塔里木河流域水资源开发利用及其环境效应

近30a来,由于塔里木河流域水资源无序的开发利用,导致了严重水土环境退化.从20世纪50-70年代,下游300km河道逐渐干涸,致使下游水文过程和生态环境严重破坏.1960-1980年下游水位由2～4m下降到4～10m;1980年后,水位年降速率是20cm.1958-1978年,塔里木河流域胡杨减少了2/3,生物量下降了1/2;1950-1990年代,塔里木河下游主要树种胡杨林减少了3820km²,而灌木和草地面积减少了200km².这种水文变化已导致水环境的明显恶化,并引起了土地沙漠化,1960-1990年代形成沙漠化土地12300km².塔里木河的盐分含量逐渐升高,1960年的最大含盐量是1.28g·L^-1,但1981-1984年达到4g·L^-1,到1998年达7.8g·L^-1.根据对沙漠化土地有机碳含量推算,近30a塔里木河流域土壤由于退化向大气中释放的有机碳多达112Tg,且28.3%来自表层0～1.0m土壤.人类活动的强度干扰是导致以上水环境变化的重要原因,解决问题的关键是提高对水资源与水土环境监测、观测、管理和恢复的科学与技术水平.     

Lake Tai: The limnology of a shallow lake in China

Lake Tai (Tai Hu) is located in the S part of the Yangtze River delta, has a surface area of 2,425 km², a mean depth of 2.12 m, and a volume of 5.15 km³. The climate of the region is characterised by an average annual air temperature of 15.7°C, precipitation of 1,178 mm and evaporation from the water surface of about 1,024 mm. The average annual water temperature is 17.1°C. A positive and a negative thermocline may occur in one day, a characteristic of polymictic lakes. The average water level is 3.03 m above Wusong datum. Total annual inflow was 8.7 km³ with a total outflow of 9.0 km³ and a residence time about 212 days during an average water year. Influent-effleunt currents and wind currents both occured in the lake with a velocity of between 0,1 and 0,3 m s^–1; the height of wind generated waves up to 1 m when the wind velocity was about 13 m s^–1. The average transparency of lake was 0.39 m and the water colour about XV-XVI. The salinity of water was 157.66 mg 1^–1, alkalinity 1.22 meq 1^–1, total hardness 1.523 meq 1^–1 and the pH 8.0. The lake water belonged to calcium bicar-bonate and calcium-sodium bicarbonate types during the study period. The biota had 114 genera of phytoplankton, 122 species of zooplankton, 68 species of benthos, 61 species of aquatic macrophytes and 106 species of fish. Ten species were considered predominant:Microcystis aeruginosa, Anabaena spiroides, Chroomonas acuta, Strobilidum velox, Tintinnopsis conicus, Corbicula fluminea, Zizania latifolia, Phragmites communis, Coilia ectenes taihuensis, and Protosalanx hyalocranius.     

Driving forces responsible for aeolian desertification in the source region of the Yangtze River from 1975 to 2005

The Yangtze River is the China’s longest river and the third-longest river in the world. The river’s source region in the Qinghai-Tibet Plateau is especially sensitive to global environmental change because of its high elevation and cold environment. Under the influence of global warming, aeolian desertified land has expanded rapidly in this area. To assess the trends in aeolian desertification from 1975 to 2005, remote-sensing and GIS technology were used to monitor the extent of aeolian desertification in 1975, 1990, 2000, and 2005. The data sources included Landsat multi-spectral scanner images acquired in 1975, Enhanced Thematic Mapper (ETM+) images acquired in 2000, and Thematic Mapper (TM) images acquired in 1990 and 2005. Images recorded between June and October were selected, when vegetation grew well, because aeolian desertified land was more easily recognized during this period. Thematic maps, including land use and geomorphologic maps, were used as supplementary data. Aeolian desertification maps (1:100000) were produced for each year from the Landsat images through visual interpretation. The area of aeolian desertified land increased by 2,678.43 km² from 1975 to 2005, accounting for 8.8% of the total area of aeolian desertified land in 1975, an increase of 89.28 km² a⁻¹. Increasing mean annual temperature and the combination of a dry, cold, and windy climate in winter and spring were mainly responsible for the expansion of desertified land.     

