Manganese and iron in hydrothermal plumes resulting from the 1996 Gorda Ridge Event

We sampled hydrothermal plumes over the N. Gorda Ridge four times between March and August 1996 to document Mn and Fe discharge resulting from a magmatic intrusion/seafloor eruption. Two separate event plumes, EP96A and B, and chronic hydrothermal emissions lasting 6 months were characterized. Shipboard time-series measurements of an event plume sample were used to calibrate an Fe phase clock useful for estimating sample age up to 6 days after fluid discharge. Samples collected from EP96A and B had Mn/heat (<0.15 nmol J^-1) and Fe/Mn (>2 mol mol^-1) ratios similar to historical event plume observations. We suggest these “signature” ratio values are generally characteristic of event plumes and hypothesize that Mn and Fe may be supplied to event plumes by different processes: Mn by entrainment of fluids from an extant shallow subseafloor reservoir, and Fe by short-lived, high-temperature water-rock reaction coincident with dike emplacement. Calculations based on the Fe phase clock indicate that the two event plumes were released more than a month apart. The largest event plume, EP96A (2.3×10⁶ M Mn and 13×10⁶ M Fe), formed 7 March soon after seismic activity began. The smaller EP96B (0.49×10⁶ M Mn and 3.5×10⁶ M Fe) was not discharged until 11 April, 3 weeks after the cessation of seismic activity detectable by SOSUS T-phase monitoring. We hypothesize that the subseafloor disturbance that triggered EP96B also resulted in the episodic flushing of a reservoir of chronic-plume-like fluids. Total event plume inventories of Mn and Fe at N. Gorda Ridge are much smaller than those associated with the 1986 event at N. Cleft segment of the Juan de Fuca Ridge, but comparable to event plume inventories at N. Cleft segment in 1987 and CoAxial segment in 1993. Mn/heat values for chronic plumes over the eruption site underlying EP96A evolved from moderate (0.25 oonmol J^-1, reflecting probable admixture with event plume formation fluids) to high (0.7 nmol J^-1, typical of chronic plumes) to low (0.1 nmol J^-1, similar to diffuse vent fluid values), marking a complete episode of intrusion/eruption-induced hydrothermal discharge.     

The 1996 Gorda Ridge eruption: geologic mapping, sidescan sonar, and SeaBeam comparison results

As part of a response effort following the February 1996 T-wave swarm on the North Gorda Ridge, camera tows were conducted at the site in April and discovered that a lava flow had erupted onto the seafloor during the earthquake swarm. The lava flow is located on axis between 42.665° and 42.688°N, just south of the axial high of the ridge segment, near the northern extent of T-wave epicenters, and under the site where a hydrothermal event plume was found 2 weeks after the swarm began. Temperature sensors on the camera sled recorded anomalies up to 0.5°C over and near the new flow, showing that it was still actively cooling. Data from camera tows, remotely operated vehicle (ROV) dives, sidescan sonar imagery, and SeaBeam resurveys show that the new flow is 2.6 km long, 400 m wide, and up to 75 m thick, with a volume of 18×10⁶ m³. We interpret that this flow was erupted during the first half of the T-wave swarm. A combination of T-wave, plume, sidescan, and SeaBeam evidence also suggests that another lava flow (not imaged by camera or ROV) may have erupted 8 km to the south between 42.605° and 42.615°N, where the second half of the T-wave swarm was concentrated. However, this possible second eruption site remains unconfirmed.     

Deep-circulation flow at mid-latitude in the western North Pacific

Direct current measurements with five moorings at 27–35°N, 165°E from 1991 to 1993 and with one mooring at 27°N, 167°E from 1989 to 1991 revealed temporal variations of deep flow at mid-latitude in the western North Pacific. The deep-circulation flow carrying the Lower Circumpolar Deep Water from the Southern Ocean passed 33°N, 165°E northwestward with a high mean velocity of 7.8 cm s⁻¹ near the bottom and was stable enough to continue for 4–6 months between interruptions of 1- or 2-months duration. The deep-circulation flow expanded or shifted intermittently to the mooring at 31°N, 165°E but did not reach 35°N, 165°E although it shifted northward. The deep-circulation flow was not detected at the other four moorings, whereas meso-scale eddy variations were prominent at all the moorings, particularly at 35°N and 29°N, 165°E. The characteristics of current velocity and dissolved oxygen distributions led us to conclude that the deep-circulation flow takes a cyclonic pathway after passing through Wake Island Passage, passing 24°N, 169.5–173°E and 30°N, 168–169°E northward, proceeds northwestward around 33°N, 165°E, and goes westward through the south of the Shatsky Rise. We did not find that the deep-circulation flow proceeded westward along the northern side of the Mid-Pacific Seamounts and eastward between the Hess Rise and the Hawaiian Ridge toward the Northeast Pacific Basin.     

