The presence and stability of ground ice in the southern hemisphere of Mars

We calculate new estimates of ground-ice stability and the depth distribution of the ice table (the depth boundary between ice-free soil above and ice-cemented soil below) and compare these theoretical estimates of the distribution of ground ice with the observed distribution of leakage neutrons measured by the Neutron Spectrometer instrument of the Mars Odyssey spacecraft's Gamma Ray Spectrometer instrument suite. Our calculated ground-ice distribution contains improvements over previous work in that we include the effects of the high thermal conductivity of ice-cemented soil at and below the ice table, we include the surface elevation dependence of the near-surface atmospheric humidity, and we utilize new high resolution maps of thermal inertia, albedo, and elevation from Mars Global Surveyor observations. Results indicate that ground ice should be about 5 times shallower than in previous predictions. While results are dependent on the atmospheric humidity, depths are generally between a few millimeters and a few meters with typical values of a few centimeters. Results are also geographically similar to previous predictions with differences due to the higher resolution of thermal inertia and the inclusion of elevation effects on humidity. Comparison with the measured epithermal-neutron count rates in the southern hemisphere indicate that the geographic distribution of the count rate is best correlated with ground ice in equilibrium with 10 to 20 pr μm (precipitable micrometers) column abundance of atmospheric water, assuming a uniform distribution with CO₂; however, given the uncertainties, 5 to 30 pr μm also may be viable. This water abundance represents a longer-term average over 100 to 1000 yr. There is a high degree of correlation between the depth of the ice table and the epithermal count rate that agrees remarkably well with predicted count rates as a function of ice-table depth. These results indicate that ground ice in the upper meter of the martian soil is in diffusive equilibrium with the atmosphere. Since ground ice in this depth zone is expected to undergo saturation/desiccation cycles with orbital variations, this ice should be younger than about 500 kyr and was emplaced under similar cold and dry climate conditions of today. Remaining differences between the predicted depths of the ice table and those inferred from the neutron data are likely to be due to subpixel heterogeneity in the martian surface including the presence of rocks, slopes, and patches of soil with varying thermophysical properties.     

Experimental study of the sublimation of ice through an unconsolidated clay layer: Implications for the stability of ice on Mars and the possible diurnal variations in atmospheric water

We have studied the sublimation of ice and water vapor transport through various thicknesses of clay (<63 μm grain size). We experimentally demonstrate that both adsorption and diffusion strongly affect the transport of water, and that the processes of diffusion and adsorption can be separately quantified once the system comes to a steady state. At shallow depths of clay, water vapor transport is determined by diffusion through both the atmosphere and the clay layer, whereas at greater depth the rate of sublimation of the ice is governed only by diffusion through the clay. Using two different models, we determine the diffusion coefficient for water vapor through unconsolidated clay layer to be 1.08±0.04×¹⁰⁻⁴ and . We also determined the adsorption isotherms for the clay layer, which follow the Langmuir theory at low water vapor pressure (<100 Pa, where a monolayer of water molecules forms on the surface of the clay) and the BET theory at higher pressure (where multiple water layers form). From our analysis of both types of isotherms we determined the adsorption constants to be and c=30±10, respectively, and specific surface areas of 1.10±0.2×¹⁰⁵ and , respectively. Finally, we report a theoretical kinetic model for the simultaneous diffusion and adsorption from which we determine adsorption kinetic constants according to the Langmuir theory of and . If the martian regolith possesses diffusive properties similar to those of the unconsolidated montmorillonite soil we investigated here, it would not represent a significant barrier to the sublimation of subsurface ice. However, at the low subsurface temperatures of high latitude (180 K on average), ice could survive from the last glaciation period (about 300 to 400,000 years ago). Higher subsurface temperatures in the equatorial regions would prevent long-timescale survival of ice in the shallow subsurface. In agreement with previous work, we show that adsorption of water by a clay regolith could provide a significant reservoir of subsurface water and it might account for the purported diurnal cycle in the water content of the atmosphere.     

