Constraints on the composition of the martian south polar cap from gravity and topography

The polar caps of Mars have long been acknowledged to be composed of unknown proportions of water ice, solid CO₂ (dry ice), and dust. Gravity and topography data are here analyzed over the southern cap to place constraints on its density, and hence composition. Using a localized spectral analysis combined with a lithospheric flexure model of ice cap loading, the best fit density of the volatile-rich south polar layered deposits is found to be 1271 kg m⁻³ with 1-σ limits of 1166 and 1391 kg m⁻³. The best fit elastic thickness of this geologically young deposit is 140 km, though any value greater than 102 km can fit the observations. The best fit density implies that about 55% dry ice by volume could be sequestered in these deposits if they were completely dust free. Alternatively, if these deposits were completely free of solid CO₂, the dust content would be constrained to lie between about 14 and 28% by volume. The bulk thermal conductivity of the polar cap is not significantly affected by these maximum allowable concentrations of dust. However, even if a moderate quantity of solid CO₂ were present as horizontal layers, the bulk thermal conductivity of the polar cap would be significantly reduced. Reasonable estimates of the present day heat flow of Mars predict that dry ice beneath the thicker portions of the south polar cap would have melted. Depending on the quantity of solid CO₂ in these deposits today, it is even possible that water ice could melt where the cap is thickest. If independent estimates for either the dust or CO₂ content of the south polar cap could be obtained, and if radar sounding data could determine whether this polar cap is presently experiencing basal melting or not, it would be possible to use these observations to place tight constraints on the present day heat flow of Mars.     

PFS/MEX observations of the condensing CO2 south polar cap of Mars

The condensing CO₂ south polar cap of Mars and the mechanisms of the CO₂ ice accumulation have been studied through the analysis of spectra acquired by the Planetary Fourier Spectrometer (PFS) during the first two years of ESA's Mars Express (MEX) mission. This dataset spans more than half a martian year, from Ls∼330° to Ls∼194°, and includes the southern fall season which is found to be extremely important for the study of the residual south polar cap asymmetry. The cap expands symmetrically and with constant speed during the fall season. The maximum extension occurs sometime in the 80°-90° Ls range, when the cap edges are as low as −40° latitude. Inside Hellas and Argyre basins, frost can be stable at lower latitudes due to the higher pressure values, causing the seasonal cap to be asymmetric. Within the seasonal range considered in this paper, the cap edge recession rate is approximately half the rate at which the cap edge expanded. The longitudinal asymmetries reduce during the cap retreat, and disappear around Ls∼145°. Two different mechanisms are responsible for CO₂ ice accumulation during the fall season, especially in the 50°-70° Ls range. Here, CO₂ condensation in the atmosphere, and thus precipitation, is allowed exclusively in the western hemisphere, and particularly in the longitudinal corridor of the perennial cap. In the eastern hemisphere, the cap consists mainly of CO₂ frost deposits, as a consequence of direct vapor deposition. The differences in the nature of the surface ice deposits are the main cause for the residual south polar cap asymmetry. Results from selected PFS orbits have also been compared with the results provided by the martian general circulation model (GCM) of the Laboratoire de Météorologie dynamique (LMD) in Paris, with the aim of putting the observations in the context of the global circulation. This first attempt of cross-validation between PFS measurements and the LMD GCM on the one hand confirms the interpretation of the observations, and on the other hand shows that the climate modeling during the southern polar night on Mars is extremely sensitive to the dynamical forcing.     

MGS TES observations of the water vapor above the seasonal and perennial ice caps during northern spring and summer