Environmental impact of an urban landfill on a coastal aquifer (El Jadida, Morocco)

The El Jadida landfill is one among many uncontrolled dumping sites in Morocco with no bottom liner. About 150 tons/day of solid wastes from mixed urban and industrial origins are placed directly on the ground. At the site of this landfill, the groundwaters circulate deeply (10–15 m) in the Cenomanian rock (calcareous–marl), which is characterised by an important permeability from cracks. The soil is sand–clay characterized by a weak coefficient of retention.The phreatic water ascends to the bottom of three quarries, which are located within the landfill. These circumstances, along with the lack of a leachate collection system, worsen the risks for a potential deterioration of the aquifer.To evaluate groundwater pollution due to this urban landfill, piezometric level and geochemical analyses have been monitored since 1999 on 60 wells. The landfill leachate has been collected from the three quarries that are located within the landfill. The average results of geochemical analyses show an important polluant charge vehiculed by landfill leachate (chloride = 5680 mg l⁻¹, chemical oxygen demand = 1000 mg l⁻¹, iron = 23 000 μg l⁻¹). They show also an important qualitative degradation of the groundwater, especially in the parts situated in the down gradient area and in direct proximity to the landfill. In these polluted zones, we have observed the following values: higher than 4.5 mS cm⁻¹ in electric conductivity, 1620 and 1000 mg l⁻¹ respectively in chlorides and sulfate (), 15–25 μg l⁻¹ in cadmium, and 60–100 μg l⁻¹ in chromium. These concentrations widely exceed the standard values for potable water.Several determining factors in the evolution of groundwater contamination have been highlighted, such as (1) depth of the water table, (2) permeability of soil and unsaturated zone, (3) effective infiltration, (4) humidity and (5) absence of a system for leachate drainage. So, to reduce the pollution risks of the groundwater, it is necessary to set a system of collection, drainage and treatment of landfill leachates and to emplace an impermeable surface at the site of landfill, in order to limit the infiltration of leachate.     

The role of supergene sulphuric acid during weathering in small river catchments in low mountain ranges of Central Europe: Implications for calculating the atmospheric CO2 budget

The geochemistry of dissolved and suspended loads in river catchments of two low mountain ranges in Central Europe allows comparison of pertinent chemical weathering rates. Distinct differences in lithology, i.e. granites prevailing in the Black Forest compared to Palaeozoic sediments in the Rhenish Massif, provide the possibility to examine the influence of lithology on weathering. Here we determine the origin of river water using the stable isotope ratio δ¹⁸O_H2O and we quantify the geogenic proportions of sulphate from stable isotope ratios δ³⁴S_SO4 and δ¹⁸O_SO4. Particularly in catchments with abundant pyrite, determination of the geogenic amount of sulphate is important, since oxidation of pyrite leads to acidity, which increases weathering. Our results show that spatially averaged silicate weathering rates are higher for the river catchments Acher and Gutach in the Black Forest (10–12 t/km²/yr) compared to the river catchments of the Möhne dam and the Aabach dam in the Rhenish Massif (2–6 t/km²/yr). Correspondingly, the CO₂ consumption by silicate weathering in the Black Forest (334–395 × 10³ mol/km²/yr) is more than twice as high as in the Rhenish Massif (28–151 × 10³ mol/km²/yr). These higher rates for watersheds of the Black Forest are likely due to steeper slopes leading to higher mechanical erosion with respective higher amounts of fresh unweathered rock particulates and due to the fact that the sediments in the Rhenish Massif have already passed through at least one erosion cycle. Carbonate weathering rates vary between 12 and 38 t/km²/yr in the catchments of the Rhenish Massif. The contribution of sulphuric acid to the silicate weathering is higher in the catchments of the Rhenish Massif (9–16%) than in the catchments of the Black Forest (5–7%) due to abundant pyrite in the sediments of the Rhenish Massif. Three times higher long-term erosion rates derived from cosmogenic nuclides compared to short-term erosion rates derived from river loads in Central Europe point to three times higher CO₂ consumption during the past 10³ to 10⁴ years.     

