The nature of Europa's dark non-ice surface material: Spatially-resolved high spectral resolution spectroscopy from the Keck telescope

We present new 1.45-1.75 μm spectra of Europa's dark non-ice material with a spectral resolution (λ/δλ) of 1200, obtained by using adaptive optics on the Keck telescope to spatially separate the spectrum of the non-ice material from that of the surrounding ice-rich regions. Despite the great increase in spectral resolution over the previous best spectra of the non-ice material, taken with Galileo's near-infrared mapping spectrometer (NIMS) with λ/δλ=66, no new fine-scale spectral structure is revealed. The smoothness of the spectra is inconsistent with available laboratory spectra of crystalline hydrated salts at Europa temperatures, but is more consistent with various combinations of non-crystalline hydrated salts and/or hydrated sulfuric acid, as have been matched to the lower-resolution NIMS spectra.     

Europa’s ridged plains and smooth low albedo plains: Distinctive compositions and compositional gradients at the leading side-trailing side boundary

This investigation uses linear mixture modeling employing cryogenic laboratory reference spectra to estimate surface compositions and water ice grain sizes of Europa’s ridged plains and smooth low albedo plains. Near-infrared spectra for 23 exposures of ridged plains materials are analyzed along with 11 spectra representing low albedo plains. Modeling indicates that these geologic units differ both in the relative abundance of non-ice hydrated species and in the abundance and grain sizes of water ice. The background ridged plains in our study area appear to consist predominantly of water ice (∼46%) with approximately equal amounts (on average) of hydrated sulfuric acid (∼27%) and hydrated salts (∼27%). The solutions for the smooth low albedo plains are dominated by hydrated salts (∼62%), with a relatively low mean abundance of water ice (∼10%), and an abundance of hydrated sulfuric acid similar to that found in ridged plains (∼27%). The model yields larger water ice grain sizes (100 μm versus 50-75 μm) in the ridged plains. The 1.5-μm water ice absorption band minimum is found at shorter wavelengths in the low albedo plains deposits than in the ridged plains (1.498 ± .003 μm versus 1.504 ± .001 μm). The 2.0-μm band minimum in the low albedo plains exhibits a somewhat larger blueshift (1.964 ± .006 μm versus 1.983 ± .006 μm for the ridged plains).The study area spans longitudes from 168° to 185°W, which includes Europa’s leading side-trailing side boundary. A well-defined spatial gradient of sulfuric acid hydrate abundance is found for both geologic units, with concentrations increasing in the direction of the trailing side apex. We associate this distribution with the exogenic effects of magnetospheric charged particle bombardment and associated chemical processing of surface materials (the radiolytic sulfur cycle). However, one family of low albedo plains exposures exhibits sulfuric acid hydrate abundances up to 33% lower than found for adjacent exposures, suggesting that these materials have undergone less processing, thus implying that these deposits may have been emplaced more recently.Modeling identifies high abundances (to 30%) of magnesium sulfate brines in the low albedo plains exposures. Our investigation marks the first spectroscopic identification of MgSO₄ brine on Europa. We also find significantly higher abundances of sodium-bearing species (bloedite and mirabilite) in the low albedo plains. The results illuminate the role of radiolytic processes in modifying the surface composition of Europa, and may provide new constraints for models of the composition of Europa’s putative subsurface ocean.     

The chemical nature of Europa surface material and the relation to a subsurface ocean

