内蒙古东乌旗巴彦都兰二长花岗岩年代学、地球化学特征及其地质意义

为了解晚古生代西伯利亚板块南缘增生造山过程中的岩浆活动特征,对东乌旗巴彦都兰二长花岗岩岩相学、锆石U-Pb年代学、锆石Hf同位素和岩石地球化学进行了研究,并讨论了岩石成因和构造环境。锆石LA-ICP-MS U-Pb定年结果为(277.2±0.7)Ma,以正的锆石εHf(t)(6.8~14.1)为特征,具有年轻的锆石地壳模式年龄(tcDM)(865~655 Ma),属于早二叠世晚期岩浆活动产物。二长花岗岩以高钾[w(K)=3.63%~4.95%,K2O/Na2O=0.91~1.47]、富碱[w(K2O+Na2O)=7.52%~9.16%]、准铝质-弱过铝质(A/CNK=0.96~1.15)为特征;稀土元素总量较低(38.82×10-6~193.20×10-6),(La/Yb)N为3.91~23.08,轻、重稀土元素分异较明显,呈弱负铕异常(δEu为0.34~1.17);富集部分大离子亲石元素(LREE、Rb、K等);Zr弱负异常、Hf弱正异常,亏损Sr、Nb、Ta、P、Ti,显示后造山花岗岩特征。综合分析表明,巴彦都兰二长花岗岩形成于伸展的构造环境中,是贺根山洋盆闭合后的后造山阶段产物,为865~655 Ma前洋壳俯冲形成的先成地壳部分熔融而成。     

广东莲花山花岗岩体锆石U-Pb年龄、地球化学特征及地质意义

广东莲花山岩体位于莲花山断裂带北部, 由规模巨大的侏罗—白垩纪花岗岩组成。本文对莲花山岩体中部进行了系统的岩石学、地球化学、锆石U-Pb同位素和Lu-Hf同位素研究, 获得片麻状花岗岩、细粒黑云母花岗岩和细-中粒黑云母花岗岩的锆石206Pb/238U年龄分别为(142.5±1.5) Ma(MWSD=3.5, N=30)、(138.9±0.6) Ma(MWSD=1.4, N=30)和(145.5±0.7) Ma(MWSD=1.2, N=28), 表明岩体为晚侏罗至早白垩世岩浆活动的产物。地球化学特征显示岩体为偏铝质-弱过铝质(A/CNK=0.97~1.1)、富碱(K2O+Na2O=6.1 wt%~ 8.1 wt%)、富钾(K2O/Na2O=1.4~1.8), 富集Rb、Th、U、K、Pb, 亏损Ba、Ta、Nb、Sr、P、Ti, 与壳源岩浆特征类似。岩体SiO2含量差异较大(69.5 wt%~80.1 wt%), 高硅样品明显经历一定程度的结晶分异, 属于分异的I型花岗岩。所有样品锆石εHf(t)值均为负值(–4.5 ~ –2.0), 在年龄-εHf(t)图中, 均落入球粒陨石演化线和华夏基底演化线之间, 暗示源岩主要为古老壳源基底物质。在此基础上, 结合区域构造-岩浆记录, 本文认为莲花山花岗岩体的形成与古太平洋板片俯冲后撤(roll back)诱发的弧后扩张作用相关。     

西藏南木林晚白垩世辉绿岩与花岗质脉岩成因及其揭示的伸展背景

青藏高原南部拉萨地块晚白垩世岩浆岩带的岩石成因和动力学对于揭示大陆碰撞之前的特提斯演化过程具有重要意义。本文报道了南木林县南部的辉绿岩岩株及侵入其中的正长花岗岩脉的锆石U-Pb年龄、Hf同位素和微量元素以及岩石地球化学数据,并探讨了晚白垩世构造-岩浆作用过程。辉绿岩年龄为93.8Ma,正长花岗岩脉年龄为92.4Ma,为同期晚白垩世岩浆活动产物。辉绿岩富集大离子亲石元素,亏损高场强元素,锆石εHf(t)为+8.5~+14.2,具有亏损的岛弧岩浆特征,可能是俯冲交代的地幔楔熔体与软流圈熔体相互作用发生部分熔融的产物;正长花岗岩具有富Si O2(74.76%~76.02%)、富K2O(4.75%~6.18%)、富碱(K2O+Na2O=7.57%~8.44%),以及过铝质特征(A/CNK=1.10~1.18),εHf(t)为+7.7~+13.0,岩石属于高分异的I型花岗岩,可能源于新生的镁铁质下地壳的部分熔融。从南木林地区产出的基性岩和酸性脉岩构成的"双峰式"岩石组合、靠近弧后的伸展构造背景、软流圈和岩石圈的共同参与、上地幔和下地壳同时产生岩浆作用等过程,结合78~100Ma岩浆作用大规模东西向带状分布等研究结果,本文认为南木林南部岩浆岩可能是在新特提斯洋壳北向俯冲挤压的同时,在大约90~100Ma时期,深部发生了板片断离或者板片回转,浅部造成了弧后伸展的构造背景。位于板片窗上方,源于交代地幔楔和软流圈相互作用产生了镁铁质岩浆,上侵后诱发下地壳部分熔融形成花岗质岩浆。基性岩石、花岗质岩石以及特殊类型的紫苏花岗岩、埃达克岩等多种岩石类型并存,表明晚白垩世时期,特提斯洋向着拉萨地块之下的总体俯冲背景下,可能存在洋脊俯冲、板片断离、板片回转等多种构造-岩浆体制。     

