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1.
1仪器及工作条件Contr AA 300连续光源火焰原子吸收光谱仪(FAAS,德国耶拿分析仪器股份公司),配有SFS 6分段流动注射和AS 52 s自动进样器,用于直接测定井水中的Ca、Fe、K、Mg和Na。仪器工作条件见表1;元素测量条件见表2。表1仪器工作条件元素测λ量/n波m长火类型焰(燃流L/气量h)助燃燃气气/比燃(宽m烧m度头)燃θ角/烧(度°头)燃(高m烧度m头)Ca 239.8559 Air/C2H260 0.130 50 0 7Fe 248.3270 Air/C2H265 0.135 50 0 8K 404.4140 Air/C2H260 0.130 50 0 8Mg 202  相似文献   

2.
1仪器及工作条件Contr AA 300连续光源火焰原子吸收光谱仪(FAAS,德国耶拿分析仪器股份公司),配有SFS 6分段流动注射和AS 52 s自动进样器,用于直接测定井水中的Ca、Fe、K、Mg和Na。仪器工作条件见表1;元素测量条件见表2。表1仪器工作条件元素测λ量/n波m长火类型焰(燃流L/气量h)助燃燃气气/比燃(宽m烧m度头)燃θ角/烧(度°头)燃(高m烧度m头)Ca 239.8559 Air/C2H260 0.130 50 0 7Fe 248.3270 Air/C2H265 0.135 50 0 8K 404.4140 Air/C2H260 0.130 50 0 8Mg 202  相似文献   

3.
本文以金为例,通过正交实验给出了1100B型原子吸收仪测定金、银、铜、铅、锌的最佳仪器工作条件及影响仪器测定的主要因素。  相似文献   

4.
刘虹  许珉  张玥  蒋新平 《矿物岩石》2000,20(1):97-100
本文研究了在50%氢卤酸介质中,用醋酸丁酯萃取富集,火焰原子吸收分光光度法于波长287.4nm,灯电流7.5mA等最佳 条件下测定岩石矿物中的镓。该法灵敏度为1.35ug.ml^-1/1%,变异系数(RSD)为2.31%,间便、快速、适用性强。  相似文献   

5.
导数-原子捕集联用火焰原子吸收法测定粉煤灰中镉   总被引:1,自引:0,他引:1  
研究并提出了将测定信号变化率的导数技术和浓缩待测原子的原子捕集技术与火焰原子吸收相联用于测定痕量镉的新技术。通过测定标准粉煤灰GBW08401和82201中痕量镉含量验证了该技术的可行性。与常规法相比,新方法的灵敏度和检出限可分别改善2~3个数量级和1~2个数量级(1~3分钟捕集条件下)。10次测定的相对偏差为6.26%~7.23%,回收率可达95%~104%。研究表明.此技术可成功地测定粉煤灰中的痕量镉。  相似文献   

6.
提出了超声波提取-火焰原子吸收光谱法测定灰岩中Fe(Ⅱ)的方法,通过对总铁含量进行测定,采用差减法计算Fe(Ⅲ)的含量,从而实现了灰岩中铁的价态分析。探讨了Al2(SO4)3溶液选择性提取岩石样品中微量Fe(Ⅱ)的化学条件及其他仪器参数。结果表明,20~30℃下,0.025 mol/L Al2(SO4)3在土液比1∶300、提取时间1 h条件下可有效提取碳酸盐相中Fe(Ⅱ)离子。该方法用于国家一级标准物质中Fe(Ⅱ)和Fe(Ⅲ)的测定,测定结果与推荐值吻合。运用本法对实际地质样品中的总铁和Fe(Ⅱ)进行分析测定,加标回收率分别为96.07%~103.23%,95.79%~102.11%。  相似文献   

7.
试验了巯基棉吸附Ag的条件,拟定了在1mol/L HNO3介质中,巯基棉富集,2mol/LHCl洗脱,火焰原子吸收光谱法测定铁矿,铜精矿,硫精矿及混合精矿中的Ag的方法。  相似文献   

8.
煤中常量和微量元素是评价煤炭质量的重要指标之一.为了确定一种可操作性强的火焰原子吸收测定煤中常量及微量元素的方法,研究了硝酸-高氯酸湿法消解煤样,火焰法测定煤样中K、Na、Ca、Mg、Zn、Cu、Fe的最佳条件.实验证明,取样量0.01~0.05 g,140℃湿法消解煤样,火焰原子吸收测定煤样中K、Na、Ca、Mg、Zn、Cu、Fe七种元素的含量准确性高,重复性好,方法简便;适合实验室分析测试,消耗少用时短,操作性强,可供相关测试单位参考.  相似文献   

9.
赵文斌 《地下水》2013,(3):95-96
运用空气-乙炔原子吸收分光光度计对水中痕量铁进行测定。探析铁的空白、自来水水样、国家标准物质的测定对实验进行质量控制及铁的最佳测定条件及呈良好线性范围的浓度,该方法具有很好的灵敏度、重现性及较快的分析速度,同时干扰也易消除。  相似文献   

10.
原子吸收法测定大洋沉积物中多种金属元素   总被引:2,自引:0,他引:2  
应用火焰原子吸收法对大洋沉积物中的Fe、Mn、Cu、Co、Ni、Pb、Zn、Ca、Mg、K、Na、Cr和Rb13个元素进行直接测定,对测试工作条件、介质、酸度和共存元素干扰等方面进行了综合考察。各元素测定的RSD(n=10)≤12%,经标准物质分析验证,结果与标准值相符,应用此法为待定值大洋沉积物标样GSMS_2和GSMS_3提供了定值数据,结果与初定值相符  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
18.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

19.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

20.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

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