Arsenic Levels in Groundwater from Quaternary Alluvium in the Ganga Plain and the Bengal Basin, Indian Subcontinent: Insights into Influence of Stratigraphy

Late Quaternary stratigraphy and sedimentation in the Ganga Alluvial Plain and the Bengal Basin have influenced arsenic contamination of groundwater. Arsenic contaminated aquifers are pervasive within lowland organic rich, clayey deltaic sediments in the Bengal Basin and locally within similar facies in narrow, entrenched river valleys within the Ganga Alluvial Plain. These were mainly deposited during early-mid Holocene sea level rise. Arsenic was transported from disseminated sources as adsorbed on dispersed phases of hydrated-iron-oxide. These were preferentially entrapped as sediment coatings on organic-rich, fine-grained deltaic and floodplain sediments. Arsenic was released later to groundwater mainly by reductive dissolution of hydrated-iron-oxide and corresponding oxidation of sediment organic matter. Strong reducing nature of groundwater in the Bengal Basin and parts of affected middle Ganga floodplains is indicated by high concentration of dissolved iron (maximum 9-35 mg/l). Groundwater being virtually stagnant under these settings, released arsenic accumulates and contaminates groundwater. The upland terraces in the Bengal Basin and in the Central Ganga Alluvial Plain, made up of the Pleistocene sediments are free of arsenic contamination in groundwater. These sediments are weakly oxidised in nature and associated groundwater is mildly reducing in general with low concentration of iron (<1 mg/l), and thus incapable to release arsenic. These sediments are also flushed free of arsenic, released if any, by groundwater flow due to high hydraulic head, because of their initial low-stand setting and later upland terraced position.     

Holocene estuarine sediments as a source of arsenic in Pleistocene groundwater in suburbs of Hanoi,Vietnam

Groundwater pollution by arsenic is a major health threat in suburban areas of Hanoi, Vietnam. The present study evaluates the effect of the sedimentary environments of the Pleistocene and Holocene deposits, and the recharge systems, on the groundwater arsenic pollution in Hanoi suburbs distant from the Red River. At two study sites (Linh Dam and Tai Mo communes), undisturbed soil cores identified a Pleistocene confined aquifer (PCA) and Holocene unconfined aquifer (HUA) as major aquifers, and Holocene estuarine and deltaic sediments as an aquitard layer between the two aquifers. The Holocene estuarine sediments (approximately 25–40 m depth, 9.6–4.8 cal ka BP) contained notably high concentrations of arsenic and organic matter, both likely to have been accumulated by mangroves during the Holocene sea-level highstand. The pore waters in these particular sediments exhibited elevated levels of arsenic and dissolved organic carbon. Arsenic in groundwater was higher in the PCA (25–94 μg/L) than in the HUA (5.2–42 μg/L), in both the monitoring wells and neighboring household tubewells. Elevated arsenic concentration in the PCA groundwater was likely due to vertical infiltration through the arsenic-rich and organic-matter-rich overlying Holocene estuarine sediments, caused by massive groundwater abstraction from the PCA. Countermeasures to prevent arsenic pollution of the PCA groundwater may include seeking alternative water resources, reducing water consumption, and/or appropriate choice of aquifers for groundwater supply.     

Role of Quaternary stratigraphy on arsenic-contaminated groundwater from parts of Middle Ganga Plain,UP–Bihar,India

Late Quaternary stratigraphy and sedimentation in the Middle Ganga Plain (MGP) (Uttar Pradesh–Bihar) have influenced groundwater arsenic contamination. Arsenic contaminated aquifers are pervasive within narrow entrenched channels and flood plains (T₀-Surface) of fine-grained grey to black coloured argillaceous organic rich Holocene sediments (Newer Alluvium). Contaminated aquifers are often located close to distribution of abandoned or existing channels and swamps. The Pleistocene Older Alluvium upland terraces (T₂-Surface) made up of oxidized yellowish brown sediments with calcareous and ferruginous concretions and the aquifers within it are free of arsenic contamination. MGP sediments are mainly derived from the Himalaya with minor inputs from the Peninsular India. The potential source of arsenic in MGP is mainly from the Himalaya. The contaminated aquifers in the Terai belt of Nepal are closely comparable in nature and age to those of the MGP. Arsenic was transported from disseminated sources as adsorbed on dispersed phases of hydrated-iron-oxidea and later on released to groundwater mainly by reductive dissolution of hydrated-iron-oxide and corresponding oxidation of organic matter in aquifer. Strong reducing nature of groundwater is indicated by high concentration of dissolved iron (11.06 mg/l). Even within the arsenic-affected areas, dugwells are found to be arsenic safe due to oxyginated nature.     

