Analysis of natural tracers and genetic runoff components in mixing models: Case study of small basins in Primor’e

An algorithm has been proposed for the diagnostics of the number of runoff genetic components and reliable chemical tracers in mixing models. The algorithm is applied to the analysis of data of hydrological—hydrochemical monitoring obtained during experimental studies on small watersheds in Elovyi Creek basin. The number of stable genetic runoff components and the list of tracers can vary from year to year depending on the state of moistening on the watershed.     

Vulnerability and risk analysis of monuments in Málaga city’s historical centre (Southern Spain)

A vulnerability analysis of some historical and monumental buildings in the city of Málaga is presented in this paper. More than twenty of these monuments were severely damaged or completely destroyed due to the large earthquake (I _max = VIII–IX) occurred in the Málaga region in October 1680. The vulnerability index methodology has been used in this paper. This technique is based on statistical data from seismic damage caused to Italian monuments for the past 30?years. For each building, vulnerability curves have been obtained and damage grades have been estimated. A comparison has been carried out between the expected damage grades and the damage observed from past earthquakes, in order to check the feasibility of applying this methodology to Spanish monuments. This comparison has been possible due to the fact that detailed seismic damage information exists for monuments in the city of Málaga that still exist today, which is a very uncommon case in Spain. Results show a good consistency between expected and observed damage, especially for the churches type. Two seismic scenarios have been proposed for the city centre, one deterministic and one probabilistic, where 54 historical and modern buildings have been analyzed. Both scenarios show worrying results, especially for the types of churches, chapels and towers, where expected high probabilities of suffering very heavy damage or even collapse have been obtained. It is highly recommended to take the necessary measures, in the hope of trying to avoid the possible damage that can be expected from future earthquakes.     

Geochemical types of natural waters in the interfluve of the Enzor’yakhi and the Yun’yakhi (eastern slope of the Polar Urals)

Natural-water chemistry in the interfluve of the Enzor’yakhi and the Yun’yakhi rivers (the eastern slope of the Polar Urals) is characterized in terms of the ratios of major ions belonging to hydrocarbonate calcium-magnesium and magnesium-calcium chemical types. From the viewpoint of evolution of the water-rock system in the region, five geochemical types of water were identified by the degree of their equilibrium with secondary minerals, reflecting different formation conditions of their chemistry. A specific feature of the region is the formation of waters of organogenic geochemical type, which are considerably enriched by organic matter, determining the specifics of migration of some chemical elements in such waters.     

Chronological reconstruction of metal contamination in the Port of Maó (Minorca, Spain)

In this work we discuss the historical record of metals as derived from a sediment core from the Port of Maó (Minorca, Spain), the second natural largest harbour in Europe. The sedimentation rate derived from radionuclide profiles increased by a factor of five since the 1960s due to the urbanisation of the town waterfront. Metal concentrations showed two different trends: (i) Pb and Sn inputs started during the second half of the 19th century and remained relatively high until mid-20th century; and (ii) Ag, Cd, Ni, Zn, Cu and Cr accumulation began in the 1940s, peaking in the late 1970s. The commissioning of a submarine outfall in 1978 reduced metal concentrations in subsequently deposited sediments since, thereafter, urban and industrial wastes have been dumped out of the estuary. This study also shows that evaluating the quality of sediments on the basis of surface concentrations may be misleading.     

Source characterization and spatio–temporal evolution of the metal pollution in the sediments of the Basque estuaries (Bay of Biscay)

According to Water Framework Directive requirements, Member States must identify and analyze effects derived from human pressures in aquatic systems. As different kind of pressures can impact water bodies at different scales, analyses of spatio-temporal evolution of water bodies becomes essential in order to understand ecosystem responses. In this investigation, an analysis of spatio-temporal evolution of sedimentary metal pollution (Cd, Cr, Cu, Hg, Ni, Pb, Zn) in 12 Basque estuaries (Bay of Biscay) is presented. Data collected in extensive sampling surveys is the basis for the GIS-based statistical approach used. The implementation of pollution abatement measures is reflected in a long-term decontamination process, mostly evident in estuaries with highest historical sediment pollution levels. Spatial evolution is determined by either naturally occurring or human driven processes. Such spatial processes are more obviously being reflected in estuaries with lower historical sediment pollution levels.     

