Groundwater and surface water connectivity within the recharge area of Guarani aquifer system during El Niño 2014–2016

Recharge areas of the Guarani Aquifer System (GAS) are particularly sensitive and vulnerable to climate variability; therefore, the understanding of infiltration mechanisms for aquifer recharge and surface run‐off generation represent a relevant issue for water resources management in the southeastern portion of the Brazilian territory, particularly in the Jacaré‐Pepira River watershed. The main purpose of this study is to understand the interactions between precipitation, surface water, and groundwater using stable isotopes during the strong 2014–2016 El Niño Southern Oscillation event. The large variation in the isotopic composition of precipitation (from ?9.26‰ to +0.02‰ for δ¹⁸O and from ?63.3‰ to +17.6‰ for δ²H), mainly associated with regional climatic features, was not reflected in the isotopic composition of surface water (from ?7.84‰ to ?5.83‰ for δ¹⁸O and from ?49.7‰ to +33.6‰ for δ²H), mainly due to the monthly sampling frequency, and groundwater (from ?7.04‰ to ?7.76‰ for δ¹⁸O and from ?49.5‰ to ?44.7‰ for δ²H), which exhibited less variation throughout the year. However, variations in deuterium excess (d‐excess) in groundwater and surface water suggest the occurrence of strong secondary evaporation during the infiltration process, corresponding with groundwater level recovery. Similar isotopic composition in groundwater and surface water, as well as the same temporal variations in d‐excess and line‐conditioned excess denote the strong connectivity between these two reservoirs during baseflow recession periods. Isotopic mass balance modelling and hydrograph separation estimate that the groundwater contribution varied between 70% and 80%, however, during peak flows, the isotopic mass balance tends to overestimate the groundwater contribution when compared with the other hydrograph separation methods. Our findings indicate that the application of isotopic mass balance methods for ungauged rivers draining large groundwater reservoirs, such as the GAS outcrop, could provide a powerful tool for hydrological studies in the future, helping in the identification of flow contributions to river discharge draining these areas.     

Active, capable, and potentially active faults — a paleoseismic perspective

Maps of faults (geologically defined source zones) may portray seismic hazards in a wide range of completeness depending on which types of faults are shown. Three fault terms — active, capable, and potential — are used in a variety of ways for different reasons or applications. Nevertheless, to be useful for seismic-hazards analysis, fault maps should encompass a time interval that includes several earthquake cycles. For example, if the common recurrence in an area is 20,000–50,000 years, then maps should include faults that are 50,000–100,000 years old (two to five typical earthquake cycles), thus allowing for temporal variability in slip rate and recurrence intervals. Conversely, in more active areas such as plate boundaries, maps showing faults that are <10,000 years old should include those with at least 2 to as many as 20 paleoearthquakes. For the International Lithosphere Programs’ Task Group II-2 Project on Major Active Faults of the World our maps and database will show five age categories and four slip rate categories that allow one to select differing time spans and activity rates for seismic-hazard analysis depending on tectonic regime. The maps are accompanied by a database that describes evidence for Quaternary faulting, geomorphic expression, and paleoseismic parameters (slip rate, recurrence interval and time of most recent surface faulting). These maps and databases provide an inventory of faults that would be defined as active, capable, and potentially active for seismic-hazard assessments.     

Methods of groundwater recharge estimation in eastern Mediterranean—a water balance model application in Greece,Cyprus and Jordan

Groundwater recharge studies in semi‐arid areas are fundamental because groundwater is often the only water resource of importance. This paper describes the water balance method of groundwater recharge estimation in three different hydro‐climatic environments in eastern Mediterranean, in northwest Greece (Aliakmonas basin/Koromilia basin), in Cyprus (Kouris basin and Larnaka area) and in Jordan (northern part of Jordan). For the Aliakmonas basin, groundwater recharge was calculated for different sub‐catchments. For the Upper Aliakmonas basin (Koromilia basin), a watershed‐distributed model was developed and recharge maps were generated on a daily basis. The mean annual recharge varied between 50 and 75 mm/year (mean annual rainfall 800 mm/year). In Cyprus, the mean groundwater recharge estimates yielded 70 mm/year in the Kouris basin. In the Larnaka area, groundwater recharge ranged from 30 mm/year (lowland) to 200 mm/year (mountains). In Jordan, the results indicated recharge rates ranging from 80 mm/year for very permeable karstified surfaces in the upper part of the Salt basin, where rainfall reaches 500 mm/year to less than 10 mm/year and to only about 1 mm/year in the southernmost part of the basin. For the north part of Jordan, a watershed‐distributed model was developed and recharge maps were generated. This water balance model was used for groundwater recharge estimations in many regions with different climatic conditions and has provided reliable results. It has turned out to be an important tool for the management of the limited natural water resources, which require a detailed understanding of regional hydro(geo)logical processes. Copyright © 2007 John Wiley & Sons, Ltd.     