Mobilization of natural arsenic in groundwater: targeting low arsenic aquifers in high arsenic occurrence areas

研究表明饮用水中微小数量的砷会对人类健康产生不利影响.世界上居住在贫穷地区的人数超过了100万,目前他们正直接饮用来自含水层中砷离子含量(>10μg/L)非安全标准的地下水.砷有时称为毒中之王,在水环境中常常以五价氧化物形式出现.自2000年以来,许多国家开始执行更为严格的10μg/L(WHO认可的居民安全饮水标准)饮用水标准,可以确定地说,在世界范围内的饮用水中检测到砷的情况越来越多.亚洲地区砷中毒的人数比世界其他地区总和还多.最受影响的地区位于南亚和东南亚富砷带,环绕恒河一雅鲁藏布江-梅克纳河三角洲及恒河平原上游的冲洪积扇含水层、红河三角洲、湄公河和伊洛瓦底江;在中国境内包括内蒙黄河冲积盆地,山西大同盆地、新疆准噶尔盆地,其中的地下水富含砷和氟化物而引发砷中毒和氟中毒.尽管还未完全掌握其中的水文地质及生物地球化学作用的详细过程,但对大多数沉积介质含水层,在还原条件下砷离子容易从沉积介质转移到地下水中.孟加拉研究实例表明地质时期尺度的冲刷降低了沉积介质中的As和有机物含量从而形成低砷地下水.这一认识为孟加拉国的降砷策略提供了科学指导,是未来水文学,矿物学,地质学和生物地球化学方面很有意义的研究方向,并有利于地砷病区低砷地下水的可持续利用.     

Arsenic toxicity of groundwater in parts of the Bengal basin in India and Bangladesh: the role of Quaternary stratigraphy and Holocene sea-level fluctuation

 Arsenic toxicity in groundwater in the Ganges delta and some low-lying areas in the Bengal basin is confined to middle Holocene sediments. Dissected terraces and highlands of Pleistocene and early Holocene deposits are free of such problems. Arsenic-rich pyrite or other arsenic minerals are rare or absent in the affected sediments. Arsenic appears to occur adsorbed on iron hydroxide-coated sand grains and clay minerals and is transported in soluble form and co-precipitated with, or is scavenged by, Fe(III) and Mn(IV) in the sediments. It became preferentially entrapped in fine-grained and organic-rich sediments during mid-Holocene sea-level rises in deltaic and some low-lying areas of the Bengal basin. It was liberated subsequently under reducing conditions and mediated further by microbial action. Intensive extraction of groundwater for irrigation and application of phosphate fertilizer possibly triggered the recent release of arsenic to groundwater. This practice has induced groundwater flow, mobilizing phosphate derived from fertilizer, as well as from decayed organic matter, which has promoted the growth of sediment biota and aided the further release of arsenic. However, the environment is not sufficiently reducing to mobilize iron and arsenic in groundwater in the Ganges floodplains upstream of Rajmahal. Thus, arsenic toxicity in the groundwater of the Bengal basin is caused by its natural setting, but also appears to be triggered by recent anthropogenic activities. Received: 23 August 1999 · Accepted: 16 November 1999     

Delineation of arsenic-contaminated zones in Bengal Delta, India: a geographic information system and fractal approach

Groundwater extracted from shallow aquifers in the Bengal Delta is contaminated with arsenic. The fluviodeltaic process that creates aquifers, ironically, extends its role to also contaminating them with arsenic. The arsenic distribution maps show a spatial association of arsenic-contaminated wells with palaeo/cut-off/abandoned channels. Weight-on-evidences analysis indicates that the zones of contamination occur around palaeo-channels within a corridor of 500–700 m that contains most of the contaminated wells. These corridors are interpreted to be the zone of channel shifting. Contaminated wells represent point fractal geometry that can be separated into isolated points and clusters. Clusters occur within the zone of channel shifting as obtained by weight-on-evidences analysis. Isolated points occur within floodplain or back swamp areas. Clusters and isolated point fractals are interpreted to reflect the process of arsenic release into groundwater. The migration of biomass within the permeable sandy domain of channel deposits is proposed to be the predominant process in generating clusters. The isolated points represent restricted biomass spreading in less permeable clay-silt dominated floodplains.     

