Predictions of the electrical conductivity and charging of the aerosols in Titan's atmosphere

The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes between 0 and 400 km. Ionization of methane and nitrogen due to galactic cosmic rays (GCR) is important at night where these ions are converted to ion clusters such as CH⁺₅CH₄, C₇H⁺₇, C₄H⁺₇, and H₄C₇N⁺. The ubiquitous aerosols observed also play an important role in determining the charge distribution in the atmosphere. Because polycyclic aromatic hydrocarbons (PAHs) are expected in Titan's atmosphere and have been observed in the laboratory and found to be electrophilic, we consider the formation of negative ions. During the night, the very smallest molecular complexes accept free electrons to form negative ions. This results in a large reduction of the electron abundance both in the region between 150 and 350 km over that predicted when such aerosols are not considered. During the day time, ionization by photoemission from aerosols irradiated by solar ultraviolet (UV) radiation overwhelms the GCR-produced ionization. The presence of hydrocarbon and nitrile minor constituents substantially reduces the UV flux in the wavelength band from the cutoff of CH₄ at 155 to 200 nm. These aerosols have such a low ionization potential that the bulk of the solar radiation at longer wavelengths is energetic enough to produce a photoionization rate sufficient to create an ionosphere even without galactic cosmic ray (GCR) bombardment. At altitudes below 60 km, the electron and positive ion abundances are influenced by the three-body recombination of ions and electrons. The addition of this reaction significantly reduces the predicted electron abundance over that previously predicted. Our calculations for the dayside show that the peaks of the charge distributions move to larger values as the altitude increases. This variation is the result of the increased UV flux present at the highest altitudes. Clearly, the situation is quite different than that for the night where the peak of the distribution for a particular size is nearly constant with altitude when negative ions are not present. The presence of very small aerosol particles (embryos) may cause the peak of the distribution to decrease from about 8 negative charges to as little as one negative charge or even zero charge. This dependence on altitude will require models of the aerosol formation to change their algorithms to better represent the effect of charged aerosols as a function of altitude. In particular, the charge state will be much higher than previously predicted and it will not be constant with altitude during the day time. Charging of aerosol particles, whether on the dayside or nightside, has a major influence on both the electron abundance and electrical conductivity. The predicted conductivities are within the measurement range of the HASI PWA instrument over most but not all, of the altitude range sampled.     

Upper stratosphere negative ion composition measurements and inferred trace gas abundances

In situ composition measurements of atmospheric negative ions were made at 40.8 km altitude using a balloon-borne mass spectrometer with large mass range and improved mass resolution. The data obtained show marked differences compared to previous data obtained mostly around or below 33 km.It appears that these differences are mostly due to a higher atmospheric temperature, a lower nitric acid vapour abundance and a larger HSO₃-vapour abundance prevailing at the higher altitude.A particularly striking feature is the relatively large fractional abundance of HSO₃-containing cluster ions.Another interesting result is that nitric acid vapour abundances can be inferred from the negative ion composition data with better accuracy than is possible for lower altitudes. The reason being that collisional ion dissociation occurring during ion sampling is less disturbing.The inferred nitric acid vapour abundance for 40.8 km altitude is consistent with current 2-dimensional model calculations.     

Negative ion chemistry in Titan's upper atmosphere

The Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere. The observations at closest approach (∼1000 km) show evidence for negatively charged ions up to ∼10,000 amu/q, as well as two distinct peaks at 22±4 and 44±8 amu/q, and maybe a third one at 82±14 amu/q. We present the first ionospheric model of Titan including negative ion chemistry. We find that dissociative electron attachment to neutral molecules (mostly HCN) initiates the formation of negative ions. The negative charge is then transferred to more acidic molecules such as HC₃N, HC₅N or C₄H₂. Loss occurs through associative detachment with radicals (H and CH₃). We attribute the three low mass peaks observed by ELS to CN⁻, C₃N⁻/C₄H⁻ and C₅N⁻. These species are the first intermediates in the formation of the even larger negative ions observed by ELS, which are most likely the precursors to the aerosols observed at lower altitudes.     

