Far-ultraviolet extinction and diffuse interstellar bands

We relate the equivalent widths of the major diffuse interstellar bands (DIBs) near 5797 and 5780 Å with different colour excesses, normalized by E ( B − V ) , which characterize the growth of interstellar extinction in different wavelength ranges. It is demonstrated that the two DIBs correlate best with different parts of the extinction curve, and the ratio of these diffuse bands is best correlated with the far-ultraviolet (UV) rise. A number of peculiar lines of sight are also found, indicating that the carriers of some DIBs and the far-UV extinction can be separated in certain environments, e.g. towards the Per OB2 association.     

Correlation patterns between 11 diffuse interstellar bands and ultraviolet extinction

We relate the equivalent widths of 11 diffuse interstellar bands, measured in the spectra of 49 stars, to different colour excesses in the ultraviolet. We find that most of the observed bands correlate positively with the extinction in the neighbourhood of the 2175-Å  bump. Correlation with colour excesses in other parts of the extinction curve is more variable from one diffuse interstellar band to another; we find that some diffuse bands (5797, 5850 and 6376 Å) correlate positively with the overall slope of the extinction curve, while others (5780 and 6284 Å) exhibit negative correlation. We discuss the implications of these results on the links between the diffuse interstellar band carriers and the properties of the interstellar grains.     

Limited diversity of the interstellar extinction law

We have applied the method of investigating extinction curves using statistically meaningful samples that was proposed by us 25 years ago. The extensive data sets of the ANS (Astronomical Netherlands Satellite) and 2MASS (Two Micron All Sky Survey) were used, together with UBV photometry to create average extinction curves for samples of OB stars. Our results demonstrate that in the vast majority of cases the extinction curves are very close to the mean galactic extinction curve. Only a few objects were found to be obviously discrepant from the average. The latter phenomenon may be related to nitrogen chemistry in translucent interstellar clouds (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

On the identification of the C60+ interstellar features

The identity of the carriers of the diffuse interstellar bands (DIBs) is one of the most fascinating puzzles of modern spectroscopy. Over the last few years the number of known DIBs has grown substantially. In this paper we discuss the two recently discovered near-infrared weak interstellar features which have already been proposed as fingerprints of the buckminsterfullerene We present and discuss measurements of the two related DIBs within a larger sample of reddened targets, observed with different spectrometers, telescopes and site conditions. We provide additional arguments in favour of the interstellar origin of the two bands. We find evidence around the 9577-Å DIB of far-wing structures, which may affect broad-band measurements. We estimate corrections and errors for telluric and stellar blends, and show that the cores of the two DIBs are well correlated with a ratio near unity within 20 per cent. Finally, we discuss their relation to the laboratory spectra of and the search for two expected weaker transitions.     

Probing the surfaces of interstellar dust grains: the adsorption of CO at bare grain surfaces

A solid-state feature was detected at around 2175 cm⁻¹ towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm⁻¹ (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm⁻¹ (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10⁻¹⁹ cm  molecule⁻¹. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H₂O ice, which is, at most, half of the abundance (relative to H₂O ice) of CO residing in H₂O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.     

The diffuse interstellar bands: a dipolebound state hypothesis

It is proposed that some, possibly many, of the unidentified diffuse interstellar absorption bands arise from rovibronic transitions between the ground states of negatively charged molecules and/or small grains, and shallow dipolebound electronic states which lie close to the electron detachment threshold. Under this hypothesis the attributes for the neutral 'molecular' frameworks are electron affinities between 1 and 3 eV and permanent electric dipole moments of 2 debye or greater. Boundbound spectra involving the lowest rotational levels have not been detected in the laboratory, but these proposed carriers appear to be capable of satisfying the main observational astronomical constraints: transitions that lie in the range from the near-ultraviolet to the near-infrared; a wide range of widths; band wavelengths that are invariant; and a large number of related but distinct carriers. The wavelengths of the lowest rotational lines of the band of the transition between the ground and a dipolebound electronic state of the CH₂CN molecule appear to be consistent with a diffuse band near 8037 Å.     

Rotational contours of CH2X chain species compared with several diffuse interstellar bands

We have calculated synthetic spectra of perpendicular and parallel rovibronic bands of cumulene carbene molecules of the form C _n H₂. The perpendicular bands are consistent with a regularly spaced group of diffuse interstellar bands (DIBs) near 6850 Å. Parallel bands calculated for these molecular structures are consistent with the intrinsic profile of the associated 6614-Å DIB. Both types of bands are expected for an electronic transition that these species should have at those energies. We could not determine if the molecule was charged or if an atom other than carbon terminated the chain-end. Constraints due to molecular geometry and temperature place the chain length at 7–15 carbons to fit the 6850-Å group and 9–13 carbons to fit the 6614-Å DIB.     

Desorption from interstellar ices

The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms: desorption resulting from H₂ formation on grains, direct cosmic ray heating and cosmic ray-induced photodesorption. Whilst qualitative differences exist between these processes (essentially deriving from the assumptions concerning the species selectivity of the desorption and the assumed threshold adsorption energies, E _t), all the three processes are found to be potentially very significant in dark cloud conditions. It is therefore important that all three mechanisms should be considered in studies of molecular clouds in which freeze-out and desorption are believed to be important.
Employing a chemical model of a typical static molecular core and using likely estimates for the quantum yields of the three processes, we find that desorption by H₂ formation probably dominates over the other two mechanisms. However, the physics of the desorption processes and the nature of the dust grains and ice mantles are very poorly constrained. We therefore conclude that the best approach is to set empirical constraints on the desorption, based on observed molecular depletions – rather than try to establish the desorption efficiencies from purely theoretical considerations. Applying this method to one such object (L16 89B) yields upper limits to the desorption efficiencies that are consistent with our understanding of these mechanisms.     