We report on new retrievals of water vapor column abundances from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data. The new retrievals are from the TES nadir data taken above the ‘cold’ surface areas in the North polar region (T_surf < 220 K, including seasonal frost and permanent ice cap) during spring and summer seasons, where retrievals were not performed initially. Retrievals are possible (with some modifications to the original algorithm) over cold surfaces overlaid by sufficiently warm atmosphere. The retrieved water vapor column abundances are compared to the column abundances observed by other spacecrafts in the Northern polar region during spring and summer and good agreement is found. We detect an annulus of water vapor growing above the edge of the retreating seasonal cap during spring. The formation of the vapor annulus is consistent with the previously proposed mechanism for water cycling in the polar region, according to which vapor released by frost sublimation during spring re-condenses on the retreating seasonal CO₂ cap. The source of the vapor in the vapor annulus, according to this model, is the water frost on the surface of the CO₂ at the retreating edge of the cap and the frost on the ground that is exposed by the retreating cap. Small contribution from regolith sources is possible too, but cannot be quantified based on the TES vapor data alone. Water vapor annulus exhibits interannual variability, which we attribute to variations in the atmospheric temperature. We propose that during spring and summer the water ice sublimation is retarded by high relative humidity of the local atmosphere, and that higher atmospheric temperatures lead to higher vapor column abundances by increasing the water holding capacity of the atmosphere. Since the atmospheric temperatures are strongly influenced by the atmospheric dust content, local dust storms may be controlling the release of vapor into the polar atmosphere. Water vapor abundances above the residual polar cap also exhibit noticeable interannual variability. In some years abundances above the cap are lower than the abundances outside of the cap, consistent with previous observations, while in the other years the abundances above the cap are higher or similar to abundances outside of the cap. We speculate that the differences may be due to weaker off-cap transport in the latter case, keeping more vapor closer to the source at the surface of the residual cap. Despite the large observed variability in water vapor column abundances in the Northern polar region during spring and summer, the latitudinal distribution of the vapor mass in the atmosphere is very similar during the summer season. If the variability in vapor abundances is caused by the variability of vapor sources across the residual cap then this would mean that they annually contribute relatively little vapor mass to significantly affect the vapor mass budget. Alternatively this may suggest that the vapor variability is caused by the variability of the polar atmospheric circulation. The new water vapor retrievals should be useful in tuning the Global Circulation Models of the martian water cycle.     

Mars CO2 cycle: Effects of airborne dust and polar cap ice emissivity

Mars General Circulation Model (GCM) simulations are presented to illustrate the importance of the ice emissivity of the seasonal CO₂ polar caps in regulating the effects of airborne dust on the martian CO₂ cycle. Simulated results show that atmospheric dust suppresses CO₂ condensation when the CO₂ ice emissivity is high but enhances it when the CO₂ ice emissivity is low. This raises the possibility that the reason for the repeatable nature of the CO₂ cycle in the presence of a highly variable dust cycle is that the CO₂ ice emissivity is “neutral” - the value that leads to no change in CO₂ condensation with changing atmospheric dust. For this GCM, the “neutral” emissivity is approximately 0.55, which is low compared to observed cap emissivities. This inconsistency poses a problem for this hypothesis. However, it is clear that the CO₂ ice emissivity is a critical physical parameter in determining how atmospheric dust affects the CO₂ cycle on Mars.     

MOC observations of four Mars year variations in the south polar residual cap of Mars

The residual south polar cap of Mars (RSPC) is distinct from the residual north polar cap both in composition and in morphology. CO₂ frost in the RSPC is stabilized by its high albedo during southern spring and summer despite the relatively large insolation during that period. The morphology of the RSPC in summer displays a bewildering variety of depressions that are formed in relatively thin layers of CO₂. The increase of the size of these depressions between each of the first three years of Mars Global Surveyor (MGS) observations may possibly signal some sort of climate change on the planet. For example, the erosion of the bright plateaus might reduce the RSPC albedo and affect the energy balance. The Mars Orbiter Cameras (MOC) on MGS observed Mars for four consecutive martian years before contact with the spacecraft was lost in late 2006. During this period coverage of the polar regions was particularly dense because MGS flew over them on every orbit. In this paper we report on the four-year behavior of the morphological features in the RSPC and on the large-scale variability in RSPC albedo over the period. The changes in the size of the surface features in the RSPC due to backwasting that were first observed between Mars years (MY) 24 and 25 and subsequently between MY25 and M26 was observed to continue at the same rate through MY 27. The results indicate that on average thicker layers in the RSPC retreat faster than thinner ones, roughly in proportion to their thickness. We argue that a simple difference in porosity between the A and B layers can explain this difference although other factors could be involved. The large-scale albedo of the RSPC decreases as the depressions are uncovered by sublimation of seasonal CO₂. However, any interannual differences in albedo due to the backwasting process are masked by interannual differences in the summer dust opacity in the RSPC region.     