Observed heating effects of conjugate photoelectrons

A gridded spherical electrostatic analyzer aboard Injun 5 has been used to measure fluxes of thermal and hyperthermal electrons at subauroral latitudes in the midnight sector of the northern ionosphere between altitudes of 2500 and 850 km. Due to the offset between the geomagnetic and geographic poles hyperthermal fluxes, consisting of energetic photoelectrons that have escaped from the sunlit southern hemisphere are observed along orbits over the Atlantic Ocean and North America but not over Asia. The ambient electron temperatures (T_e) near 2500 km have their highest values at trough latitudes for all longitudes. At altitudes near 1000 km elevated electron temperatures in the trough were not a consistent feature of the data. Equatorward of the trough, in the longitude sector to which conjugate photoelectrons have access, T_e ～ 4000 K at 2500 km and ～ 3000 K at 1000 km. For regions with the conjugate point in darkness T_e ? 2300 K over the 1000–2500 km altitude range. The effective thermal characteristics of conjugate photoelectrons are studied as functions of altitude and latitude. The observations indicate that (1) at trough latitudes elevated electron temperatures in the topside ionosphere are mostly produced by sources other than conjugate photoelectrons, and (2) at subtrough latitudes, in the Alantic Ocean-North American longitude sector, conjugate photoelectrons contribute significantly to the heating of topside electrons. Much of the conjugate photoelectron energy is deposited at altitudes >2500 km then conducted along magnetic field lines into the ionosphere.     

Three Periods in Asteroid 4197 Brightness Variations

In 1996, photometric observations of the near-Earth asteroid NEA 4197 (1982 TA) were performed at the Crimean Astrophysical Observatory. More than 2000 brightness measurements in the V band were made. The harmonic data analysis at a fairly high significance level revealed two close periods, P ₁= 3^h _.5372 ± 0^h _.0005 (amplitude 0 ^m _.4) and P ₂= 4^h _.367 ± 0^h _.001 (amplitude 0 ^m _.2). The third period, P ₃= 20^h _.26 ± 0^h _.05 (amplitude about 0 ^m _.15), was found at a lower significance level. The conclusion was drawn that the asteroid is a binary system. Its components rotate with the periods P ₁and P ₂, and P ₃is probably related to the orbital motion of the components. Assuming that the diameters of both components are equal to 2 km, the orbital radius equals 4.4 km.     

Observation of the energy distribution of thermal electrons in the midlatitude ionosphere

Results of measurements of the energy distribution of thermal electrons below 1 eV in a midlatitude upper atmosphere are presented and compared with some recent measurements at other places. Measurements are based on the Druyvesteyn method using Langmuir probes.In the periods without solar light, distribution does not depart much from Maxwellian above 0.3 eV. Below 0.2 eV, depletion and sometimes double humps are seen. In the periods with solar light, bumps are sometimes observed on the high energy tail at altitudes between 100 and 160 km. Energy distribution in the F layer above 180 km fits the Maxwellian distribution rather well. The reason for the appearance of such non-thermal electrons at lower altitudes may be due to super-elastic collisions with vibrationally excited nitrogens.     

Observations of outflowing ion beams on auroral field lines at altitudes of many earth radii

The composition, energy and angular characteristics of upward flowing ionospheric ions at altitudes greater than ～ 20,000 km have been studied by means of the PROGNOZ-7 ion composition experiment. Very narrow beams, having widths corresponding to a mirroring altitude of the order a few thousand kilometers or less, may be found up to altitudes exceeding 30,000 km on the nightside. At much higher altitudes and in regions connected to the dayside/flank boundary layer and plasma mantle, the beams are much broader than expected from adiabatic particle motions from an ionospheric source/acceleration region, suggesting that pitch angle scattering or transverse acceleration processes are present there. Considerable mass dispersion effects have also been observed in some upward flowing ionospheric ion beams. The peak energy for the O⁺ ions may differ by several keV compared to that for the H⁺ ions in one and the same ion beam at altitudes above ～ 20,000 km. The O⁺ ions in these beams have gained considerably more energy than H⁺ in the acceleration process. Many examples with a much higher O⁺ than H⁺ content in the beam have been observed. Possible mechanisms giving rise to the observed effects are discussed, one being several kV of potential drop below the neutral H, O-crossover altitude (500–1500 km). At altitudes where the upflowing ionospheric ions are intermixed with magnetosheath ions, mass dispersion effects are also observed. This dispersion often appears to be the result of a velocity filtering effect caused by the dawn-dusk electric field (earthward convection).     