Distinguishing between vapor- and liquid-formed ground ice in the northern martian regolith and potential for biosignatures preserved in ice bodies

In this study, various approaches that can potentially distinguish between vapor- and liquid-derived ground ice in the martian regolith (petrography, geochemistry, stable OH isotopes, CO₂O₂N₂Ar gas composition) are examined using terrestrial ground ice examples. Although the stable OH isotope composition ratios can distinguish between vapor- and liquid-derived terrestrial ground ice, there might be to much mixing between the various water reservoirs on Mars to effectively use it, and, like on Earth, petrographic and geochemical approaches need to be complemented with additional supporting evidences. Of the different approaches currently being employed to determine the origin of terrestrial massive ground ice and icy sediments, it is the concentration of CO₂ and the O₂/Ar, N₂/Ar and N₂/O₂ ratios of air entrapped in the ice that has proven to be the less ambiguous and most discriminatory. This is because the molar ratios of atmospheric gases change during their dissolution in water due to differences in their relative solubilities, thus providing distinctive ratios for the dissolved gases. The gas composition of air entrapped in the ice not only distinguishes between vapor- and liquid-derived ground ice, but any deviation from the theoretical dissolved values can provide insights into potential physical and biological processes operating in the subsurface, a key component for astrobiology.     

Modeling diffusion advection in the mass transfer of water vapor through martian regolith

Diffusion advection is an effect in diffusive multicomponent mass transfer that occurs when the flux vectors of the individual components do not add up to zero. This can be a significant effect for the mass transfer of water vapor from subsurface ice or liquid reservoirs through porous regolith at martian temperatures and pressures. Ignoring diffusion advection and using Fick's law alone to calculate the flux under these conditions will result in an erroneously small value while using a measured flux to calculate a diffusivity will result in an erroneously high value. The inaccuracy in both cases increases with temperature. The literature contains several examples of erroneous treatment of this effect. The correct approach is well-known from other applications of mass transfer and takes diffusion advection into account in the appropriate amount regardless of the temperature and pressure and reduces to the simple Fick's law when conditions warrant. In this way, there is no need to decide under what conditions diffusion advection is or is not important. It can be used in the transition region to pure Knudsen diffusion in a fashion similar to that used with the more limited Fickian approach.     

Water in the upper martian surface at mid- and low-latitudes: presence, state, and consequences

Sublimation of water ice is more effective than evaporation of sorption water at the same temperature. Therefore, water in the form of ice must, over geologic time-scales, have left the upper martian surface (m-scale) at mid- and low-latitudes, leaving sorption water as a possible physical form of stable subsurface water. Adsorption water is “liquid-like” at these temperatures (in the sense of a 2D-liquid). This property is the reason for the specific importance of physisorbed water under martian conditions. It is shown that unfrozen adsorption water can cause numerous physical, chemical, and possibly also biological processes in the upper martian surface and may be responsible for a number of its properties.     

Effects of ionizing radiation on the survival of bacterial spores in artificial martian regolith

Bacterial spores of Bacillus subtilis were used as a model system to study the effects of ionizing radiation on the survivability of spores uncovered and covered with artificial martian regolith. Spore survival after X-ray exposure was mainly depending on the role of non-homologous end-joining (NHEJ) as the major DNA double-strand break repair pathway during germination, the involvement of major small, acid-soluble spore proteins (SASP) as DNA radioprotectants and the coverage by martian regolith, whereas spores covered with martian regolith were significantly more sensitive to X-rays than uncovered spores, which is mainly due to the interaction of X-rays with artificial martian regolith resulting in the formation of secondary electrons and reactive oxygen species.     

Modeling sublimation of ice exposed by new impacts in the martian mid-latitudes

New impacts in the martian mid-latitudes have exposed near-surface ice. This ice is observed to slowly fade over timescales of months. In the present martian climate, exposed surface ice is unstable during summer months in the mid-latitudes and will sublimate. We model the sublimation of ice at five new impact sites and examine the implications of its persistence. Even with generally conservative assumptions, for most reasonable choices of parameters it is likely that over a millimeter of sublimation occurred in the period during which the ice was observed to fade. The persistence of visible ice through such sublimation suggests that the ice is relatively pure rather than pore-filling. Such ice could be analogous to the nearly pure ice observed by the Phoenix Lander in the “Dodo-Goldilocks” trench and suggests that the high ice contents reported by the Mars Odyssey Gamma Ray Spectrometer at high latitudes extend to the mid-latitudes. Our observations are consistent with a model of the martian ice table in which a layer with high volumetric ice content overlies pore-filling ice, although other structures are possible.     