The surface composition of Europa is of special interest due to the information it might provide regarding the presence of a subsurface ocean. One source of this information is the infrared reflectance spectrum. Certain surface regions of Europa exhibit distorted H₂O vibrational overtone bands in the 1.5 and 2.0 μm region, as measured by the Galileo mission Near Infrared Mapping Spectrometer (NIMS). These bands are clearly the result of highly concentrated solvated contaminants. However, two interpretations of their identity have been presented. One emphasizes hydrated salt minerals and the other sulfuric acid, although each does not specifically rule out some of the other. It has been pointed out that accurate chemical identification of the surface composition must depend on integrating spectral data with geochemical models, and information on the tenuous atmosphere sputtered from the surface. It is also extremely important to apply detailed chemistry when interpreting the spectral data, including knowledge of mineral dissolution chemistry and the subsequent optical signatures of ion solvation in low-temperature ice. We present studies of flash frozen acid and salt mixtures as Europa surface analogs and demonstrate that solvated protons, metal cations and inorganic anions all influence the spectra and must all, collectively, be considered when assigning Europa spectral features. These laboratory data show best correlation with NIMS Europa spectra for multi-component mixtures of sodium and magnesium bearing sulfate salts mixed with sulfuric acid. The data provide a concentration upper bound of 50-mol% for MgSO₄ and 40-mol% for Na₂SO₄. This newly reported higher sodium and proton content is consistent with low-temperature aqueous differentiation and hydrothermal processing of carbonaceous chondrite-forming materials during the formation and early evolution of Europa.     

Comparison and Interpretation of Spectral Characteristics of the Leading and Trailing Hemispheres of Europa and Callisto

Europa and Callisto are two “extreme members” in a sequence of the Galilean ice satellites formed at different distances from Jupiter. The difference in their mean density probably reflects the material density gradient that appeared even in the subplanetary disk of Jupiter. At the same time, general peculiarities in the composition of the surfaces of Europa and Callisto apparently characterize the accumulated effect of all subsequent evolutionary processes, including current volcanic activity on the satellite Io and its ionized material transfer in Jovian magnetosphere, as well as chemical reactions taking place under low-temperature (within ~90–130 K) and irradiation conditions. In 2016–2017, we observed the leading and trailing hemispheres of Europa and Callisto in the spectral range of 1.0–2.5 μm at 2-m telescope of Caucasian Mountain Observatory (CMO) of Sternberg Astronomical Institute (SAI) of Moscow State University (MSU). We found that, on a global scale, Europa and Callisto exhibit similar spectral characteristics and, particularly, the maxima in the distributions of sulfuric acid hydrate in the trailing hemispheres of the both moons, which agrees with the data of previous measurements. This can be considered as evidence for general ion implantation on these and other moons in the radiation belts of Jupiter. Moreover, our spectral data suggest that water ice and hydrates (clathrates) of other compounds are dominant or abundant in the leading hemispheres of Europa and Callisto. Specifically, we detected a weak absorption band of CH₄ clathrate centered at ~1.67 μm in the reflectance spectra of the leading (the band is more intense) and trailing (the band is less intense) hemispheres of Europa. Weak signs of the same absorption band are also in the reflectance spectra of Callisto measured at its different orientations.     

Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice

Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H₂SO₄·nH₂O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S_x, sulfur dioxide SO₂, hydrogen sulfide H₂S, and H₂SO₄·nH₂O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G_Mixture(SO₄²⁻)=f_Sulfur (r₀/r)^βG₁ molecules (100 eV)⁻¹, where f_Sulfur is the sulfur weight fraction, r is the grain radius, r₀=50 μm, β≈1.9, and G₁=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H₂SO₄) » N(S)>N(SO₂)>N(H₂S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H₂SO₄ is τ(−S)=120(r/r₀)^β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.     

Hydrate sulfuric acid after sulfur implantation in water ice

For many years an ongoing research program performed at our laboratory has had the aim to investigate the implantation of reactive ions in ices relevant to planetology by using IR spectroscopy. We present new results obtained by implanting 200 keV sulfur ions into water ice at 80 K. We have looked at the formation of sulfur-bearing molecules such as sulfuric acid, sulfur dioxide and hydrogen sulfide. We find that hydrated sulfuric acid is formed with high yield (0.65±0.1 molecules/ion). An upper limit to the production yield of SO₂ (Y0.025 molecules/ion) has been estimated; no hydrogen sulfide has been detected. The formation of hydrogen peroxide is confirmed. Ozone is not detected. The results are discussed relevant to the inquiry on the radiolytic sulfur cycle considered responsible for the formation of sulfur-bearing molecules on the surfaces of the Galilean satellites. We demonstrate that sulfur implantation efficiently forms hydrated sulfuric acid whose observed abundance is explained as caused by an exogenic process. It is more difficult to say if the observed sulfur dioxide is quantitatively supported by only sulfur implantation; additional experimental studies are necessary along with direct observations, especially at UV wavelengths such as those that could be performed by instruments on board Hubble Space Telescope or by the forthcoming World Space Observatory (WSO/UV).     

