Assessment of regional change in nitrate concentrations in groundwater in the Central Valley, California, USA, 1950s–2000s

A regional assessment of multi-decadal changes in nitrate concentrations was done using historical data and a spatially stratified non-biased approach. Data were stratified into physiographic subregions on the basis of geomorphology and soils data to represent zones of historical recharge and discharge patterns in the basin. Data were also stratified by depth to represent a shallow zone generally representing domestic drinking-water supplies and a deep zone generally representing public drinking-water supplies. These stratifications were designed to characterize the regional extent of groundwater with common redox and age characteristics, two factors expected to influence changes in nitrate concentrations over time. Overall, increasing trends in nitrate concentrations and the proportion of nitrate concentrations above 5 mg/L were observed in the east fans subregion of the Central Valley. Whereas the west fans subregion has elevated nitrate concentrations, temporal trends were not detected, likely due to the heterogeneous nature of the water quality in this area and geologic sources of nitrate, combined with sparse and uneven data coverage. Generally low nitrate concentrations in the basin subregion are consistent with reduced geochemical conditions resulting from low permeability soils and higher organic content, reflecting the distal portions of alluvial fans and historical groundwater discharge areas. Very small increases in the shallow aquifer in the basin subregion may reflect downgradient movement of high nitrate groundwater from adjacent areas or overlying intensive agricultural inputs. Because of the general lack of regionally extensive long-term monitoring networks, the results from this study highlight the importance of placing studies of trends in water quality into regional context. Earlier work concluded that nitrate concentrations were steadily increasing over time in the eastern San Joaquin Valley, but clearly those trends do not apply to other physiographic subregions within the Central Valley, even where land use and climate are similar.     

Geodynamic implications of ophiolitic chromitites in the La Cabaña ultramafic bodies,Central Chile

Chromitites (>80% volume chromite) hosted in two ultramafic bodies (Lavanderos and Centinela Bajo) from the Palaeozoic metamorphic basement of the Chilean Coastal Cordillera were studied in terms of their chromite composition, platinum-group element (PGE) abundances, and Re-Os isotopic systematics. Primary chromite (Cr# = 0.64–0.66; Mg# = 48.71–51.81) is only preserved in some massive chromitites from the Centinela Bajo ultramafic body. This chemical fingerprint is similar to other high-Cr chromitites from ophiolite complexes, suggesting that they crystallized from arc-type melt similar to high-Mg island-arc tholeiites (IAT) and boninites in supra-subduction mantle. The chromitites display enrichment in IPGE (Os, Ir, Ru) over PPGE (Rh, Pt, Pd), with PGE concentrations between 180 and 347 ppb, as is typical of chromitites hosted in the mantle of supra-subduction zone (SSZ) ophiolites. Laurite (RuS₂)-erlichmanite (OsS₂) phases are the most abundant inclusions of platinum-group minerals (PGM) in chromite, indicating crystallization from S-undersaturated melts in the sub-arc mantle. The metamorphism associated with the emplacement of the ultramafic bodies in the La Cabaña has been determined to be ca. 300 Ma, based on K-Ar dating of fuchsite. Initial ¹⁸⁷Os/¹⁸⁸Os ratios for four chromitite samples, calculated for this age, range from 0.1248 to 0.1271. These isotopic compositions are well within the range of chromitites hosted in the mantle section of other Phanaerozoic ophiolites. Collectively, these mineralogical and geochemical features are interpreted in terms of chromite crystallization in dunite channels beneath a spreading centre that opened a marginal basin above a supra-subduction zone. This implies that chromitite-bearing serpentinites in the metamorphic basement of the Coastal Cordillera are of oceanic-mantle origin and not oceanic crust as previously suggested. We suggest that old subcontinental mantle underlying the hypothetical Chilenia micro-continent was unroofed and later altered during the opening of the marginal basin. This defined the compositional and structural framework in which the protoliths of the meta-igneous and meta-sedimentary rocks of the Eastern and Western Series of the Chilean Coastal Cordillera basement were formed.     

