The Physics and Chemistry of Sputtering by Energetic Plasma Ions

Energetic ions from the solar wind, local pick-up ions or magnetospheric plasma ions impact the atmospheres and surfaces of a number of solar system bodies. These energetic incident ions deposit energy in the gas or solid. This can lead to the ejection of atoms and molecules, a process referred to as sputtering. In this paper we first describe the physics and chemistry of atmospheric and surface sputtering. We then apply this to the production of a thin atmosphere on Europa by magnetospheric ion bombardment of Europa's surface and show that Europa loses more Na atoms than it receives from the Jupiter magnetosphere. The loss of atmosphere from Mars in earlier epochs by pick-up ion sputtering of that atmosphere is also calculated. This revised version was published online in July 2006 with corrections to the Cover Date.     

Europa's Sodium Atmosphere: An Ocean Source?

Sputtering and decomposition of Europa's surface by energetic ions and electrons produce an atmosphere. Here we use a 3D Monte Carlo simulation, including collisions with the background O₂ atmosphere, to describe recent measurements of the sodium component of the atmosphere. By constraining the model with the observational data, we attempt to reconstruct the source processes, the energy distribution, and the flux of the ejected sodium. We confirm that electronic sputtering from ice-rich regions dominates the ejecta and that Europa loses between 5 and 10×10⁶ Na cm⁻² s⁻¹. This is about one order of magnitude more sodium than that implanted from the jovian magnetosphere.     

Energy Distributions for Desorption of Sodium and Potassium from Ice: The Na/K Ratio at Europa

The sputtering and decomposition of the surface of Europa by fast ions and electrons lead to the production of an atomosphere containing sodium and potassium atoms. Here time-of-flight energy distributions are measured for Na and K sputtered from a vapor-deposited ice by 200-eV electrons. These data are then used in a Monte Carlo simulation for alkalis in Europa's atmosphere. Na/K ratios versus distance from Europa are calculated and compared to the recent observations in the range 6 to 18 Europan radii from the surface. Normalizing to the observations, the Na/K ratio for the loss rates is ∼27 and the ratio for the average surface source rates is ∼20. These ratios are very different from the Na/K ratio at Io and are larger than the Na/K ratio suggested for Europa's putative subsurface ocean, consistent with fractionation on freezing and upwelling of ocean material.     

Europa's neutral cloud: morphology and comparisons to Io

Ground based observations of sodium escaping from Europa suggest the presence of an extended cloud of neutrals orbiting Jupiter. Using a Monte Carlo model we show that the large scale morphology differs from the sodium cloud at Io. At Europa, the trailing cloud is brighter and more extended than the leading cloud. We then use our results to consider the morphology of Europa's oxygen cloud.     

Potential relations between Caloris basin and Mercury's sodium exosphere

We have developed a 1D thermal model of Mercury's regolith, in order to simulate the heat diffusion in the upper subsurface (first 10 m). We assume in our model that the thermophysical properties of the Hermean regolith are similar to those of the lunar regolith. We apply our thermal model to the Caloris basin which slopes induce distortions of the surface temperature compared to results obtained for a perfect spherical planet. This thermal model is then coupled with a 3D Monte Carlo model of Mercury's sodium exosphere [Leblanc, F., Johnson, R.E., 2003. Icarus 164, 261-281; Leblanc, F., Delcourt, D., Johnson, R.E., 2003b. J. Geophys. Res. 108 (E12), doi:10.1029/2003JE002151/.5136], in order to describe the signatures of Caloris basin on Mercury's sodium exosphere in term of temporal and spatial variabilities. In particular, we find a motion of the maxima of sodium density in the exosphere towards the Northern hemisphere similar to the one observed by Potter et al. [Potter, A.E., Morgan, T.H., Killen, R.M., 1999. Planet. Space Sci., 47, 1441-1449] but did not reproduce the observed change of the emission brightness. The main conclusion of this study is that the Caloris basin-exosphere relations might be observable from the Earth which we hope will motivate new observations of Mercury's exosphere.     