Estimating parameters of groundwater recharge model in frequency domain: Karst springs Jadro and Žrnovnica

The spectral method is based on the assumption of exponential forms of autocorrelation functions of the input and output time series. The results of practical applications of the spectral method on several karst springs in Croatia show that this assumption cannot always be reliably applied to the time series of rainfall and spring discharge, especially if short time periods are analysed. For this reason, the method is modified. The scale factor between the transfer function of total rainfall and the transfer function of groundwater recharge is considered as an additional model parameter which is determined in the optimization procedure. In addition to the theoretical background, this paper also presents the results of application of the modified spectral method on the springs Jadro and ?rnovnica located in the Dinaric karst area in Croatia. The parameters of groundwater recharge model are determined separately for both the springs and the obtained values are discussed and compared with the results of previous investigations. The values of the scale factors determined in the optimization procedure are compared to the values calculated using the theoretical equation. The comparison shows that the theoretical equation underestimates the optimal values of the scale factor. The underestimations are especially evident for periods of one year. Finally, the characteristics of rainfall–runoff relations of two springs are compared using the identified transfer functions and the results of simulations of the periodogram of observed discharge by the parametric periodogram. Copyright © 2008 John Wiley & Sons, Ltd.     

Toxicity of Interactions of Zinc —Nickel,Copper —Nickel and Zinc —Nickel —Copper to a Freshwater Teleost,Lebistes reticulatus (PETERS)1

The lethal toxicity of mixtures of Zn²⁺ —Ni²⁺, Cu²⁺ —Ni²⁺ and Zn²⁺ —Cu²⁺ —Ni²⁺ to common guppy at 21£C in hard water (total hardness = 260 mg/l as CaCO₃) was studied under static bioassays test conditions with renewal of the test solutions every 24 h. The heavy metals were tested separately and in mixtures. The 48 h median lethal concentrations (LC₅₀) for individual salts were 75 mg/l Zn²⁺, 37 mg/l for Ni²⁺ and 2.5 mg/l for Cu²⁺. Concentrations were expressed in “toxic units” by taking them as proportions of LC₅₀ values. Experiments showed that in the Zn²⁺-Ni²⁺ mixture, when Ni²⁺ was more in proportion, the toxicity was more than additive. The 48 h LC₅₀ value and 95% confidence limits in the Ni²⁺-Cu²⁺ mixture were 0.684 (0.484 … 0.807) toxic units and the mixture produced more than the additive toxicity (synergism.). The LC₅₀ value and its 95% confidence limits in a Zn²⁺?Cu²⁺?Ni²⁺ mixture also suggested that the mixture was again strictly additive. The results indicate that heavy metallic mixtures would pose a greater toxicological danger to fish than the respective individual metals.     

Glacial to Holocene terrigenous organic matter input to sediments from Orca Basin, Gulf of Mexico — A combined optical and biomarker approach

In this study we assessed changes in the contribution of terrigenous organic matter (OM) to the Gulf of Mexico over the course of the last deglaciation (the last 25 kyr). To this end, we combined optical kerogen analyses with bulk sedimentary, biomarker, and compound-specific carbon isotope analyses. Samples were obtained from core MD02-2550 from Orca Basin (2249 m water depth at 26°56.77N, 91°20.74W) with temporal resolution ranging from multi-decadal to millennial-scale, depending on the proxy. All proxies confirmed larger terrigenous input during glacial times compared to the Holocene. In addition, the kerogen analyses suggest that much of the glacial OM is reworked (at least 50% of spores and pollen grains and 40% of dinoflagellate cysts). The Holocene sediments, in contrast, contain mainly marine OM, which is exceptionally well preserved. During the deglaciation, terrigenous input was generally high due to large meltwater fluxes, whereby discrepancies between different proxies call for additional influences, such as the change in distance to the river mouth, local productivity changes, and hydrodynamic particle sorting. It is possible that kerogen particles and the terrigenous biomarkers studied here represent distinct pools of land-derived OM with inputs varying independently.     