Interannual and seasonal behavior of Martian residual ice-cap albedo

The Mars Orbiter Laser Altimeter (MOLA), functioning as a high-resolution radiometer, has observed several appearances of the Martian residual ice caps. We examine these data to quantify both seasonal behavior and interannual differences. The northern residual cap (NRC) was found to be mostly stable with the exception of one, previously identified, region of strong variability. Interannual change in the extent of the NRC appears to be small and reversible on timescales of 1 or 2 years. The NRC has an elaborate seasonal evolution of albedo. Annuli of fine-grained CO₂ and water frost, which track the inner and outer edges of the seasonal CO₂ cap, cause large temporary brightenings. The NRC albedo is stable from just after solstice to L_s 150°, after which albedo decreases steadily. This late-summer darkening can be explained by shadowing within the rough topography of the NRC, leading to a lower limit on topographic relief of 80 cm. The southern residual cap (SRC) appears stable in extent. As has been previously discovered, its seasonal frost albedo behavior appears to be correlated with insolation. However, residual CO₂ appears not to share this characteristic; we use this behavioral difference to infer net deposition of CO₂ ice on the SRC during 1 out of 3 years. Uncharacteristically, the SRC abruptly darkens at L_s 320° in 1 Martian year (year beginning April 2002). Circumstantial evidence suggests atmospheric scattering by dust is responsible. The 2001 global dust-storm appears, either, to have had no effect on the polar cap albedos, or, resulted in slightly brighter ice deposits.     

Enhanced CO2 trapping in water ice via atmospheric deposition with relevance to Mars

It has been suggested that inclusions of CO₂ or CO₂ clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO₂ molecules were trapped in water ice deposited from CO₂/H₂O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H₂O ice is deposited at 140-165 K, CO₂ is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO₂ ice, and therefore this mechanism may allow for CO₂ deposition at the poles during warmer periods. The amount of trapped CO₂ varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C₄H₈O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO₂ clathrate hydrates. These results have implications for the CO₂ content, overall composition, and density of the polar deposits on Mars.     

Variability of the south polar cap of Mars in Mars years 28 and 29

We have used Mars Reconnaissance Orbiter data from 2007 and 2009 to compare summer behaviors of the seasonal and residual south polar caps of Mars in those two years. We find that the planet-encircling dust storm that occurred in the first of the two Mars years enhanced the loss of seasonal CO₂ deposits relative to the second year but did not have a large effect on the continuing erosion of the pits and mesas within the residual cap materials. This suggests that the increase of bright frost in some regions of the residual cap observed between Mariner 9 and Viking can be accommodated within observed martian weather variability and does not require unknown processes or climate change.     

Thick and thin models of the evolution of carbon dioxide on Mars

We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO₂ ice cap) for a wide range of initial inventories. We find that the initial inventory of CO₂ broadly determines the evolutionary course of the reservoirs of CO₂. The reservoirs include the atmosphere, ice cap, adsorbed CO₂ in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO₂ toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO₂ ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO₂ remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO₂ ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity.     

Observations of the north polar water ice annulus on Mars using THEMIS and TES

The Martian seasonal CO₂ ice caps advance and retreat each year. In the spring, as the CO₂ cap gradually retreats, it leaves behind an extensive defrosting zone from the solid CO₂ cap to the location where all CO₂ frost has sublimated. We have been studying this phenomenon in the north polar region using data from the THermal EMission Imaging System (THEMIS), a visible and infra-red (IR) camera on the Mars Odyssey spacecraft, and the Thermal Emission Spectrometer (TES) on Mars Global Surveyor. Recently, we discovered that some THEMIS images of the CO₂ defrosting zone contain evidence for a distinct defrosting phenomenon: some areas just south of the CO₂ cap edge are too bright in visible wavelengths to be defrosted terrain, but too warm in the IR to be CO₂ ice. We hypothesize that we are seeing evidence for a seasonal annulus of water ice (frost) that recedes with the seasonal CO₂ cap, as predicted by previous workers. In this paper, we describe our observations with THEMIS and compare them to simultaneous observations by TES and OMEGA. All three instruments find that this phenomenon is distinct from the CO₂ cap and most likely composed of water ice. We also find strong evidence that the annulus widens as it recedes. Finally, we show that this annulus can be detected in the raw THEMIS data as it is collected, enabling future long-term onboard monitoring.     