江西彭山锡多金属矿集区隐伏花岗岩体的岩石地球化学、锆石U-Pb年代学和Hf同位素组成

本文对江西彭山锡多金属矿集区隐伏花岗岩体进行了详细的锆石U-Pb年代学、Hf同位素组成和岩石地球化学研究。SHRIMP和LA-ICP-MS锆石U-Pb定年表明,该岩体年龄为128~129Ma,属燕山晚期岩浆活动的产物。详细的地球化学分析显示,彭山隐伏花岗岩体具有高硅(SiO2=75.42%~76.46%)、富碱(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)的特征,极度贫Mg(普遍MgO=0~0.07%),贫Ca(CaO=0.37%~0.69%),弱过铝质(A/CNK=1.04~1.11),富集Rb、Th、U等大离子亲石元素及Hf、Nb等高场强元素,强烈亏损Sr、Ba、Eu、P、Ti。稀土总量偏低(∑REE=41.18×10-6~85.06×10-6),强烈的Eu负异常(Eu/Eu*=0.05~0.11)。104×Ga/Al比值变化于2.75~4.04,平均值为3.19。这些特征均不同于典型的A型和S型花岗岩。岩石学和地球化学特征指示该岩体可能是一个高分异的I型花岗岩。该花岗岩中锆石εHf(t)值偏高,主要集中在-0.6~-4.5,显示在成岩过程中有地幔组分的参与,属壳幔混源花岗岩,推测该岩体的形成可能与燕山晚期华南岩石圈伸展拉张环境有关。     

藏东卡贡地区早侏罗世似斑状钾长花岗岩LA-ICP-MS锆石U-Pb年龄及地球化学特征

用LA-ICP-MS技术测得卡贡地区似斑状钾长花岗岩锆石的206Pb/238U年龄为178±2 Ma(MSWD=3.7,n=20),属于早侏罗世的产物。岩石地球化学特征表明,岩石具富碱富钾(K2 O+Na2 O=8.02%~8.76%,K2 O/Na2 O=1.71~2.11)、低铝(Al2O 3=14.08%~14.73%,A/CNK=1.01~1.04),不含透辉石和刚玉分子较低的特征;岩石普遍富集Rb、Th、K、U等大离子亲石元素,明显亏损Ba、Nb、Sr、P、Ti等元素,高场强元素Zr、Nb、Ta含量极低,(Ga/Al)×10^4值为4.48~5.06,Rb/Sr值为1.84~2.29,均显示出岩浆分异程度较高的特征;岩石的形成与俯冲消减作用有关,其构造环境由挤压环境逐渐向相对伸展环境转变,伴随着地壳深部压力减小,幔源岩浆上涌,并与上覆地壳发生部分熔融作用而形成。     