Chemical variations of hydrothermal particles in the 1996 Gorda Ridge Event and chronic plumes

In response to the 1996 magmatic intrusion on the Gorda Ridge near 42.68°N, 126.78°W in late February, we conducted three cruises to the region in March, April, and June. On all three cruises particulate samples were collected, along with CTD/nephelometer data and total dissolved Fe and Mn samples. During each cruise, we collected samples from large oblate spheroid-shaped event plumes. These event plumes had long axis diameters of about 10–15 km and ranged in depth from about 1800 to 2700 m. A strong linear correlation between nephelometer voltage and particulate Fe allowed us to estimate the total amount of particulate Fe in the event plumes at approximately 20×10⁶ moles of Fe, or 28% of the Fe in the 1986 megaplume on the Cleft Segment of the Juan de Fuca Ridge. We observed significant decreases in particulate Cu and Zn concentrations (>100% decrease in Cu/Fe and Zn/Fe ratios) between the Gorda Ridge event plumes. These results suggest that each of the two event plumes originated from a chemically distinct source fluid. Fe ferrihydrite particles maintained a constant ratio of coprecipitated oxyanion species in the two event plumes. Based upon the chemical inventories for particulate Fe, P, and V, we suggest that event plumes might play a small role in the geochemical budgets for these elements.     

Water masses and currents of deep circulation southwest of the Shatsky Rise in the western North Pacific

We conducted full-depth hydrographic observations in the southwestern region of the Northwest Pacific Basin in September 2004 and November 2005. Deep-circulation currents crossed the observation line between the East Mariana Ridge and the Shatsky Rise, carrying Lower Circumpolar Deep Water westward in the lower deep layer (θ<1.2 °C) and Upper Circumpolar Deep Water (UCDW) and North Pacific Deep Water (NPDW) eastward in the upper deep layer (1.3–2.2 °C). In the lower deep layer at depths greater than approximately 3500 m, the eastern branch current of the deep circulation was located south of the Shatsky Rise at 30°24′–30°59′N with volume transport of 3.9 Sv (1 Sv=10⁶ m³ s⁻¹) in 2004 and at 30°06′–31°15′N with 1.6 Sv in 2005. The western branch current of the deep circulation was located north of the Ogasawara Plateau at 26°27′–27°03′N with almost 2.1 Sv in 2004 and at 26°27′–26°45′N with 2.7 Sv in 2005. Integrating past and present results, volume transport southwest of the Shatsky Rise is concluded to be a little less than 4 Sv for the eastern branch current and a little more than 2 Sv for the western branch current. In the upper deep layer at depths of approximately 2000–3500 m, UCDW and NPDW, characterized by high and low dissolved oxygen, respectively, were carried eastward at the observation line by the return flow of the deep circulation composing meridional overturning circulation. UCDW was confined between the East Mariana Ridge and the Ogasawara Plateau (22°03′–25°33′N) in 2004, whereas it extended to 26°45′N north of the Ogasawara Plateau in 2005. NPDW existed over the foot and slope of the Shatsky Rise from 29°48′N in 2004 and 30°06′N in 2005 to at least 32°30′N at the top of the Shatsky Rise. Volume transport of UCDW was estimated to be 4.6 Sv in 2004, whereas that of NPDW was 1.4 Sv in 2004 and 2.6 Sv in 2005, although the values for NPDW may be slightly underestimated, because they do not include the component north of the top of the Shatsky Rise. Volume transport of UCDW and NPDW southwest of the Shatsky Rise is concluded to be approximately 5 and 3 Sv, respectively. The pathways of UCDW and NPDW are new findings and suggest a correction for the past view of the deep circulation in the Pacific Ocean.     