Evidence for ice flow prior to trough formation in the martian north polar layered deposits

The relative importance of surface mass fluxes and ice flow in shaping the north polar layered deposits (NPLD), now or in the past, remains a fundamental and open question. Motivated by observation of an apparent ice divide on Gemina Lingula (also known as Titania Lobe), we propose a two-stage evolution leading to the present-day topography on that lobe of the NPLD. Ice flow approximately balances surface mass fluxes in the first stage, but in the second stage ice flow has minimal influence and topography is modified predominantly by the formation of troughs. We focus here on evidence for the first stage, by testing the fit of topography between troughs to an ice-flow model. We find that independent model fits on distinct flow paths closely match inter-trough topography, uniformly over a broad region on Gemina Lingula, with mutually consistent and physically reasonable fitting parameters. However, our model requires ice to occupy and flow in spaces where troughs currently incise the ice. We therefore infer that the troughs (and the distribution of mass balance that caused them) post-date deposition of the inter-trough material and its modification by flow. Because trough formation has apparently altered inter-trough topography very little, we infer that trough formation must have been rapid in comparison to the (still unknown) time-scale of flow since troughs began to form. We view the evidence for past flow as strong, but we do not think that topographic evidence alone can be conclusive. Observations of englacial stratigraphy using orbital sounding radars will yield conclusive tests of our inferred mechanism for the formation of inter-trough topography.     

Limits on the trapping of atmospheric CH4 in martian polar ice analogs

Recent detection of methane (CH₄) on Mars has generated interest in possible biological or geological sources, but the factors responsible for the reported variability are not understood. Here we explore one potential sink that might affect the seasonal cycling of CH₄ on Mars - trapping in ices deposited on the surface. Our apparatus consisted of a high-vacuum chamber in which three different Mars ice analogs (water, carbon dioxide, and carbon dioxide clathrate hydrates) were deposited in the presence of CH₄ gas. The ices were monitored for spectroscopic evidence of CH₄ trapping using transmission Fourier-Transform Infrared (FT-IR) spectroscopy, and during subsequent sublimation of the ice films the vapor composition was measured using mass spectrometry (MS). Trapping of CH₄ in water ice was confirmed at deposition temperatures <100 K which is consistent with previous work, thus validating the experimental methods. However, no trapping of CH₄ was observed in the ice analogs studied at warmer temperatures (140 K for H₂O and CO₂ clathrate, 90 K for CO₂ snow) with approximately 10 mTorr CH₄ in the chamber. From experimental detection limits these results provide an upper limit of 0.02 for the atmosphere/ice trapping ratio of CH₄. If it is assumed that the trapping mechanism is linear with CH₄ partial pressure and can be extrapolated to Mars, this upper limit would indicate that less than 1% is expected to be trapped from the largest reported CH₄ plume, and therefore does not represent a significant sink for CH₄.     

Continuous monitoring of nightside upper thermospheric mass densities in the martian southern hemisphere over 4 martian years using electron reflectometry

