An H<Subscript>2</Subscript>O maser in the infrared source IRAS 20126+4104

Results of monitoring of H₂O maser in the infrared source IRAS 20126+4104, which is associated with a cool molecular cloud, are presented. The observations were carried out on the 22-meter radio telescope of the Pushchino Radio Astronomy Observatory (Russia) between June 1991 and January 2006. The spectrum of the H₂O maser emission extends from ? 16.7 to 4.8 km/s and splits into separate groups of emission features. Cyclic variations of the integrated maser flux with a period from 3.4 to 5.5 years were detected, together with strong flares of up to 220 Jy in individual emission features. It is shown that large linewidths in periods of high maser activity are due to small-scale turbulent motions of the material. An expanding envelope around a young star is accepted as a model for the source. The protostar has a small peculiar velocity with respect to the molecular cloud (～2 km/s). Individual emission features form organized structures, including multi-link chains.     

Evolution of selected components of the H<Subscript>2</Subscript>O maser in Sgr B2

We present the results of a variability study of some H₂O maser-emission components of Sgr B2, which is located in an active star-forming region. Our monitoring was conducted in 1982–2004 with the 22-m radio telescope of the Pushchino Radio Astronomy Observatory. We analyze brightness variations for the strongest groups of emission features in the H₂O spectra, mainly during periods of maser flaring activity. Each of these groups contains many components, whose radial velocities and fluxes we determined. Most of the components displayed radial-velocity drifts. We detected a correlation between the flux and radial-velocity variations for some of the components. Variability of the emission can be explained in a model in which the maser spots form elongated chains and filaments with radial-velocity gradients. During H₂O flares, the flux increases of some maser spots were accompanied by acceleration, while flux decreases were accompanied by deceleration of their motion in the dense circumstellar matter. Spectral groups of emission features are probably spatially compact structures.     

Evolution of the H<Subscript>2</Subscript>O and OH Maser Emission in W75 N

The results of a study of H₂O and OH maser emission in the complex region of active star formation W75 N are presented. Observations were obtained using the 22-m radio telescope of the Pushchino Radio Astronomy Observatory (Russia) and the Nan3ay radio telescope (France). Flaring H₂O maser features may be identified with maser spots associated with the sources VLA 1 and VLA 2. Themain H₂O flares occurred in VLA 1. The flare emission was associated with either maser clusters having closely spaced radial velocities and sizes up to ~2 AU or individual features. The maser emission is generated in a medium where turbulence on various scales is present. Analysis of the line shapes during flare maxima does not indicate the presence of the simplest structures—homogeneous maser condensations. Strong variability of the OH maser emission was observed. Zeeman splitting of the 1665-MHz line was detected for several features of the same cluster at a radial velocity of +5.5 km/s. The mean line-of-sight magnetic field in this cluster is ~0.5 mG, directed away from the observer. Flares of the OH masers may be due to gas compression at a shock or MHD wave front.     

A strong flare of the H<Subscript>2</Subscript>O maser in Sagittarius B2(M)

Results of a study of a strong flare of H₂O maser emission in the star-forming region Sgr B2(M) in 2004 are reported. The observations were carried out on the 22-m radio telescope of the Pushchino Radio Astronomy Observatory. The main emission, with its flux density reaching 3800 Jy, was concentrated in a narrow radial-velocity interval (about 3 km/s) and was most likely associated with the compact group r, while the emission at V_LSR > 64 km/s came from group q. After 1994, the variations of the H₂O maser emission in Sgr B2(M) became cyclic with a mean period of 3 years.     

The evolution of H<Subscript>2</Subscript>O maser spots in star-forming regions

Strong flares of the H₂O maser emission in sources associated with active star-forming regions are analyzed. The main characteristics of 13 flares in nine sources selected using special criteria are presented. The observed phenomena are explained as flares in double emission features. The approach of two emission features in the spectrum with increasing flux and their recession with decreasing flux is explained using a model with two physically related clumps of material that are partially superposed in the line of sight. Calculations have shown that, in this type of model, exponential amplification (unsaturated maser emission) in the overlapping parts of the clumps can produce the observed line narrowing with increasing flux. In most cases, the maser spots are inhomogeneous. During the evolution of some flares, the maser condensations may split into separate fragments. A less catastrophic evolutionary path may be an initial stage of formation of chainlike structures, which are fairly widespread in envelopes around ultracompact HII regions.     

