Frontier Mountain 93001: A coarse‐grained,enstatite‐augite‐oligoclase‐rich,igneous rock from the acapulcoite‐lodranite parent asteroid

Abstract— The Frontier Mountain (FRO) 93001 meteorite is a 4.86 g fragment of an unshocked, medium‐ to coarse‐grained rock from the acapulcoite‐lodranite (AL) parent body. It consists of anhedral orthoenstatite (Fs_{13.3 ± 0.4}Wo_{3.1 ± 0.2}), augite (Fs_{6.1 ± 0.7}Wo_{42.3 ± 0.9}; Cr₂O₃ = 1.54 ± 0.03), and oligoclase (Ab_{80.5 ± 3.3}Or_{3.1 ± 0.6}) up to >1 cm in size enclosing polycrystalline aggregates of fine‐grained olivine (average grain size: 460 ± 210 μm) showing granoblastic textures, often associated with Fe,Ni metal, troilite, chromite (cr# = 0.91 ± 0.03; fe# = 0.62 ± 0.04), schreibersite, and phosphates. Such aggregates appear to have been corroded by a melt. They are interpreted as lodranitic xenoliths. After the igneous (the term “igneous” is used here strictly to describe rocks or minerals that solidified from molten material) lithology intruding an acapulcoite host in Lewis Cliff (LEW) 86220, FRO 93001 is the second‐known silicate‐rich melt from the AL parent asteroid. Despite some similarities, the silicate igneous component of FRO 93001 (i.e., the pyroxene‐plagioclase mineral assemblage) differs in being coarser‐grained and containing abundant enstatite. Melting‐crystallization modeling suggests that FRO 93001 formed through high‐degree partial melting (≥35 wt%; namely, ≥15 wt% silicate melting and ?20 wt% metal melting) of an acapulcoitic source rock, or its chondritic precursor, at temperatures ≥1200 °C, under reducing conditions. The resulting magnesium‐rich silicate melt then underwent equilibrium crystallization; prior to complete crystallization at ?1040 °C, it incorporated lodranitic xenoliths. FRO 93001 is the highest‐temperature melt from the AL parent‐body so far available in laboratory. The fact that FRO 93001 could form by partial melting and crystallization under equilibrium conditions, coupled with the lack of quench‐textures and evidence for shock deformation in the xenoliths, suggests that FRO 93001 is a magmatic rock produced by endogenic heating rather than impact melting.     

Shock,post‐shock annealing,and post‐annealing shock in ureilites

Abstract— The thermal and shock histories of ureilites can be divided into four periods: 1) formation, 2) initial shock, 3) post‐shock annealing, and 4) post‐annealing shock. Period 1 occurred ?4.55 Ga ago when ureilites formed by melting chondritic material. Impact events during period 2 caused silicate darkening, undulose to mosaic extinction in olivines, and the formation of diamond, lonsdaleite, and chaoite from indigenous carbonaceous material. Alkali‐rich fine‐grained silicates may have been introduced by impact injection into ureilites during this period. About 57% of the ureilites were unchanged after period 2. During period 3 events, impact‐induced annealing caused previously mosaicized olivine grains to become aggregates of small unstrained crystals. Some ureilites experienced reduction as FeO at the edges of olivine grains reacted with C from the matrix. Annealing may also be responsible for coarsening of graphite in a few ureilites, forming euhedral‐appearing, idioblastic crystals. Orthopyroxene in Meteorite Hills (MET) 78008 may have formed from pigeonite by annealing during this period. The Rb‐Sr internal isochron age of ?4.0 Ga for MET 78008 probably dates the annealing event. At this late date, impacts are the only viable heat source. About 36% of ureilites experienced period 3 events, but remained unchanged afterwards. During period 4, ?7% of the ureilites were shocked again, as is evident in the polymict breccia, Elephant Moraine (EET) 83309. This rock contains annealed mosaicized olivine aggregates composed of small individual olivine crystals that exhibit undulose extinction. Ureilites may have formed by impact‐melting chondritic material on a primitive body with heterogeneous O isotopes. Plagioclase was preferentially lost from the system due to its low impedance to shock compression. Brief melting and rapid burial minimized the escape of planetary‐type noble gases from the ureilitic melts. Incomplete separation of metal from silicates during impact melting left ureilites with relatively high concentrations of trace siderophile elements.     