中国土地荒漠化的概念、成因与防治

荒漠化是指人类历史时期以来,由于人类不合理的经济活动和脆弱生态环境相互作用造成土地生产力下降,土地资源丧失,地表呈现类似荒漠景观的土地退化过程。在中国北方荒漠化形成因素中过度放牧占30．1％,过度农垦占26．9％,过度樵采占32．7％,水资源利用不当占96％,工矿交通建设中不注意环境保护占0．7％,在地区上以北方农牧交错及旱农地区荒漠化最为严重。要采取因地制宜措施和建立健全而完善的治理实施系统以达到生态、经济和社会三个效益的目的。     

Water fluxes and their control on the terrestrial carbon balance: Results from a stable isotope study on the Clyde Watershed (Scotland)

The gradients between precipitation and runoff quantities as well as their water isotopes were used to establish a water balance in the Clyde River Basin (Scotland). This study serves as an example for a European extreme with poorly vegetated land cover and high annual rainfall and presents novel water stable isotope techniques to separate evaporation, interception and transpiration with annual averages of 0.029 km³ a⁻¹, 0.220 km³ a⁻¹ and 0.489 km³ a⁻¹, respectively. Transpiration was further used to determine CO₂ uptake of the entire basin and yielded an annual net primary production (NPP) of 352 × 10⁹ g C (Giga gram) or 185.2 g C m⁻². Compared to other temperate areas in the world, the Clyde Basin has only half the expected NPP. This lower value likely results from the type of vegetation cover, which consists mostly of grasslands. Subtracting the annual heterotrophic soil respiration flux (R_h) of 392 Gg (206.1 g C m⁻² a⁻¹) from the NPP yielded an annual Net Ecosystem Productivity (NEP) of −40 Gg C, thus showing the Clyde Watershed as a source of CO₂ to the atmosphere. Despite the unusual character of the Clyde Watershed, the study shows that areas with predominant grass and scrub vegetation still have transpirational water losses that by far exceed those of pure evaporation and interception. This infers that vegetation can influence the continental water balances on time scales of years to decades.     

Groundwater resources of the middle and upper Odra River basin, southwestern Poland

 The total amount of groundwater resources in the middle and upper Odra River basin is 5200×10³ m³/d, or about 7.7% of the disposable groundwater resources of Poland. The average modulus of groundwater resources is about 1.4 L/s/km². Of the 180 'Major Groundwater Basins' (MGWB) in Poland, 43 are partly or totally located within the study area. The MGWB in southwestern Poland have an average modulus of groundwater resources about 2.28 L/s/km² and thus have abundant water resources in comparison to MGWB from other parts of the country. Several types of mineral waters occur in the middle and upper Odra River basin. These waters are concentrated especially in the Sudety Mountains. Carbon-dioxide waters, with yields of 414 m³/h, are the most widespread of Sudetic mineral waters. The fresh waters of the crystalline basement have a low mineralization, commonly less than 100 mg/L; they are a HCO₃–Ca–Mg or SO₄–Ca–Mg type of water. Various hydrochemical compositions characterize the groundwater in sedimentary rocks. The shallow aquifers are under risk of atmospheric pollution and anthropogenic effects. To prevent the degradation of groundwater resources in the middle and upper Odra River basin, Critical Protection Areas have been designated within the MGWB. Received, January 1995 Revised, May 1996, August 1997 Accepted, August 1997     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