辽东宽甸东北沟钼矿二长花岗岩年代学、地球化学及Hf同位素特征

东北沟钼矿是辽宁宽甸地区近些年发现的大型隐爆角砾岩型钼矿床。文章首次对东北沟钼矿床赋矿围岩二长花岗岩进行LA-MC-ICP-MS锆石U-Pb定年,主量元素、微量元素和Hf同位素地球化学研究,锆石U-Pb定年结果表明,二长花岗岩形成年龄为(129.4±0.3)Ma(MSWD=0.83),为燕山期构造岩浆活动产物。地球化学成分上,岩石具有富硅(SiO_2=62.21%~83.21%)、高钾(K_2O/Na_2O=3.35~20.27)和富碱(K_2O+Na_2O=5.82%~12.23%)的特点,属于钾玄岩系列。岩石富集轻稀土元素(LREE/HREE=10.26~24.21),亏损重稀土元素,具有弱负铕异常(δEu=0.63~1.07),富集大离子亲石元素(如K、Rb、Pb)和不相容元素(如Th、U)的特征,相对亏损高场强元素(如Nb、Ta、P、Ti)。锆石Hf同位素分析结果表明,东北沟钼矿二长花岗岩的ε_(Hf)(t)值为介于-12.4~-8.5,二阶段模式年龄(t_(DM2))介于442~1610 Ma,反映岩浆源区可能来源于中元古界古老地壳的再熔融。结合区域构造演化,成岩成矿构造背景为早白垩世古太平洋板块向欧亚之下俯冲,岩石圈减薄的构造环境。     

东昆仑祁漫塔格虎头崖铅锌多金属矿区花岗岩年代学、地球化学及Hf同位素特征

虎头崖铅锌多金属矿床位于东昆仑祁漫塔格地区,矿区内中酸性侵入岩体广泛发育,且与成矿关系密切。LA-ICP-MS锆石U-Pb同位素年龄测试表明,虎头崖Ⅴ矿带外围花岗闪长岩形成时代为(224.3±0.6)Ma,Ⅷ号矿带矿体下部正长花岗岩形成时代为(239.7±0.8)Ma,岩体形成时代为中—晚三叠世。岩石地球化学表明,花岗闪长岩富钾贫钠(K2O/Na2O为2.02~2.88),无明显负Eu异常(δEu为0.68~1.06),富集Rb、Th、U、K等大离子亲石元素,明显亏损Nb、P、Ti等元素,属I型花岗岩;正长花岗岩具高硅、富碱、低铁镁、贫钙磷钛的特征,负Eu强烈(δEu为0.08~0.26),富集Rb、Th、U、K,亏损P、Ti、Ba、Sr,属高分异I型花岗岩;二者均形成于后碰撞构造背景;Hf同位素组成不均一,指示其经历了壳幔岩浆混合作用,幔源物质的加入可能带来了丰富的成矿物质。     

藏东同普二叠纪高分异花岗岩的锆石U-Pb年龄和岩石成因

对具有富U或高U锆石的高硅花岗岩进行准确定年并进行成因讨论是花岗岩研究中的难题。本文以青藏高原东部江达-维西构造带北部同普岩基边缘相的高硅花岗岩为对象,开展了锆石U-Pb年代学、锆石Hf同位素和全岩元素地球化学研究。采用大激光束斑(100μm)先剥蚀2~3个脉冲的预剥蚀方法,获得了这套含富U或高U锆石高硅花岗岩的可靠锆石UPb年龄(260±1Ma)。这套高硅花岗岩具有高的Si O2含量(74.92%~76.46%)、高的全碱含量(Na2O+K2O;7.61%~8.55%)和高的分异指数(92~96),明显的Eu(Eu/Eu*=0.17~0.41)异常和显著亏损Ba、Nb、Sr、P和Ti等特征,属于典型的高分异花岗岩。本文数据,结合文献数据,指示同普高硅花岗岩为高分异I型花岗岩。富集的锆石Hf同位素组成(εHf(t)=-9.9~-5.8)指示它们来源于古老地壳物质的部分熔融。定量模拟表明它们可能由同期花岗闪长质母岩浆经历斜长石、磷灰石和富钛矿物的分离结晶作用形成。     