The unified catalogue of earthquakes in central, northern, and northwestern Europe (CENEC)—updated and expanded to the last millennium

New databases motivate improvements and extensions of the catalogue by Grünthal and Wahlström (J Seismol 7:507–531, 2003a) – G&;W03 – of earthquakes in central, northern, and northwestern Europe with M _w?≥?3.50. Data from over 30 regional catalogues, the International Seismological Centre and U.S. National Earthquake Information Center bulletins for the NE Atlantic Ocean, and many special studies were analysed, largely along the lines of the previous study. Non-tectonic, non-seismic, and non-existing as well as duplicate events were identified and removed according to our current stage of knowledge. If not given by the original source, the moment magnitude, M _w, was calculated for each event with a specified epicentral location and a given strength measure (i.e., an original magnitude of any type or, for onshore events only, an intensity). The calculations follow transformation relations derived in the present or in our previous study. The investigated area is subdivided into 22 polygons, in each of which one or more local catalogues, supplemented by data from special studies, are used. If more than one catalogue lists an event, one entry was selected according to a priority algorithm specific for each polygon. If the selected catalogue entry contains more than one strength type, one was selected for the M _w calculation according to another priority scheme. The final catalogue, CENEC, is confined to the time period 1000–2004 and magnitudes M _w?≥?3.50. This is an extension of the time period covered by G&;W03 (1300–1993). The number of events has increased from about 5,000 to about 8,000. For each entry, available information on the date, time, location (including focal depth), intensity I ₀, magnitude M _w, and source (i.e., the local catalogue or special study) are given. The strength type and value from which M _w was calculated are also indicated. The catalogue is available on the website of the GFZ German Research Centre of Geosciences.     

Population declines and heavy metal exposure of Swinhoe’s Storm Petrels (Oceanodroma monorhis) breeding on the southwest coast of Korea

We investigated the population dynamics of globally near-threatened Swinhoe’s Storm Petrels on Kugul and Chilbal islets where >90% of the world breeding population have resided for >25 years. We also determined the levels of six heavy metals in the seabird species as a possible factor affecting reproduction. Of the 892 and 307 marked burrows since 1986, the breeding density of Swinhoe’s Storm Petrels has changed significantly, based on a 55% decline at Kugul islet, and a 39% decline at Chilbal islet, suggesting that this species has suffered an extensive population decline. Of the individuals studied, five Swinhoe’s Storm Petrels and two Streaked Shearwaters had >8.0 μg/g Pb in tissues, which is a potentially lethal level in avian species. Given that substantial changes in their breeding populations may occur in a limited breeding colony, ecological threats including environmental pollutants warrant attention for global conservation of these birds.     

Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors

Abstract

Floods from the middle part of the River Morava (eastern Czech Republic) are considered over the course of the past three centuries, the study being based on data derived from documentary evidence (1691–1880), measured peak water stages, H_k (1881–1920) and peak discharges, Q_k (1916–2009), evaluated with respect to their N-year return period (H_N and Q_N ). Changes in land use and water management (water reservoirs, channel modifications) are discussed, as are factors influencing runoff conditions in the Morava catchment. Decadal synthesis of flood series identifies the highest flood activity in the decades of 1911–1920 and 1961–1970 (11 floods each), 1831–1840, 1891–1900, 1901–1910 and 1931–1940 (10 floods each). Uncertainty in this series is related to some incompleteness of documentary data in the pre-1881 period. Very low flood frequency occurred in the 1990s–2000s, although the most disastrous floods were recorded in this particular period (July 1997 at Q ₁₀₀ and March/April 2006 at Q ₂₀–Q ₅₀). Changes in flood frequency correspond partly to long-term changes in temperature and precipitation patterns.

Citation Brázdil, R., ?ezní?ková, L., Valá?ek, H., Havlí?ek, M., Dobrovolný, P., Soukalová, E., ?ehánek, T. & Skokanová, H. (2011) Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors. Hydrol. Sci. J. 56(3), 468–485.     

