Field Trials of Chaotic Advection to Enhance Reagent Delivery

Chaotic advection is a novel approach that has the potential to enhance contact between an injected reagent and target contaminants, and thereby improve the effectiveness of in situ treatment technologies. One configuration that is capable of generating chaotic advection is termed the rotated potential mixing (RPM) flow. A conventional RPM flow system involves periodically reoriented dipole flow driven by transient switching of pressures at a series of radial wells. To determine whether chaotic advection can be engineered using such an RPM flow system, and to assess the consequent impact on the spatial distribution of a conservative tracer, a series of field-scale experiments were conducted. These experiments involved the injection of a tracer in the center of a circular array of wells followed by either mixing using an engineered RPM flow system to invoke chaotic advection, or by natural processes (advection and diffusion) as the control. Pressure fluctuations from the mixing tests using the RPM flow system showed consistent peak amplitudes during injection and extraction at a frequency corresponding to the switching time, suggesting that the target hydraulic behavior was achieved with the time-dependent flow field. The tracer breakthrough responses showed oscillatory behavior at all monitoring locations during the mixing tests which indicated that the desired RPM flow was generated. The presence of chaotic advection was supported by comparisons to observations from a previous laboratory experiment using RPM flow, and the Fourier spectrum of the temporal tracer data. Results from several quantitative metrics adopted to demonstrate field-scale evidence of chaotic advection showed that mixing led to improved lateral tracer spreading and approximately uniform concentrations across the monitoring network. The multiple lines of evidence assembled in this proof-of-concept study conclusively demonstrated that chaotic advection can be engineered at the field scale. This investigation is a critical step in the development of chaotic advection as a viable and efficient approach to enhance reagent delivery.     

Geochemical imaging of flow near an artificial recharge facility, Orange County, California

Critical for the management of artificial recharge operations is detailed knowledge of ground water dynamics near spreading areas. Geochemical tracer techniques including stable isotopes of water, tritium/helium-3 (T/3He) dating, and deliberate gas tracer experiments are ideally suited for these investigations. These tracers were used to evaluate flow near an artificial recharge site in northern Orange County, California, where approximately 2.5 x 10(8) m3 (200,000 acre-feet) of water are recharged annually. T/3He ages show that most of the relatively shallow ground water within 3 km of the recharge facilities have apparent ages < 2 years; further downgradient apparent ages increase, reaching > 20 years at approximately 6 km. Gas tracer experiments using sulfur hexafluoride and xenon isotopes were conducted from the Santa Ana River and two spreading basins. These tracers were followed in the ground water for more than two years, allowing subsurface flow patterns and flow times to be quantified. Results demonstrate that mean horizontal ground water velocities range from < 1 to > 4 km/year. The leading edges of the tracer patch moved at velocities about twice as fast as the center of mass. Leading edge velocities are important when considering the potential transport of microbes and other "time sensitive" contaminants and cannot be determined easily with other methods. T/3He apparent ages and tracer travel times agreed within the analytical uncertainty at 16 of 19 narrow screened monitoring wells. By combining these techniques, ground water flow was imaged with time scales on the order of weeks to decades.     

Effects of suspended sediment characteristics and bed sediment transport on streambed clogging

Fine sediment deposition in streambeds can reduce pore water fluxes and the overall rate of hyporheic exchange, producing deleterious effects on benthic and hyporheic ecological communities. To increase understanding of the factors that control the reduction of hyporheic exchange by fine sediment deposition, we conducted experiments in a laboratory flume to observe changes in the rates of solute exchange and kaolinite clay deposition as substantial amounts of kaolinite accumulated in the streambed. Two long‐term experiments were conducted, with durations of 14 days and 29 days. Use of a laboratory flume system allowed steady stream flow conditions to be maintained throughout both experiments, and alternating injections of known quantities of kaolinite and a sodium chloride tracer were used to assess the effect of clay accumulation on hyporheic exchange directly. In the first experiment, there was no bed sediment transport and kaolinite deposition formed a highly clogged near‐surface layer that greatly reduced hyporheic exchange. Application of a fundamental model for advective hyporheic exchange indicated that the effective permeability and porosity of the streambed decreased substantially during the course of the experiment. In the second experiment, the kaolinite was prepared with different surface properties to be more mobile, and the experiment was conducted with a small degree of bed sediment transport. As a result, no distinct clogged layer developed, and the rate of hyporheic exchange was found to remain approximately constant throughout the experiment (29 days). These results indicate that increasing fine sediment loads, e.g. those that occur from changes in land use, can have substantially different impacts on hyporheic exchange and associated ecological processes depending on the stream flow conditions, the rate and frequency of bed sediment transport, and the extent of interaction of the introduced fines with bed sediments. Copyright © 2004 John Wiley & Sons, Ltd.     