Changes in the Structure of a Coastal Fish Assemblage Exploited by a Small Scale Gillnet Fishery During an El Niño–La Niña Event

During 1998 an experimental gillnet fishing survey was carried out in a Mexican Central Pacific inshore zone. One-hundred and thirty fish species belonging to 51 families and 18 orders were identified. The most abundant species wereMicrolepidotus brevipinnis (29·0% of the total abundance) and Caranx caninus (19·2%), followed by C. caballus (6·3%), Kyphosus analogus (4·3%) and C. sexfasciatus (3·4%). Thermal SST anomalies showed the existence of two periods. The first, from January to April with positive anomalies, defines the end of an El Niño episode. The second period, from May to December, constitutes the beginning of the La Niña episode. The typical seasonality in a non-anomalous year continued for a large percentage of the inshore fish community, and the effects of the anomalous event consisted of changes in seasonality of occurrence in some individual species and the unusual abundance of some uncommon species. The species richness was higher during the El Niño–La Niña event than in a non-anomalous year, and therefore the event could be considered an interannual environmental mechanism that favours fish diversity in inshore waters.     

Patterns of event and chronic hydrothermal venting following a magmatic intrusion: new perspectives from the 1996 Gorda Ridge eruption

The remote detection of a seismic swarm on the northern Gorda Ridge on 28 February 1996 prompted a three-cruise response effort to investigate event and chronic hydrothermal discharge associated with a dike intrusion. The GR1 cruise reached the northern Gorda only 10 days after seismicity began and discovered a 15 km-diameter event plume, EP96A, centered between depths 1800 and 2800 m above the shallowest portion of the axial valley axis (3100 m). One month later, GR2 returned and found only a weak, near-bottom chronic plume at the EP96A site. A few kilometers to the south, however, GR2 mapped a distinctly different chronic plume (2500–2900 m depth) as well as the edge of a second event plume, EP96B (1800–2400-m depth), above the western wall of the axial valley. EP96B was seeded with a neutrally buoyant float, which traveled 10 net km to the northwest before surfacing on 10 June at the start of GR3. Mapping around the float location fully revealed EP96B, a 10 km diameter plume with a heat content 25% that of EP96A. Extensive observations within the axial valley determined that chronic venting was effectively exhausted within three months. Models seeking to explain the perturbation of hydrothermal venting by a dike intrusion and eruption must satisfy several criteria generalized from this and previous events: (1) venting begins (or increases) with the intrusion/eruption and declines exponentially afterwards; (2) the time scale of the post-intrusion decline varies within and among sites; (3) the discharge of multiple event plumes is common; (4) an existing high-temperature vent field may not be necessary or even conducive to event plume formation; and (5) the ratio of total chronic to event discharge varies among intrusion events.     

Reconstruction of sea surface dimethylsulfide in the North Pacific during 1970s to 2000s

We proposed an empirical equation of sea surface dimethylsulfide (DMS, nM) using sea surface temperature (SST, K), sea surface nitrate (SSN, μM) and latitude (L, °N) to reconstruct the sea surface flux of DMS over the North Pacific between 25°N and 55°N: ln DMS = 0.06346 · SST − 0.1210 · SSN − 14.11 · cos(L) − 6.278 (R² = 0.63, p < 0.0001). Applying our algorithm to climatological hydrographic data in the North Pacific, we reconstructed the climatological distributions of DMS and its flux between 25 °N and 55 °N. DMS generally increased eastward and northward, and DMS in the northeastern region became to 2–5 times as large as that in the southwestern region. DMS in the later half of the year was 2–4 times as large as that in the first half of the year. Moreover, applying our algorithm to hydrographic time series datasets in the western North Pacific from 1971 to 2000, we found that DMS in the last three decades has shown linear increasing trends of 0.03 ± 0.01 nM year^− 1 in the subpolar region, and 0.01 ± 0.001 nM year^− 1 in the subtropical region, indicating that the annual flux of DMS from sea to air has increased by 1.9–4.8 μmol m^− 2 year^− 1. The linear increase was consistent with the annual rate of increase of 1% of the climatological averaged flux in the western North Pacific in the last three decades.     

