藏南马拉山高钙二云母花岗岩的年代学特征及其形成机制

马拉山片麻岩穹窿位于特提斯喜马拉雅带内,由马拉山二云母花岗岩、错布二云母花岗岩和派枯错复合淡色花岗岩组成。马拉山二云母花岗岩东西展布约10km,锆石U-Pb分析表明,马拉山二云母花岗岩的结晶时间较长,从17.6Ma到16.9Ma,或者至少是两次深熔作用的产物,分别发生在17.6Ma和16.9Ma。全岩主量元素、微量元素和Sr、Nd、Hf同位素分析表明马拉山二云母花岗岩是一个较均一岩体,具有以下特征:(1)高SiO2,Al2O3和相对较高的CaO(1.2%～2.0%);(2)较高的Sr,较低的Rb和Rb/Sr比值(<1.3),且随着Ba浓度的增加,Rb/Sr比值保持不变;(3)高度变化的Zr/Hf比值(25.9～39.9);(4)富集轻稀土,亏损重稀土,几乎无或弱的负Eu异常;(5)较一致的Sr和Nd同位素组成;(6)锆石岩浆增生边和继承性锆石的Hf同位素比值高度变化,εHf(t)分别为-20.4～-8.0和-27.2～-9.5。这些特征暗示马拉山二云母花岗岩是变泥质岩在较高温压条件下水致白云母部分熔融的产物,与藏南裂谷系的东西向伸展作用密切相关。     

粤北白沙岩体早白垩世细粒花岗岩年代学、地球化学特征及成因意义

粤北佛冈岩体北缘的白沙岩体细粒黑云母二长花岗岩LA-ICP-MS锆石U-Pb加权平均年龄为130.3±3.0Ma,表明细粒黑云母二长花岗岩侵入于早白垩世。岩体高硅(SiO2=70.64~75.01wt%),高Na2O+K2O(7.62~8.33wt%),低P2O5(0.024~0.100wt%),富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、Ta、La、Ce、Sr、P和Ti等。明显富集轻稀土元素[(La/Yb)N=6.74~54.69],显示明显的负Eu异常(δEu=0.15~0.35),少量正Eu异常(δEu=0.82~1.19)。这些地球化学特征指示细粒黑云母二长花岗岩为高分异I型花岗岩。锆石Hf同位素研究结果表明,εHf(t)=-7.3^-10.6,其平均值为-8.89。其两阶段模式年龄(T2DM)主要为1654~1865Ma(n=8),平均值为1751Ma。佛冈复式岩体早白垩世细粒黑云母二长花岗岩形成于古太平洋板块向欧亚板块俯冲的陆缘弧构造背景下,其地球化学特征表明其物质主要来源于古元古代地壳的杂砂-泥质源岩部分熔融,并有少量幔源物质参与。     

内蒙古中东部两类花岗岩地质地球化学特征及成因意义

内蒙古中东部沿凉城—土贵乌拉一线分布着大量强过铝质石榴石花岗岩及少量淡色花岗岩。石榴石花岗岩SiO2含量、A12O3/TiO2比值(小于100),Rb/Sr比值和Rb/Ba比值低,但CaO/Na2O比值高(大于0.3)。铕均为负异常,呈重稀土元素平坦、轻稀土元素中等富集的配分模式。淡色花岗岩SiO2含量高,A12O3/TiO2比值,Rb/Sr比值和Rb/Ba比值以及CaO/Na2O比值变化大。稀土元素复杂,正Eu异常、Eu异常不明显均发育。两类花岗岩微量元素特征总体相似,均显示出大离子亲石元素(K,Rb,Ba)相对富集,高场强元素(Nb,Ti,P)亏损。两类花岗岩不同的地球化学特征暗示了其源区成分及构造背景的差异。石榴石花岗岩的源区成分应为杂砂岩,熔融温度较高,来源较深;而淡色花岗岩的源区成分复杂,熔融压力较高。     