Evaluation of hydrogeochemical processes in arsenic-contaminated alluvial aquifers in parts of Mid-Ganga Basin,Bihar, Eastern India

The study region covers 1,650 km² of the Mid-Ganga Basin in Bihar, experiencing intensive groundwater draft. The area forms a part of the Gangetic alluvial plain where high incidence of arsenic groundwater contamination (>50 μg/l) has recently been detected. Seventy-seven groundwater samples have been collected and analysed for major ions, iron and arsenic. Arsenic contamination (max 620 μg/l) is confined in hand pump zones (15–35 m) within the newer alluvium deposited during Middle Holocene to Recent age. The older alluvial aquifers are arsenic-safe and recorded maximum concentration as 9 μg/l. Out of 12 hydrochemical facies identified, four have been found arsenic-affected: Ca–HCO₃, Mg–HCO₃, Ca–Mg–HCO₃ and Mg–Ca–HCO₃. The geochemical evolution of groundwater, as investigated by graphical interpretation and statistical techniques (correlation, principal component analysis) revealed that dissolution of detrital calcite, dolomite and infiltration of rainwater are the major processes shaping the groundwater chemistry in the newer alluvium. Arsenic and iron showed strong positive correlation. Rainfall infiltration, carrying organic matter from recently accumulated biomass from this flood-prone belt, plays a critical role in releasing arsenic and iron present in the sediments. Geochemical evolution of groundwater in older alluvium follows a different path, where cation-exchange has been identified as a significant process.     

Arsenic distribution and source in groundwater of Yangtze River Delta economic region,China

This thesis focuses Arsenic(As) distribution and occurrence in groundwater of Yangtze River Delta economic region, East China. 2019 groundwater samples were collected to analyze 26 chemical compositions, including As. The Principal Component Analysis(PCA) was used to find out As source in groundwater. The results show that average As concentration in groundwater of this study is 9.33 μg/l, and maximum As concentration is up to 510 μg/l. The variation coefficient is 314.34%. High arsenic phreatic water(10 μg/l) distributes along the Yangtze River and its estuary. Weak hydrodynamic conditions, wide p H value variation range and deteriorating environment are dominating factors, especially in Yangtze River Delta. The PCA suggests that arsenic in phreatic water is mainly of natural origin. Part of arsenic may directly originate from sediment organics and be related to organics decomposition.     

黄河三角洲浅层地下水盐分来源及咸化过程研究

黄河三角洲地下水咸化已成为区域最突出的生态环境问题之一。识别地下水补给及盐分来源是有效控制和改善地下水咸化问题的关键。本研究采集了研究区浅层地下水、地表水和海水等不同类型水样,利用离子比、Piper三线图、吉布斯图等方法对八大离子浓度、δD和δ¹⁸O 组成、Br和Sr 浓度等进行地下水补给研究与盐分来源辨析。结果表明:(1)黄河三角洲浅层地下水以总溶解性固体(TDS)为338 g/L的咸水为主,地下水水化学类型较为单一,主要为Cl-Na型。(2)三角洲区域地下水以大气降水补给为主,并且在补给过程中经历了不同程度的蒸发作用的影响,黄河现行流路区域地下水主要来源于河水侧渗补给,但浅层地下水含水层水平渗透性较差限制了黄河侧渗补给范围。(3)海洋是黄河三角洲浅层地下水盐分的主要来源,黄河现行流路区域及近岸地下水盐分来源于海水混合,三角洲北部刁口河等古河道区域地下水盐分主要来源于海相蒸发盐淋滤溶解。     