On the structure of Mars' atmosphere at 120–220 km

Altitude dependences of [CO₂] and [CO₂⁺] are deduced from Mariner 6 and 7 CO₂⁺ airglow measurements. CO₂ densities are also obtained from n_e radio occultation measurements. Both [CO₂] profiles are similar and correspond to the model atmosphere of Barth et al. (1972) at 120 km, but at higher altitudes they diverge and at 200–220 km the obtained [CO₂] values are three times less the model. Both the airglow and radio occultation observations show that a correction factor of 2.5 should be included into the values for solar ionization flux given by Hinteregger (1970). The ratio of [CO₂⁺]/n_e is 0.15–0.2 and, hence, [O]/[CO₂] is ～3% at 135 km. An atmospheric and ionospheric model is developed for 120–220 km. The calculated temperature profile is characterized by a value of T ≈ 370°K at h ? 220 km, a steep gradient (～2°/km) at 200-160 km, a bend in the profile at 160 km, a small gradient (～0.7°/km) below and a value of T ≈ 250°K at 120 km. The upper point agrees well with the results of the Lyman-α measurements; the steep gradient may be explained by molecular viscosity dissipation of gravity and acoustical waves (the corresponding energy flux is 4 × 10^?2 erg cm^?2sec^?1 at 180 km). The bend at 160 km may be caused by a sharp decrease of the eddy diffusion coefficient and defines K ≈ 2 × 10⁸cm²sec^?1; and the low gradient gives an estimate of the efficiency of the atmosphere heating by the solar radiation as ? ≈ 0.1.     

Observations of energetic ions in inverted V events

Simultaneous measurements of keV ions and electrons with the ESRO 1A satellite have shown the following ion characteristics among others. Ions of about 6 keV energy are strongly field-aligned on the flanks of the inverted V events (mainly through the disappearance of the ion flux near 90° pitch angle). Field-aligned electron fluxes are often found in the same regions of the inverted V events where the ions are field-aligned. At the centre of inverted V events isotropization occurs (except in some small events). The 1 keV ion flux at large pitch angles (80°) is generally not reduced very much when the 6 keV, 80° ion flux shows strongly decreased values. The ratio of the 1 to 6 keV ion flux has a maximum near the centre of an inverted V event where the electron spectrum is hardest and the 6 keV ions are isotropic (or nearly isotropic).The observations are interpreted in terms of a model with two oppositely directed field-aligned electrostatic potential drops: one upper accelerating electrons downward and one lower, produced by the electron influx, which accelerates ions downward. Ion scattering in turbulent wave fields is proposed to be responsible for the observation that the 1 keV ion flux at large pitch angles does not decrease strongly where the 6 keV ion flux does and as an explanation of the isotropization at the centre of the event. The source problem for the ions is eliminated by the precipitating electrons ionizing continuously the thin neutral atmosphere even at altitudes of a few thousand kilometers.     

A Contribution to the Understanding of Chromospheric Oscillations

We present SUMER/SOHO UV measurements of chromospheric oscillations of intensity, velocity, and linewidth observed in C i, S i, O i, and C ii lines, which are formed in the altitude range from 1000 km to 2000 km above τ ₅₀₀=1. Oscillations in lines originating at similar altitudes exhibit different behaviors which we discuss in terms of the formation of the lines.     