Hydrated minerals on Europa’s surface: An improved look from the Galileo NIMS investigation

The surface composition of Europa is of great importance for understanding both the internal evolution of Europa and its putative ocean. The Near Infrared Mapping Spectrometer (NIMS) investigation on Galileo observed Europa and the other Galilean satellites from 0.7 to 5.2 μm with spatial resolution down to a few kilometers during flybys by the spacecraft as it orbited Jupiter. These data have been analyzed and results published over the life of the Galileo mission and afterward. One result was the discovery of hydrated minerals at some locations on Europa and Ganymede. The data are noisy, especially for Europa, due to radiation affecting the NIMS electronics and detectors, and other artifacts are also present. The NIMS data are now being reprocessed using the accumulated knowledge gained over the entire missions to remove noise spikes and compensate for some other defects in the data. We are analyzing these reprocessed data in an attempt to defined better the nature of the hydrate spectral features and improve their interpretation. We report here on analyses of two NIMS reprocessed observations for the 0.7-3-μm region. A revised hydrate spectrum is calculated and mapped in detail across two lineaments. The spectrum shows the expected distorted water features but little or no spectral structure in these features. A narrow, weak spectral feature appears at 1.344 μm, which is weakly correlated with lower albedo. Several other weak features may be present but are difficult to confirm in these limited data sets. The hydrate signature shows the greatest strength within and toward the center of the lineaments, confirming and strengthening the association of the hydrate with these endogenic features. This trend may indicate that the material in the lineaments is youngest toward the center and has more water frost coverage toward the edge. A small, visually dark, circular feature has a spectrum that shows both hydrate and crystalline water ice features and perhaps contains a hydrate different in spectral characteristics and perhaps composition than found in the lineament.     

A search for temporal variability in the surface chemistry of the icy Galilean satellites

The purpose of this study was to determine if any temporal variability in the broadband UV spectral properties of the icy Galilean satellites exists, and if so, to characterize its spatial distribution as a function of longitude in order to attempt to correlate any temporal changes with satellite surface interactions with the space environment. The temporal time period examined is between 1978-1984 (referred to as the 1980s data) and those from 1995-1996 (referred to as the 1990s data). The plausible temporal characteristics detected appear to vary from one satellite to the next. For Europa possible temporal variations are concentrated on the leading, anti-jovian quadrant. Example broadband UV spectra show Europa's spectral slope decreases (and darkens) with time on the leading and anti-jovian hemispheres, but remains essentially constant with time on the trailing hemisphere. The data quality does not support any definitive temporal changes for Ganymede. Possible temporal changes seen in the Callisto data set are concentrated on the jovian hemisphere. Example broadband UV spectra for Callisto show no definitive change in slope with time. The hypothesis is that these temporal differences in UV spectral properties are caused by variations in the surface ice chemistry due to temporal variability in the space environment. It is postulated that the UV spectral changes suggested for Europa may be linked to changes in H₂O₂ concentrations, whereas the changes on Callisto may be linked to variability in SO₂ concentration.     