Observations of Extended Green Objects in the 1.35-cm H<Subscript>2</Subscript>O Line on the 22-m Pushchino Radio Telescope

Observations of H₂O maser sources at 1.35 cm associated with extended regions of 4.5-µm emission (indicated as “green” on Spitzer survey maps—so-called Extended Green Objects, EGOs) are reported. EGOs are considered as characteristic signposts of regions of formation of massive stars, which host high-velocity outflows, as well as methanol, water, and hydroxyl masers. The observations were carried out in January–May 2015 on the 22-meter radio telescope of the Pushchino Radio Astronomy Observatory. The sample studied includes 24 EGOs north of declination -29° taken from the Spitzer GLIMPSE survey, together with one of the brightest Class I methanol masers G6.05-1.45 (M8E) and the Class I methanol maser in an IRDC G359.94+0.17. H₂O maser emission was detected toward 11 of the EGOs: G11.94-0.62, G14.33-0.64, G16.59-0.06, G23.01-0.41, G24.943+0.074, G28.83-0.25, G34.3+0.2, G34.403+0.233, G35.20-0.74, G45.47+0.07, and G49.267-0.337. These including the well known H₂O maser in the W44 region, G34.3+0.2. H₂O emission from G28.83-0.25 was detected for the first time, at 77.6 km/s, with a flux density of 19 Jy in January and 16 Jy in February 2015. The source was probably caught at an early stage of the propagation of a shock wave. The Class I methanol masers G359.94+0.17 and G6.05-1.45 (M8E) and 13 of the EGOs were not detected in the H₂O line, with 3s upper limits of ~6-7 Jy. Spectra and maser-emission parameters are given for the detected H₂Omasers, for some of which strong variability of the H₂O maser emission was observed. The detected H₂Omasers, together with the Class I methanol masers and extended 4.5-µm emission, are associated with a very early stage in the development of young stellar objects in the regions of the EGOs. However, this sample of EGOs is not uniform. The presence of 44-GHz Class I methanol masers together with EGOs cannot be considered the only sign of early stages of star formation.     

Evolution of the H<Subscript>2</Subscript>O Maser Emission Zone in ON2 N

Results of a multi-faceted study of the H₂O maser emission in the region ON2 N carried out on the Very Large Array (VLA, NRAO) and 22-m radio telescope of the Pushchino Radio Astronomy Observatory are reported. The envelope around the ultracompact HII region is fairly extended and has a composite, strongly fragmented structure. The maser emission zone consists of single spots and spot clusters arranged along an arc, which is associated with a ram shock front. This shock front is nonsta-tionary, and its position changes with time. The front position probably depends on the state of activity of the central star. There can be turbulent motions of material in clusters as well as individual maser spots (such as turbulent vortices). In the turbulent-vortex model, the size of an H₂O maser spot is estimated to be 0.07–0.1 AU. Flux-correlated radial-velocity drifts of emission features have been detected, which can be accompanied by spatial displacement (proper motion) of maser spots.     

Maser emission toward the very young massive star GH2O 092.67+03.07 (IRAS 21078+5211)

Results of monitoring of the H₂O maser observed toward the infrared source IRAS 21078+5211 in the giant molecular cloud Cygnus OB7 are presented. The observations were carried out on the 22-m radio telescope of the Pushchino Radio Astronomy Observatory (Russia) from April 1992 to March 2006. Five cycles of maser activity at various levels were observed. In the periods of highest activity, the spectrum of the H₂O maser emission extended from ?43 to 12 km/s. During strong flares, the flux densities in some emission features reached nearly 600 Jy. The protostar has a small peculiar velocity with respect to the CO molecular cloud (～2 km/s). Based on the character of the radial-velocity variations and the tendency for the linewidth to increase with the flux, it is concluded that the medium is strongly fragmented and that there is a small-scale turbulent outflow of ga in the H₂O maser region, which may impede the formation of an HII region. The asymmetric distribution of the maser components in V _LSR, the difference in the average linewidths of the central and lateral clusters of components, and the fairly high radial velocities relative to the molecular cloud (especially during periods of the highest maser activity) suggest that the maser spots belong to different clusters and different structures of the source: a disk and bipolar outflow.     