Details are presented of an improved technique to use atmospheric absorption of magnetically reflecting solar wind electrons to constrain neutral mass densities in the nightside martian upper thermosphere. The helical motion of electrons on converging magnetic field lines, through an extended neutral atmosphere, is modeled to enable prediction of loss cone pitch angle distributions measured by the Magnetometer/Electron Reflectometer (MAG/ER) experiment on Mars Global Surveyor at 400 km altitude. Over the small fraction of Mars' southern hemisphere (∼2.5%) where the permanent crustal magnetic fields are both open to the solar wind and sufficiently strong as to dominate the variable induced martian magnetotail field, spherical harmonic expansions of the crustal fields are used to prescribe the magnetic field along the electron's path, allowing least-squares fitting of measured loss cones, in order to solve for parameters describing the vertical neutral atmospheric mass density profile from 160 to 230 km. Results are presented of mass densities in the southern hemisphere at 2 a.m. LST at the mean altitude of greatest sensitivity, 180 km, continuously over four martian years. Seasonal variability in densities is largely explained by orbital and latitudinal changes in dayside insolation that impacts the nightside through the resulting thermospheric circulation. However, the physical processes behind repeatable rapid, late autumnal cooling at mid-latitudes and near-aphelion warming at equatorial latitudes is not fully clear. Southern winter polar warming is generally weak or nonexistent over several Mars years, in basic agreement with MGS and MRO accelerometer observations. The puzzling response of mid-latitude densities from 160° to 200° E to the 2001 global dust storm suggests unanticipated localized nightside upper thermospheric lateral and vertical circulation patterns may accompany such storms. The downturn of the 11-year cycle of solar EUV flux is likely responsible for lower aphelion densities in 2004 and 2006 (Mars years 27 and 28).     

Study of a thermal drill head for the exploration of subsurface planetary ice layers

The recently discovered water vapor plumes on Saturn's moon Enceladus, the polar caps of planet Mars and the possible ice volcanism on the Jovian satellites call for suitable techniques to explore deep ice layers of the solar system bodies. This paper presents a novel approach to deliver scientific probes into deeper layers of planetary ice. Several existing locomotion concepts and techniques for such probes are presented. After studying the mathematical framework of the melting locomotion process, melting tests with different head forms were done to evaluate the influence of the head's geometry on the melting process. This work led to a novel concept of a thermal drill head, using heat and mechanical drill in combination to penetrate the ice. We compare the performance of such a hybrid concept versus the melting penetration alone by a mathematical model and tests in ice with a prototype of the melting drill head.     

Landslides in Valles Marineris (Mars): A possible role of basal lubrication by sub-surface ice

There is much interest on the occurrence of water and ice in the past history of Mars. Because landslides on Mars are much better conserved than their terrestrial counterparts, a physical examination and morphological analysis can reveal significant details on the depositional environment at the instant of failure. A study of the landslides in Valles Marineris based on their physical aspect is presented and the velocity of the landslides is calculated with a stretching block model. The results show that the landslides were subject to strong basal lubrication that made them travel at high speed and to long distances. We use physical analysis to explore the four alternative possibilities that the natural lubricant of the landslides in Valles Marineris was either ice, deep water, a shallow carpet of water, or evaporites. Examination of the furrows present on the surface of the landslide deposits shows that either sub-surface ice or evaporites were likely present on the floor of Valles Marineris during the mass failures.     

Stability of ice on Mars and the water vapor diurnal cycle: Experimental study of the sublimation of ice through a fine-grained basaltic regolith

In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained (<63, 63-125, and 125-250 μm) basaltic powder under simulated martian conditions. Sublimation rates at shallower depths, <10 mm, were determined to be affected by mass transfer through the atmosphere in addition to the basalt layer. For greater depths, the measured diffusion coefficients for water vapor moving through basalt grains were 1.56±0.53×¹⁰⁻⁴, 2.05±0.82×¹⁰⁻⁴, and for the <63, 63-125, and 125-250 μm basaltic layers, respectively. Through the Brunauer, Emmett and Teller (BET) isotherm, which assumes multiple molecular layers of adsorbed water, we determined the adsorption constants of 52.6±8.3 at 270 K for <63 μm, 39.0±6.4 at 267 K for 63-125 μm, and 54.3±9.3 at 266 K for 125-250 μm, resulting in surface areas of 2.6±0.1×¹⁰⁴, 1.7±0.3×¹⁰⁴, , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, <50 pr μm, shallow, 10 mm, ice deposits would last for >10 h at ∼224 K, just above the freezing point of saturated CaCl₂. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago.     