New reflectance spectra of 40 asteroids: A comparison with the previous results and an interpretation

This paper presents and discusses selected reflectance spectra of 40 Main Belt asteroids. The spectra have been obtained by the author in the Crimean Laboratory of the Sternberg Astronomical Institute (2003–2009). The aim is to search for new spectral features that characterize the composition of the asteroids’ material. The results are compared with earlier findings to reveal substantial irregularities in the distribution of the chemical-mineralogical compositions of the surface material of a number of minor planets (10 Hygiea, 13 Egeria, 14 Irene, 21 Lutetia, 45 Eugenia, 51 Nemausa, 55 Pandora, 64 Angelina, 69 Hesperia, 80 Sappho, 83 Beatrix, 92 Undina, 129 Antigone, 135 Hertha, and 785 Zwetana), which are manifest at different rotation phases. The vast majority of the analyzed high-temperature asteroids demonstrate subtle spectral features of an atypical hydrated and/or carbonaceous chondrite material (in the form of impurities or separate units), which are likely associated with the peculiarities of the formation of these bodies and the subsequent dynamic and impact processes, which lead, inter alia, to the delivery of atypical materials. Studies of 4 Vesta aboard NASA’s Dawn spacecraft have found that asteroids of similar types can form their own phyllosilicate generations provided that their surface material contains buried icy or hydrated fragments of impacting bodies. The first evidence has been obtained of a spectral phase effect (SPE) at small phase angles (≤4°) for 10 Hygiea, 21 Lutetia, and, possibly, 4 Vesta. The SPE manifests itself in an increasing spectral coefficient of brightness in the visible range with decreasing wavelength. This effect is present in the reflectance spectrum of CM2 carbonaceous material at a phase angle of 10° and absent at larger angles (Cloutis et al., 2011a). The shape of Hygeia’s reflectance spectra at low phase angles appears to be controlled by the SPE during the most part of its rotation period, which may indicate a predominantly carbonaceous chondrite composition on a part of the asteroid’s surface. For Vesta, the SPE may manifest itself in the flat or slightly concave shape of the asteorid’s reflectance spectra at some of the rotation phases, which is likely caused by the increased number of dark spots on corresponding parts of its surface.     

Aircraft observations of Venus' near-infrared reflection spectrum: Implications for cloud composition

We have obtained measurements of Venus' reflection spectrum in the 1.2 to 4.1-μm spectral region from a NASA-Ames operated Lear jet. This was accomplished by observing both Venus and the sun with a spectrometer that contained a circular, variable interference filter, whose effective spectral resolution was 2%. The aircraft results were compared with computer generated spectra of a number of cloud candidates. The only substance which gave an acceptable match to the profile of Venus' strong 3-μm absorption feature, was a water solution of sulfuric acid, that had a concentration of 75% or more H₂SO₄ by weight. However, our spectra also show a modest decline in reflectivity from 2.3 μm towards 1.2-μm wavekength, which is inconsistent with the flat spectrum of sulfuric acid in this spectral region. We hypothesize that this decline is due to impurities in the sulfuric acid droplets.We also compared our list of cloud candidates with several other observed properties of the Venus clouds. While this comparison does not provide as unique an answer as did our analysis of the 3-μm band, we find that, in agreement with the results of Young (1973) and Sill (1973), concentrated sulfuric acid solutions are compatible with these additional observed properties of the Venus clouds. We conclude that the visible cloud layer of Venus is composed of sulfuric acid solution droplets, whose concentration is 75% H₂SO₄, or greater, by weight.     

Geothermal conditions for gas hydrate stability in the Beaufort-Mackenzie area: the global change aspect

