Metal speciation and environmental impact on sandy beaches due to El Salvador copper mine, Chile

Several coastal rocky shores in northern Chile have been affected by the discharges of copper mine tailings. The present study aims to analyze the chemical speciation of heavy metals in relation to the diversity of sessile species in the rocky intertidal benthic community on the northern Chilean coast, which is influenced by the presence of copper mine tailings. In particular, the chemical forms of Cd, Cu, Fe, Mn, Ni, Pb and Zn in beach sediment samples collected in the area influenced by El Salvador mine tailings were studied using a sequential chemical extraction method. In general, all the elements present a maximum concentration in the area near the actual discharge point (Caleta Palito). With regard to Cu and Mn, the concentrations range between 7.2-985 and 746-22,739 microg/g respectively, being lower than background levels only in the control site of Caleta Zenteno. Moreover, the correlation coefficients highlight that Fe, Mn and Ni correlate significantly and positively in the studied area, showing a possible common, natural origin, whilst Cu shows a negative correlation with Fe, Mn and Ni. It could be possible that Cu has an anthropogenic origin, coming from mining activity in the area. Cd, Fe, Mn, Ni, Pb and Zn are mostly associated with the residual phase, whilst Cu presents a different speciation pattern, as resulted from selective extractions. In fact, Cu is highly associated with organic and exchangeable phases in contaminated localities, whilst it is mainly bound to the residual phase in control sites. Moreover, our results, compared to local biological diversity, showed that those sites characterized by the highest metal concentrations in bioavailable phase had the lowest biodiversity.     

Environmental impact in sandy beaches of copper mine tailings at Chañaral, Chile

Since 1938, untreated copper mine tailings of Potrerillos and El Salvador have been disposed into the sea at Chañaral, Chile (26° 21′ Lat. S., 70° 42′ Long. W.). Over 220×10⁶ t of sediments have been dumped. This pollution has caused drastic geomorphological changes in the c. 16 km contaminated area. The occurrence of new artificial beaches and modification of coastal contours are reported. Sandy beach macrofauna monitoring (1975–1982) demonstrated a progressive lowering of density and biomass in those communities affected by copper mine tailings.     

The earthquake sequence of May 1951 at Jucuapa, El Salvador

Three earthquakes that happened over two days in May 1951 caused extensive damage to villages in a small area of eastern El Salvador (Central America). Contemporary hypocentral solutions indicated focal depths, confirmed by re-calculations using available seismic data, of the order of 90 km, suggesting events associated with the subducted Cocos plate. Macroseismic observations strongly indicate that the earthquakes were of very shallow focus and this is supported by wave-form modeling and the appearance of seismograms recorded in Guatemala. A re-evaluation of the location and source characteristics for these events is presented, together with a fault plane solution and additional macroseismic evidence. The implications for seismic hazard and risk assessment in Central America, where shallow earthquakes of moderate magnitude, frequently occurring in clusters, pose the greatest threat to settlements which, like the area affected by these events, are concentrated along the axis of Quaternary volcanoes.     

Vanadium sublimates from the fumaroles of Izalco volcano, El Salvador

Prior to the recent discovery of high-temperature vanadium sublimates at the fumaroles of Izalco volcano, El Salvador, the only vanadium minerals known were those formed at low-temperature surface conditions. Six new vanadium compounds have already been discovered at Izalco volcano, and five of these have been elevated to mineral status. Two of the minerals are among the most vanadium-rich compounds known in nature.Field studies and studies of the crystal chemistry of the sublimate phases have allowed delineation of the conditions of exsolution of vanadium-bearing gases from the magma and conditions of sublimation of the vanadium compounds. A vanadium halogen or oxyhalogen gas phase was exsolved from a basaltic magma when the magma was 550 m below the summit crater. As the gas rose to the fumaroles and mixed with the atmosphere, the oxygen fugacity rose from that of the magma to at least 10^−3,5 bar. At the fumaroles, the vanadium compounds sublimated at various temperatures, but a minimum temperature of 760° can be determined for one of the phases based on geothermometry determined from phase relations in the system CuO-V₂O₅. The studies have demonstrated that a vanadium-bearing gas can segregate from a magma with normal basaltic concentrations of vanadium.     