中国沙漠化研究的理论与实践

中国的沙漠化研究的理论与实践在过去的十多年里取得了一些成果。据此,本文对沙漠化的概念、成因、过程、指征、后果、发展趋势及其治理等方面进行扼要的介绍。研究表明,沙漠化是一种人为活动与自然资源、环境不相协调所产生的以风沙活动为主要标志的土地退化过程。我国北方沙漠化土地的蔓延速率从50年代末期至70年代中期的年均1560km²发展到近十多年来的年均2100km²;实践证明,沙漠化土地作为一种土地资源可以通过合理的整治过程而恢复其原有的生产潜力。     

Distribution of polycyclic musks in water and particulate matter of the Lippe River (Germany)

The occurrence and distribution of polycyclic musks in the Lippe River system (a tributary of the Rhine River, Germany) was investigated in order to observe the dynamic transport and partitioning of these compounds between aqueous and particulate phases after their discharge into the river by sewage effluents. 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[g]-2-benzopyrane (HHCB), 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene (AHTN), 6-acetyl-1,1,2,3,3,5-hexamethylindane (AHMI) and 4-acetyl-1,1-dimethyl-6-tert.-butylindane (ADBI) concentrations were determined in 19 water and surface sediment samples which were taken from a longitudinal section of the river. HHCB and AHTN were present in each of the water samples at concentrations ranging from <10 to 180 ng l⁻¹ and <10 to 70 ng l⁻¹, respectively. The load of dissolved HHCB and AHTN was calculated on the basis of compound concentrations in water and the corresponding river runoff data and ranged from 3 to 293 g day⁻¹ and from 1 to 108 g day⁻¹, respectively. Increasing loads of HHCB and AHTN along the river reflect a high input of sewage effluents to the densely populated areas along the central part of the river. Decreasing loads at the lower reaches indicate that in the corresponding river sections the rate of removal of musks was higher than the rate of input. Degradation and/or adsorption to particulate matter are processes that might explain this phenomenon. Consequently, high concentrations of HHCB and AHTN were detected in surface sediments from the Lippe River (from 5 to 191 μg kg⁻¹ and from 2 to 1399 μg kg⁻¹, respectively). HHCB/AHTN ratios in sediment samples were lower (average 1.2) than in water samples (average 2.9), suggesting the preferential adsorption of AHTN to particulate matter.     

Sedimentary record of black carbon in the Pearl River estuary and adjacent northern South China Sea

The concentrations of black carbon (BC) and δ¹³C_BC were determined in sediments of three dated cores from the Pearl River estuary (core PR-3) and adjacent northern South China Sea (cores SS-30, E2). For comparison, the total organic C (TOC) contents and δ¹³C_TOC in the sediments were also measured. Relatively higher concentrations and fluxes of BC were found in sedimentary core PR-3, taken in the Pearl River estuary. The BC concentration profiles or fluxes correlated well with fossil-fuel usage in the Pearl River Delta. Maximum BC fluxes occurred in the late 1970s to early 1980s as recorded in core PR-3, and in the 1950s (core SS-30), reflecting the maximum BC emission in the Pearl River Delta and Hong Kong region, respectively. After the 1980s, a rapid decrease of BC fluxes and a light δ¹³C_BC excursion were presumably due to improvements in combustion and pollution-control technologies and a shift of energy structure from biomass and coal to a mixture of coal, gas, oil and biomass. The fossil BC that contributed to total BC in core PR-3 increased from 20–30% to 70–80% during the last five decades. The study also shows that BC correlates well with terrestrial organic matter and that the ratio of BC to TOC is a good pollution indicator in relation to anthropogenic activities.     