The atmospheric circulation and dust activity in different orbital epochs on Mars

A general circulation model is used to evaluate changes to the circulation and dust transport in the martian atmosphere for a range of past orbital conditions. A dust transport scheme, including parameterized dust lifting, is incorporated within the model to enable passive or radiatively active dust transport. The focus is on changes which relate to surface features, as these may potentially be verified by observations. Obliquity variations have the largest impact, as they affect the latitudinal distribution of solar heating. At low obliquities permanent CO₂ ice caps form at both poles, lowering mean surface pressures. At higher obliquities, solar insolation peaks at higher summer latitudes near solstice, producing a stronger, broader meridional circulation and a larger seasonal CO₂ ice cap in winter. Near-surface winds associated with the main meridional circulation intensify and extend polewards, with changes in cap edge position also affecting the flow. Hence the model predicts significant changes in surface wind directions as well as magnitudes. Dust lifting by wind stress increases with obliquity as the meridional circulation and associated near-surface winds strengthen. If active dust transport is used, then lifting rates increase further in response to the larger atmospheric dust opacities (hence circulation) produced. Dust lifting by dust devils increases more gradually with obliquity, having a weaker link to the meridional circulation. The primary effect of varying eccentricity is to change the impact of varying the areocentric longitude of perihelion, l, which determines when the solar forcing is strongest. The atmospheric circulation is stronger when l aligns with solstice rather than equinox, and there is also a bias from the martian topography, resulting in the strongest circulations when perihelion is at northern winter solstice. Net dust accumulation depends on both lifting and deposition. Dust which has been well mixed within the atmosphere is deposited preferentially over high topography. For wind stress lifting, the combination produces peak net removal within western boundary currents and southern midlatitude bands, and net accumulation concentrated in Arabia and Tharsis. In active dust transport experiments, dust is also scoured from northern midlatitudes during winter, further confining peak accumulation to equatorial regions. As obliquity increases, polar accumulation rates increase for wind stress lifting and are largest for high eccentricities when perihelion occurs during northern winter. For dust devil lifting, polar accumulation rates increase (though less rapidly) with obliquity above o=25°, but increase with decreasing obliquity below this, thus polar dust accumulation at low obliquities may be increasingly due to dust lifted by dust devils. For all cases discussed, the pole receiving most dust shifts from north to south as obliquity is increased.     

MARCI and MOC observations of the atmosphere and surface cap in the north polar region of Mars

We used MGS-MOC and MRO-MARCI daily mapping images of the North Polar Region of Mars from 16 August 2005 (L_s = 270°) to 21 May 2009 (L_s = 270°), covering portions of three consecutive martian years (MY 27-MY 29), to observe the seasonal behavior of the polar ice cap and atmospheric phenomena. The rate of cap regression was similar in MY 28 and MY 29, but was advanced by 3.5° of L_s (∼7-8 sols) in MY 29. The spatial and temporal behaviors of dust and condensate clouds were similar in the two years and generally in accord with prior years. Dust storms (>100 km²) were observed in all seasons, with peak activity occurring at L_s = 10-20° from 50°N to 70°N and at L_s = 135-140° from 70°N to 90°N. The most active quadrant was 0-90°W in MY 28, shifting to 180-270°W in MY 29. The majority of regional storms in both years developed in longitudes from 10°W to 60°W. During late summer the larger storms obscure the North Polar Region in a cloud of dust that transitions to north polar hood condensate clouds around autumnal equinox.Changes in the distribution of perennial ice deposits, especially in Olympia Planum, were observed between the 2 years, with the MY 29 ice distribution being the most extensive observed to date. Modeling suggests that the small, bright ice patches on the residual cap are not the result of slope or elevation effects. Rather we suggest that they are the result of local meteorological effects on ice deposition. The annual darkening and brightening of peripheral areas of the residual cap around summer solstice can be explained by the sublimation of a brighter frost layer revealing an underlying darker, ice rich layer that itself either sublimes to reveal brighter material below or acts as a cold trap, attracting condensation of water vapor that brightens the surface. An alternative explanation invokes transport and deposition of dust on the surface from the cap interior, and later removal of that dust. The decrease in cap albedo and accompanying increase in near surface atmospheric stability may be related to the annual minimum of polar storm activity near northern summer solstice.     

