Baseline models of trace elements in major aquifers of the United States

Trace-element concentrations in baseline samples from a survey of aquifers used as potable-water supplies in the United States are summarized using methods appropriate for data with multiple detection limits. The resulting statistical distribution models are used to develop summary statistics and estimate probabilities of exceeding water-quality standards.The models are based on data from the major aquifer studies of the USGS National Water Quality Assessment (NAWQA) Program. These data were produced with a nationally-consistent sampling and analytical framework specifically designed to determine the quality of the most important potable groundwater resources during the years 1991–2001.The analytical data for all elements surveyed contain values that were below several detection limits. Such datasets are referred to as multiply-censored data. To address this issue, a robust semi-parametric statistical method called regression on order statistics (ROS) is employed.Utilizing the 90th–95th percentile as an arbitrary range for the upper limits of expected baseline concentrations, the models show that baseline concentrations of dissolved Ba and Zn are below 500 μg/L. For the same percentile range, dissolved As, Cu and Mo concentrations are below 10 μg/L, and dissolved Ag, Be, Cd, Co, Cr, Ni, Pb, Sb and Se are below 1–5 μg/L.These models are also used to determine the probabilities that potable ground waters exceed drinking water standards. For dissolved Ba, Cr, Cu, Pb, Ni, Mo and Se, the likelihood of exceeding the US Environmental Protection Agency standards at the well-head is less than 1–1.5%. A notable exception is As, which has approximately a 7% chance of exceeding the maximum contaminant level (10 μg/L) at the well head.     

Composition of marsh gases in the central and eastern United States

Summer samples of marsh gases in Minnesota (fresh-water), Louisiana, and Delaware (fresh-water and brackish-water) yielded 50–85% methane, 3–52% “excess nitrogen”, 4–15% carbon dioxide, and small amounts of traces of hydrogen, carbon monoxide, propane, hydrogen sulfide, and C₄–C₇ hydrocarbons. These types of gas flows were found to decrease drastically in winter periods of sampling, and large amounts of “air” accumulate in some marsh and lake sediments. Carbon dioxide decreases in the winter samples, but carbon monoxide and hydrogen sulfide showed relative increases. Ethane is present in several, and butane in one, sample from Minnesota in the fall. There is a drop in “excess nitrogen” (non-air N₂) in the winter as compared to summer samples.Specimens of marsh plants were placed in culture flasks with mud from each collecting locality and allowed to culture for several months. In composition, the cultured gases are predominantly methane, carbon dioxide, and “excess nitrogen”. Hydrogen, ethane, propane, and hydrogen sulfide are minor components. Carbon monoxide was not detected, in contrast to marsh gases. Phragmites from industrially polluted Delaware Bay evolved many additional hydrocarbons in culture, pH and Eh were monitored for Typha in culture; pH remained near 7 and Eh near − 100 mV after stabilization.Carbohydrate analyses of marsh plants indicate xylans exceed cellulose as a major source of methane in these samples; mannose, galactose, and arabinose are also important potential contributors.Delta carbon-13 values of methane from marsh gases sampled are more negative than those from laboratory-cultured source plants, whereas delta deuterium values from methane from marsh gases are less negative than those of cultured source plants.     

Recharge and salination processes in the carbonate aquifers in Israel

Limestone and dolostone aquifers play a major role in the water supply system of Israel. In many cases, there are brackish to saline springs at their outlets. The source of the saline water and the mechanism of salinization differ from place to place. In some cases, it is due to mixing with seawater (Mediterranean or Dead Sea) at the fresh-saline water interface, while in other cases deepseated brines emerge along regional faults. The general policy for reclaiming the fresh component of the water before mixing with the saline component is to try to catch the fresh water as far as possible upstream from the outlet. In most cases, this is the area where the mixing takes place. The main case histories in Israel are discussed in this paper.     