Arcellacean (thecamoebian) evidence of land-use change and eutrophication in Frenchman’s Bay, Pickering, Ontario

Frenchmans Bay, on the northern shore of Lake Ontario, has been negatively impacted by eutrophication in the last 50 years through urbanization and the use of chemical fertilizers. Eutrophication began with wholesale land clearance and agricultural practises beginning in the mid-nineteenth century and reached a peak with urbanization after World War II. Eutrophication and the effects of land-use changes on the watershed were investigated by a combined analysis of the sediment magnetic properties and arcellacean (thecamoebian) microfauna. Micropaleontological analyses were conducted on two 2-m-long cores (FMB1 and FMB2) every 10 cm (42 samples) and magnetic susceptibility was measured at 2-cm intervals. Both cores showed a distinct correlative transition at 60 cm and 110 cm that was marked by a rapid increase in thecamoebian concentrations (from approx. 10×10³ to 30×10³ specimens per cc) and a large increase in Cucurbitella tricuspis (from approx. 10–20% to 40–70%). This transition correlated with a marked increase in magnetic susceptibility (150–200×10^–8 m³ Kg^–1) at the same depth, which was attributed to elevated levels of detrital magnetic minerals derived from land clearance and soil erosion in the watershed. It was indicated by ²¹⁰ Pb dates indicate that there was a gradual onset of eutrophication in the mid-nineteenth century (AD 1850±56) and a more rapid rise in the mid-1940s to late 1950s. The initial increase in eutrophication was due to land clearing, agricultural development and increased nutrient loadings. The major eutrophication increase in the 1950s was from urbanization and storm sewer discharge loaded with high yield chemical fertilizers from lawns and gardens. This high concentration of nutrients has led to an unprecedented level of eutrophication within the wetland.     

Iron isotopes in acid mine waters and iron-rich solids from the Tinto–Odiel Basin (Iberian Pyrite Belt, Southwest Spain)

The isotopic composition of Fe was determined in water, Fe-oxides and sulfides from the Tinto and Odiel Basins (South West Spain). As a consequence of sulfide oxidation in mine tailings both rivers are acidic (1.45 < pH < 3.85) and display high concentrations of dissolved Fe (up to 420 mmol l^− 1) and sulphates (up to 1190 mmol l^− 1).The δ⁵⁶Fe of pyrite-rich samples from the Rio Tinto and from the Tharsis mine ranged from − 0.56 ± 0.08‰ to + 0.25 ± 0.1‰. δ⁵⁶Fe values for Fe-oxides precipitates that currently form in the riverbed varied from − 1.98 ± 0.10‰ to 1.57 ± 0.08‰. Comparatively narrower ranges of values (− 0.18 ± 0.08‰ and + 0.21 ± 0.14‰) were observed in their fossil analogues from the Pliocene–Pleistocene and in samples from the Gossan (the oxidized layer that formed through exposure to oxygen of the massive sulfide deposits) (− 0.36 ± 0.12‰ to 0.82 ± 0.07‰). In water, δ⁵⁶Fe values ranged from − 1.76 ± 0.10‰ to + 0.43 ± 0.05‰.At the source of the Tinto River, fractionation between aqueous Fe(III) and pyrite from the tailings was less than would be expected from a simple pyrite oxidation process. Similarly, the isotopic composition of Gossan oxides and that of pyrite was different from what would be expected from pyrite oxidation. In rivers, the precipitation of Fe-oxides (mainly jarosite and schwertmannite and lesser amounts of goethite) from water containing mainly (more than 99%) Fe(III) with concentrations up to 372 mmol l^− 1 causes variable fractionation between the solid and the aqueous phase (− 0.98‰ < Δ⁵⁶Fe_{solid–water} < 2.25‰). The significant magnitude of the positive fractionation factor observed in several Fe(III) dominated water may be related to the precipitation of Fe(III) sulphates containing phases.     

Temporal variability of phosphorus fractions in Irish karst springs

Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg l^–1) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg l^–1) and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg l^–1), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg l^–1 due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge.     