Relation of lava compositions to volcano size and structure in El Salvador

Most of the lavas at the nine volcanic centers along the volcanic front of El Salvador are basalts, basaltic andesites and andesites. The compositional variation within and among these centers can be explained by fractionation processes within the crust. Cognate gabbroic inclusions found in the lavas have appropriate mineralogy (plagioclase, olivine, magnetite and augite) to be cumulates formed by fractional crystallization. Two main variation trends occur, depending on the proportion of plagioclase removal. The more common, or normal, trend has a high (> 55%) proportion of plagioclase being removed. A less common, Al-rich, trend has a low (40%) proportion of plagioclase being removed. The Al-rich trend is found only at volcanoes that lack large negative Bouguer gravity anomalies. These volcanoes are unlikely to have large shallow magma chambers and fractionation probably occurs deeper in the crust where plagioclase removal is inhibited.The incompatible element (Na₂O, K₂O, Rb, Ba) contents of lavas vary systematically with the volume of the volcanic centers. At the same level of SiO₂, large volcanic centers have higher incompatible element contents than small volcanic centers. This suggests that open system fractionation in a periodically refilled chamber is the controlling factor. The large difference in Ba contents of lavas between eastern (low) and western (high) El Salvador suggests a difference in the mantle source region.     

The 2005 eruption of Ilamatepec (Santa Ana) volcano,El Salvador

We report the stratigraphic sequence of the 2005 eruption of Ilamatepec volcano together with sedimentological and chemical analyses of its products.Structural and textural characteristics of the deposits indicate that the eruption was driven by a small-volume rhyolitic intrusion at shallow levels, which resulted first in the collapse of the existing hydrothermally altered fan of previous deposits inside the crater lake, driving phreatic explosions with launching of blocks on ballistic trajectories; later the magma interacted with lake waters producing several hydromagmatic pyroclastic density currents (PDCs). These flows were energetic enough to knock down pine trees up to distances of 1.8 km from the crater in the E-NE sector of the volcano. Finally, ejection of ballistic blocks that landed on previously emplaced, wet pyroclastic density current deposits, caused the generation of a lahar that flowed down the steep eastern flank toward the El Jabillal gully. Subsequent lahars occurred as a result of intense rain caused by hurricane Stan.Radiocarbon ages on paleosols and charcoal fragments, separating previous volcanogenic sequences, indicate that similar eruptions have occurred more frequently in the past centuries, than previously thought.The new data confirms that Ilamatepec volcano is one of the most active volcanoes in El Salvador. Nevertheless, more detailed studies of the eruptive sequence of Ilamatepec volcano are mandatory to establish future eruptive patterns.     

Transition from mildly-tholeiitic to calc-alkaline suite: the case of Chichontepec volcanic centre, El Salvador, Central America

The Chichontepec volcano is a Plio-Pleistocene composite volcano that erupted lavas ranging from high-alumina basalts to dacites. It experienced a caldera-forming paroxysmal eruption during the early Pleistocene. Pre-caldera lavas are mildly tholeiitic and they evolved mainly by low pressure crystal fractionation, notwithstanding the fact that most mafic lavas (low-MgO high-alumina basalts) retain traces of polybaric evolution. Conversely, post-caldera lavas, which are mainly pyroxene andesites, are clearly calc-alkaline, having evolved by open-system crystal fractionation. Sr–Nd isotopic data and trace elements characteristics indicate that the same mantle source was involved in the petrogenesis of these series. Modelling the AFC process showed that it did not play any role in the petrogenesis of these rocks; a crystal fractionation model is considered to be more relevant. A slight variation in the fractionating assemblage could have caused the transition from an early mildly tholeiitic trend to a late calc-alkaline one. Mineralogical evidence, mass-balance calculations and elemental chemistry support this hypothesis, assuming that the greater amount of pyroxene on the liquidus is at the expense of plagioclase; this would have prevented the trend in iron enrichment.     