Using a thermal tracer to estimate overland and rill flow velocities

Flow velocity is a basic hydraulic property of surface flows and its precise calculation is necessary for process based hydrological models, such as soil erosion and rill development models, as well as for modelling sediment and solute transport by runoff. This study presents a technique based on infrared thermography to visualize very shallow flows and allow a quantitative measurement of overland flow and rill flow velocities. Laboratory experiments were conducted to compare the traditional dye tracer technique with this new thermal tracer technique by injecting a combined tracer (heated dye) into shallow flowing surface water. The leading edge tracer velocities estimated by means of infrared video and by the usual real imaging video were compared. The results show that thermal tracers can be used to estimate both overland and rill flow velocities, since measurements are similar to those resulting from using dye tracers. The main advantage of using thermography was the higher visibility of the leading edge of the injected tracer compared with the real image videos. Copyright © 2013 John Wiley & Sons, Ltd.     

Comparison of approaches for predicting solute transport: sandbox experiments

The main purpose of this paper was to compare three approaches for predicting solute transport. The approaches include: (1) an effective parameter/macrodispersion approach (Gelhar and Axness 1983); (2) a heterogeneous approach using ordinary kriging based on core samples; and (3) a heterogeneous approach based on hydraulic tomography. We conducted our comparison in a heterogeneous sandbox aquifer. The aquifer was first characterized by taking 48 core samples to obtain local-scale hydraulic conductivity (K). The spatial statistics of these K values were then used to calculate the effective parameters. These K values and their statistics were also used for kriging to obtain a heterogeneous K field. In parallel, we performed a hydraulic tomography survey using hydraulic tests conducted in a dipole fashion with the drawdown data analyzed using the sequential successive linear estimator code (Yeh and Liu 2000) to obtain a K distribution (or K tomogram). The effective parameters and the heterogeneous K fields from kriging and hydraulic tomography were used in forward simulations of a dipole conservative tracer test. The simulated and observed breakthrough curves and their temporal moments were compared. Results show an improvement in predictions of drawdown behavior and tracer transport when the K tomogram from hydraulic tomography was used. This suggests that the high-resolution prediction of solute transport is possible without collecting a large number of small-scale samples to estimate flow and transport properties that are costly to obtain at the field scale.     

Design and Testing of a Convenient Benchtop Sandbox for Controlled Flow Experiments

A benchtop sandbox constructed from nested storage tanks (NeSTs), was assembled for studying flow and transport in porous media. Molded plastic storage containers, purchased at a department store, were modified to fashion the tanks. The remaining construction materials were also inexpensive and the NeST design made it virtually leak‐proof. The uniformity of flow in the NeST was evaluated with three independent tracer tests. Estimated velocities were within about ±20% including all test results, indicating a high degree of predictability and uniformity in the flow. The NeST is a simple and robust tool suitable for research and teaching purposes, particularly for the testing of flow measurement sensors like the point velocity probes.     

The Effect of Toluene-Substrate Concentration on Biological Clogging and Sloughing in Porous Media

One-dimensional flow experiments on biological clogging were carried out by biostimulating columns packed with glass beads, sterilized, and inoculated with toluene-utilizing bacteria. Biostimulation consisted of continuously injecting toluene at four concentrations (3.0 ± 0.9, 6.1 ± 0.8, 8.7 ± 1.6, and 11.3 ± 0.8 mg/L). The results of column flow experiments indicated that a threshold concentration of toluene exists below which the total biomass in the column can be kept at a steady-state level. The column cores were extruded and segmented to determine the biomass distribution throughout the column at clogging. Clogging resulted in a significant buildup of filamentous bacteria close to the inlet end. Based on the nucleotide sequence of 16S rRNA genes, the dominant filamentous bacteria were identified as Nocardia farcinica. A 235-d column experiment demonstrated that the clogging near injection points can be controlled by keeping the influent concentration of toluene below the threshold.     