Ozone depletion and UV-B radiation in the Antarctic—Limitations to ecological assessment

Ozone depletion has been detected in the upper atmosphere over the Antarctic since the late 1970s. This depletion results in increased fluences of incident ultraviolet-B radiation in Antarctic environments. There is considerable information available about the chemical and physical characteristics of this atmospheric phenomenon, but the ecological impact of this annual pollution cycle has not been determined. Only a few studies on the UV-photobiology of Antarctic organisms have been initiated, and neither the extent of ecosystem modification nor the time scale for ecosystem response are known.     

Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.     

Deconstructing geomorphology: an appreciation of the contributions of Barbara A. Kennedy (1943–2014)

Barbara Kennedy has left only a small body of work, consisting principally of eight research papers, nine commentaries and two books. Its extent belies its importance. Read systematically, the work represents a sustained and important critique of the direction taken by mainstream geomorphology since the process‐focused reorientation of the mid‐twentieth century. Copyright © 2014 John Wiley & Sons, Ltd.     

Significance of stemflow in groundwater recharge. 2: A cylindrical infiltration model for evaluating the stemflow contribution to groundwater recharge

A primary model for evaluating the effect of stemflow on groundwater recharge has been developed. The model, a cylindrical infiltration model (CI model), is based on the infiltration area of stemflow-induced water instead of canopy projected area for determining the stemflow inputs to the soil surface. The estimated ratio of recharge rate by stemflow to the total recharge rate determined with this model agrees closely with values obtained from the mass balance of chloride in subsurface waters. This primary model is considered to be useful for estimating the effect of stemflow on groundwater recharge.     

On the behaviour of the induction arrows over a buried conductive plate — a numerical model study

Two-dimensional numerical model calculations, employing a finite difference technique, are used to study the behaviour of the induction arrows, for a range of periods, for a conductive plate of (i) semi-infinite and (ii) finite width in uniform and layered resistive hosts. The results for the conductive plate at the surface of the host have application to a uniform-depth ocean, while the results for the plate buried at some depth in the resistive host have application to a conductive sill in a resistive Earth. The numerical results indicate that for a profile over the plate-host vertical interface the in-phase arrows for all periods and locations point towards the conductive plate, while the quadrature arrows at periods near the characteristic period of the model are oppositely directed on either side of the interface so as to point towards each other and towards the interface for nearby locations, both over the conductive plate and the resistive host. Further, the quadrature arrow undergoes a second reversal over the resistive host at a distance from the interface that is somewhat dependent on the period. Thus, at either side of the location of this second reversal, the quadrature induction arrows are again oppositely directed, but pointing away from each other, with the arrows near the interface pointing towards, and the more distant arrows pointing away from the conductive plate. The period range for the quadrature-arrow reversal is characteristic of conductivities and layer depths. The features of the quadrature-arrow sign reversals at and near the interface are in accordance with the earlier laboratory analogue model results of Hebert et al. for the Newfoundland coastal region and Nienaber et al. for a conductive plate in a resistive host.

It is suggested that in practice the sign reversal of the quadrature arrow may aid in locating a conductor-host interface, and that if the conductivity of the host is known, the maximum in the anomalous vertical magnetic field response may permit an approximate determination of the conductive-layer depth.     

An improved numerical implementation of Calder's stochastic model of rainfall interception — a note

Two stratagems are described that are necessary to ensure the successful implementation of Calder's stochastic model of rainfall interception for high-intensity rain storms in which condensation occurs over prolonged periods.     

Subduction-related episodes of K-alkaline magmatism (15–0.1 Ma) and geodynamic implications in the north Tyrrhenian — central Italy region: a review

In the north Tyrrhenian region and adjoining shores of Alpine Corsica and central Italy, four magmatic phases (15–14; 8–6; 5–2; and 1.3–0.1 Ma) are present which consist prevailingly of either old acidic and lamproitic rocks or young (1.3–0.1 Ma) basic volcanics with potassic–ultrapotassic affinity (the rocks of the K and HK series of the Roman province, and the kamafugitic rocks). Composition, age and location of the igneous phases reveal a geochemical polarity oriented from west to east. The episodes of magmatic activity reflect the evolution of the geodynamic environment (ensialic plate convergence): backarc stretching and attenuation of an Alpine orogenic wedge were accompanied by the eastward roll-back and progressive steepening of the descending Adria plate. The latter process led to enhanced metasomatic modifications of the mantle wedge composition and to eruption of the large volumes of KS and HKS volcanic rocks in central Italy (0.6–0.1 Ma).