Gases locked in hydrates or trapped beneath a gas hydrate cap within the earth are potential contributors to the greenhouse effect, and therefore both thermal conditions of and occurrences of the methane hydrates should be considered in the study of past climate change and of future global warming. The decomposition of methane hydrates triggered by an increase in near surface temperatures and the subsequent upward migration of released gases is occurring at present in the Beauffort-Mackenzie area of northern Canada. In addition to surface warming, the warming effect of the upward flow of the deep fluids, recharged in high elevation areas bordering the Alaska and Yukon coastal plain, may also be a factor in the release of methane directly from deeper buried hydrates in the fluid discharge zones. Any assessment of the total methane contribution to the atmosphere and the rate of the release requires a knowledge of the distribution, spatially and with depth, the temperature and composition of the gas hydrates. In this study the zones of methane hydrate stability are predicted by a thermal method and compared with the distribution of hydrates detected on well logs. An extensive hydrate prone layer extending to as deep as 1400±200 m over an area of 50,000 km² is predicted by the thermal data and hydrate stability field. Comparison of the predicted maximum depths of methane hydrate stability with the maximum depths of hydrate occurrences in 52 wells shows general agreement in the areas of thick offshore and onshore permafrost. Differences in several areas of up to 400 m between the thermally predicted hydrate base and the deepest detected hydrates (detected hydrates are deeper than the predicted ones) can be explained by changes in gas composition. Otherwise low near-surface thermal gradients of approximately 15 mK/m to 20 mK/m (in comparison with observed deep thermal gradients of 25–40 mK/m) would be needed to explain the existence of deep hydrates in the area of the southern Mackenzie Delta trough and offshore north of 71° N latitude. Unfortunately there is no reliable industrial temperature observation from wells to support the latter. Such regional studies of the distribution of gas hydrates, including the stability of those deposits, form a crucial component of an assessment of the influence of gas hydrate formation and decomposition on the proportion of methane present in the earth's atmosphere. Current estimates suggest that between 10.E18 and 10.E21 tonnes of methane may be presently locked in gas hydrate deposits. To fully assess the total amount and the potential contribution to global warming, similar regional assessments are needed for each of the major areas of occurrence, especially in the circumpolar regions which are subject to the greatest increase in temperature conditions.     

Are the clouds of venus sulfuric acid?

Water solutions of sulfuric acid, containing about 75% H₂SO₄ by weight, have a refractive index within 0.01 of the values deduced from polarimetric observations of the Venus clouds. These solutions remain liquid at the cloud temperature, thus explaining the spherical shape of the cloud particles (droplets). The equilibrium vapor pressure of water above such solutions is 0.01 that of liquid water or ice, which accounts for the observed dryness of the cloud region. Furthermore, H₂SO₄ solutions of such concentration have spectra very similar to Venus in the 8–13 μm region; in particular, they explain the 11.2 μm band. Cold sulfuric acid solutions also seem consistent with Venus spectra in the 3–4 μm region. The amount of acid required to make the visible clouds is quite small, and is consistent with both the cosmic abundance of sulfur and the degree of out-gassing of the planet indicated by known atmospheric constituents. Sulfuric acid occurs naturally in volcanic gases, along with known constituents of the Venus atmosphere such as CO₂, HCl, and HF ; it is produced at high temperature by reactions between these gases and common sulfate rocks. The great stability and low vapor pressure of H₂SO₄ and its water solutions explain the lack of other sulfur compounds in the atmosphere of Venus—a lack that is otherwise puzzling.Sulfuric acid precipitation may explain some peculiarities in Venera and Mariner data. Because sulfuric acid solutions are in good agreement with the Venus data, and because no other material that has been proposed is even consistent with the polarimetric and spectroscopic data, H₂SO₄ must be considered the most probable constituent of the Venus clouds.     

Spectral comparison of heavily hydrated salts with disrupted terrains on Europa

Hydrated magnesium sulfate salts have been proposed as major components of the disrupted, reddish terrains on the surface of Europa. This is based on near-infrared reflectance spectra which contain distorted and asymmetric water absorption features typical of moderately hydrated materials such as hexahydrite (MgSO₄⋅6H₂O) and epsomite (MgSO₄⋅7H₂O). Hydrated magnesium sulfates having many waters of hydration could produce improved spectral matches. Here we present cryogenic laboratory spectra of highly hydrated sulfur-bearing salts, including hexahydrite, epsomite, bloedite (Na₂Mg(SO₄)₂⋅4H₂O), mirabilite (Na₂SO₄⋅10H₂O), sodium sulfide nonahydrate (Na₂S⋅9H₂O), supersaturated MgSO₄, NaHCO₃, and Na₂SO₄ brines, and magnesium sulfate dodecahydrate (MgSO₄⋅12H₂O). All have been measured under conditions of pressure and temperature appropriate to the surface environment of Europa. Novel methods for preparation, verification and analysis of MgSO₄⋅12H₂O, which is not stable at standard temperature and pressure (STP), are described. At 100 K, all of these materials exhibit distorted and asymmetric absorption features similar to those in the Europa observations, as well as several weaker, narrow absorptions having widths ranging from 15 to 80 nm. While the agreement with Galileo NIMS observations of dark terrains on Europa is indeed better for highly hydrated salts than for salts of lower hydration states, we conclude that none of these materials alone can account for all of the observed spectral character. As previously suggested, Europa's reddish material appears to be a complex mixture of sulfate hydrates and other materials.     