Al‐Mg systematics of hibonite‐bearing Ca,Al‐rich inclusions from Ningqiang

Abstract– Hibonite‐bearing Ca,Al‐rich inclusions (CAIs) usually occur in CM and CH chondrites and possess petrographic and isotopic characteristics distinctive from other typical CAIs. Despite their highly refractory nature, most hibonite‐bearing CAIs have little or no ²⁶Mg excess (the decay product of ²⁶Al), but do show wide variations of Ca and Ti isotopic anomalies. A few spinel‐hibonite spherules preserve evidence of live ²⁶Al with an inferred ²⁶Al/²⁷Al close to the canonical value. The bimodal distribution of ²⁶Al abundances in hibonite‐bearing CAIs has inspired several interpretations regarding the origin of short‐lived nuclides and the evolution of the solar nebula. Herein we show that hibonite‐bearing CAIs from Ningqiang, an ungrouped carbonaceous chondrite, also provide evidence for a bimodal distribution of ²⁶Al. Two hibonite aggregates and two hibonite‐pyroxene spherules show no ²⁶Mg excesses, corresponding to inferred ²⁶Al/²⁷Al < 8 × 10^?6. Two hibonite‐melilite spherules are indistinguishable from each other in terms of chemistry and mineralogy but have different Mg isotopic compositions. Hibonite and melilite in one of them display positive ²⁶Mg excesses (up to 25‰) that are correlated with Al/Mg with an inferred ²⁶Al/²⁷Al of (5.5 ± 0.6) × 10^?5. The other one contains normal Mg isotopes with an inferred ²⁶Al/²⁷Al < 3.4 × 10^?6. Hibonite in a hibonite‐spinel fragment displays large ²⁶Mg excesses (up to 38‰) that correlate with Al/Mg, with an inferred ²⁶Al/²⁷Al of (4.5 ± 0.8) × 10^?5. Prolonged formation duration and thermal alteration of hibonite‐bearing CAIs seem to be inconsistent with petrological and isotopic observations of Ningqiang. Our results support the theory of formation of ²⁶Al‐free/poor hibonite‐bearing CAIs prior to the injection of ²⁶Al into the solar nebula from a nearby stellar source.     

Production rates of cosmogenic helium‐3, neon‐21, and neon‐22 in ordinary chondrites and the lunar surface

Abstract— The production of ³He, ²¹Ne, and ²²Ne in meteoroids of various sizes and in the lunar surface was investigated. The LAHET code system, a purely physical model for calculating cosmic‐ray particle fluxes, was used to simulate cosmic‐ray particle interactions with extraterrestrial matter. We discuss the depth and size dependence of the shielding parameter ²²Ne/²¹Ne, which is used for reconstruction of pre‐atmospheric sizes, depth, and exposure histories. The ²²Ne/²¹Ne ratio decreases with increasing depth or pre‐atmospheric size but then increases with depth in very large objects. This increase with depth in the ²²Ne/²¹Ne ratio means that this ratio is a poor indicator of shielding in some large objects. The dependence of ³He/²¹Ne as function of ²²Ne/²¹Ne was also calculated, and differences between the calculations and the Bern line are discussed.     

Argon‐40/argon‐39 age of the El'gygytgyn impact event,Chukotka, Russia

Abstract— Lake El'gygytgyn, Chukotka, Russia, lies in a ～18 km crater of presumably impact origin. The crater is sited in Cretaceous volcanic rocks of the Okhotsk‐Chukotka volcanic belt. Laser ⁴⁰Ar/³⁹Ar dating of impact‐melted volcanic rocks from the rim of Lake El'gygytgyn yields a 10‐sample weighted plateau age of 3.58 ± 0.04 Ma. The Ar step‐heating method was critical in this study in identifying inherited Ar in the samples due to incomplete degassing of the Cretaceous volcanic rocks during impact melting. This age is consistent with, but more precise than, previous K‐Ar and fission‐track ages and indicates an “instantaneous” formation of the crater. This tight age control, in conjunction with the presence of impactites, shocked quartz, and other features, is consistent with an impact origin for the structure and seems to discount internal (volcanogenic) origin models.     

Comparison of dust‐to‐gas ratios in luminous,ultraluminous, and hyperluminous infrared galaxies

The dust‐to‐gas ratios in three different samples of luminous, ultraluminous, and hyperluminous infrared galaxies are calculated by modelling their radio to soft X‐ray spectral energy distributions (SED) using composite models which account for the photoionizing radiation from H II regions, starbursts, or AGNs, and for shocks. The models are limited to a set which broadly reproduces the mid‐IR fine structure line ratios of local, IR bright, starburst galaxies. The results show that two types of clouds contribute to the IR emission. Those characterized by low shock velocities and low preshock densities explain the far‐IR dust emission, while those with higher velocities and densities contribute to the mid‐IR dust emission. Clouds with shock velocities of 500 km s^–1 prevail in hyperluminous infrared galaxies. An AGN is found in nearly all of the ultraluminous infrared galaxies and in half of the luminous infrared galaxies of the sample. High IR luminosities depend on dust‐to‐gas ratios as high as ∼0.1 by mass, however most hyperluminous IR galaxies show dustto‐gas ratios much lower than those calculated for the luminous and ultraluminous IR galaxies. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Two‐stage polybaric formation of the new enriched,pyroxene‐oikocrystic,lherzolitic shergottite,NWA 7397