Numerical simulation of the effect of heavy groundwater abstraction on groundwater–surface water interaction in Langat Basin, Selangor, Malaysia

The paper aims at evaluating the interaction between ground and surface water along the Langat River in Malaysia through the development of a numerical simulation. Malaysia has been experiencing a rapid economic growth since the last few decades, driven by many factors such as agriculture, industry, and the like. The demand for water in these sectors has increased so tremendously that surface water has been utilized in conjunction to groundwater. Approximately 18,184 m³ of water per day is obtained from the aquifer to supply to the steel factory. There are also workshops, petroleum stations, and houses in the area thus causing the water quantity and quality to degrade. In terms of quantity, the pumping activity has altered the interaction between the groundwater and surface water. Therefore, a numerical model was proposed and two aquifer layers were simulated, with the first layer being approximately >20 m in depth and the second layer >100 m. The recharge estimated from the tank model was input into the groundwater modeling. The effects of the surface water to the aquifer were included in the simulation by defining the river conductance, river bed, and river level. The calibrated model (error about 0.9 m) was achieved and applied to predict the flow pattern in its natural state without the pumping and with the pumping states. As a result, in the first scenario, the stream was in an effluent condition influenced by the groundwater from the northeast to the west. A hyporheic flow occurred and was observed from the contour map. The flow system was changed in the second scenario when the pumping activity was included in the simulation. The groundwater lost its original function but received leakage from the stream near the pumping sites. The findings of this study will help the local authorities and other researchers to understand the aquifer system in the area and assist in the preparation of a sustainable groundwater management.     

Assessment of changes in the area of the water conservation forest in the Qilian Mountains of China’s Gansu province, and the effects on water conservation

The Qilian Mountains water conservation forest in Gansu province is an important ecological barrier surrounding the oasis in China’s Hexi Corridor. The water they provide is the basis for the existence and sustainable socioeconomic development of those oases. As a result of unsustainable use of the water conservation forest until the 1980s, the oasis ecosystems of the Hexi region were seriously damaged, and the oasis areas experienced deterioration of their ecological environment. In this paper, Landsat images were used to monitor the temporal and spatial changes in area of water conservation in Qilian Mountains of China’s Gansu province and to assess the effect on water conservation by analyzed relationship between water conservation forest area, climatic data and hydrological data. The results showed that the forest covered 15.1% of the study area in 2007 and has followed different trends during the study period. From 1978 to 1990, the forest area decreased; however, from 1990 to 2007, the forest area increased, with a faster rate of increase from 1990 to 2000, and the rate of increase averaged 2,733.89 ha per year since 1990. The water conservation forest appears to play an important role in flood control, runoff regulation, the prevention of soil erosion, and water conservation; and these benefits increase with an increasing area of forest.     

Effect of a native forest canopy on rainfall chemistry in China’s Qinling Mountains

This study investigated the effect of a pine/oak forest canopy on rainfall chemistry in the Qinling Mountains. The area is an important water source for China’s North-to-South Water Transfer Project. Rainfall and throughfall samples were collected at the Huoditang Natural Forest in 1999, 2004, and 2009. Analyses of the samples indicated that the forest canopy had several important effects on rainfall chemistry. Rainfall pH generally increased as water passed through the canopy. On average, the rainfall pH increased by 0.54 pH units. The canopy’s effect declined after deciduous trees lost their leaves late in the sampling season. Rainfall NO₃ ^? concentrations generally declined as water passed through the forest canopy, but PO₄ ^3? concentrations generally increased. On average, rainfall NO₃ ^? concentration declined by 0.135 mg/L as it passed though the forest canopy and PO₄ ^3? increased by 0.85 mg/L. The forest canopy had a mitigating effect on the base cation content of throughfall. Specifically, K⁺, Na⁺, Ca²⁺ and Mg²⁺ were leached from the canopy when the concentration of these cations in rainfall was low. In contrast, K⁺, Na⁺, Ca²⁺ and Mg²⁺ were absorbed by the canopy when the concentration of these cations in rainfall was high. The pH of rainfall, as well as its K⁺, Ca²⁺ and Mg⁺ concentration, influenced the effect of the forest canopy on the base cation content of throughfall. The concentration of Cd, Pb, and Zn in rainfall generally decreased as water passed through the forest canopy, but the concentration of Fe in rainfall generally increased. The Cd concentration decreased by an average of 3.938 μg/L, the Pb concentration decreased by an average of 8.457 μg/L, and the Zn concentration decreased by an average of 0.986 mg/L. The Fe concentration increased by an average of 0.009 mg/L. The canopy’s ability to absorb Cd declined after several rainfall events in which rainfall Cd concentrations were relatively high.     