River dissolved and solid loads in the Lesser Antilles: New insight into basalt weathering processes

We present here the first available estimations of chemical weathering and associated atmospheric CO₂ consumption rates as well as mechanical erosion rate for the Lesser Antilles. The chemical weathering (100–120 t/km²/year) and CO₂ consumption (1.1–1.4 × 10⁶ mol/km²/year) rates are calculated after subtraction of the atmospheric and hydrothermal inputs in the chemical composition of the river dissolved loads. These rates thus reflect only the low-temperature basalt weathering. Mechanical erosion rates (approx. 800–4000 t/km²/year) are estimated by a geochemical mass balance between the dissolved and solid loads and mean unaltered rock. The calculated chemical weathering rates and associated atmospheric CO₂ consumption rates are among the highest values worldwide but are still lower than those of other tropical volcanic islands and do not fit with the HCO₃⁻ concentration vs. 1/T correlation proposed by Dessert et al. (2001). The thick soils and explosive volcanism context of the Lesser Antilles are the two possible keys to this different weathering behaviour; the development of thick soils limits the chemical weathering and the presence of very porous pyroclastic flows allows an important water infiltration and thus subsurface weathering mechanisms, which are less effective for atmospheric CO₂ consumption.     

Permian basaltic rocks in the Tarim basin, NW China: Implications for plume–lithosphere interaction

There are large areas of Permian basaltic rocks in the Tarim basin (PBRT) in northwestern China. Precise Ar–Ar dating of these rocks revealed an eruption age span of 262 to 285 Ma. Most of the PBRT is composed of alkaline basaltic rocks with high TiO₂ (2.43%–4.59%, weight percent), high Fe₂O₃ + FeO (12.63%–17.83%) and P₂O₅ (0.32%–1.38%) contents. Trace elements of these rocks have affinities with oceanic island basalts (OIB), as shown in chondrite normalized rare earth elements (REE) diagrams and primitive mantle normalized incompatible elements diagrams. The rocks show complex Sr–Nd isotopic character based on which they can be subdivided into two distinct groups: group 1 has relatively small initial (t = 280 Ma)⁸⁷Sr/⁸⁶Sr ratio ( 0.7048) and positive εNd(t) (3.42–4.66) values. Group 2 has relatively large initial ⁸⁷Sr/⁸⁶Sr ratio (0.7060–0.7083) and negative εNd(t) (from − 2.79 to − 2.16) values. Lead isotopes are even more complex with variations of (²⁰⁶Pb/²⁰⁴Pb)t, (²⁰⁷Pb/²⁰⁴Pb)t and (²⁰⁸Pb/²⁰⁴Pb)t ranging from 17.9265 to 18.5778, 15.4789 to 15.6067 and 37.2922 to 38.1437, respectively. Moreover, these two groups have different trace elements ratios such as Nb/La, Ba/Nb, Zr/Nb, Nb/Ta and Zr/Hf, implying different magmatic processes. Based on the geochemistry of basaltic rocks and an evaluation of the tectonics, deformation, and the compositions of crust and lithospheric mantle in Tarim, we conclude that these basaltic rocks resulted from plume–lithosphere interaction. Permian mantle plume caused an upwelling of the Tarim lithosphere leading to melting of the asthenospheric mantle by decompression. The magma ascended rapidly to the base of lower crust, where different degrees of assimilation of OIB-like materials and fractionation occurred. Group 1 rocks formed where the upwelling is most pronounced and the assimilation was negligible. In other places, different degrees of assimilation and fractionation account for the geochemical traits of group 2.     

Land use history and status of land desertification in the Heihe River basin

An analysis, over historical times, of the influence of natural factors such as climate, geological activity, existing landforms, and the activity of aeolian sands on the desertification of oases and other lands in the Heihe River basin of northwestern China revealed that desertification occurred more or less quickly according to whether the prevailing climate was cold or warm, respectively. In the 1990s, the area of desertified lands in the lower reaches of the Heihe River (Ejin region) was 29.1% greater than in the mid 1980s. However, the rate of desertification in the middle reaches of the Heihe River basin was relatively slower, only 9.4% from 1949 to 1990 (or 0.27% per year). Since 1990, the rate of desertification has been stable. By 2000, the total area of land desertification in the mid to lower reaches of the Heihe River basin was 13,508.4 km², or 11.8% of the region monitored. Of the total land desertification area, the regions of Linze, Gaotai, Sunan, Jiuquan, Jia Yuguan, and Jinta accounted for 1.70, 1.71, 1.43, 0.85, 0.28, and 9.39%, respectively, whereas the Ejin region’s 11,434.64 km² accounted for 84.65%, indicating that land desertification in the lower Heihe River basin was particularly severe. The causes responsible for the occurrence and development of land desertification in the Heihe River basin were analyzed.     