Modelling dispersion in complex open channel flows: Fuzzy calibration (2)

In a special opportunity, detailed measurements of the flow in an overbank flow in the Flood Channel Facility at HR Wallingford were used in conjunction with tracer test data to assess the effectiveness of dispersion models based around random particle tracking (RPT). Ten different RPT models based on different assumptions and levels of information about the nature of the Lagrangian velocity field were investigated. Multiple simulations were used to calibrate variable parameters controlling the average magnitude of the perturbations for each model by comparison with observed concentrations at one cross-section. The calibrated models were then used to predict concentration distributions further downstream. Several of the calibrated models showed close agreement between observed and predicted concentration distributions. The most complex models using the most information about the velocity distributions were no better (and in some cases worse) in prediction than the simplest models investigated. It would appear that our knowledge of the system, despite the quality of the experiments, is too uncertain to infer a precise model structure.     

Modelling dispersion in complex open channel flows: Equifinality of model structure (1)

In a special opportunity, detailed measurements of the flow in an overbank flow in the Flood Channel Facility at HR Wallingford were used in conjunction with tracer test data to assess the effectiveness of dispersion models based around random particle tracking (RPT). Ten different RPT models based on different assumptions and levels of information about the nature of the Lagrangian velocity field were investigated. Multiple simulations were used to calibrate variable parameters controlling the average magnitude of the perturbations for each model by comparison with observed concentrations at one cross-section. The calibrated models were then used to predict concentration distributions further downstream. Several of the calibrated models showed close agreement between observed and predicted concentration distributions. The most complex models using the most information about the velocity distributions were no better (and in some cases worse) in prediction than the simplest models investigated. It would appear that our knowledge of the system, despite the quality of the experiments, is too uncertain to infer a precise model structure.     

Characterizing solute transport with transient storage across a range of flow rates: The evidence of repeated tracer experiments in Austrian and Italian streams

Solute transport in rivers and streams with hyporheic zone exchange and/or in-stream storage is typically affected by the prevailing flow rate. The research reported here focuses on stream tracer experiments repeated many times along the same Austrian (Mödlingbach) and Italian (Torrente Lura) channel reaches to characterize parameter dependency on flow rate. Both groups of data sets showed an increase of storage zone area and main stream area with discharge. In either case, a strong negative correlation was obtained between storage zone residence time and flow rate. From the Mödlingbach data, no clear relationship with Q emerged for the dispersion coefficient and the dead zone ratio, whereas Torrente Lura showed a clear positive correlation of the dispersion coefficient with the flow rate and a slightly negative Q-dependency for the dead zone ratio. Mödlingbach and Torrente Lura results are presented against the background of other repeat experiments reported in literature.     

Application of ERT,Saline Tracer and Numerical Studies to Delineate Preferential Paths in Fractured Granites

Accurate quantification of in situ heterogeneity and flow processes through fractured geologic media remains elusive for hydrogeologists due to the complexity in fracture characterization and its multiscale behavior. In this research, we demonstrated the efficacy of tracer-electrical resistivity tomography (ERT) experiments combined with numerical simulations to characterize heterogeneity and delineate preferential flow paths in a fractured granite aquifer. A series of natural gradient saline tracer experiments were conducted from a depth window of 18 to 22 m in an injection well (IW) located inside the Indian Institute of Technology Hyderabad campus. Tracer migration was monitored in a time-lapse mode using two cross-sectional surface ERT profiles placed in the direction of flow gradient. ERT data quality was improved by considering stacking, reciprocal measurements, resolution indicators, and geophysical logs. Dynamic changes in subsurface electrical properties inferred via resistivity anomalies were used to highlight preferential flow paths of the study area. Temporal changes in electrical resistivity and tracer concentration were monitored along the vertical in an observation well located at 48 m to the east of the IW. ERT-derived tracer breakthrough curves were in agreement with geochemical sample measurements. Fracture geometry and hydraulic properties derived from ERT and pumping tests were further used to evaluate two mathematical conceptualizations that are relevant to fractured aquifers. Results of numerical analysis conclude that dual continuum model that combines matrix and fracture systems through a flow exchange term has outperformed equivalent continuum model in reproducing tracer concentrations at the monitoring wells (evident by a decrease in RMSE from 199 to 65 mg/L). A sensitivity analysis on model simulations conclude that spatial variability in hydraulic conductivity, local-scale dispersion, and flow exchange at fracture-matrix interface have a profound effect on model simulations.     