Trace metals in the Western Pacific: temporal and spatial variability in the concentrations of Cd, Cu, Mn and Ni

Profiles of total dissolvable Cd, Cu, Mn and Ni are reported for samples collected from the southwest Pacific in 1989, from the western equatorial Pacific along 155°E at 5°S, 0° and 5°N in 1990 and 1993, and along the equator from 143°E to 152°E and in the Bismarck Sea in 1997 and 2000. Profiles of Cd along 155°E in 1990 and along the equator were essentially the same but, in 1993, Cd values at 5°N were higher by a factor of about 1.5–2 than at 5°S over the depth range 500–1500 m. Similar, but less pronounced, differences were observed for PO₄ and Ni. Cd and Ni were both strongly correlated with PO₄, and an even stronger correlation was found between Ni and Cd. The concentration of Ni did not fall below ≈2 nmolkg⁻¹, even in the nitrate-depleted waters of the western equatorial Pacific, where primary production is strongly dependent on recycled nitrogen (mainly ammonia and urea). It is proposed that this residual Ni is not bioavailable and that Ni could be biolimiting, since the metabolism of urea requires the nickel-containing enzyme urease. The impact of the Sepik River on Cd, Cu and Ni concentrations was small but elevated concentrations of Mn were observed near the Sepik River and close to the coast suggesting that the rivers and sediments on the north coast of New Guinea are a significant local source of Mn to the Bismarck Sea. Simple mass balance calculations show that the elevated levels of Mn observed in the Equatorial Undercurrent cannot be due to input from the rivers of New Guinea and they were attributed to the trapping of particulate matter due to strong current shear. A strong hydrothermal source of Mn was observed in the central Bismarck Sea.     

Geochronology and geochemistry of lavas from the 1996 North Gorda Ridge eruption

Radiometric dating of three North Gorda Ridge lavas by the ²¹⁰Po–²¹⁰Pb method confirms that an eruption occurred during a period of increased seismic activity along the ridge during late February/early March 1996. These lavas were collected following detection of enhanced T-phase seismicity and subsequent ocean bottom photographs documented the existence of a large pillow mound of fresh-appearing lavas. ²¹⁰Po–²¹⁰Pb dating of these lavas indicates that an eruption coinciding with this seismicity did occur (within analytical error) and that followup efforts to sample the recent lava flows were successful. Compositions of the three confirmed young lavas and eleven other samples of this contiguous “new flow” sequence are distinct from older lavas from this area but are variable at a level outside analytical uncertainty. These intraflow variations can not easily be related to a single, common parent magma. Compositional variability within the new flow is compared to that of other recently documented individual flow sequences, and this comparison reveals a strong positive correlation of compositional variance with flow volumes spanning a range of >2 orders of magnitude. The geochemical heterogeneity in the North Gorda new flow probably reflects incomplete mixing of magmas generated from a heterogeneous mantle source or from slightly different melting conditions of a single source. The compositional variability, range in sample ages (up to 6 weeks) and range in active seismicity (4 weeks) imply that this relatively large flow was erupted over an interval of several weeks.     

Spreading-rate dependence of hydroacoustic and teleseismic seismicity of ridge-transform systems: East Pacific Rise,Galapagos Ridge,and Mid-Atlantic Ridge

Seismicity in ocean ridge-transform systems reveals fundamental processes of mid-ocean ridges, while comparisons of seismicity in different oceans remain rare due to a lack of detection of small events. From 1996 to2003, the Pacific Marine Environmental Laboratory of the National Oceanic and Atmospheric Administration(NOAA/PMEL) deployed several hydrophones in the eastern Pacific Ocean and the northern Atlantic Ocean.These hydrophones recorded earthquakes with small magnitudes, providing us with...     

The Namib Col Current

Recent measurements indicate the transatlantic extent of the Namib Col Current at depths of 1300–3000 m near Lat. 22°S in the South Atlantic Ocean. This current forms a continuous circulation structure from the Namib Col on the Walvis Ridge to the western trough, though its characteristic change as deep water with varying properties enters and leaves the current owing to a meridional flow component. Transport estimates from hydrographic sections on the Walvis Ridge and at 15°W near the crest of the Mid-Atlantic Ridge indicate a strength of about 3 × 10⁶ m³ s⁻¹. The current is part of a larger-scale eastward flow at Lon. 25°W; transport estimates across the salinity maximum core there show a similar strength. Associated with this high-salinity high-oxygen current is a basin-wide front in these properties of varying intensity (weaker in the east) marking the transition to deep water whose North Atlantic characteristics have been partly erased by mixing with Circumpolar Deep Water in the southwest South Atlantic. The water which finally crosses the Walvis Ridge is supplied both by the eastward flow of this (diluted) North Atlantic Deep Water and by a general southeastward interior flow from the northern Angola Basin. Evidence suggests that this deep water continues south in the eastern Cape Basin, leaving the South Atlantic near the African continent.     