Digging deep for ice in Isidis Planitia—New constraints on subsurface volatile concentrations from thermal modeling

The Isidis Planitia region on Mars usually is regarded as a comparably attractive site for landing missions based on engineering constraints such as elevation and smooth regional topography. The Mars Express landed element Beagle 2 was deployed to this area, and the southern margin of the basin was selected as one of the backup landing sites for the NASA Mars Exploration Rovers.Especially in the context of the Beagle 2 mission, Isidis Planitia has been discussed as a place which might have experienced a volatile-rich history with associated potential for biological activity [e.g. Bridges et al., 2003. Selection of the landing site in Isidis Planitia of Mars Probe Beagle 2. J. Geophys. Res. 108(E1), 5001, doi: 10.1029/2001JE001820]. However the measurements of by the GRS instrument on Mars Odyssey indicate a maximum inferred water abundance of only 3 wt% in the upper few meters of the surface [Feldman et al., 2004. Global distribution of near-surface hydrogen on Mars. J. Geophys. Res. 109, E09006, doi: 10.1029/2003JE002160]. Based on these measurements this area seems to be one of the driest spots in the equatorial region of Mars.To support future landing site selections we took a more detailed look at the minimum burial depth of stable ice deposits in this area, focusing as an example on the planned Beagle 2 landing site. We are especially interested in the likelihood of ground ice deposits within the range of proposed subsurface sampling tools as drills or ‘mole’-like devices [Richter et al., 2002. Development and testing of subsurface sampling devices for the Beagle 2 Lander. Planet. Space Sci. 50, 903-913] given reasonable physical constraints for the surface and near surface material.For a mission like ExoMars [Kminek, G., Vago, J.L., 2005. The Aurora Exploration Program—The ExoMars Mission. In: Proceedings of the 35th Lunar and Planetary Science Conference, abstract no. 1111, 15-19 March 2004, League City, TX] with a focus on finding traces of fossil life the area might be of potential interest, because these traces would be better conserved in the dry soil. Modeling and measurement indicate that Isidis Planitia is indeed a dry place and any hypothetical ground ice deposits in this region are out of range of currently proposed sampling devices.     

Origin of the martian dichotomy and Tharsis from a giant impact causing massive magmatism

The origin of the ancient martian crustal dichotomy and the massive magmatic province of Tharsis remains an open problem. Here, we explore numerically a hypothesis for the origin of these two features involving both exogenic and endogenic processes. We propose a giant impact event during the late stage of planetary formation as the source of the southern highland crust. In a second stage, the extraction of excess heat by vigorous mantle convection on the impacted hemisphere leads to massive magmatism, forming a distinct Tharsis-like volcanic region. By coupling short-term and long-term numerical simulations, we are able to investigate both the early formation as well as the 4.5 Gyr evolution of the martian crust. We demonstrate numerically that this exogenic-endogenic hypothesis is in agreement with observational data from Mars.     

The impact of martian mesoscale winds on surface temperature and on the determination of thermal inertia

Radiative control of surface temperature is a key characteristic of the martian environment and its low-density atmosphere. Here we show through meteorological modeling that surface temperature can be far from radiative equilibrium over numerous sloping terrains on Mars, where nighttime mesoscale katabatic winds impact the surface energy budget. Katabatic circulations induce both adiabatic atmospheric heating and enhancement of downward sensible heat flux, which then becomes comparable to radiative flux and acts to warm the ground. Through this mechanism, surface temperature can increase up to 20 K. One consequence is that warm signatures of surface temperature over slopes, observed through infrared spectrometry, cannot be systematically associated with contrasts of intrinsic soil thermal inertia. Apparent thermal inertia maps retrieved thus far possibly contain wind-induced structures. Another consequence is that surface temperature observations close to sloping terrains could allow the validation of model predictions for martian katabatic winds, provided contrasts in intrinsic thermal inertia can be ruled out. The thermal impact of winds is mostly discussed in this paper in the particular cases of Olympus Mons/Lycus Sulci and Terra Meridiani but is generally significant over any sloped terrains in low thermal inertia areas. It is even general enough to apply under daytime conditions, thereby providing a possible explanation for observed afternoon surface cooling, and to ice-covered terrains, thereby providing new insights on how winds could have shaped the present surface of Mars.     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Spectral imaging of martian water ice clouds and their diurnal behavior during the 1999 aphelion season (Ls = 130°)