Biodiversity of rocky intertidal benthic communities associated with copper mine tailing discharges in northern Chile

Copper mine tailings have been discharged around the city of Chanaral, in northern Chile, for more than 60 years. This report summarizes a 17-month long monitoring study of species richness and biodiversity at five intertidal sites around the point of the tailing discharge. Total dissolved copper in sites close to the point of discharge varied between 8.72 microg/l and 34.15 microg/l, showing that there has not been a significant reduction since 1994. However, species richness has increased, suggesting a possible recovery of the system. While diversity of sessile organisms correlates negatively with dissolved copper, diversity of mobile invertebrates did not correlate with the metal concentration. To explain the observed results we discuss the role of algal turf interference on the distribution of mobile invertebrates at reference sites, a top-down effect caused by the absence of carnivores at impacted sites, and an avoidance strategy by some species to reduce their contact with contaminated seawater.     

A sediment quality triad assessment of the impact of copper mine tailings disposal on the littoral sedimentary environment in the Atacama region of northern Chile

A sediment quality triad (SQT) assessment was made of the impact of copper mine tailings disposal on littoral meiofaunal assemblages in the Atacama region of northern Chile. This situation is unusual in that the disposal is direct into the high-energy coastal system and not via a river estuary or other low-energy environment. This situation also allows for the examination of the impact of copper mine tailings in the absence of confounding effects from other pollutants. The three components of the SQT were: 1. an analysis of the bioavailable metals in both the sedimentary porewater and the adjacent seawater, 2. a microcosm bioassay of both sediments and seawaters using meiofaunal assemblages, and 3. quantitative field samples of the meiofaunal assemblages. Twelve study sites with varying degrees of impact were used, including three reference sites. The study identified that both the meiofaunal assemblage densities and taxa diversities decrease with increasing levels of bioavailable copper, that the Foraminifera and Harpacticoida are sensitive to copper, and that otoplanid Turbellaria are often characteristic of impacted sites; tailings also have both chemical and physical impacts on the environment. In some cases the physical impact of tailings is more important in excluding some organisms e.g. the interstitial polychaete, Saccocirrus sonomacus, from a site than is their chemical impact.     

Crater Lake Temperature Changes of the 2005 Eruption of Santa Ana Volcano,El Salvador,Central America

A sudden eruption at Santa Ana occurred on 1 October 2005, producing an ash-and-gas plume to a height in excess of 10 km above the volcano. Several days before, thermal infrared images of the crater provided precursory signals of the eruption. A significant increase in the extent and intensity of the fumarolic field inside the crater rim and of the surface temperature of the crater’s lake was observed. Changes in energy input was also estimated to explain the increase in lake temperature based on energy/mass balance calculations.     

Analysis of spatial distribution of mining tremors occurring in Rudna copper mine (Poland)

The distribution of mining tremors is strictly related to the exploitation progress of mining works and, consequently, to the local stress field. In case the distribution is known, it is possible to determine future area of intensive seismicity in exploited mining panel. In the paper, an analysis of working face-to-tremor distance for Rudna copper mine in Poland is presented. In order to develop a spatial model of tremors’ occurrence in the exploited mine, the seismicity of four mining sections in the five-month period was investigated and the tremors’ distribution was obtained. It was compared with the spatial distribution of tremors in coal mines found in the literature. The results show that the places where tremors mostly occur — the vicinity of the face, in front of it — coincide with the high-stress area predicted by literature models. The obtained results help to predict the future seismic zone connected with planned mining section, which can be used in seismic hazard analysis.     

Anomalous Diffuse CO2 Emission prior to the January 2002 Short-term Unrest at San Miguel Volcano, El Salvador, Central America

On January 16, 2002, short-term unrest occurred at San Miguel volcano. A gas-and-steamash plume rose a few hundred meters above the summit crater. An anomalous microseismicity pattern, about 75 events between 7:30 and 10:30 hours, was also observed. Continuous monitoring of CO₂ efflux on the volcano started on November 24, 2001, in the attempt to provide a multidisciplinary approach for its volcanic surveillance. The background mean of the diffuse CO₂ emission is about 16 g m^-2 d^-1, but a 17- fold increase, up to 270 g m^-2 d^-1, was detected on January 7, nine days before the January 2002 short-term unrest at San Miguel volcano. These observed anomalous changes on diffuse CO₂ degassing could be related to either a sharp increase of CO₂ pressure within the volcanic-hydrothermal system or degassing from an uprising fresh gas-rich magma within the shallow plumbing system of the volcano since meteorological fluctuations cannot explain this observed increase of diffuse CO₂ emission.     