Numerical simulation of the winter polar wave clouds observed by Mars Global Surveyor Mars Orbiter Laser Altimeter

In 1998, the Mars Orbiter Laser Altimeter revealed the presence of isolated or quasi-periodic thick clouds during the martian polar night. They are believed to be composed of CO₂ ice particles and to be tilted against the wind direction, a feature characteristic of vertically propagating orographic gravity waves. To support that interpretation, we present here numerical simulations with a two-dimensional anelastic model of stratified shear flow that includes simple CO₂ ice microphysics. In some of the simulations presented, the orography is an idealized trough, with dimensions characteristic of the many troughs that shape the Mars polar cap. In others, it is near the real orography. In the polar night conditions, our model shows that gravity waves over the north polar cap are strong enough to induce adiabatic cooling below the CO₂ frost point. From this cooling, airborne heterogeneous nucleation of CO₂ ice particles occurs from the ground up to the altitude of the polar thermal inversion. Although the model predicts that clouds can be present above 15 km, only low altitude clouds can backscatter the Laser beams of MOLA at a detectable level. Accordingly, the shape of the Laser echoes is related to the shape of the clouds at low level, but do not necessarily coincide with the top of the clouds. The model helps to interpret the cloud patterns observed by MOLA. Above an isolated orographic trough, an isolated extended sloping cloud tilted against the wind is obtained. The model shows that the observed quasi-periodic clouds are due to the succession of small-scale topographic features, rather than to the presence of resonant trapped lee waves. Indeed, the CO₂ condensation greatly damps the buoyancy force, essential for the maintenance of gravity waves far from their sources. Simulations with realistic topography profiles show the cloud response is sensitive to the wind direction. When the wind is directed upslope of the polar cap, on the one hand, a large scale cloud, modulated by small-scale waves, forms just above the ground. On the other hand, when the wind is directed downslope, air is globally warmed, and periodic ice clouds induced by small-scale orography form at altitudes higher than 3-5 km above the ground. In both cases, a good agreement between the simulated echoes and the observed one is obtained. According to our model, we conclude that the observed clouds are quasi-stationary clouds made of moving ice particles that successively grow and sublimate by crossing cold and warm phases of orographic gravity waves generated by the successive polar troughs. We also find that the rate of ice precipitation is relatively weak, except when there is a large scale air dynamical cooling.     

Residual south polar cap of Mars: Stratigraphy, history, and implications of recent changes

The residual south polar cap (RSPC) of Mars includes a group of different depositional units of CO₂ ice undergoing a variety of erosional processes. Complete summer coverage of the RSPC by ∼6-m/pixel data of the Context Imager (CTX) on Mars Reconnaissance Orbiter (MRO) has allowed mapping and inventory of the units in the RSPC. Unit maps and estimated thicknesses indicate the total volume of the RSPC is currently <380 km³, and represents less than 3% of the total mass of the current Mars atmosphere. Scarp retreat rates in the CO₂ ice derived from comparison of High Resolution Imaging Science Experiment (HiRISE) data with earlier images are comparable to those obtained for periods up to 3 Mars years earlier. These rates, combined with sizes of depressions suggest that the oldest materials were deposited more than 125 Mars years ago. Most current erosion is by backwasting of scarps 1-12 m in height. This backwasting is initiated by a series of scarp-parallel fractures. In the older, thicker unit these fractures form about every Mars year; in thinner, younger materials they form less frequently. Some areas of the older, thicker unit are lost by downwasting rather than by the scarp retreat. A surprising finding from the HiRISE data is the scarcity of visible layering of RSPC materials, a result quite distinct from previous interpretations of layers in lower resolution images. Layers ∼0.1 m thick are exposed on the upper surfaces of some areas, but their timescale of deposition is not known. Late summer albedo changes mapped by the CTX images indicate local recycling of ice, although the amounts may be morphologically insignificant. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) data show that the primary material of all the different forms of the RSPC is CO₂ ice with only small admixtures of water ice and dust.     