Triplet spectra of H<Subscript>2</Subscript>O masers and protoplanetary disks

An analysis of the H₂O maser emission associated with protoplanetary disks is presented. Triplet H₂O spectra can be formed at certain stages in the evolution of Keplerian disks. The dependence of the mass of the central star in the Keplerian disk on the disk radius is derived. The calculations are based on the distribution of the water-vapor molecules (maser spots). In S140, the observed elongated maser spots (chains) with a smoothly varying line-of-sight velocity are interpreted as protoplanetary structures with a small intrinsic rotation.     

Observations of OH and H<Subscript>2</Subscript>O Maser Emission in the Star-Forming Region S128

Results of monitoring hydroxyl and water masers in the star-forming region S128 are presented. A large number of emission features in the 1665 MHz OH line have been detected in both circular polarizations. In spite of the strong variability of the flux density in the main 1665 MHz line, the radial velocities of the features remained constant. Zeeman splitting of the 1720MHz line equal to 0.86 km/s was detected, corresponding to a longitudinal magnetic field of 3.6 mG. The variability of the H²O emission has a cyclic character with a quasi-period of 4–14 yrs. The evolution of individual features confirms that the H²O sources A and B are associated with an ionization front between two colliding CO clouds, and shows that the activity was transferred from maser B to maser A in 1999–2001.     

Search for H<Subscript>2</Subscript>O Maser Flares in Regions of Formation of Massive Stars

Results of systematic observations of a sample of bright H₂O maser sources with fluxes, on average, exceeding 200 Jy in their main spectral feature during April–September 2017 (G25.65+1.05, G25.825?0.178, G27.184?0.082, G34.403+0.233, G35.20?0.74, G43.8?0.13, G107.30+5.64) are presented. These observations were carried out in preparation for Very Long Baseline Interferometry observations with an array including the Crimean Astrophysical Observatory 22-m radio telescope. All these sources display fairly strong variability during the time interval considered, encompassing fluxes from ～40 to ～2300 Jy. A flare reaching ～17 000 Jy was detected at a velocity of 42.8 km/s in G25.65+1.05 on September 7, 2017, which subsequently grew to 60 000 Jy at the end of September 2017. This suggests the presence of compact maser structures. The velocities covered by various spectral components range from 5 to 20 km/s. In three sources (G25.65+1.05,G25.825?0.178,G35.20?0.74), a general growth in the fluxes of all the spectral features is observed, which may indicate variations in the conditions for pumping by an external source, for example, variations in the infrared flux from a central source or the passage of a shock. Possible evidence for the presence of bipolar outflows or disk structures in G25.65+1.05 is discussed.     

Variability of the OH and H<Subscript>2</Subscript>O maser emission toward AS 501

The results of observations of OH (λ = 18 cm) and H₂O (λ = 1.35 cm) masers toward AS 501 obtained with the Nançay Observatory Radio Telescope (France) and the 22-m radio telescope of the Pushchino Radio Astronomy Observatory (Russia), respectively, are presented. Nine cycles of H₂O maser activity ranging from 2.8 to 6.0 years were detected, identifying AS 501 as an irregular variable star. Zeeman splitting was found only in the 1612-MHz satellite line at ?59.2 km/s. The splitting is 0.11 km/s, corresponding to a line-of-sight magnetic field strength of 0.48 mG. The field is directed toward the observer. The detected radial-velocity drift of the H₂O emission features can be explained in a model with elongated filaments with radial-velocity gradients.     

Chain-type structure in the H<Subscript>2</Subscript>O maser NGC 7538N

An analysis of the H₂O maser emission toward the source NGC 7538N, which is associated with an active star-forming region, is reported. The analysis is based on 24 years of monitoring in the 1.35-cm line using the the 22-m radio telescope of the Pushchino Radio Astronomy Observatory in 1981–2005 with a spectral resolution of 0.101 km/s. Individual spectral components have been isolated, and temporal drifts in their radial velocities found. From time to time, the drifts were accompanied by velocity jumps. This can be explained if there are chains consisting of clumps of material that are elongated in the radial direction toward the star and have a radial-velocity gradient. In 1982–2005, two maser activity cycles were observed, during which the chains were activated. We propose that shocks consecutively cross the chain elements and excite maser emission in them. The longest chain, at a radial velocity of ?58 km/s, has not fewer than 15 links. For a shock velocity of 15 km/s, the chain step is estimated to be ≤1.5 AU. The chains could be located in a circumstellar disk with a width of ≤10¹⁵ cm. A structure in the form of a rotating nonuniform vortex with the rotation period of about 1.6 years has also been detected. The translational motion of the vortex may be a consequence of its orbital motion within the protoplanetary disk.     

