front. This indicates that the previously defined “precursor events” are not uniquely associated with H events but are part of the millennial-scale variability. Major growth of the ice sheet occurred after 29 ka with the Barra Ice Stream attaining a shelf-edge position and generating turbiditic flows on the Barra–Donegal Fan at ～27 ka. The ice sheet reached its maximum extent at H2 (24 ka), earlier than interpreted in previous studies. Rapid retreat, initially characterised by peak IRD flux, during Greenland Interstadial 2 (23 ka) was followed by readvance between 22 and 16 ka. Readvance during H1 was only characterised by BIIS ice streams draining central dome(s) of the ice sheet, and was followed by rapid deglaciation and ice exhaustion. The evidence for a calving margin and IRD supply from the BIIS during Greenland Stadial 1 (Younger Dryas event) is equivocal. The timing of the initiation, maximum extent, deglacial and readvance phases of the BIIS interpreted from the IRD flux record is strongly supported by recent independent data from both the Irish Sea and North Sea sectors of the ice sheet.     

40Ar/39Ar laser probe evidence concerning the age and associated hazards of the Lake Nyos Maar,Cameroon

The waters of Lake Nyos are impounded by a fragile natural dam composed of pyroclastic rocks ejected during the formation of the lake crater (maar). Lateral erosion of this dam has reduced its width from over 500 m to only 45 m. Published whole-rock K-Ar ages of about 100 ka on juvenile basalt from the dam suggests that erosion has been slow and that the dam poses no imminent threat. New apparent ⁴⁰Ar/³⁹Ar ages of 1.4 to 232 Ma on xenocrystic K-feldspar contained in the basalt show that the xenocrysts, whose source is the 528-Ma crystalline basement, are carriers of inherited radiogenic ⁴⁰Ar and would cause the whole-rock K-Ar ages to be too old. The best estimate for the age of the maar is provided by a ¹⁴C age of 400 ± 100 yr BP on charcoal from the base of the dam. This young age indicates that the dam is eroding at a relatively rapid rate; its failure, perhaps within a few decades, would result in a major flood and imperil thousands of people living downstream in Cameroon and eastern Nigeria.     

The origin of massive diamicton facies by iceberg rafting and scouring, Scoresby Sund, East Greenland

Almost 90% of 39 m of core material recovered from Scoresby Sund and the adjacent East Greenland shelf is massive diamicton, interpreted to be formed predominantly by the release of iceberg rafted debris and reworking by iceberg scouring. There is also likely to be a contribution from suspension settling of fines derived from glaciofluvial sources. Model calculations suggest that the ¹⁴C derived Holocene sedimentation rate of 0.1-0.3 m 1000 yr⁻¹ in Scoresby Sund can be accounted for mainly by iceberg rafting of debris. A further 4% of core material is of gravel or coarse sand lenses, interpreted to reflect iceberg dumping of debris. Intensive iceberg scouring, which reworks sea floor sediments, is observed on acoustic records from over 30 000 km² of the Scoresby Sund fiord system and the adjacent East Greenland shelf (69-72°N and 75°N). The rate of iceberg production from Greenland Ice Sheet outlet glaciers, and iceberg drift tracks on the shelf, suggests that iceberg rafting and scouring may be important over a significant proportion of the 500 000 km² area above the shelf break. The relatively extensive modern occurrence of massive diamicton, formed by iceberg rafting and scouring, together with suspension settling of fines, suggests that it may also be a significant facies in the glacier-influenced geological record. The recognition in the geological record of the massive diamicton facies described above may also indicate the former presence of fast flowing ice sheet outlet glaciers.     

Amphibole Ar/Ar Geochronology from the Okcheon Metamorphic Belt, South Korea and its Tectonic Implications

An understanding of the Okcheon Metamorphic Belt (OMB) in South Korea is central to unraveling the tectono-metamorphic evolution of East Asia. Amphibole-bearing rocks in the OMB occur as calcsilicate layers and lenses in psammitic rocks, in the psammitic rocks themselves, and in the mafic volcanic layers and intrusives. Most amphiboles fail to show ⁴⁰Ar/³⁹Ar plateau ages; those that do have ages ranging from 132 to 975 Ma. The disturbed age pattern and wide variation in ⁴⁰Ar/³⁹Ar ages can be related to metamorphic grade, retrograde chemical reactions, excess Ar and amphibole composition. The oldest age (975 Ma) can be interpreted either as an old igneous or metamorphic age predating sedimentation or a false age caused by excess Ar. The youngest age of 132 Ma and the disturbed age pattern found in amphiboles from rocks located close to Jurassic granitoids are the result of retrograde thermal metamorphic effects accompanying intrusion of the granitoids. Some medium- or coarse-grained amphiboles in the calcsilicates are aggregates of fine-grained crystals. As a result, they are heterogeneous and prove to be readily affected by excess Ar. A disturbed age pattern in amphiboles from the calcsilicates occurring in the high-grade metamorphic zone may also be the product of excess Ar. On the other hand, the disturbed pattern of amphiboles present in the calcsilicates from the low-grade metamorphic zone could arise from both excess Ar and mixed ages. However, amphiboles from psammitic rocks and some calcsilicates in the high-grade metamorphic zone and in intrusive metabasites display real plateau ages of 237 to 261 Ma. The temperature conditions in the high-grade metamorphic zone were higher than the argon closing temperature for amphibole, and the amphiboles in this zone give plateau ages only when they are homogeneous in composition, lack excess Ar, and have not been thermally affected by intrusion of the granitoids. The unmodified ⁴⁰Ar/³⁹Ar ages prove rather younger than the age of the Late Paleozoic metamorphic event of 280 to 300 Ma, but they are close to muscovite K-Ar ages of 263 to 277 Ma. These ⁴⁰Ar/³⁹Ar amphibole ages are interpreted as the time of cooling that followed the main regional, intermediate-P/T metamorphic climax. The results demonstrate that interpretation of ⁴⁰Ar/³⁹Ar amphibole ages in an area subjected to several metamorphic events can be accomplished only by undertaking a thorough tectono-metamorphic study, accompanied by detailed chemical analysis of the amphiboles.     

