Alkalinity determination in hypersaline solutions: a method for overcoming glass electrode errors

The non-ideality of commercially available glass pH electrode normally used for alkalinity determination by the Gran-type titration has been examined and its effect on the accuracy of the estimated alkalinity evaluated. It is found that slope errors of the glass electrode could be a limiting factor to the accuracy that can be obtained. This error source could be eliminated altogether by applying the proposed ‘slope correction’ algorithm which uses the titration data for in situ slope calibration of the glass electrode. Application of the proposed method eliminates the need for calibration of the glass electrode and the requirement for thermostating the test solution.     

自研高精度pH传感器的标定、校正方法及其在海水原位观测中的应用

电化学方法是测量海水pH值的主要方法之一。针对自主研发的基于铱金属及其氧化物电极的pH传感器,建立了海水环境下仪器标定和数据校正的方法,并在近岸和大洋环境中进行了原位测试的应用。仪器标定包括：(1)依照海水pH分析的标度要求选取适当的标定缓冲试剂;(2)以标准海水替代常用的2-氨基吡啶(AMP)溶液制备标定缓冲体系。数据校正主要包括温度背景校正及误差校正。海区原位测试应用以及与其他同类仪器对比表明,标定体系差异带来的误差可达1.00 pH单位,数据校正可提升测试精度0.10～3.00 pH单位不等。仪器的标定与数据校正方法能有效提高该自研pH传感器的测量精度。     

中国海洋水色遥感器瑞利散射定标研究

水色遥感是海洋环境监测的主要技术手段之一.对于任何海洋水色遥感器来说,监测其在轨期间的定标系数变化是非常重要的,否则无法得到精确的定量产品.以我国“HY-1B”卫星水色遥感器为研究对象,开展了基于大洋水体上空的瑞利散射定标方法研究,利用通过对SeaWiFS数据叶绿素、离水辐亮度和气溶胶产品进行分析,选择了符合条件的7个海区实施大气瑞利散射定标,根据2010年12月份选定的4个区域定标结果得到不同海区/不同时间获得的定标系数一致性较好,CH1至CH6的定标系数标准差分布在0.9％～2.1％的范围内,因此瑞利散射定标是有效的非现场定标方法,具有较高的定标精度,其总误差在4.09％.     

基于荧光猝灭溶解氧传感器的校准方法研究

溶解氧是海洋水质监测的常规关键参数,基于荧光猝灭原理研制的溶解氧传感器具有准确度高、稳定性好和可长期在线测量等优点,已经被广泛用于海水溶解氧浓度监测.针对传感器可能发生的数据漂移和显著偏差可能造成的准确度问题,本文设计了一套专门的校准装置和校准方法.通过严格控制校准水体的温度和溶解氧浓度,测量待校准传感器和参比传感器的...     

基于洋面目标模拟的卫星反射波段观测质量分析初探

卫星观测数据质量是遥感应用的前提,传统的场地定标、交叉定标、稳定目标定标等都只能反映限定观测条件下的卫星数据质量。为了更全面的评估反射波段的观测数据质量,本文提出了一种基于6SV矢量辐射传输模式的全球洋面目标卫星观测模拟,以及基于双差分析的卫星观测质量分析方法,并将该方法应用于FY-3B MERSI,发现FY-3B MERSI可见光波段相对于Aqua MODIS存在系统性偏差和与扫描角相关的偏差特征(主要由偏振影响所致)。相对于传统的定标检验方法,该方法可以提供各种观测几何条件下的全球分析样本,可以发现卫星数据在空间分布、扫描、偏振依赖等方面的质量缺陷。     

基于分形插值技术的MODIS资料几何纠正方法

在讨论了MODIS（Moderate Resolution Imaging Spectroradiometer,中分辨率成像光谱仪）遥感图像几何畸变的成因后,引入了利用MODIS数据间的互补性去除这种“双眼皮”现象的概念,其后采用了分形插值的方法对数据进行重采样。在与其它几何纠正和插值方法进行对比的结果表明,该方法能较好地去除边缘重叠影响,并能保持原有云图的特征和信息,对MODIS资料数据的后续反演工作有一定意义。     

基于Kriging插值方法的MODIS资料几何纠正方法

在讨论了MODIS中分辨率成像光谱仪(Moderate Resolution Imaging Spectroradiometer)遥感图像几何畸变的成因后,文章引入了利用MODIS数据间的互补性去除这种"双眼皮"现象的概念,其后采用了Kriging插值的方法对数据进行重采样.在与其他几何纠正和插值方法进行比对后结果表明,该方法能较好地去除边缘重叠影响,并能保持原有云图的特征和信息,对MODIS资料数据在后续的反演工作中有一定意义.     

The estimation of ocean bottom seismographs' coupling characteristics by means of microshock recordings

A transient technique was used for estimating the bottom-instrument response function in experiments with bottom seismographs (OBS) in deep ocean. The sharp mechanical impacts on bottom seismograph usually induced by bottom displacements under the instrument (microshocks) are suggested as rough analogues of the impulses for the bottom-instrument system transient calibration. It has been found that microshocks has usually sufficiently small duration to be used for coupling characteristics estimates. Test measurements have shown that in many cases this method makes it possible to distinguish spectral features characterising earthquakes and seismic noise wavetrains from those which are caused by coupling resonances of the OBS-sediment inter-face.     

利用南海石油平台的卫星雷达高度计定标与检验

在对南海石油平台所处的南海北部海域海底地形、平均海平面、风浪时空分布等进行分析基础上,利用南海石油平台水位计对Jason-2卫星高度计进行了测高绝对定标,定标结果为30.9 cm±7.8 cm,分析发现南海北部中尺度涡可能对定标结果产生影响;利用南海石油平台测波雷达对Jason-1高度计有效波高进行了精度检验,Jason-1高度计Ku波段和C波段有效波高测量的均方根误差分别为0.43 m和0.45 m。分析和检验结果表明,南海石油平台所处海洋环境条件、平台上装载的水位计和测波雷达均满足卫星雷达高度计定标与检验要求。南海石油平台定标场预期可用于中国海洋二号卫星和其他卫星高度计的定标与检验。     

Preliminary calibration results of the HY-2B altimeter’s SSH at China’s Wanshan calibration site

Satellite altimeter needs to be calibrated to evaluate the accuracy of sea surface height data. The dedicated altimeter calibration field needs to establish a special calibration strategy and needs to evaluate its calibration ability. This paper describes absolute calibration of HY-2B altimeter SSH using the GPS calibration method at the newly Wanshan calibration site, located in the Wanshan Islands, China. There are two HY-2B altimeter passes across the Wanshan calibration site. Pass No. 362 is descending and the ground track passes the east of Dan’gan Island. Pass No. 375 is ascending and crosses the Zhiwan Island. The GPS data processing strategy of Wanshan calibration site was established and the accuracy of GPS calibration method of Wanshan calibration site was evaluated. Meanwhile, the processing strategies of the HY-2B altimeter for the Wanshan calibration site were established, and a dedicated geoid model data were used to benefit the calibration accuracy. The time-averaged HY-2B altimeter bias was approximately 2.12 cm with a standard deviation of 2.08 cm. The performance of the HY-2B correction microwave radiometer was also evaluated in terms of the wet troposphere path delay and showed a mean difference ?0.2 cm with a 1.4 cm standard deviation with respect to the in situ GPS radiosonde.