Crystal chemistry of selenates with mineral-like structures. III. Heteropolyhedral chains in the crystal structure of [Mg(H<Subscript>2</Subscript>O)<Subscript>4</Subscript>(SeO<Subscript>4</Subscript>)]<Subscript>2</Subscript>(H<Subscript>2</Subscript>O)

The crystal structure of a new compound [Mg(H₂O)₄(SeO₄)]₂(H₂O) (monoclinic, P2 ₁/a, a = 7.2549(12), b = 20.059(5), c = 10.3934(17) Å, β = 101.989(13), V = 1479.5(5) ų) has been solved by direct methods and refined to R ₁ = 0.059 for 2577 observed reflections with |F _hkl | ≥ 4σ|F _hkl |. The structure consists of [Mg(H₂O)₄(SeO₄)]⁰ chains formed by alternating corner-sharing Mg octahedrons and (SeO₄)^2? tetrahedrons. O atoms of Mg octahedrons that are shared with selenate tetrahedrons are in a trans orientation. The heteropoly-hedral octahedral-tetrahedral chains are parallel to the c axis and undulate within the (010) plane. The adjacent chains are linked by hydrogen bonds involving H₂O molecules not bound with M²⁺ cations.     

Volatile (H<Subscript>2</Subscript>O,CO<Subscript>2</Subscript>, Cl,S) budget of the Central American subduction zone

After more than a decade of multidisciplinary studies of the Central American subduction zone mainly in the framework of two large research programmes, the US MARGINS program and the German Collaborative Research Center SFB 574, we here review and interpret the data pertinent to quantify the cycling of mineral-bound volatiles (H₂O, CO₂, Cl, S) through this subduction system. For input-flux calculations, we divide the Middle America Trench into four segments differing in convergence rate and slab lithological profiles, use the latest evidence for mantle serpentinization of the Cocos slab approaching the trench, and for the first time explicitly include subduction erosion of forearc basement. Resulting input fluxes are 40–62 (53) Tg/Ma/m H₂O, 7.8–11.4 (9.3) Tg/Ma/m CO₂, 1.3–1.9 (1.6) Tg/Ma/m Cl, and 1.3–2.1 (1.6) Tg/Ma/m S (bracketed are mean values for entire trench length). Output by cold seeps on the forearc amounts to 0.625–1.25 Tg/Ma/m H₂O partly derived from the slab sediments as determined by geochemical analyses of fluids and carbonates. The major volatile output occurs at the Central American volcanic arc that is divided into ten arc segments by dextral strike-slip tectonics. Based on volcanic edifice and widespread tephra volumes as well as calculated parental magma masses needed to form observed evolved compositions, we determine long-term (10⁵ years) average magma and K₂O fluxes for each of the ten segments as 32–242 (106) Tg/Ma/m magma and 0.28–2.91 (1.38) Tg/Ma/m K₂O (bracketed are mean values for entire Central American volcanic arc length). Volatile/K₂O concentration ratios derived from melt inclusion analyses and petrologic modelling then allow to calculate volatile fluxes as 1.02–14.3 (6.2) Tg/Ma/m H₂O, 0.02–0.45 (0.17) Tg/Ma/m CO₂, and 0.07–0.34 (0.22) Tg/Ma/m Cl. The same approach yields long-term sulfur fluxes of 0.12–1.08 (0.54) Tg/Ma/m while present-day open-vent SO₂-flux monitoring yields 0.06–2.37 (0.83) Tg/Ma/m S. Input–output comparisons show that the arc water fluxes only account for up to 40 % of the input even if we include an “invisible” plutonic component constrained by crustal growth. With 20–30 % of the H₂O input transferred into the deeper mantle as suggested by petrologic modeling, there remains a deficiency of, say, 30–40 % in the water budget. At least some of this water is transferred into two upper-plate regions of low seismic velocity and electrical resistivity whose sizes vary along arc: one region widely envelopes the melt ascent paths from slab top to arc and the other extends obliquely from the slab below the forearc to below the arc. Whether these reservoirs are transient or steady remains unknown.     