Thermal state and complex geology of a heterogeneous salty crust of Jupiter's satellite, Europa

The complex geology of Europa is evidenced by many tectonic and cryomagmatic resurfacing structures, some of which are “painted” into a more visible expression by exogenic alteration processes acting on the principal endogenic cryopetrology. The surface materials emplaced and affected by this activity are mainly composed of water ice in some areas, but in other places there are other minerals involved. Non-ice minerals are visually recognized by their low albedo and reddish color either when first emplaced or, more likely, after alteration by Europan weathering processes, especially sublimation and alteration by ionizing radiation. While red chromophoric material could be due to endogenic production of solid sulfur allotropes or other compounds, most likely the red substance is an impurity produced by radiation alteration of hydrated sulfate salts or sulphuric acid of mainly internal origin. If the non-ice red materials or their precursors have a source in the satellite interior, and if they are not merely trace contaminants, then they can play an important role in the evolution of the icy crust, including structural differentiation and the internal dynamics. Here we assume that these substances are major components of Europa's cryo/hydrosphere, as some models have predicted they should be. If this is an accurate assumption, then these substances should not be neglected in physical, chemical, and biological models of Europa, even if major uncertainties remain as to the exact identity, abundance, and distribution of the non-ice materials. The physical chemical properties of the ice-associated materials will contribute to the physical state of the crust today and in the geological past. In order to model the influence of them on the thermal state and the geology, we have determined the thermal properties of the hydrated salts. Our new lab data reveal very low thermal conductivities for hydrated salts compared to water ice. Lower conductivities of salty ice would produce steeper thermal gradients than in pure ice. If there are salt-rich layers inside the crust, forming salt beds over the seafloor or a briny eutectic crust, for instance, the high thermal gradients may promote endogenic geological activity. On the seafloor, bedded salt accumulations may exhibit high thermochemical gradients. Metamorphic and magmatic processes and possible niches for thermophilic life at shallow suboceanic depths result from the calculated thermal profiles, even if the ocean is very cold.     

Large,solid particles in the clouds of Venus: Do they exist?

The discovery of large, solid particles in the clouds of Venus is one of the most significant findings of Pioneer Venus because it means that a substantial mass of the clouds is composed of a material other than sulfuric acid. The evidence which suggests that solid particles form a distinctive size mode is reexamined. The mode is defined by a discontinuity between two size ranges of the Pioneer Venus particle size spectrometer. This discontinuity could represent a real size mode. However, it could also be an artifact of the measurement technique. R. G. Knollenberg (1984) discusses several possible instrumental effects which might have caused this discontinuity. It is hypothesized herein that such effects did occur and that the large particles are really the tail of the mode 2 sulfuric acid particle size distribution and are not a separate mode of solid particles. Using such a revised size distribution, it is shown that all of the Pioneer Venus and Venera optical data from the lower clouds can be explained with sulfuric acid droplets without introducing any solid particles. As a by-product of this analysis, it is also found that the upper clouds of Venus must contain a material with a higher refractive index than sulfuric acid. A small quantity of sulfur could account for this observation.     