Circulation and mixing of Mediterranean water west of the Iberian Peninsula

The spreading of water of Mediterranean origin west of the Iberian Peninsula was studied with hydrographic data from several recent cruises and current measurements from the BORD-EST programme. The vertical breakdown of the “Mediterranean salt” content reveals the dominant contribution of the so-called lower core of the outflow (60%), and the significant fraction (22%) brought downward to levels below 1500 m by diffusion. Intense salinity maxima in the upper core (18%) are only encountered south of 38°N in the vein flowing northward along the continental slope, and at a few stations in the deep ocean. Apart from the coastally trapped vein, other preferred paths of the water mass are revealed by the horizontal distributions of salinity maximum and Mediterranean Water percentage. One is southward, west of the Gorringe Bank, and two northwestward ones lie around 40°N and west of the Galicia Bank. Year-long velocity measurements in the Tagus Basin show westward mean values of 7 × 10⁻² m s⁻¹ at 1000 m associated with a very intense mesoscale variability. This variability is related to the pronounced dynamical signature of the outflow which favours instability in any branch having detached from the slope current. From a mixing point of view, the strong interleaving activity occurring near Cape St-Vincent is illustrated, but its contribution to the downstream salinity decrease in the coastally trapped vein is weak. Current and meddy detachment play the dominant role, with a scaling estimate of their associated lateral diffusivity of order 500 m² s⁻¹. The statistical distribution of the density ratio parameter, which governs double-diffusion at the base of the Mediterranean Water, was found to be very tight around R_π = 1.3 in the temperature range of 5°C< φ < 8°C. North of 40°N, the presence of a fraction of Labrador Sea Water in the underlying water is shown to decrease that parameter and should favour the formation of salt fingers.     

A deep cyclonic gyre in the Australian–Antarctic Basin

The traditional image of ocean circulation between Australia and Antarctica is of a dominant belt of eastward flow, the Antarctic Circumpolar Current, with comparatively weak adjacent westward flows that provide anticyclonic circulation north and cyclonic circulation south of the Antarctic Circumpolar Current. This image mostly follows from geostrophic estimates from hydrography using a bottom level of no motion for the eastward flow regime which typically yield transports near 170 Sv. Net eastward transport of about 145 Sv for this region results from subtracting those westward flows. This estimate is compatible with the canonical 134 Sv through Drake Passage with augmentation from Indonesian Throughflow (around 10 Sv).A new image is developed from World Ocean Circulation Hydrographic Program sections I8S and I9S. These provide two quasi-meridional crossings of the South Australian Basin and the Australian–Antarctic Basin, with full hydrography and two independent direct-velocity measurements (shipboard and lowered acoustic Doppler current profilers). These velocity measurements indicate that the belt of eastward flow is much stronger, 271 ± 49 Sv, than previously estimated because of the presence of eastward barotropic flow. Substantial recirculations exist adjacent to the Antarctic Circumpolar Current: to the north a 38 ± 30 Sv anticyclonic gyre and to the south a 76 ± 26 Sv cyclonic gyre. The net flow between Australia and Antarctica is estimated as 157 ± 58 Sv, which falls within the expected net transport of 145 Sv.The 38 Sv anticyclonic gyre in the South Australian Basin involves the westward Flinders Current along southern Australia and a substantial 33 Sv Subantarctic Zone recirculation to its south. The cyclonic gyre in the Australian–Antarctic Basin has a substantial 76 Sv westward flow over the continental slope of Antarctica, and 48 ± 6 Sv northward-flowing western boundary current along the Kerguelen Plateau near 57°S. The cyclonic gyre only partially closes within the Australian–Antarctic Basin. It is estimated that 45 Sv bridges westward to the Weddell Gyre through the southern Princess Elizabeth Trough and returns through the northern Princess Elizabeth Trough and the Fawn Trough – where a substantial eastward 38 Sv current is hypothesized. There is evidence that the cyclonic gyre also projects eastward past the Balleny Islands to the Ross Gyre in the South Pacific.The western boundary current along Kerguelen Plateau collides with the Antarctic Circumpolar Current that enters the Australian–Antarctic Basin through the Kerguelen–St. Paul Island Passage, forming an energetic Crozet–Kerguelen Confluence. Strongest filaments in the meandering Crozet-Kerguelen Confluence reach 100 Sv. Dense water in the western boundary current intrudes beneath the densest water of the Antarctic Circumpolar Current; they intensely mix diapycnally to produce a high potential vorticity signal that extends eastward along the southern flank of the Southeast Indian Ridge. Dense water penetrates through the Ridge into the South Australian Basin. Two escape pathways are indicated, the Australian–Antarctic Discordance Zone near 125°E and the Geelvinck Fracture Zone near 85°E. Ultimately, the bottom water delivered to the South Australian Basin passes north to the Perth Basin west of Australia and east to the Tasman Basin.     