A comparison of recharge rates in aquifers of the United States based on groundwater-age data

An overview is presented of existing groundwater-age data and their implications for assessing rates and timescales of recharge in selected unconfined aquifer systems of the United States. Apparent age distributions in aquifers determined from chlorofluorocarbon, sulfur hexafluoride, tritium/helium-3, and radiocarbon measurements from 565 wells in 45 networks were used to calculate groundwater recharge rates. Timescales of recharge were defined by 1,873 distributed tritium measurements and 102 radiocarbon measurements from 27 well networks. Recharge rates ranged from?<?10 to 1,200?mm/yr in selected aquifers on the basis of measured vertical age distributions and assuming exponential age gradients. On a regional basis, recharge rates based on tracers of young groundwater exhibited a significant inverse correlation with mean annual air temperature and a significant positive correlation with mean annual precipitation. Comparison of recharge derived from groundwater ages with recharge derived from stream base-flow evaluation showed similar overall patterns but substantial local differences. Results from this compilation demonstrate that age-based recharge estimates can provide useful insights into spatial and temporal variability in recharge at a national scale and factors controlling that variability. Local age-based recharge estimates provide empirical data and process information that are needed for testing and improving more spatially complete model-based methods.     

Relations between climatic variability and hydrologic time series from four alluvial basins across the southwestern United States

Hydrologic time series of groundwater levels, streamflow, precipitation, and tree-ring indices from four alluvial basins in the southwestern United States were spectrally analyzed, and then frequency components were reconstructed to isolate variability due to climatic variations on four time scales. Reconstructed components (RCs), from each time series, were compared to climatic indices like the Pacific Decadal Oscillation (PDO), North American Monsoon (NAM), and El Niño-Southern Oscillation (ENSO), to reveal that as much as 80% of RC variation can be correlated with climate variations on corresponding time scales. In most cases, the hydrologic RCs lag behind the climate indices by 1–36 months. In all four basins, PDO-like components were the largest contributors to cyclic hydrologic variability. Generally, California time series have more variation associated with PDO and ENSO than the Arizona series, and Arizona basins have more variation associated with NAM. ENSO cycles were present in all four basins but were the largest relative contributors in southeastern Arizona. Groundwater levels show a wide range of climate responses that can be correlated from well to well in the various basins, with climate responses found in unconfined and confined aquifers from pumping centers to mountain fronts.     

Effect of the dilution process on the attenuation of contaminants in aquifers

This paper discusses the effects of the dilution process on levels of aquifer contamination attenuation, developing analytical equations for application in theoretical and practical cases. The key finding is that, in aquifers, the dilution process causes a reduction of the contaminant concentration. Analytical equations for the assessment of the contaminant attenuation capacity, by means of the dilution process in an aquifer, are put forward. In particular, the attenuation of the contaminant concentration in an aquifer, and thus the dilution, is described by the volumetric flow rate per unit width perpendicular to the flow direction (q _u). Moreover, a classification of q _u was developed, considering six classes of attenuation capacity due to dilution. For the equations validation, nitrate contamination attenuation due to dilution was analysed in two sample areas in Piedmont (North-West Italy). The results confirmed the hypothesis, evidencing high nitrate concentrations in areas with low q _u values, connected to low dilution rate of the contaminant in the groundwater; vice versa, low nitrate concentrations were evidenced in areas with high q _u values, due to a high nitrate dilution rate.     

Analysis of a database for anthropogenic sinkhole triggering and zonation in the Naples hinterland (Southern Italy)

Anthropogenic sinkholes are generally due to the collapse of man-made underground caves and represent a major threat, especially in urban contexts, where they could cause damage to people, buildings and lifelines. The hinterland of Naples (Campania, Southern Italy) is one of the most urbanized areas of Italy and is historically affected by frequent sinkhole phenomena. This study analyzes a database of both man-made caves and sinkholes collected by the authors over several years. The aim is to comprehend the predisposing and triggering factors of sinkholes in order to attempt a zonation of occurrence. The predisposing factor resulted to be the presence of a preexisting network of caves within the Campanian Ignimbrite tuff and their geometric features. Generally, the shallower the depth of the chamber roof and the lower the thickness of the vault, the higher is the frequency of sinkholes. Furthermore, an intrinsic fragility is represented by the access shafts of vertical wells, usually filled in and abandoned. Meanwhile, the main triggering mechanism identified consists in saturation of the subsoil, due to water leaks coming from buried sewage and water pipelines. The macrozonation of sinkhole occurrence shows that the highest class is achieved where the tuff is shallow and both man-made caves and historical sinkholes are present.