The H<Subscript>2</Subscript>O supermaser region in Orion KL: Epoch 1982.9

Radio interferometric observations of an H₂O maser flare in the Orion Nebula at epoch 1982.9 have been used to determine the flare’s spatial structure. Antennas in the Crimea, Effelsberg, and Onsala were used. The emission region consists of three groups of components. The angular sizes of the components are 0.2–0.9 mas, and the widths of the emitted lines are 0.2–0.7 km/s. The velocities of the components are correlated with their relative positions, which correspond to expanding concentric rings. Assuming a 1 M_⊙ protostar in a Keplerian approximation, the radius of the inner ring R is 15 AU, the velocity of its rotation V_rot is 8.98 km/s, and the radial component of the velocity V_rad is 1.79 km/s. For the outer ring, R=15.7 AU, V_rot=8.79 km/s, and V_rad=2.61 km/s.     

Evolution of the H2O maser emission in G10.6-0.4

The water-vapor maser emission in the source G10.6-0.4 associated with an active starforming region (OB star cluster) is analyzed. The maser was monitored from 1981–2004 using the 22-meter radio telescope of the Pushchino Radio Astronomy Observatory. Statistical processing of the results revealed the presence of structural formations on various scales. The individual H₂O maser features may form ordered structures with velocity (V _LSR) gradients, localized in separate clusters of maser features. The statistical variations of the V _LSR values for the maser components may be due to the accretion of material onto the OB star cluster in G10.6-0.4 together with the rotation of the molecular cloud core. A model with a rotating, nonuniform condensation of accreted material in the vicinity of the stellar cluster is proposed to explain the variations of the velocity centroid of the H₂O spectra. The integrated flux variations are explained well by a model in which the central source is an OB star cluster, possibly containing five to six stars. An important role in the evolution of the maser emission, as well as of the source as a whole, may be played by turbulent motions of the gas.     

H<Subscript>2</Subscript>O masers and protoplanetary disk dynamics in IC 1396 N

We report H₂O maser line observations of the bright-rimmed globule IC 1396 N using a ground-space interferometer with the 10-m RadioAstron radio telescope as the space-based element. The source was not detected on projected baselines >2.3. Earth diameters, which indicates a lower limit on the maser size of L > 0.03 AU and an upper limit on the brightness temperature of 6.25 × 10¹² K. Fringe-rate maps are prepared based on data from ground-ground baselines. Positions, velocities and flux densities of maser spots were determined. Multiple low-velocity features from ?4.5 km/s to +0.7 km/s are seen, and two high-velocity features of V _LSR = ?9.4 km/s and V _LSR = +4.4 km/s are found at projected distances of 157 AU and 70 AU, respectively, from the strongest low-velocity feature at V _LSR = ~+0.3 km/s. Maser components from the central part of the spectrum fall into four velocity groups but into three spatial groups. Three spatial groups of low-velocity features detected in the 2014 observations are arranged in a linear structure about ~200 AU in length. Two of these groups were not detected in 1996 and possibly are jets which formed between 1996 and 2014. The putative jet seems to have changed direction in 18 years, which we explain by the precession of the jet under the influence of the gravity of material surrounding the globule. The jet collimation can be provided by a circumstellar protoplanetary disk. There is a straight line orientation in the “V _LSR-Right Ascension” diagram between the jet and the maser group at V _LSR = ~+0.3 km/s. However, the central group with the same position but at the velocity V _LSR ~ ?3.4 km/s falls on a straight line between two high-velocity components detected in 2014. Comparison of the low-velocity positions from 2014 and 1996, based on the same V _LSR-Right Ascension diagram for low-velocity features, shows that the majority of the masers maintain their positions near the central velocity V _LSR = ~0.3 km/s during the 18 year period.     

The effect of alkalis and polymerization on the solubility of H<Subscript>2</Subscript>O and CO<Subscript>2</Subscript> in alkali-rich silicate melts