Sputtering of ice grains and icy satellites in Saturn's inner magnetosphere

Icy grains and satellites orbiting in Saturn's magnetosphere are immersed in a plasma that sputters their surfaces. This limits the lifetime of the E-ring grains and ejects neutrals that orbit Saturn until they are ionized and populate its magnetosphere. Here we re-evaluate the sputtering rate of ice in Saturn's inner magnetosphere using the recent Cassini data on the plasma ion density, temperature and composition [Sittler Jr., E.C., et al., 2007a. Ion and neutral sources and sinks within Saturn's inner magnetosphere: Cassini results. Planet. Space Sci. 56, 3-18.] and a recent summary of the relevant sputtering data for ice [Famá, M., Shi, J., Baragiola, R.A., 2008. Sputtering of ice by low-energy ions. Surf. Sci. 602, 156-161.]. Although the energetic (>10 keV) ion component at Saturn is much smaller than was assumed to be the case after Voyager [Jurac, S., Johnson, R.E., Richardson, J.D., Paranicas, C., 2001a. Satellite sputtering in Saturn's magnetosphere. Planet. Space Sci. 49, 319-326; Jurac, S., Johnson, R.E., Richardson, J.D., 2001b. Saturn's E ring and production of the neutral torus. Icarus 149, 384-396.], we show that the sputtering rates are sensitive to the temperature of the thermal plasma and are still robust, so that sputtering likely determines the lifetime of the grains in Saturn's tenuous E-ring.     

Cassini UVIS observations of Europa's oxygen atmosphere and torus

Observations of the Europa environment using the Cassini UltraViolet Imaging Spectrograph (UVIS) show the presence of an extended atomic oxygen atmosphere in addition to the bound molecular oxygen atmosphere first detected by Hubble Space Telescope in 1994 [D.T. Hall, D.F. Strobel, P.D. Feldman, M.A. McGrath, H.A. Weaver, 1995, Detection of an oxygen atmosphere on Jupiter's moon Europa, Nature 373, 677-679]. The atomic oxygen measurement provides a direct constraint on the sputtering and loss of Europa's water ice surface and the interaction of Europa's atmosphere with Jupiter's magnetosphere. We derive a loss rate for O₂ based on the emission rate of the OI 1356 Å multiplet. UVIS detected substantial variability in the oxygen emission from Europa's oxygen atmosphere that we attribute to the viewing geometry. B.H. Mauk, D.G. Mitchell, S.M. Krimigis, E.C. Roelof, C.P. Paranicas [2003, Energetic neutral atoms from a trans-Europa gas torus at Jupiter, Nature 421, 920-922] inferred the presence of a torus of neutral gas at Europa's orbit based on Cassini's energetic neutral atom (ENA) image of the Jupiter system acquired with the Magnetospheric Imaging Instrument (MIMI), with the most likely torus constituents being hydrogen and oxygen species sputtered from Europa. Cassini UVIS data rule out O and O₂ as the possible torus species reported by Mauk et al. however, unless the torus density is so low that it is undetectable by UVIS (less than 8 atoms / cm³). The UVIS observations indicate the presence of atomic hydrogen and possibly other species, but a full analysis is deferred to a following paper. The hydrogen in the present observations shows a local-time asymmetry and complex spatial distribution.     

Europa's Oxygen Exosphere and Its Magnetospheric Interaction

The newly detected oxygen atmosphere of Europa is modeled by invoking charged particle sputtering with H₂O and O₂molecules as the main ejecta. The magnetospheric corotating ions could provide the required source strength (∼3 × 10²⁶sec⁻¹) of O₂molecules if a fraction (∼20%) of the exospheric ions were recycled to Europa's surface where they produce additional sputtering product. Two exospheric components are expected to form: an extended corona with a size of a few satellite radii which is composed of sputtered molecules in ballistic motion, and a thermal population with a surface density of 10⁸–10⁹cm⁻³and a scale height of about 20 km. The electron impact ionization of this exosphere would lead to an Io-like interaction with the jovian magnetosphere with a field-aligned Birkeland current of about 5 × 10⁵A.     