The influence of dissolved petroleum hydrocarbon residues on natural phytoplankton biomass

The effect of dissolved petroleum hydrocarbons in the environment on phytoplankton biomass measured as chlorophyll a was studied near the oil tanker route in the southern Bay of Bengal. In the transect from 5° N, 77° E to 5° N, 87° E the concentrations of dissolved petroleum hydrocarbons were negatively correlated with phytoplankton biomass, whereas in the 0° N, 87° E to 1° N, 79° E transect they were positively correlated with phytoplankton biomass. The mean petroleum hydrocarbon concentrations in the two transects were 12·12 ± 4·67 μg litre⁻¹ and 11·23 ± 4·5 μg litre⁻¹, respectively.It is surmised that the effect of dissolved petroleum hydrocarbons on phytoplankton biomass varies depending on the nature rather than the quantity of petroleum hydrocarbons present. Culture studies with unialgal Nitzschia sp. in seawater collected from selected stations in the study area as well as in artificial seawater spiked with the water-soluble petroleum hydrocarbon fraction of light Arabian Crude support this.     

Thermal evolution of the western Svalbard margin

The northern Norwegian-Greenland Sea opened up as the Knipovich Ridge propagated from the south into the ancient continental Spitsbergen Shear Zone. Heat flow data suggest that magma was first intruded at a latitude of 75° N around 60 m.y.b.p. By 40–50 m.y.b.p. oceanic crust was forming at a latitude of 78° N. At 12 m.y.b.p. the Hovgård Transform Fault was deactivated during a northwards propagation of the Knipovich Ridge. Spreading is now in its nascent stages along the Molloy Ridge within the trough of the Spitsbergen Fracture Zone. Spreading rates are slower in the north than the south. For the Knipovich Ridge at 78° N they range from 1.5–2.3 mm yr^-1 on the eastern flank to 1.9–3.1 mm yr^-1 on the western flank. At a latitude of 75° N spreading rates increase to 4.3–4.9 mm yr^-1.Thermal profiles reveal regions of off-axial high heat flow. They are located at ages of 14 m.y. west and 13 m.y. east of the northern Knipovich Ridge, and at 36 m.y. on the eastern flank of the southern Knipovich Ridge. These may correspond to episodes of increased magmatic activity; which may be related to times of rapid north-wards rise axis propagation.The fact that the Norwegian-Greenland Sea is almost void of magnetic anomalies may be caused by the chaotic extrusion of basalts from a spreading center trapped within the confines of an ancient continental shear zone. The oblique impact of the propagating rift with the ancient shear zone may have created an unstable state of stress in the region. If so, extension took place preferentially to the northwest, while compression occurred to the southeast between the opening, leaking shear zone and the Svalbard margin. This caused faster spreading rates to the northwest than to the southeast.     

Bacterial and viral abundances in hydrothermal event plumes over northern Gorda Ridge

This study presents first-time observations of bacterial and viral abundances in hydrothermal event plumes. Two water-column event plumes were formed in conjunction with seismic events and seafloor volcanic eruptions on the northern Gorda Ridge in February–March 1996. Epifluorescence counts of bacteria and viruses were performed on water samples from 3 successive cruises staged in the 10–90 days that followed the onset of seismicity. Relative to background seawater at these 1800–3200 m depths, bacterial abundance was enhanced by 2–3 fold within both event plumes. In contrast, viral numbers were below background seawater values in the younger and more intense of the two event plumes (EP96A), and enhanced in the other (EP96B). Changes in viral abundance may be a secondary response to that of plume bacteria as well as being influenced by particle formation and precipitation within the plumes. Lower bacteria/heat, virus/heat and virus/bacteria ratios in EP96A versus EP96B confirm distinct differences in the microbial response to event plume formation, possibly related to observed differences in plume chemistry.     