Albedo models for the residual south polar cap on Mars: Implications for the stability of the cap under near-perihelion global dust storm conditions

It is uncertain whether the residual (perennial) south polar cap on Mars is a transitory or a permanent feature in the current Martian climate. While there is no firm evidence for complete disappearance of the cap in the past, clearly observable changes have been documented. Observations suggest that the perennial cap lost more CO₂ material in the spring/summer season prior to the Mariner 9 mission than in those same seasons monitored by Viking and Mars Global Surveyor. In this paper we examine one process that may contribute to these changes—the radiative effects of a planet encircling dust storm that starts during late Martian southern spring on the stability of the perennial south polar cap. To approach this, we model the radiative transfer through a dusty planetary atmosphere bounded by a sublimating CO₂ surface.A critical parameter for this modeling is the surface albedo spectrum from the near-UV to the thermal-IR, which was determined from both space-craft and Earth-based observations covering multiple wavelength regimes. Such a multi-wavelength approach is highly desirable since one spectral band by itself cannot tightly constrain the three-parameter space for polar surface albedo models, namely photon “scattering length” in the CO₂ ice and the amounts of intermixed water and dust.Our results suggest that a planet-encircling dust storm with onset near solstice can affect the perennial cap's stability, leading to advanced sublimation in a “dusty” year. Since the total amount of solid CO₂ removed by a single storm may be less than the total CO₂ thickness, a series of dust storms would be required to remove the entire residual CO₂ ice layer from the south perennial cap.     

Comparison between polar regions of Mars from HEND/Odyssey data

In this paper, we have analyzed neutron spectroscopy data gathered by the High Energy Neutron Detector (HEND) instrument onboard Mars Odyssey for comparison of polar regions. It is known that observation of the neutron albedo of Mars provides important information about the distribution of water-ice in subsurface layers and about peculiarities of the CO₂ seasonal cycle. It was found that there are large water-rich permafrost areas with contents of up to ∼50% water by mass fraction at both the north and south Mars polar regions. The water-ice layers at high northern latitudes are placed close to the surface, but in the south they are covered by a dry and relatively thick (10-20 cm) layer of soil. Analysis of temporal variations of neutron flux between summer and winter seasons allowed the estimation of the masses of the CO₂ deposits which seasonally condense at the polar regions. The total mass of the southern seasonal deposition was estimated as 6.3×¹⁰¹⁵ kg, which is larger than the total mass of the seasonal deposition at the north by 40-50%. These results are in good agreement with predictions from the NASA Ames Research Center General Circulation Model (GCM). But, the dynamics of the condensation and sublimation processes are not quite as consistent with these models: the peak accumulation of the condensed mass of CO₂ occurred 10-15 degrees of Ls later than is predicted by the GCM.     

Yearly comparisons of the martian polar caps: 1999-2003 Mars Orbiter Camera observations

The Mars Global Surveyor Mars Orbiter Camera wide-angle cameras were used to obtain images of the north and south seasonal and residual polar caps between 1999 and 2003. Wide-angle red camera images were used in assembling mosaics of the north and south polar recessions and regression rates were measured and compared. There are small variations in the north polar recession between 2000 and 2002, especially between LS=7° and LS=50°, however there is no evidence for the plateau in the recession curves that has been observed in some prior years. The south polar recession changes very little from year to year, and the 2001 dust storm had little if any effect on the average cap recession that year. Albedo values of the geographic north pole were measured using wide-angle red and blue camera images, and the residual south polar cap configuration was compared between the three years observed by MOC. The albedo of the geographic north pole generally varies between 0.5 and 0.6 as measured from MOC wide-angle red camera images. There were only minor variations near the edges of the residual south polar cap between the three years examined.     