Surface-bounded atmosphere of Europa

A 1-D collisional Monte Carlo model of Europa's atmosphere is described in which the sublimation and sputtering sources of H₂O molecules and their molecular fragments are accounted for as well as the radiolytically produced O₂. Dissociation and ionization of H₂O and O₂ by magnetospheric electron, solar UV-photon and photo-electron impact, and collisional ejection from the atmosphere by the low-energy plasma are taken into account. Reactions with the surface are discussed, but only adsorption and atomic oxygen recombination are included in this model. The size of the surface-bounded oxygen atmosphere of Europa is primarily determined by a balance between atmospheric sources from irradiation of the satellite's icy surface by the high-energy magnetospheric charged particles and atmospheric losses from collisional ejection by the low-energy plasma, photo- and electron-impact dissociation, and ionization and pick-up from the surface-bounded atmosphere. A range of sources rates for O₂ to H₂O are used with a larger oxygen-to-water ratio than suggested by laboratory measurements in order to account for differences in adsorption onto grains in the regolith. These calculations show that the atmospheric composition is determined by both the water and oxygen photochemistry in the near-surface region, escape of suprathermal oxygen and water into the jovian system, and the exchange of radiolytic water products with the porous regolith. For the electron impact ionization rates used, pick-up ionization is the dominant oxygen loss process, whereas photo-dissociation and atmospheric sputtering are the dominant sources of neutral oxygen for Europa's neutral torus. Including desorption and loss of water enhances the supply of oxygen species to the neutral torus, but hydrogen produced by radiolysis is the dominant source of neutrals for Europa's torus in these models.     

X-ray probes of magnetospheric interactions with Jupiter's auroral zones, the Galilean satellites, and the Io plasma torus

Remote observations with the Chandra X-ray Observatory and the XMM-Newton Observatory have shown that the jovian system is a source of X-rays with a rich and complicated structure. The planet's polar auroral zones and its disk are both powerful sources of X-ray emission. Chandra observations revealed X-ray emission from the Io plasma torus and from the Galilean moons Io, Europa, and possibly Ganymede. The emission from the moons is due to bombardment of their surfaces by highly energetic magnetospheric protons, and oxygen and sulfur ions. These ions excite atoms in their surfaces leading to fluorescent X-ray emission lines. These lines are produced against an intense background continuum, including bremsstrahlung radiation from surface interactions of primary magnetospheric and secondary electrons. Although the X-ray emission from the Galilean moons is faint when observed from Earth orbit, an imaging X-ray spectrometer in orbit around one or more of these moons, operating from 200 eV to 8 keV with 150 eV energy resolution, would provide a detailed mapping of the elemental composition in their surfaces. Surface resolution of 40 m for small features could be achieved in a 100-km orbit around one moon while also remotely imaging surfaces of other moons and Jupiter's upper atmosphere at maximum regional resolutions of hundreds of kilometers. Due to its relatively more benign magnetospheric radiation environment, its intrinsic interest as the largest moon in the Solar System, and its mini-magnetosphere, Ganymede would be the ideal orbital location for long-term observational studies of the jovian system. Here we describe the physical processes leading to X-ray emission from the surfaces of Jupiter's moons and the properties required for the technique of imaging X-ray spectroscopy to map the elemental composition of their surfaces, as well as studies of the X-ray emission from the planet's aurora and disk and from the Io plasma torus.     

Effects of Io ejecta on Europa

We examine the effects of Io ejecta on the surface and environment of Europa. We find that the observed sulfur on the trailing side of Europa, when interpreted as a deposit in equilibrium between implanation of, and sputtering by, corotating Io ejecta, implies a slow loss of material from Europa by sputtering. From this we infer that the spectrum of particles sputtered from water ice is soft. The quantity of observed sulfur and its confinement to the trailing hemisphere appear to exclude significant implantation and sputtering by energetic heavy ions. We also conclude that the contribution from Europa to the magnetospheric plasma (even at Europa itself) is negligible compared to the matter ejected from Io.     

Thermal-orbital evolution of Io and Europa

Coupled thermal-orbital evolution models of Europa and Io are presented. It is assumed that Io, Europa, and Ganymede evolve in the Laplace resonance and that tidal dissipation of orbital energy is an internal heat source for both Io and Europa. While dissipation in Io occurs in the mantle as in the mantle dissipation model of Segatz et al. (1988, Icarus 75, 187), two models for Europa are considered. In the first model dissipation occurs in the silicate mantle while in the second model dissipation occurs in the ice shell. In the latter model, ice shell melting and variations of the shell thickness above an ocean are explicitly included. The rheology of both the ice and the rock is cast in terms of a viscoelastic Maxwell rheology with viscosity and shear modulus depending on the average temperature of the dissipating layer. Heat transfer by convection is calculated using a parameterization for strongly temperature-dependent viscosity convection. Both models are consistent with the present orbital elements of Io, Europa, and Ganymede. It is shown that there may be phases of quasi-steady evolution with large or small dissipation rates (in comparison with radiogenic heating), phases with runaway heating or cooling and oscillatory phases during which the eccentricity and the tidal heating rate will oscillate. Europa's ice thickness varies between roughly 3 and 70 km (dissipation in the silicate layer) or 10 and 60 km (dissipation in the ice layer), suggesting that Europa's ocean existed for geological timescales. The variation in ice thickness, including both convective and purely conductive phases, may be reflected in the formation of different geological surface features on Europa. Both models suggest that at present Europa's ice thickness is several tens of km thick and is increasing, while the eccentricity decreases, implying that the satellites evolve out of resonance. Including lithospheric growth in the models makes it impossible to match the high heat flux constraint for Io. Other heat transfer processes than conduction through the lithosphere must be important for the present Io.     