新疆北部青河县阿斯喀尔特铍矿区花岗质岩石年代学及地球化学特征

新疆北部青河县阿斯喀尔特铍矿床的形成与岩浆活动密切相关,是中国花岗岩型铍矿床的典型代表。对矿区斑状二云母二长花岗岩进行LA-ICP-MS锆石U-Pb年龄测试,获得其加权平均年龄为(216.7±2.8)Ma(MSWD=0.48),表明该岩体形成时代为晚三叠世,据此限定阿斯喀尔特铍矿床成矿时代略晚于216 Ma,为晚三叠世—早侏罗世。岩石具有高硅(w(Si O2)=70.86%~76.34%)、富碱(ALK=5.54~9.30)、富铝(w(Al_2O_3)=13.00%~14.74%,A/CNK=0.99~1.23)、低钛(w(Ti O2)=0.02%~0.18%)和镁(w(Mg O)=0.02%~1.21%)特征,为过铝质中钾-高钾岩石系列。稀土元素配分型式显示LREE的相对弱富集,HREE较平坦以及Eu弱-中等的负异常(δEu=0.37~0.90),呈略右倾型。微量元素Ba、Sr、Hf、Ti等具负异常,Rb、Th、K、Nb、Ta、La、Ce、Nd、Sm等具正异常,Rb/Sr比值较高(9.34~26.81),显示出S型花岗岩特征。结合区域资料,认为阿斯喀尔特铍矿矿区印支期花岗岩形成于后造山构造阶段,可能是上地壳含砂泥质岩石部分熔融的产物。     

西昆仑甜水海地块南屏雪山早古生代花岗岩地球化学、Hf同位素特征及其壳幔岩浆作用

南屏雪山早古生代花岗岩体位于西昆仑甜水海地块东段,主要岩性为中粒含斑黑云母二长花岗岩(485Ma)和中细粒黑云母二长花岗岩(528Ma)。化学组成上,两者均具有高硅、富碱,贫TFe2O3、MgO和CaO的特征,属高钾钙碱性弱过铝质系列;微量和稀土元素组成上,两者均富Rb、Th、U、K、Pb和轻稀土,贫Ba、Sr、Nb、Ta、Ti和P,Rb/Sr、Rb/Ba、Nb/Ta和Y/Yb比值高,具有明显的Eu负异常,其Zr、Nb、Ce、Y等高场强元素均较之典型A型花岗岩偏低,综合地质地球化学特征的判别表明南屏雪山花岗岩应属高分异的I型花岗岩。中粒含斑黑云母二长花岗岩和中细粒黑云母二长花岗岩均具有较均一的正εHf(t)值(0.9~5.3和1.4~5.6)和中元古代的二阶段模式年龄TDM2(1118~1398Ma和1136~1396Ma),相似的地球化学特征和锆石Hf同位素组分暗示两者可能是同源岩浆演化的产物。结合区域构造演化历史,推测在早古生代原特提斯洋存在双向俯冲,南屏雪山早古生代花岗岩则是在早寒武世-早奥陶世(528~485 Ma)原特提斯洋持续向南的俯冲消减-碰撞造山过程中,诱导幔源岩浆上涌底侵下地壳,诱发区内中元古代新生地壳物质至少两次部分熔融(早寒武世和早奥陶世),并经历一定程度的分离结晶作用而形成的。     

广东良口黄田埔高分异Ⅰ型花岗岩地球化学特征及大地构造意义

广州从化区良口亚髻山霞石正长岩为典型岩石遗迹,在碱性岩体野外填图研究过程中,新发现东侧分布有黄田埔高分异花岗岩,形成时间约(146±13)Ma,为晚侏罗世岩浆活动产物。元素地球化学特征显示硅高、钾富、分异指数高、Rb/Sr比值高以及Rb/Ba、Nb/Ta、Zr/Hf、TFeO/MgO比值低;稀土元素ΣREE平均值为248 g/t,ΣCe/ΣYb平均值为2.34,δEu(0.16)负异常明显;Ga(×10~4)/Al比值较低(平均值为3.47),Zr+Nb+Ce+Y含量(平均值为264g/t)低于A型花岗岩(350 g/t);I(Sr)值为0.691 8~0.712 8,平均值为0.708 1;ε_(Nd)(t)值为-3.5~-10.0,平均值为-6.7。元素地球化学、同位素地球化学和同位素年代学综合研究结果表明,岩株的形成可能与上地幔岩浆分异有关,为高分异Ⅰ型花岗岩。     