Arsenic exposure through groundwater in the middle Ganga plain in the Varanasi environs,India: A future threat

The study area covers an about 100 km² of the middle Ganga plain in Uttar Pradesh, experiencing intensive groundwater extraction. In order to recognize the arsenic contamination zones of the Varanasi environs, sixty eight groundwater samples have been collected and analyzed for major ions, iron and arsenic. Twenty one sediment samples in the four boreholes were also collected to deduce the source of arsenic in the groundwater. The preliminary survey reports for the first time indicates that part of rural and urban population of Varanasi environs are drinking and using for irrigation arsenic contaminated water mostly from hand tube wells (<70 m). The study area is a part of middle Ganga plain which comprises of Quaternary alluvium consists of an alternating succession of clay, clayey silt and sand deposits. The high arsenic content in groundwater samples of the study area indicates that 14% of the samples are exceeding the 10 μg/l and 5% of the samples are exceeding 50 μg/l. The high arsenic concentration is found in the villages such as Bahadurpur, Madhiya, Bhojpur, Ratanpur, Semra, Jalilpur, Kateswar, Bhakhara and Kodupur (eastern side of Ganga River in Varanasi), situated within the newer alluvium deposited during middle Holocene to Recent. The older alluvial aquifers situated in the western side of the Ganga River are arsenic safe (maximum As concentration of 9 μg/l) though the borehole sediments shows high arsenic (mean 5.2 mg/kg) and iron content (529 mg/kg) in shallow and medium depths. This may be due to lack of reducing conditions (i.e organic content) for releasing arsenic into the groundwater. Rainfall infiltration, organic matter from recently accumulated biomass from flood prone belt in the newer alluvium plays a critical role in releasing arsenic and iron present in sediments. The main mechanism for the release of As into groundwater in the Holocene sandy aquifer sediments of Varanasi environs may be due to the reductive dissolution of Fe oxyhydroxide present as coatings on sand grains as well as altered mica content. The high societal problems of this study will help to mitigate the severity of arsenic contamination by providing alternate drinking water resources to the people in middle Ganga plain and to arrange permanent arsenic safe drinking water source by the authorities.     

Contamination of shallow aquifers by arsenic in upper reaches of Tista river at Siliguri–Jalpaiguri area of West Bengal, India

Arsenic is present in groundwater at Siliguri–Jalpaiguri area, West Bengal, India. This is the place where Tista river descending from the Himalayas meets the alluvial plain. The area represents alluvial fan and floodplains of Tista, Mahananda-Balasan, Jaladhaka and its tributaries. In the river sediment samples, para- and ferro-magnetic minerals within 0.3–0.05 mm fraction contain 9–80 ppm of arsenic. The study indicates that iron bearing minerals viz. biotite, hornblende as well as iron coated grains of the sediment are major contributors towards arsenic budget. Though magnetite as a mineral shows maximum arsenic content (22 ppm), it is volumetrically not of much significance. Measurement of groundwater collected from tube wells shows up to 0.05 ppm of arsenic. These arsenic contaminated tube wells occur in a linear fashion along the course of the rivers. Moreover, localization of contaminated tube wells coincides with the change of channel gradient as observed in longitudinal section. The study enumerates a cause–effect relationship of arsenic occurrence with river gradient and fluvial sedimentation.     

A study on groundwater recharge in the Anyanghe River alluvial fan,North China Plain,based on hydrochemistry,stable isotopes and tritium

Studies on groundwater recharge are essential for sustainable exploitation of groundwater resources, especially in areas of extensive groundwater exploitation such as the Anyanghe River alluvial fan (ARAF) in the North China Plain (NCP). However, the recharge sources and processes and the contribution of each recharge flow component remain unclear. This study used hydrochemistry, stable isotopes, and tritium to investigate sources and underlying processes of groundwater recharge, along with the steady flow Mixing Cell Model (MCMsf) to quantify the proportion of each source flow for the shallow confined groundwater system in the medial fan. The results showed that groundwater mainly originates from precipitation occurring on the eastern Taihang Mountain area with average elevation estimated at 700–1,000 m above sea level during the East Asia summer monsoon period since 1952. Recharge mechanisms are: (1) river water seepage for the unconfined aquifers of the proximal and medial fan; (2) lateral flow for the confined aquifers of the medial and distal fan; and (3) precipitation infiltration for the phreatic water system. The MCMsf simulation showed that the shallow confined groundwater system in the central zone of the medial fan mainly recharged by the lateral flow from the proximal fan, a constant and considerable recharge flow from the southwestern and southern hills, and river water seepage in the medial fan; the lateral recharge flow from the Zhanghe alluvial aquifer was insignificant by comparison. The results of this study can act as a valuable reference for sustainable groundwater management in the ARAF.