We report high-spectral-resolution (λ/δλ = 800-2300) near-infrared mapping observations of Mars at L_s = 130° (April 1999), which were obtained by drift-scanning the cryogenic long-slit spectrometer at the KPNO 2.2-m telescope across the disk. Data were reformatted into calibrated spectral image cubes (x,y,λ) spanning 2.19 to 4.12 μm, which distinguish atmospheric CO₂ features, solar lines, and surface and aerosol features. Maps of relative band depth between 3.0 and 3.5 μm trace water ice clouds and show the diurnal evolution of features in the persistent northern summer aphelion cloud belt, which was mapped contemporaneously but at fixed local time by the Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES). Cloud optical depth, particle sizes, and ice aerosol content were estimated using a two-stream, single-layer scattering model, with Mie coefficients derived from recently published ice optical constants, followed by a linear spectral deconvolution process. A comparison of data and model spectra shows evaporating nighttime clouds in the morning followed by afternoon growth of a prominent orographic cloud feature on the west flank of Elysium Mons. Cloud optical depth at 3.2 μm evolved to 0.28 ± 0.13 and ice aerosol column abundance to 0.9 ± 0.3 pr μm in the afternoon. Column abundances as large as 0.17 pr μm were retrieved in nonorographic clouds within the aphelion cloud band around midday. These clouds exhibit a modest decline in optical depth during the afternoon. Results show that ice particle radii from <2 μm to >4 μm exist in both cloud types. However, large particles dominate the spectra, consistent with recent MGS/TES emission phase function measurements of aphelion cloud aerosol properties.     

A microphysically-based approach to modeling emissivity and albedo of the martian seasonal caps

A new model of albedo and emissivity of the martian seasonal caps represented as porous CO₂ slabs containing spherical voids and dust particles is described. In the model, a radiative transfer model is coupled with a microphysical model in order to link changes in albedo and emissivity to changes in porosity caused by ice metamorphism. The coupled model is capable of reproducing temporal changes in the spectra of the caps taken by the Thermal Emission Spectrometer onboard the Mars Global Surveyor and it can be used as the forward model in the retrievals of the caps' physical properties (porosity, dust abundance, void and dust grain size) from the spectra. Preliminary results from such inversion studies are presented.     

Detectability of minor constituents in the martian atmosphere by infrared and submillimeter spectroscopy

Spectroscopic remote sensing in the infrared and (sub)millimeter range is a powerful technique that is well suited for detecting minor species in planetary atmospheres (Planet Space Sci. 43(1995) 1485). Yet, only a handful of molecules in the Mars atmosphere (CO₂, CO and H₂O along with their isotopic species, O_3, and more recently H₂O₂ and CH₄) have been detected so far by this method. New high performance spectroscopic instruments will become available in the future in the infrared and (sub)millimeter range, for observations from the ground (infrared spectrometers on 8 m class telescopes, large millimeter and submillimeter interferometers) and from space, in particular the Planetary Fourier Spectrometer (PFS) aboard Mars Express (MEx), and the Heterodyne Instrument for the Far-Infrared (HIFI) aboard the Herschel Space Observatory (HSO). In this paper we will present results of a study that determines detectability of minor species in the atmosphere of Mars, taking into account the expected performance of the above spectroscopic instruments. In the near future, a new determination of the D/H value is expected with the PFS, especially during times of maximum H₂O abundance in the martian atmosphere. PFS is also expected to place constraints on the abundance of several minor species (H₂O₂,CH₄,CH₂O, SO₂, H₂S, OCS, HCl) above any local outgassing sources, the hot spots. It will be possible to obtain complementary information on some minor species (O₃,H₂O₂, CH₄) from ground-based infrared spectrometers on large telescopes. In the more distant future, HIFI will be ideally suited for measuring the isotopic ratios with unprecedented accuracy. Moreover, it should be able to observe O₂, which has not yet been detected spectroscopically in the IR/submm range, as well as H₂O₂. HIFI should also provide upper limits for several species that have not yet been detected (HCl, NH₃, PH₃) in the atmosphere of Mars. Some species (SO, SO₂,H₂S, OCS, CH₂O) that may be observable from the ground could be searched for with present single-dish antennae and arrays, and in the future with the Atacama Large Millimeter Array (ALMA) submillimeter interferometer.