The effect of alkalis on the solubility of H₂O and CO₂ in alkali-rich silicate melts was investigated at 500 MPa and 1,250 °C in the systems with H₂O/(H₂O + CO₂) ratio varying from 0 to 1. Using a synthetic analog of phonotephritic magma from Alban Hills (AH1) as a base composition, the Na/(Na + K) ratio was varied from 0.28 (AH1) to 0.60 (AH2) and 0.85 (AH3) at roughly constant total alkali content. The obtained results were compared with the data for shoshonitic and latitic melts having similar total alkali content but different structural characteristics, e.g., NBO/T parameter (the ratio of non-bridging oxygens over tetrahedrally coordinated cations), as those of the AH compositions. Little variation was observed in H₂O solubility (melt equilibrated with pure H₂O fluid) for the whole compositional range in this study with values ranging between 9.7 and 10.2 wt. As previously shown, the maximum CO₂ content in melts equilibrated with CO₂-rich fluids increases strongly with the NBO/T from 0.29 wt % for latite (NBO/T = 0.17) to 0.45 wt % for shoshonite (NBO/T = 0.38) to 0.90 wt % for AH2 (NBO/T = 0.55). The highest CO₂ contents determined for AH3 and AH1 are 1.18 ± 0.05 wt % and 0.86 ± 0.12 wt %, respectively, indicating that Na is promoting carbonate incorporation stronger than potassium. At near constant NBO/T, CO₂ solubility increases from 0.86 ± 0.12 wt % in AH1 [Na/(Na + K)] = 0.28, to 1.18 ± 0.05 wt % in AH3 [Na/(Na + K)] = 0.85, suggesting that Na favors CO₂ solubility on an equimolar basis. An empirical equation is proposed to predict the maximum CO₂ solubility at 500 MPa and 1,100–1,300 °C in various silicate melts as a function of the NBO/T, (Na + K)/∑cations and Na/(Na + K) parameters: \({\text{wt}}\% \;{\text{CO}}_{2} = - 0.246 + 0.014\exp \left( {6.995 \cdot \frac{\text{NBO}}{T}} \right) + 3.150 \cdot \frac{{{\text{Na}} + {\text{K}}}}{{\varSigma {\text{cations}}}} + 0.222 \cdot \frac{\text{Na}}{{{\text{Na}} + {\text{K}}}}.\) This model is valid for melt compositions with NBO/T between 0.0 and 0.6, (Na + K)/∑cation between 0.08 and 0.36 and Na/(Na + K) ratio from 0.25 to 0.95 at oxygen fugacities around the quartz–fayalite–magnetite buffer and above.     

Experimental determination of liquidus H<Subscript>2</Subscript>O contents of haplogranite at deep-crustal conditions

The liquidus water content of a haplogranite melt at high pressure (P) and temperature (T) is important, because it is a key parameter for constraining the volume of granite that could be produced by melting of the deep crust. Previous estimates based on melting experiments at low P (≤0.5 GPa) show substantial scatter when extrapolated to deep crustal P and T (700–1000 °C, 0.6–1.5 GPa). To improve the high-P constraints on H₂O concentration at the granite liquidus, we performed experiments in a piston–cylinder apparatus at 1.0 GPa using a range of haplogranite compositions in the albite (Ab: NaAlSi₃O₈)—orthoclase (Or: KAlSi₃O₈)—quartz (Qz: SiO₂)—H₂O system. We used equal weight fractions of the feldspar components and varied the Qz between 20 and 30 wt%. In each experiment, synthetic granitic composition glass + H₂O was homogenized well above the liquidus T, and T was lowered by increments until quartz and alkali feldspar crystalized from the liquid. To establish reversed equilibrium, we crystallized the homogenized melt at the lower T and then raised T until we found that the crystalline phases were completely resorbed into the liquid. The reversed liquidus minimum temperatures at 3.0, 4.1, 5.8, 8.0, and 12.0 wt% H₂O are 935–985, 875–900, 775–800, 725–775, and 650–675 °C, respectively. Quenched charges were analyzed by petrographic microscope, scanning electron microscope (SEM), X-ray diffraction (XRD), and electron microprobe analysis (EMPA). The equation for the reversed haplogranite liquidus minimum curve for Ab_36.25Or_36.25Qz_27.5 (wt% basis) at 1.0 GPa is \(T = - 0.0995 w_{{{\text{H}}_{ 2} {\text{O}}}}^{ 3} + 5.0242w_{{{\text{H}}_{ 2} {\text{O}}}}^{ 2} - 88.183 w_{{{\text{H}}_{ 2} {\text{O}}}} + 1171.0\) for \(0 \le w_{{{\text{H}}_{ 2} {\text{O}}}} \le 17\) wt% and \(T\) is in °C. We present a revised \(P - T\) diagram of liquidus minimum H₂O isopleths which integrates data from previous determinations of vapor-saturated melting and the lower pressure vapor-undersaturated melting studies conducted by other workers on the haplogranite system. For lower H₂O (<5.8 wt%) and higher temperature, our results plot on the high end of the extrapolated water contents at liquidus minima when compared to the previous estimates. As a consequence, amounts of metaluminous granites that can be produced from lower crustal biotite–amphibole gneisses by dehydration melting are more restricted than previously thought.