North Pacific Tropical Water: its climatology and temporal changes associated with the climate regime shift in the 1970s

North Pacific Tropical Water (NPTW) is characterized as a subsurface salinity maximum flowing in the North Equatorial Current and is the main source of salt for the North Pacific. We briefly describe the climatological features of its formation and circulation, and then examine temporal changes in its properties associated with the climate regime shift in the 1970s. We use a variety of data, which include the repeat hydrographic sections along 130°E, 137°E, 144°E and 155°E meridians, the hydrographic data from the Hawaii Ocean Time-series, the World Ocean Atlas 1994, and available gridded data of wind stress and evaporation. The classical idea that NPTW originates from the zone of the highest sea surface salinity at 20°–30°N centered around the international date line and spreads along the isopycnal geostrophic flow patterns is confirmed. Further, it is shown that the meridional extent of NPTW along 137°E is from 10°N to 23°N on average and the highest salinity core lies at about 15°N and 24.0σ_θ, and that the portion of NPTW north (south) of about 15°N originates from the formation region west (east) of the date line. NPTW in the 137°E section changed remarkably associated with the mid-1970s regime shift. North of 15°N NPTW increased both in its salinity and thickness while to the south of 15°N only its salinity increased and its thickness remained unchanged. The westward geostrophic velocity is increased significantly in both the southern and northern parts of NPTW. The northern thickening and speedup and the southern speedup increased NPTW transport across 137°E. The changes in the thermohaline forcing such as evaporation and Ekman salt convergence in the NPTW formation region possibly contributed to the increases in salinity in the southern part of NPTW, but not to that of the northern part. On the other hand, the increased Ekman pumping accounts for the increase of the NPTW inventory and transport at 137°E. The increased salinity of NPTW at 137°E, especially its northern portion, was presumably caused by an increase in its formation rate rather than changes in the sea surface salinity in its formation region; the thicker the NPTW layer is, the saltier is the core that tends to survive the mixing processes.     

Reactive mercury in the central North Atlantic Ocean

The level of reactive mercury in pelagic waters near the Mid Atlantic Ridge, south of the Azores, and in the Sargasso Sea, north of Bermuda, was studied. The reactive Hg concentration in both locations was shown to be fairly uniform with depth at a level of 2.5 ± 0.5 pmol l⁻¹. The profiles show no indication of a simple Hg-nutrient relationship. The deep water from the Famous area was also sampled and showed no elevated Hg levels.     

Increase of anthropogenic CO2 in the Pacific Ocean over the last two decades

The multiple-parameter linear regression method (Monitoring global ocean carbon inventories. Ocean Observing System Development Panel, Texas A&M University, College Station, TX, 1995, 54pp; Global Biogeochem. Cycles 13 (1999) 179) is used to compare inorganic carbon data from the GEOSECS CO₂ survey in the Pacific Ocean in 1973 to the WOCE/JGOFS global CO₂ survey in the 1990s. A model of total dissolved inorganic carbon (DIC) as a function of five variables (AOU, θ, S, Si, and PO₄) has been developed from the recent CO₂ survey data (namely CGC91 and CGC96) in the Pacific Ocean. After correcting for a systematic DIC offset of −30.3±7 μmol kg⁻¹ from the GEOSECS data, the residual DIC based on this model as computed from GEOSECS data has been used to estimate the anthropogenic CO₂ penetration in the Pacific Ocean. In the Northeast Pacific, we obtained an increase of CO₂ of 21.3±7.9 mol m⁻² over the period from GEOSECS in 1973 to CGC91 in 1991. This gives a mean anthropogenic CO₂ uptake rate of 1.3±0.5 mol m⁻² yr⁻¹ over this 17 year time period. In the South Pacific, north of 50°S between 180° and 120°W region, the integrated anthropogenic CO₂ inventory is estimated to be 19.7±5.7 mol m⁻² over the period from GEOSECS in 1974 to CGC96 in 1996. The equivalent mean CO₂ uptake rate is estimated to be 0.9±0.3 mol m⁻² yr⁻¹ over the 22 years. These results are compared with the isopycnal method (Nature 396 (1998) 560) to estimate the anthropogenic CO₂ signal in the Northeast Pacific (30°N, 152°W) at the crossover region between CGC91 and GEOSECS. The results of the isopycnal method are consistent with those derived from the MLR method. Both methods show an increase in anthropogenic CO₂ inventory in the ocean over two decades that is consistent with the increase expected if the ocean uptake has kept pace with the atmospheric CO₂ increase.