     

Deeper groundwater chemistry and geochemical modeling of the arsenic affected western Bengal basin,West Bengal,India

A regional scale hydrogeochemical study of a ∼21,000-km² area in the western Bengal basin shows the presence of hydrochemically distinct water bodies in the main semiconfined aquifer and deeper isolated aquifers. Spatial trends of solutes and geochemical modeling indicate that carbonate dissolution, silicate weathering, and cation exchange control the major-ion chemistry of groundwater and river water. The main aquifer water has also evolved by mixing with seawater from the Bay of Bengal and connate water. The isolated aquifers contain diagenetically altered water of probable marine origin. The postoxic main aquifer water exhibits overlapping redox zones (metal-reducing, sulfidic and methanogenic), indicative of partial redox equilibrium, with the possibility of oxidation in micro-scale environments. The redox processes are depth-dependent and hydrostratigraphically variable. Elevated dissolved As in the groundwater is possibly related to Fe(III) reduction, but is strongly influenced by coupled Fe–S–C redox cycles. Arsenic does not show good correlations with most solutes, suggesting involvement of multiple processes in As mobilization. The main river in the area, the Bhagirathi–Hoogly, is chemically distinctive from other streams in the vicinity and probably has little or no influence on deep groundwater chemistry. Arsenic in water of smaller streams (Jalangi and Ichamati) is probably introduced by groundwater discharge during the dry season.     

Hydrochemical and isotopic evidence of recharge,apparent age,and flow direction of groundwater in Mayo Tsanaga River Basin,Cameroon: bearings on contamination

Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO₃ type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO₄ chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ¹⁸O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ¹⁸O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and regional flow regimes gets older towards the basins` margin with coeval enrichment in F⁻ and depletion in NO₃ ⁻. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic fluoride. The basins salinization is still at an early stage.     

Changes of δ<Superscript>18</Superscript>O and δD along the Dousitu River,Inner Mongolia,China, and their evidence of river water evaporation

On the basis of the hydrogeology of the Dousitu River drainage basin, the changes of water flow rate, δ¹⁸O and δD along the Dousitu River are discussed according to measured and analytical results. Changes of flow rate along the Dousitu River agree well with groundwater level contours and the recharge and discharge of groundwater to the river. When compared with other types of water in the area, it is obvious that the ¹⁸O and D of river waters have experienced evaporation. The changes of δ¹⁸O and δD along the Dousitu River are mainly caused by combined effects of groundwater recharge and river water evaporation. The recharge of groundwater makes δ¹⁸O and δD of the river water decrease. Evaporation makes δ¹⁸O and δD of the river water increase. The evaporation fractions of the river water are calculated using the kinetic fractionation theory. Results showed as much as 10–30% of water was evaporated in different segments of Dousitu River.     

同位素水化学指示的新疆孔雀河流域地下水与地表水关系

地下水是孔雀河流域农业灌溉的主要水源之一,其对本地区经济发展的支撑作用日益增强.为实现孔雀河流域水资源合理开发和生态保护,采用环境同位素和水化学方法,研究了孔雀河流域地下水与地表水关系.结果表明:地下水的主要补给来源为河水.含水层成因类型和现代河道分布共同控制着孔雀河流域地下咸淡水的空间分布格局;氢氧稳定同位素对不同水...     