Crystal chemistry of wadsleyite II and water in the Earth’s interior

Wadsleyite II is a variably hydrous magnesium-iron silicate phase similar to spinelloid IV and a potential host for H in the Transition Zone of the Earths mantle. Two separate samples of wadsleyite II synthesized at 17.5 GPa and 1400°C and at 18 GPa and 1350°C have been characterized by electron microprobe, single-crystal X-ray diffraction, visible, IR, Raman, and Mössbauer spectroscopies, and transmission electron microscopy including electron energy-loss spectroscopy. The two samples have the following chemical formulae: Mg_1.71Fe_0.18Al_0.01H_0.33Si_0.96O₄ and Mg_1.60Fe_0.22Al_0.01 H_0.44Si_0.97O₄. Mössbauer spectroscopy and electron energy loss spectroscopy (EELS) indicate that about half of the iron present is ferric. Refinement of the structures shows them to be essentially the same as spinelloid IV. Calculated X-ray powder diffraction patterns show only subtle differences between wadsleyite and wadsleyite II. The hydration mechanism appears to be protonation of the non-silicate oxygen (O2) and possibly the oxygens surrounding the partially vacant tetrahedral site Si2, charge-balanced by cation vacancies in Si2, M5 and M6. The unit cell volume of this phase and its synthesis conditions indicate that it may be an intermediate phase occurring between the fields of wadsleyite and ringwoodite, if sufficient trivalent cations are available. The unit cell parameters have been refined at pressures up to 10.6 GPa by single-crystal X-ray diffraction in the diamond anvil cell. The refined bulk modulus for the sample containing 2.8 wt% H₂O is 145.6 ± 2.8 GPa with a K of 6.1 ± 0.7. Similar to wadsleyite and ringwoodite, hydration has a large effect on the bulk modulus. The presence of this phase in the mantle could serve to obscure the seismic expression of the phase boundary between wadsleyite and ringwoodite near 525 km. The large apparent effect of hydration on bulk modulus is consistent with hydration having a larger effect on seismic velocities than temperature in the Transition Zone.     

Origin and recharge estimates of groundwater in the ordos plateau,People’s Republic of China

Groundwater is a valuable resource in the semiarid Ordos Plateau region where abundant mineral resources, such as coal, natural gas, and halite, are present. With resources development, groundwater demand will increase dramatically. The origin identification and recharge estimates of groundwater are significant components of sustainable groundwater development in the Ordos Plateau. Groundwater and precipitation samples were taken and the isotopic compositions δ²H, δ¹⁸O, and chloride were analyzed to identify groundwater origins and to estimate recharge rates. The δ²H and δ¹⁸O of the groundwater show that the groundwater recharge is of meteoric origin. The chloride mass balance (CMB) method was used to quantify recharge rates of groundwater in the Ordos Plateau, which varies from 2.93 to 22.11% of the effective annual rainfall. Recharge rates estimated by CMB were compared with values obtained from other methods and were found to be in good agreement. This study can be used to develop effective programs for groundwater management and development.     

Review on transboundary aquifers in People’s Republic of China with case study of Heilongjiang-Amur River Basin

Groundwater, as a precious resource hidden underground, is an important component of the global water system. Transboundary aquifers containing substantial amount of groundwater often carry crucial ecological and social implications. Yet, it is unfortunate that transboundary aquifers have hardly been in the forefront of political and scientific discussions, and have not received due attention by policymakers. This article attempts to summarize the investigation on the eight transboundary aquifers that China shares with the neighboring countries. An overview on the groundwater resources in China, including its distribution, exploitation and challenges is also provided. Hydrogeological condition of the Heilongjiang-Amur River Basin aquifer, which is one of the eight major aquifers, is further elaborated. Cooperative activities carried out by China and Russia on monitoring and management of this aquifer are also presented.     