Scour and flow field around a spur dike in a 90° bend

Spur dike is an important element in river training that creates rapid variations in flow field, sediment transport and bed topography. The mechanism of flow and sediment transport in a channel bend is very complex, especially when a spur dike is constructed in a bend. Most of previous investigations on flow behavior and scour around spur dike were carried out in straight channels. In this paper results of experiments on flow field and scour around a spur dike in a 90 degree channel bend are presented. Sand with uniform grain size was used as the bed material. Experiments were conducted for different locations and different lengths of spur dikes at the bend with different values of discharge. The three dimensional flow fields around a spur dike were investigated. The maximum depth of scour was correlated to the Froude numbers, lengths and the locations of spur dike in the bend.     

Scour and flow field around a spur dike in a 90° bend

Spur dike is an important element in fiver training that creates rapid variations in flow field, sediment transport and bed topography. The mechanism of flow and sediment transport in a channel bend is very complex, especially when a spur dike is constructed in a bend. Most of previous investigations on flow behavior and scour around spur dike were carried out in straight channels. In this paper results of experiments on flow field and scour around a spur dike in a 90 degree channel bend are presented, Sand with uniform grain size was used as the bed material, Experiments were conducted for different locations and different lengths of spur dikes at the bend with different values of discharge, The three dimensional flow fields around a spur dike were investigated, The maximum depth of scour was correlated to the Froude numbers, lengths and the locations of spur dike in the bend.     

Effects of hydraulic structures on river morphological processes

Study of hydraulic structures such as groins and bandal-like structures can provide valuable information on their influences on morphological processes in natural rivers.These structures usually used for bank protection and formation of deep navigation channel can locally create complex flow patterns,reduce flow velocities and also increase the flood levels.Most of the previous studies are focused on structures like groins under non-submerged flow condition.However,the recent demand of nature friendly low cost and sustainable methods for river bank protection and channel formation leads to the necessity of study different type of structures like bandal-like structures.In this context, this study investigates the flow characteristics and sediment transport process influenced by bandal-like structures through laboratory experiments.The experiments were carried out under live-bed scour condition with sediment supplied from the inlet for two submergence(non-submerged and submerged)conditions.The experimental measurements contribute to better understand the mechanism of deposition/erosion process around different type of hydraulic structures.The performance of bandal-like structures considering the erosion around the structures,the deposition near the bank and the formation of deep main channel show promising results compared with conventional structures such as groins(impermeable and permeable ones).     

Determination of the conduit structure in a karst aquifer based on tracer data—Lurbach system,Austria

A structure model was used to analyse solute‐transport parameter estimates based on tracer breakthrough curves. In the model system, groundwater flow is envisioned to be organised in a complex conduit network providing a variety of short circuits with relative small carrying capacities along different erosion levels. The discharge through the fully filled conduits is limited owing to void geometries and turbulent flow; thus, a hierarchic overflow system evolves where conduits are (re‐)activated or dried up depending on the flow condition. Exemplified on the Lurbach–Tanneben karst aquifer, the applicability of the model approach was tested. Information derived from multi‐tracer experiments performed at different volumetric flow rates enabled to develop a structural model of the karst network, under constraint of the geomorphological and hydrological evolution of the site. Depending on the flow rate, groundwater is divided into up to eight flow paths. The spatial hierarchy of flow paths controls the sequence of flow path activation. Conduits of the topmost level are strongly influenced by reversible alteration processes. Sedimentation or blocking causes an overflow of water to the next higher conduit. Flow path specific dissolutional denudation rates were estimated using the temporal development of the partial discharge. Copyright © 2012 John Wiley & Sons, Ltd.     