The radiolysis of SO2 and H2S in water ice: Implications for the icy jovian satellites

Spectra of Europa, Ganymede, and Callisto reveal surfaces dominated by frozen water, hydrated materials, and minor amounts of SO₂, CO₂, and H₂O₂. These icy moons undergo significant bombardment by jovian magnetospheric radiation (protons, electrons, and sulfur and oxygen ions) which alters their surface compositions. In order to understand radiation-induced changes on icy moons, we have measured the mid-infrared spectra of 0.8 MeV proton-irradiated SO₂, H₂S, and H₂O-ice mixtures containing either SO₂ or H₂S. Samples with H₂O/SO₂ or H₂O/H₂S ratios in the 3-30 range have been irradiated at 86, 110, and 132 K, and the radiation half-lives of SO₂ and H₂S have been determined. New radiation products include the H₂S₂ molecule and HSO⁻₃, HSO⁻₄, and SO²⁻₄ ions, all with spectral features that make them candidates for future laboratory work and, perhaps, astronomical observations. Spectra of both unirradiated and irradiated ices have been recorded as a function of temperature, to examine thermal stability and phase changes. The formation of hydrated sulfuric acid in irradiated ice mixtures has been observed, along with the thermal evolution of hydrates to form pure sulfuric acid. These laboratory studies provide fundamental information on likely processes affecting the outer icy shells of Europa, Ganymede, and Callisto.     

The spatial morphology of Europa's near-surface O2 atmosphere

Results from a three-dimensional ballistic model of Europa's O₂ atmosphere are presented. Hubble Space Telescope (HST) ultraviolet observations show spatially non-uniform O₂ airglow from Europa. One explanation for this is that the O₂ atmosphere is spatially non-uniform. We show that non-uniform ejection of O₂ alone cannot reproduce the required morphology, but that a non-uniform distribution of reactive species in Europa's porous regolith can result in a non-uniform O₂ atmosphere. By allowing O₂ molecules to react with Europa's visibly dark surface material, we produced a spatially non-uniform atmosphere which, assuming uniform electron excitation of O₂ over the trailing hemisphere, compares favorably with the morphology suggested by the HST observations. This model, which requires a larger source of O₂ than has previously been estimated, can in principal be tested by the New Horizons observations of Europa's O₂ atmosphere.     

Chemical and physical properties of the variegated Pluto and Charon surfaces

We present new photometric and spectroscopic observations of the Pluto–Charon system carried out at the VLT-ESO (Chile) with two 8-m telescopes equipped with the FORS2, ISAAC and SINFONI instruments. The spectra were obtained in the 0.6–2.45 μm range with a spectral resolution from 300 to 1500. The SINFONI data were obtained using adaptive optics, allowing a complete separation of the two bodies. We derive both objects’ magnitudes in the near infrared and convert them into albedo values. These first near infrared photometric data allow to adjust the different parts of Pluto’s spectrum, provided by the three instruments. We run spectral models in order to give chemical and physical constraints on the surface of Pluto and Charon. We discuss the dilution properties of the methane ice and its implications on Pluto’s surface. The heterogeneities of the pure and diluted methane ice on Pluto’s surface is also investigated. The high signal-to-noise level of the data and our analyses may support the presence of ethane ice on the surface of Pluto, which is one of the main products of the methane irradiation and photolysis. The analyses of the spectra of Charon suggest that the water ice is almost completely in its crystalline form and that the ammonia compound is hydrated on the surface of this satellite.     

Probing Europa's interior with natural sound sources

Europa's interior structure may be determined by relatively simple and robust seismo-acoustic echo sounding techniques. The strategy is to use ice cracking events or impacts that are hypothesized to occur regularly on Europa's surface as sources of opportunity. A single passive geophone on Europa's surface may then be used to estimate the thickness of its ice shell and the depth of its ocean by measuring the travel time of seismo-acoustic reflections from the corresponding internal strata. Quantitative analysis is presented with full-field seismo-acoustic modeling of the Europan environment. This includes models for Europan ambient noise and conditions on signal-to-noise ratio necessary for the proposed technique to be feasible. The possibility of determining Europa's ice layer thickness by surface wave and modal analysis with a single geophone is also investigated.