An overview of the city of Gweru,Zimbabwe’s water supply chain capacity: towards a demand-oriented approach in domestic water service delivery

Following complaints about water shortages in some areas of Gweru, the paper assessed the availability of enabling capacities to efficiently and sufficiently deliver water to the residents of Gweru in line with the existing level of demand. The key inspected capacity aspects were infrastructure, human resources, finances and physical availability of raw water at source. Purposively selected informants from Zimbabwe National Water Authority (ZINWA) and Gweru city council (GCC) provided data on the infrastructural, financial and human resources situation of GCC. Dam levels data for Gweru’s three supply dams were obtained from ZINWA records through the assistance of Sanyati Catchment Hydrologist. The raw water availability was assessed with the aid of Mann–Kendall test using a 10 years period data set from 2003 to 2012 for trend analysis. Findings revealed that the water sources were not experiencing major changes in water levels, to be precise, the changes were insignificant. However, given the increase in population and demand, any slightest negative change in the supply chain would further widen the gap between supply and demand. The study also uncovered that GCC had challenges in terms of the infrastructure, mainly due to financial constraints. Notably, GCC was not experiencing high staff turnover, but it was however, seriously under staffed and failing to effectively monitor water use in the city. Therefore, strong financial injection is required to support staff and resuscitate the reticulation system. Given the perpetual water shortages in Gweru and the status quo in the supply chain, water demand management strategies, wastewater use and consumer education are consequently proposed as measures that would ensure continuous water supply for all needs in the city.     

‘There’s no future here’: The time and place of children’s migration aspirations in Peru

This article examines young Peruvians’ aspirations and the role of migration in their imagined futures, from a generational perspective. The data come from Young Lives, a long-term study of childhood poverty combining survey and qualitative approaches with children and their parents. The paper uses a biographical approach that sees migration as part of individual biographies as well as social structures and life course processes. The aim is to deepen understanding of the social contexts in which aspirations for and by children are generated, paying close attention to family migration histories, dynamic household contexts, and children’s migration networks. The analysis focuses on the time-spaces of migration aspirations, showing the way past, present and future are interconnected. It also emplaces aspirations by focusing on the way aspirations by and for children are constituted in and through particular places. The conclusion reflects on the role of poverty and argues that ‘aspirations’ are about much more than abstract ‘futures’; they orient actions in the present and say a great deal about young people’s current realities and relationships.     

Groundwater recharge and evolution of water quality in China’s Jilantai Basin based on hydrogeochemical and isotopic evidence

We investigated major ions, stable isotopes, and radiocarbon dates in a Quaternary aquifer in semi-arid northwestern China to gain insights into groundwater recharge and evolution. Most deep and shallow groundwater in the Helan Mountains was fresh, with total dissolved solids <1,000 mg L^?1 and Cl^? <250 mg L^?1. The relationships of major ions with Cl^? suggest strong dissolution of evaporites. However, dissolution of carbonates, albite weathering, and ion exchange are also the major groundwater process in Jilantai basin. The shallow desert groundwater is enriched in δ¹⁸O and intercepts the local meteoric water line at δ¹⁸O = ?13.4 ‰, indicating that direct infiltration is a minor recharge source. The isotope compositions in intermediate confined aquifers resemble those of shallow unconfined groundwater, revealing that upward recharge from intermediate formations is a major source of shallow groundwater in the plains and desert. The estimated residence time of 10.0 kyr at one desert site, indicating that some replenishment of desert aquifers occurred in the late Pleistocene and early Holocene with a wetter and colder climate than at present.     

Temporal stability of soil water storage and its influencing factors on a forestland hillslope during the rainy season in China’s Loess Plateau