中国东北平原西部荒漠化现状、成因及其治理途径研究

中国东北平原西部土地荒漠化,主要表现为土地沙漠化和土地盐碱化,它属于荒漠化的两种类型。东北 平原西部分布着科尔沁沙地和松嫩沙地,前者是全国五大沙漠之一。文章全面、系统地对该地区编制了 1∶1000000荒漠化图和量算出土地沙漠化面积。东北平原西部土地沙漠化面积为72280.6km2,占土地总面积的 22.2%。自20世纪50年代至80年代末,土地沙漠化面积迅速扩大,平均每年以1.5%～3.7%的速度递增;自9 年代以来,沙漠化呈现出逆转趋势,但就总体而言,沙漠化发展仍然大于逆转。东北平原西部土地盐碱化面积 33850.79km2,占土地总面积10.44%,主要分布在松嫩平原,面积为23329.19km2,占土地总面积15.2%,它是世 界上苏打盐碱化土壤的三大片之一,土地盐碱化每年以1.4%～2.5%速率正在发展。所以,该地区的土地荒漠化 不仅制约着当地农、牧业和农村经济的发展,影响周围和毗邻国家的生态环境安全,而且已危及当地人民的生存。 东北平原西部荒漠化的形成有自然因素和人为因素,前者有物源和气候变化等原因,后者有草原超载过牧、滥 垦、滥伐滥櫵、乱挖,河流上中游修建水库等原因,以及冻融作用的特殊原因,致使荒漠化形成和发展。     

Chemistry of fluids from a natural analogue for a geological CO2 storage site (Montmiral, France): Lessons for CO2–water–rock interaction assessment and monitoring

Chemical and isotope studies of natural CO₂ accumulations aid in assessing the chemical effects of CO₂ on rock and thus provide a potential for understanding the long-term geochemical processes involved in CO₂ geological storage. Several natural CO₂ accumulations were discovered during gas and oil exploration in France’s carbogaseous peri-Alpine province (south-eastern France) in the 1960s. One of these, the Montmiral accumulation at a depth of more than 2400 m, is currently being exploited. The chemical composition of the water collected at the wellhead has changed in time and the final salinity exceeds 75 g/L. These changes in time can be explained by assuming that the fraction of the reservoir brine in the recovered brine–CO₂–H₂O mixture varies, resulting in variable proportions of H₂O and brine in the sampled water. The proportions can be estimated in selected samples due to the availability of gas and water flowrate data. These data enabled the reconstruction of the chemical and isotope composition of the brine. The proportions of H₂O and brine can also be estimated from isotope (δ²H, δ¹⁸O) composition of collected water and δ¹⁸O of the sulfates or CO₂. The reconstituted brine has a salinity of more than 85 g/L and, according to its Br⁻ content and isotope (δ²H, δ¹⁸O, δ³⁴S) composition, originates from an evaporated Triassic seawater that underwent dilution by meteoric water. The reconstitution of the brine’s chemical composition enabled an evaluation of the CO₂–water–rock interactions based on: (1) mineral saturation indices; and (2) comparison with initial evaporated Triassic seawater. Dissolution of K- and SO₄-containing minerals such as K-feldspar and anhydrite, and precipitation of Ca and Mg containing minerals that are able to trap CO₂ (carbonates) are highlighted. The changes in concentration of these elements in the brine, which are attributed to CO₂ interactions, illustrate the relevance of monitoring the water quality at future industrial CO₂ storage sites.