Optical emission at 5800 Å in the Red Rectangle and the 5797-Å diffuse interstellar band

An analysis of the intensity and spatial distribution of the discrete 5800-Å emission band in the spectrum of the Red Rectangle has been used to constrain the abundance and physical properties of the carrier of this emission. An origin in a large (>30 C atom) molecule is indicated. This molecule is formed in situ in the Red Rectangle, but is also a component of the diffuse interstellar medium. The UV photodissociation probability for this molecule is ≲10⁻⁵ per absorbed photon, and the luminescence efficiency is in the range 10⁻²–10⁻³. This molecule may be a product of the dissociation of carbonaceous dust.     

Porous interstellar grains

Recent observations of stellar composition suggest that elements in the Sun are significantly more abundant than in other stars. The reduction in the available element budget implies a drastic revision in current models of interstellar dust. Theoretical models are therefore exploring fluffy, porous physical structure for the grain material. Since a detailed exact treatment of extinction cross-sections is mandatory for a correct understanding of the nature of interstellar dust, we present a technique based on the multipole expansions of the electromagnetic field, which has proven to be general, flexible and powerful in treating scattering of light by porous, composite, arbitrarily shaped particles. The results of this study speak in favour of core–mantle structures characterized by the presence of porosities.     

The role of the geometry and dust environment in stationary models of translucent interstellar clouds

A full radiative transfer model is presented for the ultraviolet (UV) radiation impinging on an interstellar cloud of spherical or finite plane-parallel slab geometry containing gas and dust. The penetration of the UV photons is coupled to detailed chemical processes. Photodestruction rates of atomic and molecular species are calculated from the corresponding cross-sections. We show that CO line intensities are quite sensitive to geometrical effects and to the extinction curve in the far-UV.     

Comparison of 13CO line and far-infrared continuum emission as a diagnostic of dust and molecular gas physical conditions – II. The simulations: testing the method

The reliability of modelling the far-infrared continuum to  ¹³CO  J = 1 → 0  spectral line ratios applied to the Orion clouds (see previous paper in the series) on the scales of several parsecs (i.e. ∼7 pc) is tested by applying the models to simulated data. The two-component models are found to give the dust–gas temperature difference,  Δ T   , to within 1 or 2 K. However, other parameters like the column density per velocity interval and the gas density can be wrong by an order of magnitude or more. In particular, the density can be systematically underestimated by an order of magnitude or more. The overall mass of the clouds is estimated correctly to within a few per cent.
These results may permit us to reliably constrain estimates of the Orion clouds' physical parameters, based on the real observations of the far-infrared continuum and  ¹³CO  J = 1 → 0  spectral line. Nevertheless, other systematics must be treated first. These include the effects of background/foreground subtraction, effects of the H  i component of the interstellar medium, and others. These will be discussed in a future paper.     

On the band-to-continuum intensity ratio in the infrared spectra of interstellar carbonaceous dust

Published interpretations of the relative intensity variations of the unidentified infrared bands (UIBs) and their underlying continuum are discussed. An alternative model is proposed, in which a single carrier for both emits (a) mostly a continuum when it is electronically excited by photons (visible or UV), or (b) exclusively the UIBs, when only chemical energy is deposited by H capture on its surface, inducing only nuclear vibrations. The bands will dominate in atomic H regions but will be overcome by thermal continuum radiation when the ambient field is strong but lacks dissociating photons (900–1100 Å). The model applies to photodissociation regions as well as to limbs of molecular clouds in the interstellar medium and agrees quantitatively with recent satellite observations. It gives indications on atomic H density and UIB intensity provided the ambient radiation field is known. It invokes no chemical, electronic, structural or size change to interpret the observed intensity variations.     

The chemistry of transient microstructure in the diffuse interstellar medium

Transient microstructure in the diffuse interstellar medium (ISM) has been observed towards Galactic and extragalactic sources for decades, usually in lines of atoms and ions, and, more recently, in molecular lines. Evidently, there is a molecular component to the transient microstructure. In this paper, we explore the chemistry that may arise in such microstructure. We use a photodissociation region (PDR) code to model the conditions of relatively high density, low temperature, very low visual extinction and very short elapsed time that are appropriate for these objects. We find that there is a well-defined region of parameter space where detectable abundances of molecular species might be found. The best matching models are those where the interstellar microstructure is young (<100 yr), small (∼100 au) and dense  (>10⁴ cm⁻³)  .     

Very high resolution profiles of four diffuse interstellar bands

Ultra-high-resolution  ( R ∼ 300 000)  profiles of four diffuse interstellar bands (DIBs) are presented. The λλ 5797-, 5850-, 6196- and 6379- Å DIBs were observed towards the reddened supergiant HD 24398, a line of sight free of Doppler splitting; thus the observed profiles can be considered as intrinsic to the DIB carriers. Three of the profiles show substructure which supports the hypothesis of a molecular origin for these DIBs.