Large-scale vegetation restoration in China’s Loess Plateau has been initiated by the central government to control soil and water losses since 1999. Knowledge of the spatio-temporal distribution of soil water storage (SWS) is critical to fully understand hydrological and ecological processes. This study analysed the temporal stability of the SWS pattern during the rainy season on a hillslope covered with Chinese pine (Pinus tabulaeformis Carr.). The soil water content in eight soil layers was obtained at 21 locations during the rainy season in 2014 and 2015. The results showed that the SWS at the 21 locations followed a normal distribution, which indicated moderate variability with the coefficients of variation ranging from 14 to 33%. The mean SWS was lowest in the middle slope. The spatial pattern of SWS displayed strong temporal stability, and the Spearman correlation coefficient ranged from 0.42 to 0.99 (p < 0.05). There were significant differences in the temporal stability of SWS among different soil layers (p < 0.01). The spatial patterns of SWS distribution showed small differences in different periods. The best representative locations of SWS were found at different soil depths. The maximum RMSE and MAE at 0–1.6 m soil depth for the rainy season were 4.27 and 3.54 mm, respectively. The best representative locations determined during a short period (13 days) can be used to estimate the mean SWS well for the same rainy season, but not for the next rainy season. Samples of SWS collected over a fortnight during the rainy season were able to capture the spatial patterns of soil moisture. Roots were the main factor affecting the temporal stability of SWS. Rainfall increased the temporal stability of the soil water distribution pattern. In conclusion, the SWS during the rainy season had a strong temporal stability on the forestland hillslope.     

Drinking water quality in Nepal’s Kathmandu Valley: a survey and assessment of selected controlling site characteristics

Water was sampled from over 100 sources in Nepal’s Kathmandu Valley, including municipal taps, dug wells, shallow-aquifer tube wells, deep-aquifer tube wells, and dhunge dharas (or stone spouts, public water sources that capture groundwater or surface water). Information was gathered on user preference and site and well characteristics, and water was examined for indicators of contamination from sewage, agriculture, or industry. Most problematic were total coliform and Escherichia coli bacteria, which were present in 94 and 72% of all the water samples, respectively. Contamination by nitrate, ammonia and heavy metals was more limited; nitrate and ammonia exceeded Nepali guidelines in 11 and 45% of the samples, respectively. Arsenic and mercury exceeded WHO guidelines in 7 and 10% of the samples, respectively, but arsenic never exceeded the less strict Nepali guideline. Significant differences existed in contamination levels between types of sources; dug wells and dhunge dharas, being the shallowest, were the most contaminated by bacteria and nitrate; deep-aquifer tube wells were the most contaminated by arsenic. Whereas E. coli concentrations decreased with depth, iron and ammonia concentrations increased with depth. These relationships account for people choosing to drink water with higher levels of bacterial contamination based on its superior (non-metallic) taste and appearance.     

Measurement of the difference in the Earth’s gravitational potentials with the help of a transportable quantum clock

The results of the Russia’s first ground-based experiment for determination of the difference in the Earth’s gravitational potentials on the basis of the measurement of the gravitational effect of the time delay with the help of a high-stability transportable atomic clock are provided. The reference atomic clock was placed in Moscow oblast, and a transportable quantum clock with an instability of 3 × 10^–15 was placed in the Caucasus Mountains, with a difference in height of the clocks of 1804 m. The measured difference in the gravitational potentials between the positions of the two quantum clocks was (182.0 ± 3.1)10²m²s^-2 at a relative measurement error of no more than 1.7%.     

An interdisciplinary political ecology of drinking water quality. Exploring socio-ecological inequalities in Lilongwe’s water supply network

Urban political ecology attempts to unravel and politicize the socio-ecological processes that produce uneven waterscapes. At the core of this analysis are the choreographies of power that influence how much water flows through urban infrastructure as well as where it flows, thereby shaping conditions and quality of access in cities. If these analyses have been prolific in demonstrating uneven distribution of infrastructures and water quantity, the political ecology of water quality remains largely overlooked. In this paper, we argue that there is a clear theoretical and practical need to address questions of quality in relation to water access in the South. We show that conceptual resources for considering differentiated drinking water quality are already present within urban political ecology. We then contend that an interdisciplinary approach, highlighting the interdependencies between politics, power, and physiochemical and microbiological contamination of drinking water, can further our understandings of both uneven distribution of water contamination and the conceptualisation of inequalities in the urban waterscape. We illustrate our argument through the case of water supply in Lilongwe, Malawi. Our political ecology analysis starts from an examination of the physicochemical and microbiological quality of water supplied by the formal water utility across urban spaces in Lilongwe. We then present the topography of water (quality) inequalities in Lilongwe and identify the political processes underlying the production of differentiated water quality within the centralised network. This paper thereby serves as a deepening of urban political ecology as well as a demonstration of how this approach might be taken forward in the analysis of urbanism and water supplies.