北喜马拉雅淡色花岗岩地球化学: 区域对比、岩石成因及其构造意义

北喜马拉雅出露一系列片麻岩穹窿,这些穹窿被形成于27.5～10Ma的淡色花岗岩侵入.淡色花岗岩的岩石类型为二云母花岗岩,它们的主量元素组成为SiO2=70.97%～74.54%、K2O+Na2O=6.27%～8.09%、K2O/Na2O=0.91～1.36及A/CNK=1.10～1.33.然而,它们在微量元素组成上呈现出较大的变化:Rb=(41～322)×10-6、Sr=(26～139)×10-6、Ba=(135～594)×10-6、(La/Yb)N=0.97～17.31、Eu/Eu=0.29～0.72.北喜马拉雅淡色花岗岩的主量元素和微量元素组成特征类似于高喜马拉雅中新世的二云母花岗岩,而在Ti、Mg、Ca、Ba含量和Rb/Sr比值上明显不同于高喜马拉雅中新世的电气石-白云母花岗岩.北喜马拉雅淡色花岗岩(87Sr/86Sr)t=0.7344～0.8503(t=10Ma),εNd(10Ma)=-12.5～-19.3,与高喜马拉雅淡色花岗岩无明显差异.在岩石成因上,北喜马拉雅和高喜马拉雅中新世淡色花岗岩均起因于构造减压作用,由此导致白云母发生脱水反应诱发高喜马拉雅结晶岩系的深熔.但北喜马拉雅淡色花岗岩形成的地质背景明显不同于高喜马拉雅淡色花岗岩,前者具有较长的时间跨度,开始形成于喜马拉雅渐新世的地壳增厚期,之后形成于中新世穹窿片麻岩的折返时期,而高喜马拉雅淡色花岗岩与中新世高喜马拉雅结晶岩系的构造挤出作用有关.因此,北喜马拉雅和高喜马拉雅淡色     

喜马拉雅淡色花岗岩成因与稀有金属成矿潜力

喜马拉雅淡色花岗岩世界瞩目,具有重要的理论研究和找矿意义,但是其成因争议较大。本文统计了两千余件样品的全岩主微量地球化学、Sr-Nd-Pb-Hf同位素、锆石/独居石/磷钇矿等副矿物原位U-Pb年龄和锆石Hf同位素等,试图全面地总结喜马拉雅淡色花岗岩的研究进展和现状。喜马拉雅淡色花岗岩分为南北两带,北带花岗岩主要出露于特提斯喜马拉雅和片麻岩穹隆中,而南带花岗岩主要发育在高喜马拉雅顶部和东-西构造结中。从北往南,成岩时代逐渐变新;南北两带均以二云母花岗岩和(石榴石-电气石)白云母花岗岩为主,两期(始新世和中新世)中-基性岩脉和埃达克质岩主要在北带中发育。新生代岩浆活动分为5个阶段：49~40 Ma、39~29 Ma、28~15 Ma、14~7 Ma、6~0.7 Ma,分别主要与新特提斯洋壳板片断离、印度陆壳板片的低角度俯冲、断离或回撤、南北向撕裂(裂谷)和东西构造结的快速隆升有关。喜马拉雅淡色花岗岩起源于高喜马拉雅杂岩系的不一致(不平衡)部分熔融,并经历了矿物分离结晶的高分异演化。淡色花岗岩属于强过铝质岩石,具有高Si、K、Na,低Ca、Fe、Mg、Ti、Mn,高的Rb/Sr、Y/Ho值,低的Th/U、Nb/Ta、Zr/Hf、K/Rb值,稀土元素总量较低,负Eu异常明显的地球化学特征。随着成岩时代变新,Sr-Nd-Pb-Hf等同位素都指示岩浆源区中古老地壳物质的占比逐步增加。喜马拉雅淡色花岗岩/伟晶岩中Li、Be、W、Sn、Ta、Cs和Rb等稀有元素的富集系数大于10,伟晶岩属于典型的LCT型伟晶岩。喜马拉雅新生代淡色花岗岩带有望成为一条新的世界级的Li-Be-Sn-W-Ta稀有金属成矿带。     