The effect of ground ice on the Martian seasonal CO2 cycle

The mostly carbon dioxide (CO₂) atmosphere of Mars condenses and sublimes in the polar regions, giving rise to the familiar waxing and waning of its polar caps. The signature of this seasonal CO₂ cycle has been detected in surface pressure measurements from the Viking and Pathfinder landers. The amount of CO₂ that condenses during fall and winter is controlled by the net polar energy loss, which is dominated by emitted infrared radiation from the cap itself. However, models of the CO₂ cycle match the surface pressure data only if the emitted radiation is artificially suppressed suggesting that they are missing a heat source. Here we show that the missing heat source is the conducted energy coming from soil that contains water ice very close to the surface. The presence of ice significantly increases the thermal conductivity of the ground such that more of the solar energy absorbed at the surface during summer is conducted downward into the ground where it is stored and released back to the surface during fall and winter thereby retarding the CO₂ condensation rate. The reduction in the condensation rate is very sensitive to the depth of the soil/ice interface, which our models suggest is about 8 cm in the Northern Hemisphere and 11 cm in the Southern Hemisphere. This is consistent with the detection of significant amounts of polar ground ice by the Mars Odyssey Gamma Ray Spectrometer and provides an independent means for assessing how close to the surface the ice must be. Our results also provide an accurate determination of the global annual mean size of the atmosphere and cap CO₂ reservoirs, which are, respectively, 6.1 and 0.9 hPa. They also indicate that general circulation models will need to account for the effect of ground ice in their simulations of the seasonal CO₂ cycle.     

Sublimation kinetics of CO2 ice on Mars

Dynamic models of the martian polar caps are in abundance, but most rely on the assumption that the rate of sublimation of CO₂ ice can be calculated from heat transfer and lack experimental verification. We experimentally measured the sublimation rate of pure CO₂ ice under simulated martian conditions as a test of this assumption, developed a model based on our experimental results, and compared our model's predictions with observations from several martian missions (MRO, MGS, Viking). We show that sun irradiance is the primary control for the sublimation of CO₂ ice on the martian poles with the amount of radiation penetrating the surface being controlled by variations in the optical depth, ensuring the formation and sublimation of the seasonal cap. Our model confirmed by comparison of MGS-MOC and MRO-HiRISE images, separated by 2-3 martian years, shows that ∼0.4 m are currently being lost from the south perennial cap per martian year. At this rate, the ∼2.4-m-thick south CO₂ perennial cap will disappear in about 6-7 martian years, unless a short-scale climatic cycle alters this rate of retreat.     

Quantum chemical calculation on the potential energy surface of H2CO3 and its implication for martian chemistry

A detailed theoretical study of the potential energy surface of H₂CO₃ is explored at the CCSD(T)//B3LYP/aug-cc-pVTZ level. On the potential energy surface, 12 isomers of H₂CO₃ are located. Their molecular properties such as geometries, vibrational frequencies, rotational constants, dipole moments, gas-phase acidities, and relative energies are calculated. Various reaction pathways and decomposition products have also been discussed. Among these products, CO₂ and H₂O are definitely the most favorable products with predominant abundance. Large energy barriers are predicted for other dissociation channels leading to the formation of oxygen, formaldehyde, and so on. These high energy channels are not important thermodynamically and kinetically, but they might occur in the presence of cosmic rays in astronomic environments. From the present work we suggest that chemical reactions between CO₂ and H₂O at the polar ice caps could be a potential source of H₂CO and O₂, in addition to the previously proposed mechanisms, i.e., the oxidation of methane and cosmic-ray-mediated production through the intermediate H₂CO₃. The results of the present work may provide useful data to improve our understanding of icy chemistry at the polar caps on Mars.