Anomalous Emissions of SO2 During the Recent Eruption of Santa Ana Volcano, El Salvador, Central America

Santa Ana volcano in western El Salvador, Central America, had a phreatic eruption at 8:05 am (local time) on October 1, 2005, 101 years after its last eruption. However, during the last one hundred years this volcano has presented periods of quiet degassing with fumarolic activity and an acidic lake within its crater. This paper presents results of frequent measurements of SO₂ degassing using the MiniDOAS (Differential Optical Absorption Spectroscopy) system and a comparison with the volcanic seismicity prior to the eruption, during, and after the eruption. Vehicle measurements of SO₂ flux were taken every hour during the first nine days of the eruption and daily after that. The period of time reported here is from August to December, 2005. Three periods of degassing are distinguished: pre-eruptive, eruptive, and post-eruptive periods. The intense activity at Santa Ana volcano started in July 2005. During the pre-eruptive period up to 4306 and 5154 ton/day of SO₂ flux were recorded on October 24 and September 9, 2005, respectively. These values were of the same order of magnitude as the recorded values just after the October 1^st eruption (2925 ton/day at 10:01 am). Hourly measurements of SO₂ flux taken during the first nine days after the main eruptive event indicate that explosions are preceded by an increase in SO₂ flux and that this parameter reaches a peak after the explosion took place. This behavior suggests that increasing accumulation of exsolved magmatic gases occurs within the magmatic chamber before the explosions, increasing the pressure until the point of explosion. A correlation between SO₂ fluxes and RSAM (Real Time Seismic Amplitude Measurements) is observed during the complete sampling period. Periodic fluctuations in the SO₂ and RSAM values during the entire study period are observed. One possible mechanism explaining these fluctuations it that convective circulation within the magmatic chamber can bring fresh magma periodically to shallow levels, allowing increasing degasification and then decreasing degasification as the batch of magma lowers its gas content, becomes denser, and sinks to give space to a new magma pulse. These results illustrate that the measurements of SO₂ flux can provide important warning signals for incoming explosive activity in active volcanoes.     

The El Salvador earthquakes of January and February 2001: context, characteristics and implications for seismic risk

The small Central American republic of El Salvador has experienced, on average, one destructive earthquake per decade during the last hundred years. The latest events occurred on 13 January and 13 February 2001, with magnitudes M_w 7.7 and 6.6, respectively. The two events, which were of different tectonic origin, follow the patterns of the seismicity of the region although neither event has a known precedent in the earthquake catalogue in terms of size and location. The earthquakes caused damage to thousands of traditionally built houses and triggered hundreds of landslides, which were the main causes of fatalities. The earthquakes have clearly demonstrated trends of increasing seismic risk in El Salvador due to rapid population expansion in areas of high shaking and landslide hazard, exacerbated by deforestation and uncontrolled urbanisation. The institutional mechanisms required for the control of land use and building practice are very weak and present a major obstacle to risk mitigation.     

Analysis of elastoplasticity and rheology due to mining subsidence

At present, as the easily mining resources are being increasingly depleted, the exploitation of coal under buildings, water-bodies and railways is imminent for the sustainable production. Probability in-tegral method is a general method for mining subsidence in the coal system. Because of poor under-standing of mining subsidence for other sections, the authors suggest probability integral method for the study of coal mining under buildings, water-bodies and railways. Moreover, the calculation result of probability integral method should be corrected by numerical simulation method. Based on practical projects, the impact has been evaluated on the security of Xifeihe left embankment under coal mining. Combining with the results of probability integral method, we propose that the 600 m far from em-bankment is a good rationality. This article provides the basis for the rational exploitation of coal re-source which is a major practical problem under the premise of Water Infrastructure Security. Fur-thermore, it also can be served as a reference for the similar projects, such as mining Xiaolangdi res-ervoir area, mining Yuecheng reservoir and mining the major channels of Middle Route South to North Water Transfer.     