Hydrogeochemistry of Urban Floodplain Aquifer Under the Influence of Contaminated River Seepage in Delhi (India)

Hydrogeochemical and hydrodynamic surface/groundwater interactions were investigated at the urban floodplain aquifer in Delhi, India. The heavily polluted Yamuna River is in hydraulic contact to the groundwater and river seepage results in a contamination plume. A conceptual redox zonation was developed based on the occurrence or absence of terminal electron acceptors. The redox zonation shows an inverted zonation from sulphate-reducing conditions close to the river over manganese- and iron-reducing conditions to a mixed oxic/suboxic zone. This study shows that the occurrence of problematic substances such as ammonium and arsenic in the groundwater is a consequence of the high load of untreated sewage in the river in combination with losing river conditions. Sequential extraction of aquifer material was performed to obtain information on geochemical availability of arsenic associated with different mineral phases and binding forms. Geogenic and anthropogenic arsenic sources contribute to overall arsenic concentration, and arsenic is found to be attributed mainly to amorphous iron oxide and sulphidic phases in the sediment. The contamination plume at the urban floodplain aquifer makes the groundwater unfit for drinking water purposes.     

Climate change and groundwater resources in Mekong Delta,Vietnam

Groundwater resources have considerable influences on the human population and socioeconomic development of Vietnam and the Mekong River Delta (MRD). This paper presents an overview of the relationship between climate change and groundwater in the MRD, including the challenges, strategies and technical measures. Our results showed that groundwater levels are related to other climate and hydrological variables (i.e., rainfall, river levels, etc.); therefore, the impacts of climate change on the groundwater resources of the Mekong delta are significant, especially on groundwater recharge. Based on the results of this study, it is recommended that groundwater development in the future should focus on reducing groundwater harvesting, enhancing groundwater quantity by establishing artificial works and exploiting surface water. This study suggests that the Artificial Neural Network (ANN) model is an effective tool for forecasting groundwater levels in periods of 1 month and 3 months for aquifers in the natural and tidal regime areas of the delta.     

Hydrogeochemical characteristics of groundwater from the two main aquifers in the Red River Delta,Vietnam

In the Red River Delta, situated in the northern part of Vietnam, nearly its entire population depends solely on groundwater for daily water consumptions. For this reason, groundwater quality assessments must be carefully carried out using hydrogeochemical properties, to ensure effective groundwater resource planning for the Delta’s present and future groundwater use. In this study, the spatial and seasonal changes in the hydrogeochemical characteristics of groundwater in the two main aquifers of the RRD were investigated by analyzing the physicochemical data obtained in 2011 from 31 conjunctive wells in the Delta’s Holocene unconfined aquifer (HUA) and Pleistocene confined aquifer (PCA) using the Piper diagram and the Gibbs diagram. Results of the data analysis show that the groundwater in both aquifers in the upstream area of the delta is dominated by the [Ca²⁺–HCO₃⁻] water-type, while the [Na⁺–Cl⁻] dominates along the middle-stream and downstream areas. Seasonal changes in the hydrogeochemical facies in both aquifers, comparing the results for the dry and the rainy seasons, were detected in about one third of the sampling wells, which were mainly located at the upstream portion of the Delta. The hydrogeochemical facies of HUA were different from that of PCA by about 45% of the sampling wells in both the dry and the rainy seasons, which were found mostly in the upstream and middle-stream areas.     

Trace elements and environmental isotopes as tracers of surface water–groundwater interaction: a case study at Xin’an karst water system,Shanxi Province,Northern China

In this case study, silica concentration, oxygen and strontium isotopes of water samples were used to study surface water–groundwater interaction at the Xin’an karst water system. The silica concentration in rain water is commonly less than 1 mg/l. In the areas around the south tributary of the Zhuozhang River, silica concentrations in the groundwater in Quaternary aquifers range between 4.04 and 7.66 mg/l while that of the surface water varies from 1.49 to 6.9 mg/l. Silica concentrations of most surface water samples increase with TDS, indicating the effect of groundwater recharge on river water chemistry. On the contour map of silica concentration of groundwater in Quaternary aquifers, samples located close to surface water often have lower silica concentrations as a result of surface water recharge. Both overland flow and surface water have impact on karst water according to our hydrogeochemical study of stable oxygen isotope, Sr isotope and strontium contents. Calculation results of three end member mixing model show that the contribution of karst water, surface water and overland flow water is 45, 28 and 27%, respectively.