An assessment and test of Enceladus as an important source of Saturn’s ring atmosphere and ionosphere

The existence of an oxygen exosphere and ionosphere in Saturn’s main ring region has been confirmed by the Saturn Orbital Insertion (SOI) observations of the Cassini spacecraft. Through the ion-molecule collisions, the ring atmosphere could serve as a source of ions throughout Saturn’s magnetosphere. If photolysis of ice in the main rings is the dominant source of O₂, then the complex structure of the ring atmosphere/ionosphere and the injection rate of neutral O₂ will be subject to modulation by the seasonal variation of Saturn along its orbit (Tseng, Wei-Ling, Ip, W.-H., Johnson, R.E., Cassidy, T.A., Erlod, M.K. [2010]. Icarus 206, 382-389). In addition, the radio and plasma wave science (RPWS) instrument onboard Cassini found that a large amount of the Enceladus-originated water-group plasma would be deposited on the outer edge of the A ring (Farrell, W.M., Kaiser, M.L., Gurnett, D.A., Kurth, W.S., Persoon, A.M., Wahlund, J.E., Canu, P. [2008]. Geophys. Res. Lett. 35, L02203). A large amount of Enceladus’ plume neutrals (water-group neutrals) would collide with the main rings through collisional interaction with the ambient neutrals and plasma ions (Jurac, S., Richardson, J.D. [2007]. Geophys. Res. Lett. 34, L08102; Cassidy, T.A., Johnson, R.E. [2010]. Icarus, in press). These absorbed ions and neutrals could be recycled to neutral oxygen molecules via grain-surface chemistry to contribute the ring oxygen atmosphere. In this work, we have examined the mass budget of the ring oxygen atmosphere of Saturn taking into account such an “exogenic” source. The maximum O₂ source rate from recycling of Enceladus-originated plasma and neutrals is probably comparable or higher to the one from photolytic decomposition of ices. In the above case, the neutral O₂ source rate would be independent of the solar insolation angle. Therefore, even at Saturn’s Equinox, the extended oxygen atmosphere still could be an important supplier of oxygen ions in the saturnian magnetosphere. We have performed several studies for different recycling source rates from Enceladus. These predictions need further the Cassini Plasma Spectrometer (CAPS) and the Magnetospheric Imaging Instrument (MIMI) observations to be verified in future.     

Decametric modulation lanes as a probe for inner jovian magnetosphere

We use the specific scintillations of jovian decametric radio sources (modulation lanes), which are produced by plasma inhomogeneities in the vicinity of that planet, to probe the inner magnetosphere of Jupiter. The positions and frequency drift of 1762 lanes have been measured on the DAM spectra from archives. A special 3D algorithm is used for space localization of field-aligned magnetospheric inhomogeneities by the frequency drift of modulation lanes. As a result, the main regions of the lane formation are found: the Io plasma torus; the magnetic shell of the Gossamer Ring at Thebe and Amalthea orbits; and the region above the magnetic anomaly in the northern magnetosphere. It is shown that modulation lanes reveal the depleted magnetic tubes in practically unvisited, innermost regions of the jovian magnetosphere. The local and probably temporal plasma enhancement is found at the magnetic shell of Thebe satellite. Hence, the modulation lanes are a valuable instrument for remote sensing of those parts of jovian magnetosphere, which are not studied yet in situ.     