II. Combined numerical model of ion and neutral composition above 120 km

A coupled neutral-ionic photochemical model has been used to interpret the ionic composition of the Venusian dayside ionosphere measured by the orbiter retarding potential analyser (ORPA) experiment on board the NASA Pioneer-Venus orbiter spacecraft. The electron and ion temperatures also measured by the ORPA are used for calculating the plasma-diffusion coefficients and scale heights for ions. The neutral temperature profiles and the densities of neutral constituents, particularly CO₂ and O, play key roles in the determination of the height profiles of the ionic constituents. All these quantities vary substantially in the Venusian thermosphere near the terminator; the models presented are representatives of the solar zenith angle ～65°. The predicted O₂⁺ densities below ～200km agree particularly well with observations by the ORPA, but the model values are significantly less than those measured by the orbiter ion mass spectrometer (OIMS). Models predict much smaller densities than observed values for all molecular ions above ～200km. The reason for the turn-up trend of the concentration gradient of molecular ions observed at these heights by both ORPA and OIMS is unknown. One of the models can predict O⁺ ion densities above ～200km compatible with observations, if an effective vertical escape flux (φ10⁸cm^?2sec^?1) is assumed at the ionopause. The neutral air density required to explain the observed ion composition is about 1.4 times larger than the values measured by the orbiter neutral mass spectrometer (ONMS).     

Predictions of the electrical conductivity and charging of the aerosols in Titan's atmosphere

The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes from 0 to 400 km. Ionization due to both galactic cosmic rays and electron precipitation from the Saturnian magnetosphere is considered. This ionization results in free electrons and the primary ions N₂⁺ and N⁺ which are then rapidly converted into secondary ions such as H₂CN⁺ and NH₄⁺ which in turn form ion clusters such as H₂CN⁺(HCN)_n and NH₄⁺(NH₃)_m. In contrast to the atmospheres of Venus and Earth, we find no species in the Titan atmosphere that lead to the formation of appreciable concentrations of negative ions. Consequently, the predicted conductivity is quite different in that a substantial concentration of electrons exists all the way to the surface of Titan. The ubiquitous aerosols observed in the Titan atmosphere also play an important role in determining the charge distribution in the atmosphere. At altitudes above 100 km and for aerosol concentrations above approximately 10/cc, the recombination of electrons and positive ions is controlled by the recombination on the surface of the aerosols rather than by the gas-kinetic recombination rate. For small aerosol concentrations, the ratio of the number of charges per particle to the radius of the particle is approximately 30, for radii in microns. This value is similar to that obtained by previous investigators for terrestrial noctilucent clouds. Because the aerosol particles are highly charged, coagulation is inhibited, particle sizes are smaller, and their settling rates are reduced. As a consequence, the optical depth of the atmosphere is much higher than it would be if the particles were uncharged.     

Observed composition of the ionosphere of Venus: Implications for the ionization peak and the maintenance of the nightside ionosphere

Across the nightside of Venus, daily measurements from the PV Orbiter Ion Mass Spectrometer often indicate an ionosphere of relatively abundant concentration, with a composition characteristic of the dayside ionosphere. Such conditions are interspersed by other days on which the ionosphere appears to largely “disappear” down to about 200 km, with ion concentrations at lower heights also much reduced. These characteristics, coupled with observations of strong day to night flows of O⁺ in the upper ionosphere, support arguments that ion transport from the dayside is important for the maintenance of the nightside ionosphere. Also, U.S. and Soviet observations of nightside energetic electron fluxes have prompted consideration of impact ionization as an additional nightside ion source. The details of the ion and neutral composition at low altitudes on the nightside provide an important input for further analysis of the maintenance process. In the range 140–160 km, strong concentrations of O₂⁺ and NO⁺ indicate that the ionization peak is at times composed of at least two prominent ion species. Nightside concentrations of O₂⁺ and NO⁺ as large as 10⁵ and 10⁴/cm³, respectively, appear to require sources in addition to that provided by transport. The most probable sources are considered briefly, and no satisfactory explanation is yet found for the observed NO⁺ concentrations. Further analysis beyond the scope of this paper is required to resolve this issue.     