     

Modelling the response of an alluvial aquifer to anthropogenic and recharge stresses in the United States Southern Great Plains

This paper uses Visual MODFLOW to simulate potential impacts of anthropogenic pumping and recharge variability on an alluvial aquifer in semi-arid northwestern Oklahoma. Groundwater withdrawal from the aquifer is projected to increase by more than 50% (relative to 1990) by the year 2050. In contrast, climate projections indicate declining regional precipitation over the next several decades, creating a potential problem of demand and supply. The following scenarios were simulated: (1) projected groundwater withdrawal, (2) a severe drought, (3) a prolonged wet period, and (4) a human adjustment scenario, which assumes future improvements in water conservation measures. Results indicate that the combined impacts of anthropogenic pumping and droughts would create drawdown of greater than 12 m in the aquifer. Spatially, however, areas of severe drawdown will be localized around large-capacity well clusters. The worst impacts of both pumping and droughts will be on stream–aquifer interaction. For example, the projected aquifer pumpage would lead to a total streamflow loss of 40%, creating losing stream system regionally. Similarly, a severe drought would lead to a total streamflow loss of >80%. A post-audit of the model was also carried out to evaluate model performance. By simulating various stress scenarios on the alluvial aquifer, this study provides important information for evaluating management options for alluvial aquifers.     

Environmental impacts of groundwater overdraft: selected case studies in the southwestern United States

The southwestern United States—this papers study region—is home to large urban centers and features a thriving agro-industrial economic sector. This region is also one of the driest in North America, with highly variable seasonal and inter-annual precipitation regimes and frequent droughts. The combination of a large demand for usable water and semi-arid climate has led to groundwater overdraft in many important aquifers of the region. Groundwater overdraft develops when long-term groundwater extraction exceeds aquifer recharge, producing declining trends in aquifer storage and hydraulic head. In conjunction with overdraft, declines in surface-water levels and streamflow, reduction or elimination of vegetation, land subsidence, and seawater intrusion are well documented in many aquifers of the southwestern United States. This work reviews case studies of groundwater overdraft in this region, focusing on its causes, consequences, and remedial methods applied to counter it.     

Genesis of carbonate in pyrope from ultramafic diatremes on the Colorado Plateau,southwestern United States

Mineral associations and compositions of carbonates within pyrope crystals are clues to the genesis of mantle carbonate and to the character of metasomatic melts in depleted peridotite. The pyrope crystals are in ultramafic diatremes of the Navajo field on the Colorado Plateau. Although inclusions of olivine and pyroxene are typically monomineralic, 4 of 6 inclusions of carbonates and hydrates are polymineralic. Polymineralic assemblages include: pargasite-magnesite-dolomite-apatite-spinel; pargasite-dolomite-Ba phlogopite (with 10% BaO); olivine-dolomite-spinel; edenite-chlorite; and olivine-ilmenite-spinel. Magnesite and chlorite are present also as monomineralic inclusions. The two inclusions with pargasite plus carbonate are in the same garnet; the association of carbonates plus hydrates and the enrichment in Ba are evidence that the included minerals originated from melt trapped in pyrope. The pargasite and mica are F-poor and contain about 0.4 and 1.1 wt% Cl, respectively, more than any other analyzed mantle amphibole or mica. If the parent melts of such inclusions are similar to those responsible for trace-element metasomatism of continental lithosphere, then these melts have higher Cl/F ratios than those inferred from typical xenolith minerals. Amphibole-garnet and olivine-spinel equilibration temperatures are in the range 500–700° C, so the garnets cooled to low temperatures within the mantle following inclusion of melt. All the hydrates and carbonates may have formed from trapped melt, but evidence is strong only for the complex pargasite-carbonate-mica inclusions. Two garnets containing chlorite are more Cr-rich and Fe-poor than most other inclusion-bearing pyropes, and the chlorite may have been included during prograde metamorphism of subducted lithosphere.     