江西富城岩体西部过铝质细粒花岗岩锆石U-Pb年龄和地球化学特征

针对江西会昌富城岩体年代学的不同结论,对该岩体西部的细粒花岗岩进行了锆石U-Pb 年代学研究,并分析了细
粒花岗岩和粗粒花岗岩的岩石地球化学和锆石Hf 同位素地球化学特征,探讨了该岩体的成因和构造背景。细粒花岗岩LAICP-
MS 锆石U-Pb 定年结果表明,成岩年龄为219.1~221.5 Ma（平均220 Ma）,为印支期岩浆活动产物;岩石地球化学组成
上表现为高硅（SiO2=71.7%~78.2%）、富碱（K2O+Na2O=7.16%~8.13%,K2O/Na2O=2.00~3.53）、强过铝（A/CNK=1.11~1.26）,贫Ca,Mg; 稀土元素总量较低（ΣREE=72.9×10-6~203.0×10-6),Eu 负亏损强烈, 富集Rb,Cs,K,Pb等大离子亲石元素和Th,U,Ta,Zr等高场强元素,贫Ba,Sr,P,Ti 等元素;综合岩相学和岩石地球化学特征表明该岩体为S型花岗岩。粗粒花岗岩定年结果表明,成岩年龄为227 Ma,也为印支期岩浆活动的产物;岩石地球化学组成上同样表现为高硅
（SiO2=75.1%~76.3%）、富碱（K2O+Na2O=7.39%~8.72%,K2O/Na2O=1.79~2.60）、弱过铝到强过铝（A/CNK=0.9~1.14）,贫Ca,Mg。稀土元素总量较低（ΣREE=125.5×10-6~160.2×10-6）,Eu负亏损强烈,富集Rb,Cs,K,Pb 等大离子亲石元素和Th,U,Ta,Zr 等高场强元素,贫Ba,Sr,P,Ti 等元素;综合岩相学和岩石地球化学特征表明该岩体为S 型花岗岩。同位素组成方面,富城细粒花岗岩体的εHf（t ）值变化于-2.3~-10.8 之间,平均为-7.5,两阶段模式年龄为1.4~1.96 Ga,粗粒花岗岩体的εHf（t ）值变化于-5.0~-19.8之间,平均为-8.8,两阶段模式年龄为1.59~2.51 Ga,表明源岩为元古代壳源富泥质变质组分经过部分熔融,再经过分离结晶作用,在同碰撞构造背景下形成了富城细粒花岗岩和粗粒花岗岩。     

宝鸡花岗岩体锆石U-Pb年龄、地球化学和Hf同位素组成

宝鸡花岗岩体出露于商丹缝合带北部,是秦岭构造带中规模较大的复式深成岩体之一,呈不规则岩基产出。该花岗岩体具有多期次侵位的特征,前人对其岩石地球化学特征及其成因研究相对薄弱,其形成时代存在不同认识。因此,进一步的岩石学、地球化学、年代学和同位素组成研究可以为理解秦岭造山带中生代造山过程和岩浆作用提供基础科学依据。岩石学和地球化学特征表明,宝鸡花岗岩体主体为石英二长岩、二长花岗岩和钾长花岗岩,属亚碱性系列、高钾钙碱性I型花岗岩。其Si O2质量分数为63%~73%,富Al2O3(13.3%~15.6%),相对富K2O,K2O/Na2O比值多数大于1,铝饱和指数(A/CNK)为0.87~1.10,属于准铝质—弱过铝质系列。轻重稀土元素分馏,但程度相对弱,富集大离子亲石元素(如:Rb、Ba、Th、U),亏损高场强元素(如:Nb、Ta、Zr、P、Ti),部分岩石具有高Sr/Y比值,弱Eu负异常。中重稀土元素分馏现象不强烈,且中稀土元素亏损,可能暗示源区没有石榴石残留,而有角闪石残留相。不同类型的花岗岩具有相似的微量、稀土元素组成,暗示相似的源区和或构造环境。本文分析了具有代表性的14个岩石样品的锆石U-Pb年龄。锆石多呈柱状或短柱状,内部振荡环带清晰,Th/U比均大于0.1,具有负Eu异常和正Ce异常,是典型的岩浆成因。锆石U-Pb年龄变化范围较大,195~217 Ma,而且晚期酸性脉体U-Pb年龄~170 Ma。4个样品的锆石Hf同位素分析结果显示,不同期次和不同岩性样品具有不同的Hf同位素组成特征。石英二长岩(217 Ma)初始εHf值为-3.6~+1.1,Hf模式年龄~1.5~1.2 Ga;二长花岗岩(212Ma)初始εHf值为-1.3~+4.4,Hf模式年龄~1.3~1.0 Ga;二长闪长岩(213 Ma)初始εHf值为-15.1~-9.3,Hf模式年龄~2.2~1.8 Ga;晚期钾长花岗岩(196 Ma)初始εHf值变化范围较大,为-18.8~-5.0,Hf模式年龄~2.4~1.6 Ga;表明岩浆源区组成较复杂,具有古老的地壳物质和地幔或新生地壳物质参与。结合同位素年代学和地球化学特征,宝鸡花岗岩复式岩体可能由三期岩浆侵位构成,第一期为石英二长岩,岩浆源区以中、晚元古代壳源岩石为主,有部分幔源组分或新生地壳物质的贡献;第二期为二长花岗岩,原岩以新生地壳或幔源物质为主;第三期钾长花岗岩岩浆源区可能为更古老的地壳物质。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.