A comprehensive numerical simulation of Io’s sublimation-driven atmosphere

Io’s sublimation-driven atmosphere is modeled using the direct simulation Monte Carlo (DSMC) method. These rarefied gas dynamics simulations improve upon earlier models by using a three-dimensional domain encompassing the entire planet computed in parallel. The effects of plasma heating, planetary rotation, inhomogeneous surface frost, molecular residence time of SO₂ on the exposed (non-volatile) rocky surface, and surface temperature distribution are investigated. Circumplanetary flow is predicted to develop from the warm dayside toward the cooler nightside. Io’s rotation leads to a highly asymmetric frost surface temperature distribution (due to the frost’s high thermal inertia) which results in circumplanetary flow that is not axi-symmetric about the subsolar point. The non-equilibrium thermal structure of the atmosphere, specifically vibrational and rotational temperatures, is also examined. Plasma heating is found to significantly inflate the atmosphere on both the dayside and nightside. The plasma energy flux causes high temperatures at high altitudes but plasma energy depletion through the dense gas column above the warmest frost permits gas temperatures cooler than the surface at low altitudes. A frost map (Douté, S., Schmitt, B., Lopes-Gautier, R., Carlson, R., Soderblom, L., Shirley, J., and the Galileo NIMS Team [2001]. Icarus 149, 107-132) is used to control the sublimated flux of SO₂ which can result in inhomogeneous column densities that vary by nearly a factor of four for the same surface temperature. A short residence time for SO₂ molecules on the “rock” component is found to smooth lateral atmospheric inhomogeneities caused by variations in the surface frost distribution, creating an atmosphere that looks nearly identical to one with uniform frost coverage. A longer residence time is found to agree better with mid-infrared observations (Spencer, J.R., Lellouch, E., Richter, M.J., López-Valverde, M.A., Jessup, K.L, Greathouse, T.K., Flaud, J. [2005]. Icarus 176, 283-304) and reproduce the observed anti-jovian/sub-jovian column density asymmetry. The computed peak dayside column density for Io assuming a surface frost temperature of 115 K agrees with those suggested by Lyman-α observations (Feaga, L.M., McGrath, M., Feldman, P.D. [2009]. Icarus 201, 570-584). On the other hand, the peak dayside column density at 120 K is a factor of five larger and is higher than the upper range of observations (Jessup, K.L., Spencer, J.R., Ballester, G.E., Howell, R.R., Roesler, F., Vigel, M., Yelle, R. [2004]. Icarus 169, 197-215; Spencer et al., 2005).     

Detection of a southern peak in Mercury's sodium exosphere with the TNG in 2005

A long term plan of observations of the sodium exosphere of Mercury began in 2002 by using the high resolution echelle spectrograph SARG and a devoted sodium filter at the 3.5 m Galileo National Telescope (TNG) located in La Palma, Canary Islands. This program is meant to investigate the variations of the sodium exosphere appearance under different conditions of observations, namely Mercury's position along its orbit, phase angle and different solar conditions, as reported by previous observations in August 2002 and August 2003 [Barbieri, C., Verani, S., Cremonese, G., Sprague, A., Mendillo, M., Cosentino, R., Hunten, D., 2004. Planet. Space Sci. 52, 1169-1175; Leblanc, F., Barbieri, C., Cremonese, G., Verani, S., Cosentino, R., Mendillo, M., Sprague, A., Hunten, D., 2006. Icarus 185 (2), 395-402].Here we present the analysis of data taken in June 29th and 30th and in July 1st 2005, when Mercury's true anomaly angle (TAA) was in the range 124-130°. The spectra show particularly intense sodium lines with a distinctive peak in emission localized in the southern hemisphere at mid-latitudes. This seems to be a persistent feature related to consecutive favorable IMF conditions inducing localized enhancements of surface sodium density. The comparison with previous data taken by Potter et al. [Potter, A.E., Killen, R.M., Morgan, T.H., 2002. Meteorit. Planet. Sci. 37 (9), 1165-1172] evidences a surprising consistency of the anti-sunward component, which appears to remain constant regardless of the changing illumination and space weather conditions at Mercury.     