Development of a methodology for assessing the environmental impact of radioactivity in Northern Marine environments

The requirement to assess the impacts of radioactivity in the environment explicitly and transparently is now generally accepted by the scientific community. A recently developed methodology for achieving this end for marine ecosystems is presented within this paper. With its clear relationship to an overarching system, the marine impact assessment is built around components of environmental transfer, ecodosimetry and radiobiological effects appraisal relying on the use of "reference organisms". Concentration factors (CFs), dynamic models and, in cases where parameters are missing, allometry have been employed in the consideration of radionuclide transfer. Dose conversion coefficients (DCCs) have been derived for selected flora and fauna using, inter alia, dose attenuation and chord distribution functions. The calculated dose-rates can be contextualised through comparison with dose-rates arising from natural background and chronic dose-rates at which biological effects have been observed in selected "umbrella" endpoints.     

Temporal variation in the diversity and cover of sessile species in rocky intertidal communities affected by copper mine tailings in northern Chile

Several coastal rocky shores in the northern Chile have been affected by the discharges of copper mine tailings. In spite of this, the temporal and spatial variation on the diversity and composition of their intertidal benthic communities has scarcely been studied. The objectives of the present study were to analyse and to compare quantitatively the temporal variation on the diversity, cover and composition of sessile species in rocky intertidal benthic communities of the northern Chilean coast, in relation to the presence of copper mine tailings. The results show that the drastic reduction on the sessile species diversity and the monopolization of the substrate exerted by the green algae Enteromorpha compressa, are common and permanent features of the intertidal rocky shores affected by copper mine tailings. Such spatial (between sites) and temporal (seasonal) variation of these changes has been associated with the relative concentrations of trace metals and inorganic particles of the mining wastes. Our results suggest that the mechanical effects of resuspended and settling tailings are a more likely cause.     

Marine and coastal environmental awareness building within the context of UNESCO's activities in Asia and the Pacific

UNESCO is one of the specialized agencies under the United Nations charged with the advancement and improvement of education, social and natural sciences, culture and communication. This global mandate translates into programmes in the field tailored to the member states' specific requirements that build on the full breadth of expertise available in UNESCO. Environmental awareness building is an integral component of many of UNESCO's programmes. This paper describes how UNESCO addresses the need for awareness building in a variety of settings under different programmes and sectors. A first example is taken from the work of the education sector, which aims at introducing innovative learning methods and curricula that change or cultivate the perspective of people of all ages on sustainable development. The second example is taken from the Man and Biosphere Programme. The Biosphere Reserve concept has had a long history within UNESCO and is increasingly applied to protected areas in the coastal zone. Notable examples are Ranong Biosphere Reserve in Thailand, Can Gio Biosphere Reserve in Vietnam and the Island of Palawan in the Philippines. The concept is currently experiencing a revival as more and more countries realize the importance of striking a balance between human development and strict conservation. Many people know about UNESCO through the so-called World Heritage Sites. These are sites that are recognized by the world community as particular monuments, either natural or cultural, that warrant preservation for the whole of mankind. In the Asia-Pacific region, there are quite a number of coastal and marine sites that have been designated as natural world heritage sites, e.g. Halong Bay in Vietnam, the Komodo marine national park, Indonesia, the Great Barrier Reef in Australia, East-Rennell Island in the Solomon Islands, and Tubbataha Reef in the Philippines. The need for a cross-sectoral approach is evident under the so-called Coastal Zone and Small Islands endeavour, which aims at assisting Member States towards environmentally sound, socially equitable and culturally appropriate development in coastal regions and in small islands. Four examples of current pilot projects (Surin Island, Thailand, Jakarta Bay, Indonesia, Upolo Island, Samoa and Ulugan Bay, the Philippines) are highlighted. Each setting and each audience requires a different strategy. UNESCO's strength is to learn from all these experiences and make such new insights universally available and to put novel concepts into practice.