Metasomatic transformations of carbonate rocks observable in quarries of Riverside, California, United States

The results of skarn-forming processes at contacts of the multiphase Southern California Batholith with carbonate rocks accessible to study in quarries in Riverside, California, involve prograde metasomatic transformations of marmorized dolomites and calcareous rocks in contact with granitic melts and contaminated magmas. The processes of contact assimilation are proved to have been controlled by the emplacement of granitic melts overheated relative to subliquidus melts (with the overheated melts prone to approach the composition of granodiorite, syenite, and gabbro) into skarnified marbles. The degree of magma overheating was evaluated based on G.F. Smith’s data on linear melting temperature variations for anhydrous intrusive rocks with various SiO₂ concentrations (<750°C for granites and >1100°C for contaminated rocks, ΔT 350°). This corresponds to the thermal regime of the development of mineralogically contrasting hypabyssal skarn aureoles: magnesian at contacts with granite magmas and calcic at contacts with melts of high basicity. The peripheral parts of the aureoles ubiquitously contain preserved zones of forsterite calciphyres and periclase marbles, whereas skarns at mafic intrusions consist of high-temperature silicates of decreasing Mg contents: monticellite, merwinite, melilite, and spurrite. Prograde and retrograde mineralforming processes in the metasomatic rocks and their facies affiliation are analyzed, and the chemical composition of the minerals are examined. The Riverside skarn aureoles are compared with other compositionally contrasting skarn aureoles that developed in contacts with granite magmas and melts of increasing basisity.     

Windstorms in the United States

High winds are one of the nation’s leading damage-producing storm conditions. They do not include winds from tornadoes, winter storms, nor hurricanes, but are strong winds generated by deep low pressure centers, by thunderstorms, or by air flow over mountain ranges. The annual average property and crop losses in the United States from windstorms are $379 million and windstorms during 1959–1997 caused an average of 11 deaths each year. Windstorms range in size from a few hundred to hundreds of thousands square kilometers, being largest in the western United States where 40% of all storms exceed 135,000 km². In the eastern United States, windstorms occur at a given location, on average, 1.4 times a year, whereas in the western US point averages are 1.9. Midwestern states average between 15 and 20 wind storms annually; states in the east average between 10 and 25 storms per year; and West Coast states average 27–30 storms annually. Storms causing insured property losses >$379 million and windstorms during 1959–1997 caused an average of 11 deaths each year. Windstorms range in size from a few hundred to hundreds of thousands square kilometers, being largest in the western United States where 40% of all storms exceed 135,000 km². In the eastern United States, windstorms occur at a given location, on average, 1.4 times a year, whereas in the western US point averages are 1.9. Midwestern states average between 15 and 20 wind storms annually; states in the east average between 10 and 25 storms per year; and West Coast states average 27–30 storms annually. Storms causing insured property losses >1 million, labeled catastrophes, during 1952–2006 totaled 176, an annual average of 3.2. Catastrophic windstorm losses were highest in the West and Northwest climate regions, the only form of severe weather in the United States with maximum losses on the West Coast. Most western storms occurred in the winter, a result of Pacific lows, and California has had 31 windstorm catastrophes, more than any other state. The national temporal distribution of catastrophic windstorms during 1952–2006 has a flat trend, but their losses display a distinct upward trend with time, peaking during 1996–2006.     