Secondary and sesquinary craters on Europa

We address impact cratering on Io and Europa, with the emphasis on the origin of small craters on Europa as secondary to the primary impacts of comets on Io, Europa, and Ganymede. In passing we also address the origin of secondary craters generated by Zunil, a well-studied impact crater on Mars that is a plausible analog to impact craters on Io. At nominal impact rates, and taking volcanic resurfacing into account, we find that there should be 1.3 impact craters on Io, equally likely to be of any diameter between 100 m and 20 km. The corresponding model age of Europa's surface is between 60 and 100 Ma. This range of ages does not include a factor three uncertainty stemming from the uncertain sizes and numbers of comets. The mass of basaltic impact ejecta from Io to reach Europa is found to meet or exceed the micrometeoroid flux as a source of rock-forming elements to Europa's ice crust. To describe impact ejecta in more detail we adapt models for impact-generated spalls and Grady-Kipp fragments originally developed by Melosh. Our model successfully reproduces the observed size-number distributions of small craters on both Mars and Europa. However, the model predicts that a significant fraction of the 200-500 m diameter craters on Europa are not traditional secondary craters but are instead sesquinary craters caused by impact ejecta from Io that had gone into orbit about Jupiter. This prediction is not supported by observation, which implies that high speed spalls usually break up into smaller fragments that make smaller sesquinary craters. Iogenic basalts are also interesting because they provide stratigraphic horizons on Europa that in principle could be used to track historic motions of the ice, and they provide materials suitable to radiometric dating of Europa's surface.     

Vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ northern spring equinox from 2006 to 2008

Long-slit spectroscopy observations of Uranus by the United Kingdom Infrared Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s northern spring equinox in December 2007.The observed reflectance spectra in the Long J (1.17-1.31 μm) and H (1.45-1.65 μm) bands, obtained with the slit aligned along Uranus’ central meridian, have been fitted with an optimal estimation retrieval model to determine the vertical cloud profile from 0.1 to 6-8 bar over a wide range of latitudes. Context images in a number of spectral bands were used to discriminate general zonal cloud structural changes from passing discrete clouds. From 2006 to 2007 reflection from deep clouds at pressures between 2 and 6-8 bar increased at all latitudes, although there is some systematic uncertainty in the absolute pressure levels resulting from extrapolating the methane coefficients of Irwin et al. (Irwin, P.G.J., Sromovsky, L.A., Strong, E.K., Sihra, K., Teanby, N.A., Bowles, N., Calcutt, S.B., Remedios, J.J. [2006] Icarus, 181, 309-319) at pressures greater than 1 bar, as noted by Tomasko et al. and Karkoschka and Tomasko (Tomasko, M.G., Bezard, B., Doose, L., Engel, S., Karkoschka, E. [2008] Planet. Space Sci., 56, 624-647; Karkoschka, E., Tomasko, M. [2009] Icarus). However, from 2007 to 2008 reflection from these clouds throughout the southern hemisphere and from both northern and southern mid-latitudes (30° N,S) diminished. As a result, the southern polar collar at 45°S has diminished in brightness relative to mid-latitudes, a similar collar at 45°N has become more prominent (e.g. Rages, K.A., Hammel, H.B., Sromovsky, L. [2007] Bull. Am. Astron. Soc., 39, 425; Sromovsky, L.A., Fry, P.M., Ahue, W.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R., van Dam, M.A. [2008] vol. 40 of AAS/Division for Planetary Sciences Meeting Abstracts, pp. 488-489; Sromovsky, L.A., Ahue, W.K.M., Fry, P.M., Hammel, H.B., de Pater, I., Rages, K.A., Showalter, M.R. [2009] Icarus), and the lowering reflectivity from mid-latitudes has left a noticeable brighter cloud zone at the equator (e.g. Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557;Karkoschka, E., Tomasko, M. [2009] Icarus). For such substantial cloud changes to have occurred in just two years suggests that the circulation of Uranus’ atmosphere is much more vigorous and/or efficient than is commonly thought. The composition of the main observed cloud decks between 2 and 6-8 bar is unclear, but the absence of the expected methane cloud at 1.2-1.3 bar (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987] J. Geophys. Res., 92, 14987-15001) is striking (as previously noted by, among others, Sromovsky, L.A., Irwin, P.G.J., Fry, P.M. [2006] Icarus, 182, 577-593; Sromovsky, L.A., Fry, P.M. [2007] Icarus, 192, 527-557; Sromovsky, L.A., Fry, P.M. [2008] Icarus, 193, 252-266; Karkoschka, E., Tomasko, M. [2009] Icarus) and suggests that cloud particles may be considerably different from pure condensates and may be linked with stratospheric haze particles drizzling down from above, or that tropospheric hazes are generated near the methane condensation level and then drizzle down to deep pressures as suggested by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus).The retrieved cloud structures were also tested for different assumptions of the deep methane mole fraction, which Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009] Icarus) find may vary from ∼1-2% in polar regions to perhaps as much as 4% equatorwards of 45°N,S. We found that such variations did not significantly affect our conclusions.