Northwest Africa (NWA) 7397 is a newly discovered, enriched, lherzolitic shergottite, the third described example of this group. This meteorite consists of two distinct textural lithologies (1) poikilitic—comprised of zoned pyroxene oikocrysts, with chadacrysts of chromite and olivine, and (2) nonpoikilitic—comprised of olivine, low‐Ca and high‐Ca pyroxene, maskelynite, and minor abundances of merrillite, spinel, ilmenite, and pyrrhotite. The constant Ti/Al ratios of pyroxene oikocrysts suggests initial crystallization of the poikilitic lithology at depth (equivalent to pressures of approximately 10 kbar), followed by crystallization of the nonpoikilitic lithology at shallower levels. Oxygen fugacity conditions become more oxidizing during crystallization ranging from fO₂ conditions of approximately QFM‐2 to QFM‐0.7. Magma calculated to be in equilibrium with the major rock‐forming minerals is LREE‐enriched relative to depleted or intermediate shergottites and has flat overall profiles. Therefore, we suggest that the parental magma for NWA 7397 had sampled an enriched, oxidized, Martian geochemical source, similar to that of other enriched basaltic and olivine‐phyric shergottites. We present a polybaric formation model for the lherzolitic shergottite NWA 7397, to account for the petrologic constraints. Three successive stages in the development of NWA 7397 are discussed (1) formation of a REE‐enriched parental magma from a distinct Martian mantle reservoir; (2) magma ponding and development of a staging chamber concomitant with initial crystallization of the poikilitic lithology; and (3) magma ascent to the near surface, with entrainment of cumulates from the staging chamber and subsequent crystallization of the nonpoikilitic lithology en route to the surface.     

Micro‐Raman spectroscopic study of fine‐grained,shock‐metamorphosed rock fragments from the Australasian microtektite layer

Abstract— –Shock‐metamorphosed rock fragments have been found in the Australasian microtektite layer from the South China Sea. Previous X‐ray diffraction (XRD) studies indicate that the most abundant crystalline phases in the rock fragments are coesite, quartz, and a 10 Å phase (mica/clay?). In addition, the presence of numerous other phases was suggested by scanning electron microscopy (SEM) and energy‐dispersive X‐ray (EDX) analysis. In the present research, ten of the rock fragments, which had previously been studied using SEM/EDX, were studied by micro‐Raman spectroscopy. The presence of K‐feldspar, plagioclase, rutile, ilmenite, titanite, magnetite, calcite, and dolomite were confirmed. In addition, the high‐pressure TiO₂ polymorph with an α‐PbO₂ structure (i.e., TiO₂II) was found in several rock fragments. Two grains previously thought to have been zircon, based on their compositions, were found to have Raman spectra that do not match the Raman spectra of zircon, reidite, or any of the possible decomposition products of zircon or their high‐pressure polymorphs. We speculate that the ZrSiO₄ phase might be a previously unknown high‐pressure polymorph of zircon or one of its decomposition products (i.e., ZrO₂ or SiO₂). The presence of coesite and TiO₂ II, and partial melting and vesiculation suggest that the rock fragments containing the unknown ZrSiO₄ phase must have experienced shock pressures between 45 and 60 GPa. We conclude that micro‐Raman spectroscopy, in combination with XRD and SEM/EDX, is a powerful tool for the study of small, fine‐grained impact ejecta.     

Petrography,geochemistry, and argon‐40/argon‐39 ages of impact‐melt rocks and breccias from the Ames impact structure,Oklahoma: The Nicor Chestnut 18‐4 drill core