Development of high precision Rb-Sr phlogopite and biotite geochronology; an alternative to Ar/Ar tri-octahedral mica dating

Potassium-Ar and Rb-Sr dating of minerals was fundamental in early efforts to date magmatic and metamorphic processes and paved the way for geochronology to become an important discipline within the earth sciences. Although K-Ar and, in particular, ⁴⁰Ar/³⁹Ar dating of micas is still widely applied, Rb-Sr dating of micas has declined in use, even though numerous studies demonstrated that tri-octahedral mica yields geologically realistic, and more reliable and reproducible Rb-Sr ages than the K-Ar or ⁴⁰Ar/³⁹Ar system. Moreover, a reduction of uncertainties typically reported for Rb-Sr ages (ca. 1%) can now be achieved by application of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) rubidium isotope dilution measurements (<0.3%). Replicate Rb-Sr biotite ages from the Oslo rift, Norway, yield an external reproducibility of ±0.3% (n=4) and an analytical error of ±0.8 Ma for individual ages that vary between 276.9 and 275.5 Ma. Conventional thermal ionisation mass spectrometry (TIMS) Rb analysis on the same mineral separates yields ages between 276.1 and 271.7 Ma, three times the spread compared to Rb MC-ICPMS data. Biotite and phlogopite from the central Nagssugtoqidian orogen, West Greenland, yield ⁴⁰Ar/³⁹Ar plateau ages (ca. 1700 Ma) with a spread of ±150 Ma, while Rb-Sr ages on either biotite or phlogopite separates have a much narrower range of ±10 Ma. This comparison of Rb-Sr and ⁴⁰Ar/³⁹Ar ages demonstrates the robustness of the Rb-Sr system in tri-octahedral micas and cautions against the sole use of ⁴⁰Ar/³⁹Ar tri-octahedral mica ages to date geological events. Analytical errors of 16 Ma for these Rb-Sr mica ages determined by TIMS are reduced to <±5 Ma when the Rb concentration is determined by MC-ICPMS. All the TIMS and MC-ICPMS data from the Nagssugtoqidian orogen agree within assigned analytical uncertainties. However, high precision Rb-Sr dating by MC-ICPMS can resolve geological information obscured by TIMS age determinations. TIMS data for seven phlogopite samples form an isochron age of 1645±6 Ma, and thus, no differentiation in age between the different samples can be made. In contrast, MC-ICPMS Rb measurements on the same samples reveal two distinct populations with ages of 1633±3 or 1652±5 Ma.Combining the mica Rb-Sr geochronological data with the well-constrained thermal history of this ancient orogen, we estimate the closure temperature of the Rb-Sr system in 1-2 mm slowly cooled phlogopite crystals, occurring in a matrix of calcite and plagioclase to be ∼435 °C, and at least 50 °C above that of biotite.     

Greenland ice sheet history since the last glaciation

The position of the Inland Ice margin during the late Wisconsin-Würm glaciation (ca. 15,000 yr BP) is probably marked by offshore banks (submarine moraines?) in the Davis Strait. The history of the Inland Ice since the late Wisconsin-Würm can be divided into four principal phases: (1) Relatively slow retreat from the offshore banks occurred at an average rate of approximately 1 km/100 yr until ca. 10,000 yr BP (Younger Dryas?) when the Taserqat moraine system was formed by a readvance. (2) At ca. 9500 yr BP, the rate of retreat increased markedly to about 3 km/100 yr, and although nearly 100 km of retreat occurred by ca. 6500 yr BP, it was punctuated by frequent regional reexpansions of the Inland Ice that formed extensive moraine systems at ca. 8800-8700 yr BP (Avatdleq-Sarfartôq moraines), 8400-8100 yr BP (Angujârtorfik-Fjord moraines), 7300 yr BP (Umîvît moraines), and 7200-6500 yr BP (Keglen-Mt, Keglen moraines). (3) Between 6500 and 700 yr BP, discontinous ice-margin deposits and ice-disintegration features were formed during retreat, which may have continued until the ice margin was near or behind its present position by ca. 6000 yr BP. Most of the discontinuous ice-margin deposits occur within 5–10 km of the present ice margin, and may have been formed by two main phases of readvance at ca. 4800-4000 yr BP and 2500-2000 yr BP. (4) Since a readvance at ca. 700 yr BP, the Inland Ice margin has undergone several minor retreats and readvances resulting in deposition of numerous closely spaced moraines within about 3 km of the present ice margin. The young moraines are diffieulto to correlate regionally, but several individual moraines have the following approximate ages: A.D. 1650, 1750, and 1880–1920.Inland Ice fluctuations in West Greenland were very closely paralleled by Holocene glacial events in East Greenland and the eastern Canadian Aretic. Such similarity of glacier behavior over a large area strongly suggests that widespread climatic change was the direct cause of Holocene glacial fluctuations. Moreover, historical advances of the Inland Ice margin followed slight temperature decreases by no more than a few decades, and ¹⁸O data from Greenland ice cores show that slight temperature decreases occurred frequently throughout the Holocene. Therefore, we conclude that construction of the major Holocene moraine systems in West Greenland was caused by slight temperature decreases, which decreased rates of ablation and thereby produced practically immediate advances of the ice sheet margin, but did not necessarily affect the long-term equilibrium of the ice sheet.