Observations concerning the relationship between the quiet-time ring current and electron temperatures at trough latitudes

The relationship between the simultaneously observed positions of the maximum omnidirectional flux of the quiet-time ring current positive ions (Λ_φ) and the maximum electron temperature Λ_T in the trough is studied in the midnight sector of the topside ionosphere. Λ_φ maps to the inner edge of the plasma sheet where ring current fluxes change from nearly isotropic to trapped. At altitudes near 2500 km, the electron temperature at trough latitudes were always sharply peaked. Although Λ_φ varied with the level of geomagnetic activity, (Λ_φ ? Λ_T) did not. These observations support the hypothesis that the quiet-time ring current is the source of elevated electron temperatures found near the plasmapause. Below 1300 km, peaked electron temperature distributions in the trough were not consistent features of the data. It is shown that (Λ_φ ? Λ_T) increased with decreasing altitude. The possible influences of a westward component to the convective electric field and ionospheric refraction of ion cyclotron waves are discussed.     

Daytime ionosphere of Venus as studied with Veneras 9 and 10 dual-frequency radio occultation experiments

We present results of the dual-frequency radio sounding of the Venusian ionosphere carried out by the Venera 9 and 10 satellites in 1975. Thirteen height profiles of electron density for different solar zenith angles varying from 10 to 87° have been obtained by analyzing the refraction bending of radiorays in the sounded ionssphere. The main maximum of electron density at a height of 140–150 km depends on the solar zenith angle and is 1.4 to 5 × 10⁵ cm^?3. The lower maximum is determined definitely to be at ～130 km high. In the main and lower maxima the electron density variations with solar zenith angle are in good agreement with the Chapman layer theory. For the first time it is found that the height of the upper boundary for the daytime ionosphere (h_i) depends regularly on the solar zenith angle. At Z_⊙ < 60°, h_i does not exceed 300 km while at Z_⊙ > 60°, it increases with Z_⊙ and comes up to ～ 600 km at Z_⊙ ～ 80°.     

Studies of Planetary Atmospheres by Stellar Occultations: Application to Mars and Venus

We consider the application of the stellar occultation method to the studies of planetary atmospheres and its history and briefly describe the instruments designed for such measurements (SPICAM/Mars-96, GOMOS/ENVISAT). In comparison with solar occultations, this method allows the profiles to be measured almost at any time of the day and at any location of the planet, irrespective of the orbit of the spacecraft from which observations are carried out. Based on the measuring characteristics of the SPICAM-Light UV spectrometer for the spectral range 118–320 nm with a resolution of 0.9 nm (for the ESA Mars Express Mission; launched in June 2003), we simulate the capabilities of the method to study the Martian atmosphere. In stellar occultation measurements, the stellar spectrum changes because of the absorption by CO₂ and O₃, other gases, and aerosols. The profiles of the CO₂ and O₃ density (and, hence, the temperature) and the aerosol content can be restored by solving the inverse problem. Observations of bright stars (no fewer than 30) three to five times in a turn allow us to measure the atmospheric density at altitudes 10–150 km with an accuracy of about 2% and the temperature at altitudes 20–130 km with an accuracy of 3 K. Ozone is measured with an accuracy of several percent at altitudes 25–40 km or lower, depending on the conditions. Optically thin clouds and hazes, particularly on the nightside where no measurements are possible in reflected light, can be studied. The SPICAV experiment, which is similar to SPICAM-Light, is part of the Venus Express (to be launched in 2005) scientific payload. On Venus, stellar occultations can be used to measure the atmospheric temperature and density above clouds at altitudes up to 130–150 km and to study the SO₂ profile. The results of our simulations can be easily extended to instruments with different measuring characteristics.     

Altitude variation of ultraviolet oxygen night airglow

Night airglow of oxygen 130.4 and 135.6 nm emissions was measured by a spectrophotometer aborad an S520 sounding rocket, launched at 19:50 JST (10:50 UT) on 14 February, 1982 from Kagoshima, Japan. The altitude variation of the emissions was obtained from 110 to 266 km at zenith angles of 35.5°±4°. The emission intensity around 260 km was about 160R and is roughly compatible with model calculations taking account of O⁺+e ^– radiative recombination as well as O⁺–O^– mutual neutralization. Some excess of about 50R, compared to the model calculation, was observed around 200 km. Possible explanations of the excess are: (i) remnant oxygen ions during the transition period from day to night and (ii) diffuse radiation from the background sky. Model calculations taking account of remnant oxygen ions were also performed by adding an excess electron density to the original density profile. However, it was found that an unreasonably large electron density is required around 200 km (5×10⁵ cm^–3) to produce the observed intensity. It is also probable that some contribution from the background sky is present in the observed intensity.     