Assessment of water and bottom sediment conditions in the bights of Koz’mina and Lake Vtoroe (Nakhodka Gulf,Peter the Great Bay,the Sea of Japan)

The state of the water area in the Bays of Koz’mina and Lake Vtoroe (Nakhodka Gulf is evaluated. The data given include water temperature and salinity, biochemical oxygen demand, pH, alkalinity, chlorophyll a, organic matter, biogenic elements, oil products, detergents, polycyclic aromatic hydrocarbons, phenols, and organochlorine pesticides in water and bottom sediments. Pollutants may enter the system of bights from both onshore sources and the open part of the bay. The water and bottom sediments in this part of the bay show higher values of BOD5 and the concentrations of oil products, polycyclic aromatic hydrocarbons, phenols, and organochlorine pesticides. The anthropogenic load on the water body is shown to increase because of the new industrial construction on its shore.     

Spatial and Temporal Dynamics of Sources and Water Regime of the Ugol’naya-Dionisiya River (Anadyr Lowland,Chukotka)

Water Resources - For the first time, by analyzing the spatial variations and diurnal dynamics of the water regime of the small river of the Anadyr Lowland, the main sources were studied and the...     

Batch and Column Experiments to Support Heavy Metals (Cu,Zn, and Mn) Transport Modeling in Alluvial Sediments Between the Mogan Lake and the Eymir Lake,Gölbaşı, Ankara

This article describes laboratory batch sorption and column transport experiments that were conducted using heterogeneous alluvial sediments with a wide physical characteristic from wells, located between Lake Mogan and Lake Eymir, Gölbaşı, Ankara. The batch sorption experiment was conducted in two separate systems, that is, single and multicomponents. Single batch experiment was performed to determine equilibrium condition between the heavy metal ions and the soil adsorption sites. The sorption isotherms data from multibatch experiments were used to calculate the sorption parameters. Single batch experiment indicated that equilibrium was attained within 9 days from the start of the sorption test. As a result of multicomponents batch experiments, for Zn and Mn, the sorption process was well described by the Freundlich or Langmuir isotherm model, whereas sorption of Cu was better described by the linear isotherm model. The K_d of Cu were found to be highest in soil 1 (32550.350 L kg⁻¹) and lowest in soil 5 (18170.76 L kg⁻¹). The maximum and minimum sorption capacity values for Zn were found to be in soil 1 (10985.148 mg kg⁻¹) and in soil 2 (8597.14 mg kg⁻¹) units, respectively. [Correction added after online publication 15 July, 2010: In the preceding sentence, the words “minimum” and “maximum” were initially switched.] Similarly, soil 1 (7587.391 mg kg⁻¹) and soil 5 (4908.695 mg kg⁻¹) units provided the maximum and minimum values for Mn. In the column experiments, flow and tracer transport was studied under saturated conditions using conservative tracer to determine the transport parameters. Transport parameter values were obtained by curve-fitting using the nonlinear least-squares optimization code CXTFIT. Results of the column experiments indicated that the dispersivity values obtained for soil samples were in the range of 0.024 to 1.13 cm.     

Temporal variations of focal mechanisms in the Novy Kostel focal zone (Vogtland/NW-Bohemia)—comparison of the swarms of 1994, 1997 and 2000

The seismicity in the Vogtland/NW-Bohemia region is mainly characterized by the occurrence of earthquake swarms. A key to a better understanding of the reasons of earthquake swarms can be provided by focal mechanism investigations. Here we present focal mechanisms for 12 of the strongest events (M_L⩾3.0) for the new swarm of 2000. With more than 10,000 events and magnitudes up to 3.7 the new swarm is the most prominent one since the big swarm in 1985/1986. The focal mechanisms of the swarm 2000 show different styles of faulting, namely strike-slip, normal and reverse faulting. There are indications for systematic temporal variations in the dislocation type. A comparison with the mechanisms of the preceding swarms of 1985/1986, 1994 and 1997 which all took place at the same location shows similarities in the faulting types and orientations of the nodal planes for the swarms of 1985/1986, 1994 and 2000. However, the focal mechanisms of 1997 do not fit into the scheme of the others. The focal mechanisms have also been used to determine the regional stress field. It turned out that the stress field in the Vogtland/NW-Bohemia region does not substantially differ from the known stress field in West and Central Europe. It is a strike slip regime with a SE–NW directed σ₁-axis and a NE–SW directed σ₃-axis.     