Factors affecting the movement and persistence of nitrate and pesticides in the surficial and upper Floridan aquifers in two agricultural areas in the southeastern United States

Differences in the degree of confinement, redox conditions, and dissolved organic carbon (DOC) are the main factors that control the persistence of nitrate and pesticides in the Upper Floridan aquifer (UFA) and overlying surficial aquifer beneath two agricultural areas in the southeastern US. Groundwater samples were collected multiple times from 66 wells during 1993–2007 in a study area in southwestern Georgia (ACFB) and from 48 wells in 1997–98 and 2007–08 in a study area in South Carolina (SANT) as part of the US Geological Survey National Water-Quality Assessment Program. In the ACFB study area, where karst features are prevalent, elevated nitrate-N concentrations in the oxic unconfined UFA (median 2.5 mg/L) were significantly (p = 0.03) higher than those in the overlying oxic surficial aquifer (median 1.5 mg/L). Concentrations of atrazine and deethylatrazine (DEA; the most frequently detected pesticide and degradate) were higher in more recent groundwater samples from the ACFB study area than in samples collected prior to 2000. Conversely, in the SANT study area, nitrate-N concentrations in the UFA were mostly <0.06 mg/L, resulting from anoxic conditions and elevated DOC concentrations that favored denitrification. Although most parts of the partially confined UFA in the SANT study area were anoxic or had mixed redox conditions, water from 28 % of the sampled wells was oxic and had low DOC concentrations. Based on the groundwater age information, nitrate concentrations reflect historic fertilizer N usage in both the study areas, but with a lag time of about 15–20 years. Simulated responses to future management scenarios of fertilizer N inputs indicated that elevated nitrate-N concentrations would likely persist in oxic parts of the surficial aquifer and UFA for decades even with substantial decreases in fertilizer N inputs over the next 40 years.     

Groundwater recharge in semi-arid carbonate aquifers under intensive use: the Estepa Range aquifers (Seville, southern Spain)

Quantifying groundwater recharge in carbonate aquifers located in semi-arid regions and subjected to intensive groundwater use is no easy task. One reason is that there are very few available methods suitable for application under such climatic conditions, and moreover, some of the methods that might be applied were originally designed with reference to non-carbonate aquifers. In addition, it is necessary to take into account the fact that, in any given aquifer, groundwater recharge is modified by the groundwater exploitation. Here we focus on four methods selected to assess their suitability for estimating groundwater recharge in carbonate aquifers affected by intensive exploitation. The methods were applied to the Estepa Range aquifers of Seville, southern Spain, which are subjected to different degrees of exploitation. Two conventional methods were used: chloride mass balance and daily soil–water balance. These results were compared with the results obtained by means of two non-conventional methods, designed for application to the carbonate aquifers of southern Spain: the APLIS and ERAS methods. The results of the different methods are analogous, comparable to those obtained in nearby non-exploited carbonate aquifers, confirming their suitability for use with carbonate aquifers in either natural or exploited regimes in a semi-arid climate.     

Faunal utilization of created intertidal eastern oyster (Crassostrea virginica) reefs in the southeastern United States

Oyster cultch was added to the lower intertidal marsh-sandflat fringe of three previously createdSpartina alterniflora salt marshes. Colonization of these created reefs by oysters and other select taxa was examined. Created reefs supported numerous oyster reef-associated faunas at equivalent or greater densities than adjacent natural reefs. Eastern oyster (Crassostrea virginica) settlement at one site of created reef exceeded that of the adjacent natural reefs within 9 mo of reef creation. After only 2 yr, harvestable-sizeC. virginica (>75 mm) were present in the created reefs along with substantial numbers ofC. virginica clusters. The created reefs also had a higher number of molluscan, fish, and decapod species than the adjacent natural reefs. After 2 yr the densities ofC. virginica, striped barnacle (Balanus amphitrite), scorched mussel (Brachidontes exustus), Atlantic ribbed mussel (Geukensia demissa), common mud crab (Panopeus herbstii), and flat mud crab (Eurypanopeus depressus) within the created reefs were equivalent to that of adjacent natural reefs. From these data it is evident that created oyster reefs can quickly acquire functional ecological attributes of their natural counterparts. Because the demand for oysters continues to increase in the face of dwindling natural resources, habitat creation techniques need to evolve and these approaches need to consider the ancillary ecological benefits reef creation may provide. Reef function as well as physical and ecological linkages of oyster reefs to other habitats (marsh, submerged aquatic vegetation, and bare bottom) should be considered when reefs are created in order to provide the best use of resources to maintain the integrity of estuarine systems.     