VARIABILITY OF MELTWATER AND SOLUTE FLUXES FROM HOMOGENEOUS MELTING SNOW AT THE LABORATORY SCALE

Four experiments were performed to examine the relationship between the meltwater flow field and ion release from melting snow. A 0.4 m³ volume of snow was placed in a Plexiglass box and melted from above using a heating plate. The meltwater and solute fluxes issuing from the bottom of the snow were monitored. In experiments with NaCl tracer added to the snow, the solute concentrations were generally lower in the flow fingers than in the background wetting front. Dye tracer experiments revealed contemporaneous areas of concentrated dye and dilute meltwater in flow fingers. This suggests that the meltwater in flow fingers is diluted by low concentration water from the top of the snowpack. Flow fingers contribute more meltwater flux primarily because the flow is maintained for a longer period of time than in the non-finger areas; however, the relative contribution of flow fingers to solute flux was apparently not as great as that of the background wetting front because of dilution of solute in the flow finger areas.     

Feasibility of Deep Nutrients Delivery into a Prince William Sound Beach for the Bioremediation of the Exxon Valdez Oil Spill

Delivery of dissolved chemicals to potentially bioremediate oil from the Exxon Valdez oil spill was investigated at Smith Island, Prince William Sound, Alaska. Two transects for tracer application were installed: one at a clean area and another at an oiled area. Tracer delivery occurred under ambient pressure through manifolds. Lithium in LiBr/sea water solution was the inert tracer, and the solution (82.6 mg/L of lithium) was released at a flow rate of 0.23 L/min for 58.5 h. While maintaining the flow rate, the solution was switched to sea water (i.e., 0.0 mg/L of lithium) for 16 h. The results show that the tracer moved landward with rising tides and seaward with falling tides. The plume got deeper moving landward and shallower moving seaward of the manifold. Thus, in situations where oil biodegradation is limited by the availability of nutrients or oxygen, applying these chemicals by this technique would allow them to reach entrapped oil seaward of the manifold from below. The seaward plume traveling speed (around 2.0 m/d) suggests that this technique is logistically feasible from a hydraulic point of view.     

Sediment removal efficiency of siphon dredging with wedge-type suction head and float tank

Siphon dredging with a float tank and different siphon suction heads, including the plain-type and wedge-type with/without side holes, through flume experiments were used to investigate the reservoir sediment removal efficiency. The experiment revealed maximum suction pressure and velocity when the distance from the suction head to the bed was about 25% of suction head diameter. Suction pressure decreased rapidly as the distance from the suction head to the bed increased to 50% and 100% of suction head diameter. Suction pressure achieved by wedge-type suction head was only 16.9-17.6% of that around plain-type suction head, and the velocity around wedge-type suction head was 64.7-68.4% of that around plain-type suction head. However the plain-type suction head was easily clogged doe to its long bobbing period. The average bobbing period for the plain-type suction head was about 105-263% that of the wedge-type suction head. The sediment removal efficiency was achieved when float tank diameter was 3-4 times that of the suction head. Flow discharge and sediment removal increased as the suction head diameter and side hole diameter increased, respectively. The most efficient side hole area was an area within 15% of suction head area. Totally, the optimal sediment removal efficiency was the wedge angle of 20° with 3 side holes. The efficiency of sediment dredging by siphon suction with a suction tube passing through the dam bottom was better than that with suction passing over the top of the dam. The wedge-type siphon suction with a float tank is preferable for sediment dredging in small reservoirs because it is inexpensive and efficient.     

On the effect of subinertial phenomena on the internal lee waves generation in the Strait of Gibraltar

The generation of internal lee waves (ILW) in the Strait of Gibraltar takes place in the main sill where the tidal flow interacts with a submarine obstacle. The tidal flow is perturbed by subinertial phenomena of different nature summarized in the subinertial currents that can inhibit the ILW generation. The authors present an attempt to randomize the problem by the introduction of a Gaussian noise in the Taylor–Goldstein equation. The random number sets are generated from the statistical distribution of the previously isolated random part of the subinertial currents from experimental data taken in the area during the Gibraltar Experiment 94–96. The effect of the noise is translated into a continuous spreading of the spectrum around the solution of the noise-free problem. A stability analysis is carried out in order to determine the single neutral modes of oscillations and the phase space is divided onto regions of stability and instability as a function of the inflowing subinertial current. The methodology and results could be useful for the design and timing of oceanographic surveys in straits where the ILWs occur.