Basin-scale analysis of rainfall and runoff in Peru (1969–2004): Pacific,Titicaca and Amazonas drainages

Abstract

We present a procedure for estimating Q95 low flows in both gauged and ungauged catchments where Q95 is the flow that is exceeded 95% of the time. For each step of the estimation procedure, a number of alternative methods was tested on the Austrian data set by leave-one-out cross-validation, and the method that performed best was used in the final procedure. To maximise the accuracy of the estimates, we combined relevant sources of information including long streamflow records, short streamflow records, and catchment characteristics, according to data availability. Rather than deriving a single low flow estimate for each catchment, we estimated lower and upper confidence limits to allow local information to be incorporated in a practical application of the procedure. The components of the procedure consist of temporal (climate) adjustments for short records; grouping catchments into eight seasonality-based regions; regional regressions of low flows with catchment characteristics; spatial adjustments for exploiting local streamflow data; and uncertainty assessment. The results are maps of lower and upper confidence limits of low flow discharges for 21 000 sub-catchments in Austria.     

Source parameters of small and moderate earthquakes in the area of the 2009 L’Aquila earthquake sequence (central Italy)

The main goal of this study is to provide moment tensor solutions for small and moderate earthquakes of the 2009 L’Aquila seismic sequence (central Italy). The analysis was performed by using data coming from the permanent Italian seismic network run by the Istituto Nazionale di Geofisica e Vulcanologia (INGV) and the “Cut And Paste” (CAP) method based on broadband waveform inversion. Focal mechanisms, source depths and moment magnitudes are determined through a grid search technique. By allowing time shifts between synthetics and observed data the CAP method reduces dependence of the solution on the assumed velocity model and on earthquake location. We computed seismic moment tensors for 312 earthquakes having local magnitude in the range between 2.7 and 5.9. The CAP method has made possible to considerably expand the database of focal mechanisms from waveform analysis in the lowest magnitude range (i.e. in the neighborhood of magnitude 3) without overlooking the reliability of results. The obtained focal mechanisms generally show NW–SE striking focal planes in agreement with mapped faults in the region. Comparisons with the already published solutions and with seismological and geological information available allowed us to proper interpret the moment tensor solutions in the frame of the seismic sequence evolution and also to furnish additional information about less energetic seismic phases. Focal data were inverted to obtain the seismogenic stress in the study area. Results are compatible with the major tectonic domain. We also obtained a relation between moment and local magnitude suitable for the area and for the available magnitude range.     

Geochemistry of the subduction-related magmatic rocks in the Dahong Mountains, northern Hubei Province——Constraint on the existence and subduction of the eastern Mianle oceanic basin

Being a composite collisional orogen between North China and South China blocks, the Qinling orogenic belt is the key to understand the composite combination, prolonged evolutionary history and their continental dynamics. The main suture between north and south Qinling, called Shangdan suture zone (SDSZ), had been studied in detail for about twenty years. Recently, another suture zone, called Mianl黣 suture zone (MLSZ), has been identified in the Qinling Mountains. It is characterized b…     

Diatoms from Bottom Sediments of Karakel’ Lake (Central Caucasus) and a Reconstruction of Regional Climate Events in the Late Holocene

Data on diatom complexes from bottom deposits of Lake Karakel’ (the Karachayevo-Cherkessian Republic) have been analyzed. The principle of unification of bioindication methods has been applied. The hydrological parameters of lake water (temperature, pH, and saprobithy) have been reconstructed over a period of 2000 years. The results of isotopic dating of bottom sediments have been used. For the first time for the Central Caucasus, the current and Late Holocene diatom alga complexes have been described. Photographs of the most abundant and significant lower taxa of diatom algae are given.     

Geochemical tracing and modeling of surface and deep water–rock interactions in elementary granitic watersheds(Strengbach and Ringelbach CZOs,France)

From the study of the Strengbach and Ringelbach watersheds we propose to illustrate the interest of combining the geochemical tracing and geochemical modeling approaches on surface and deep borehole waters,to decipher the diversity of the water flow and the associated water–rock interactions in such elementary mountainous catchments. The results point to a clear geochemical typology of waters depending on the water circulations(deep vs. hypodermic) within the substratum.