A beam/plasma interaction in the high-altitude auroral ionosphere

Ambient thermal electrons are found to be heated to temperatures as high as 10⁵ K by the passage of a field-aligned beam of suprathermal electrons through the ionosphere at altitudes over 660 km. These secondary electrons will increase the proportion of 630 nm emission, caused by the primary electron precipitation, and change the secondary electron spectrum observed at lower altitudes from that expected on the basis of atmospheric collisions alone.     

A model of the terrestrial ionosphere in the altitude interval 50–4000 km II. Molecular ions (N2 +, NO+, O2 +) and electron density

Empirical models of molecular ion densities (N₂ ⁺, NO⁺, O₂ ⁺) and the electron density (N _e ) are presented in the altitude interval 50–4000 km as functions of time (diurnal, annual), space (position, altitude) and solar flux (F _10.7). Using observations of 6 satellites (AE-C, AE-D, AE-E, ALOUETTE-2, ISIS-1, ISIS-2), 4 incoherent scatter stations (Arecibo, Jicamarca, Millstone Hill, St Santin) and more than 700 D-region profiles, this model describes the global gross features of the ionosphere for quiet geophysical conditions (K _p 3).The molecular ion densities and the electron density increase with increasing altitude up to a maximum (or several maxima) - and decrease from thereon with increasing height. Between ~80 and 200 km, the main ionic constituents are NO⁺ and O₂ ⁺; below ~80 km cluster ions are predominating. During local summer conditions the molecular ions and N _e increase around polar latitudes and decrease correspondingly during local winter. The diurnal variations are intrinsically coupled to the individual plasma layers; in general, the molecular ion and electron densities are enhanced during daytime and depleted during nighttime (for details and exceptions, see text).     

The Effects of Altitude-Dependent Wave Particle Interactions on the Polar Wind Plasma

The energization of charged particles, due to interaction with the ambient electromagnetic turbulence, has a significant influence on the plasma transport in space. The effect of wave-particle interactions on the outflow characteristics of polar wind plasma was investigated. The theoretical model included gravitational acceleration (g), polarization electrostatic field (Ep), and divergence of the geomagnetic field. Within the simulation region (1.7 to 10 earth radii, Re) the ions were assume to be collisionless and the electrons to obey a Boltzmann relation. Profiles of altitude-dependent diffusion coefficients [D⊥ (O+) and D⊥ (H+)] were computed from the wave spectral density (S) observed by the Plasma Wave Instrument (PWI) on board DE-1. The effects of WPI were introduced via a Monte Carlo technique, and an iterative approach was used in order to converge to self-consistent results. The main conclusions of this study were the following. As a result of perpendicular heating, the temperature anisotropy (T| /T⊥) was reduced and even reversed (T| < T⊥) at high altitudes. The O+ velocity distribution function developed a conic shape at high altitudes. The altitudes above which the WPI influences the O+ ions were lower than those for the H+ ions. The escape flux of O+ could be enhanced by more than an order of magnitude while the H+ flux remains constant. The O+ ions are heated more efficiently than the H+ ions, especially at low altitudes due to the 'pressure cooker' effect. As the ions are heated and move to higher altitudes, the ion's Larmor radius a _L may become comparable to the perpendicular wavelength λ⊥. As the ratio aL /λ⊥ becomes > 1, the heating rate becomes self-limited and the ion distribution displays toroidal features. This result is consistent with the observation of O+ toroidal distribution in the high altitude ionosphere. Finally, the large variability in the wave spectral density S was studied. This variability was found to change our results only in a quantitative manner, while our conclusions remained qualitatively unchanged. This revised version was published online in July 2006 with corrections to the Cover Date.