Late Quaternary carbonate sedimentation and paleo-oceanography in the eastern Norwegian Sea

Four gravity cores from the eastern Norwegian Sea are studied. Absolute accumulation rates are quantified and variations in carbonate sedimentation and their implications for the paleo-oceanographic history of the Norwegian Sea are described. In the eastern Norwegian Sea, interglacial, ice-free conditions were developed during oxygen-isotope stages 1 and 5e. Open water conditions were probably the norm during the summer season, also during glacial stages. Slightly elevated summer temperatures in periods during isotope stages 2 and 7 are demonstrated by increased contents of subpolar planktic foraminifera. The deep waters of the eastern Norwegian Sea have been well oxygenated during most of the last 250,000 years. Organic-rich sediments and intensive carbonate dissolution in some parts of isotope stages 4 and 6 indicate corrosive bottom waters. A permanent ice cover and low saline surface waters, as found in the Arctic Ocean today, may have been developed in these periods. Well-preserved foraminiferal assemblages from stage 2 show more oxygenated bottom waters and more effective bottom water renewal in this period than during stage 3.     

Water and poverty in the United States

Contrary to reports of 100% access to safe water and sanitation in international surveys, the United States (US) has a complex landscape of low-income water problems. This paper begins with a critical international perspective on water and poverty in the US. It shows that the US had a declining role in international water programs during the late-20th century, which contributed to limited international awareness of low-income water programs in the US, and limited US awareness of low-income water issues. To address the first problem, we provide an overview of low-income water programs in the US with an emphasis on those that serve small communities. We then examine census data on inadequate water systems in Colorado, which indicate that severe plumbing deficiencies persist despite these public water programs. Inadequate plumbing rates are lower than income poverty rates, however, which indicate partially successful strategies for achieving low-income water services. Analysis of local data in urban, rural, and mountainous areas of the state shows that poverty and water problems are correlated in complex ways, which has implications for all nations striving for universal access to safe water and sanitation.     

The impacts of pasture- and manure-spreading on microbial groundwater quality in carbonate aquifers

Hydrogeological and microbiological research is in progress to analyze the interaction between groundwater and microbial pollutants, produced by pasture and/or manure spreading, in the areas of different carbonate aquifers of southern Italy. Several springs and wells were studied, and the precipitation, the discharge, the groundwater level and the classic microbial indicators of pollution were monitored weekly or daily. The experimental results show that the pasture and the manure spreading produced microbial contamination of the groundwater, even if runoff infiltration in swallow holes does not exist. The time dependence of microbial contamination shows a series of peaks irregularly distributed, related to the precipitation that produce effective infiltration.     

Groundwater origin and flow along selected transects in Ethiopian rift volcanic aquifers

The disruption of lithologies by cross-cutting faults and the variability in volcanic structures make the hydrogeology of the rifted volcanic terrain in Ethiopia very complex. Along two transects, selected due to their hydrogeologic characteristics, groundwater flow, depth of circulation and geochemical evolution have been conceptualized. The groundwater flow continuity between the high rainfall plateau bounding the rift and the rift valley aquifers depends principally on the nature of the bounding faults. Up to 50% of recharge to the rift aquifers comes from the plateau as groundwater inflow where the rift is cross cut by transverse fault zones. Recharge from the mountains is found to be insignificant where the rift is bounded by marginal grabens; channel loss and local precipitation are the principal sources of recharge to the rift aquifers in such cases. At a regional scale, there is a clear zonation in the geochemical compositions of groundwaters, the result of aquifer matrix composition differences. The environmental isotope results show that the majority of the aquifers contain modern groundwaters. In a few localities, particularly in thermal groundwaters representing deeper circulation, palaeo-groundwaters have been identified. Deeper groundwaters in the rift floor have a uniform ¹⁴C age ranging between 2,300 and 3,000 years.