湘中白马山复式岩体成因及其成矿效应

白马山复式岩体位于湘西雪峰山弧形构造隆起带与湘中白马山-龙山-紫云山EW向构造带的交汇处,由水车、龙潭、小沙江和龙藏湾超单元花岗岩组成。锆石LA-ICP-MS U-Pb同位素定年显示,水车、龙潭、小沙江、龙藏湾超单元花岗岩的侵位年龄分别为424.9±2.2Ma、228.2±1.3Ma、225.3±1.1Ma和215.0±1.2Ma。水车超单元形成于加里东期,其余3个超单元花岗岩均形成于印支晚期,首次系统搭建了白马山复式岩体的年代学格架。印支期龙潭和小沙江超单元花岗岩具有低硅、低碱、准铝质-弱过铝质的特点,显示较强的Rb、Th、U、Pb正异常和Nb、Sr、P、Ti负异常,具有较弱的负Eu异常(δEu为0.55~1.07);富集Sr同位素[(~(87)Sr/~(86)Sr)i=0.719027~0.721297]、亏损Nd同位素[ε_Nd(t)=-10.5~-9.4]和锆石Hf同位素[ε_Hf(t)=-7.7~-4.1],具有古老的Nd同位素(1.76~1.85Ga)和Hf同位素(1.42~1.83Ga)二阶段模式年龄。相反,龙藏湾超单元花岗岩具有高硅、高碱、强过铝质的特点,显示较强的Rb、Th、U、Ta、Pb正异常和Ba、Nb、Sr、Ti负异常,显示强的负Eu异常(δEu=0.28~0.51)和高(~(87)Sr/~(86)Sr)i值(0.741441~0.748761),具有负的ε_Nd(t)值(-11.3~-10.7)和ε_Hf(t)值(-11.5~-3.5),Nd同位素(1.87~1.91Ga)和Hf同位素(1.47~1.97Ga)二阶段模式年龄更老。结合元素和同位素地球化学特征,可推断出龙潭和小沙江超单元花岗岩是华南古老地壳基底中基性变质火成岩混有变质沉积岩发生部分熔融形成的I型或者I-S过渡性质的花岗质岩石,而龙藏湾超单元花岗岩则由华南成熟度更高的古老地壳基底富粘土变沉积岩发生部分熔融形成的S型花岗岩。白马山复式岩体中印支期超单元花岗岩很可能是华南板块受印支板块碰撞挤压后地壳发生伸展减薄,由加厚的地壳发生部分熔融形成的。这些印支期花岗岩与其周缘的金、钨矿床在时、空上具有密切联系,可能具有良好的成矿潜力;湘中地区印支期花岗岩的成岩、成矿作用在强度和广度上可能远高于过去的传统认识。     

藏南吉隆淡色花岗岩地球化学特征、成因机制及其构造动力学意义

藏南吉隆淡色花岗岩体位于大喜马拉雅淡色花岗岩带的中部,是吉隆地区藏南拆离系剪切带上部的重要组成部分。地球化学特征显示,岩石具有高SiO_2(72.09%~74.02%)、Al_2O_3(14.54%~15.59%)和K_2O(4.55%~5.59%)含量,高K_2O/Na_2O比值(1.12~1.55)和A/CNK值(1.14~1.18),属于高钾钙碱性过铝质S型花岗岩。富集大离子亲石元素Rb和放射性生热元素U,亏损Ba、Nb、Sr和Zr等元素,具有明显的轻重稀土元素分异和Eu负异常(δEu=0.37~0.54)。具有高的Rb/Sr比值(3.6~9.7)和低的CaO/Na_2O比值(0.15~0.25),指示源区为泥质岩区;(~(87)Sr/~(86)Sr)_i和ε_(Nd)(t)变化范围分别为0.7548~0.7586和-14.0~-13.1,与大喜马拉雅变泥质岩的Sr-Nd同位素组成一致;锆石边部的ε_(Hf)(t)介于-16.0~-8.5之间,位于大喜马拉雅变泥质岩中碎屑锆石的演化线上,表明淡色花岗岩的源岩为大喜马拉雅变泥质岩。岩石(~(87)Sr/~(86)Sr)_i较高而Sr浓度较低,且随着Ba浓度的增加,Rb/Sr比值降低,表明淡色花岗岩是无水条件下白云母脱水熔融形成的,部分熔融可能与藏南拆离系(STDS)伸展拆离导致的深部构造减压密切相关。吉隆淡色花岗岩的形成反映了地壳伸展减薄背景下,构造减压导致的深部地壳物质中含水矿物(白云母)脱水熔融并沿向北伸展的STDS侵位的构造动力学过程。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861