Abstract— The 15 km diameter Ames structure in northwestern Oklahoma is located 2.75 km below surface in Cambro‐Ordovician Arbuckle dolomite, which is overlain by Middle Ordovician Oil Creek Formation shale. The feature is marked by two concentric ring structures, with the inner ring of about 5 km diameter probably representing the collapsed remnant of a structural uplift composed of brecciated Precambrian granite and Arbuckle dolomite. Wells from both the crater rim and the central uplift are oil‐ and gas‐producing, making Ames one of the economically important impact structures. Petrographic, geochemical, and age data were obtained on samples from the Nicor Chestnut 18‐4 drill core, off the northwest flank of the central uplift. These samples represent the largest and best examples of impact‐melt breccia obtained so far from the Ames structure. They contain carbonate rocks, which are derived from the target sequence. The chemical composition of the impact‐melt breccias is similar to that of target granite, with variable carbonate admixture. Some impact‐melt rocks are enriched in siderophile elements indicating the possible presence of a meteoritic component. Based on stratigraphic arguments, the age of the crater was estimated at 470 Ma. Previous ⁴⁰Ar‐³⁹Ar dating attempts of impact‐melt breccias from the Dorothy 1–19 core yielded plateau ages of about 285 Ma, which is in conflict with the stratigraphic age. The new ⁴⁰Ar‐³⁹Ar age data obtained on the melt breccias from the Nicor Chestnut core by ultraviolet (UV) laser spot analysis resulted in a range of ages with maxima around 300 Ma. These data could reflect processes related either the regional Nemaha Uplift or resetting due to hot brines active on a midcontinent‐wide scale, perhaps related to the Alleghenian and Ouachita orogenies. The age data indicate an extended burial phase associated with thermal overprint during Late Pennsylvanian‐Permian.     

Contribution to the study of F‐G‐K‐M binaries. X. HD 54901, HD 120544 and HD 123280, three nearby F‐type spectroscopic binaries

The orbital elements of HD 54901, HD 120544 and HD 123280, three nearby F‐type spectroscopic binaries, are presented. They are based on observations made between 1982 and 2004 with the CORAVEL instrument of Observatoire de Haute‐Provence. Physical parameters are derived for the two components of HD 54901 (SB2) and for the primaries of HD 120544 and HD 123280. The rotation‐revolution synchronism of the detected components is investigated. Pseudosynchronism is very likely achieved by the F7 V secondary component of HD 54901, whereas the F2/3 IV primary has not yet reached this stage. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Thermochemical stability of low‐iron,manganese‐enriched olivine in astrophysical environments

Abstract– Low‐iron, manganese‐enriched (LIME) olivine grains are found in cometary samples returned by the Stardust mission from comet 81P/Wild 2. Similar grains are found in primitive meteoritic clasts and unequilibrated meteorite matrix. LIME olivine is thermodynamically stable in a vapor of solar composition at high temperature at total pressures of a millibar to a microbar, but enrichment of solar composition vapor in a dust of chondritic composition causes the FeO/MnO ratio of olivine to increase. The compositions of LIME olivines in primitive materials indicate oxygen fugacities close to those of a very reducing vapor of solar composition. The compositional zoning of LIME olivines in amoeboid olivine aggregates is consistent with equilibration with nebular vapor in the stability field of olivine, without re‐equilibration at lower temperatures. A similar history is likely for LIME olivines found in comet samples and in interplanetary dust particles. LIME olivine is not likely to persist in nebular conditions in which silicate liquids are stable.     

Boltysh,another end‐Cretaceous impact

Abstract— The Chixculub impact occurred at the Cretaceous/Tertiary (K/T) boundary, and although several other Late Cretaceous and Paleogene impact craters have, at times, been linked with the K/T boundary, isotope geochronology has demonstrated that all have significantly different ages. The currently accepted age of the 24 km diameter Boltysh crater, a K‐Ar whole‐rock age, places it in the Coniacian at 88 ± 3 Ma. However, comprehensive Ar‐Ar dating of a range of melt samples yields a mean age of 65.17 ± 0.64 Ma, within errors of the K/T boundary. Several of the fresh samples exhibit signs of excess argon but this seems to be concentrated in rapidly crystallized glass‐rich samples. The Ar‐Ar age confirms an earlier fission track measurement and thus two dating techniques have yielded an age within errors of the K/T boundary for this crater. Crucially, although the ages of Boltysh and Chixculub are within errors, they may not have formed synchronously. Craters of 24 km diameter occur much more commonly than impacts of Chixculub dimensions, but their proximity does raise the important question of how many impacts there might have been close to the K/T boundary.     

The sun‐as‐a‐star solar spectrum

The Sun is the only star for which individual surface features can be observed directly. For other stars, the properties of starspots, stellar rotation, stellar flares, etc, are derived indirectly via variation of star‐integrated spectral line profiles or their luminosity measurements. Solar disk‐integrated and disk‐resolved observations allow for investigations of the contribution of individual solar disk features to sun‐as‐a‐star spectra. Here, we provide a brief overview of three sun‐as‐a‐star programs, currently in operation, and describe recent improvements in observations and data reduction for the Integrated Sunlight Spectrometer (ISS), one of three instruments comprising the Synoptic Optical Long‐term Investigations of the Sun (SOLIS) system. Next, we discuss studies employing sun‐as‐a‐star observations (including Ca II K line as proxy for total unsigned magnetic flux and 2800 MHz radio flux) as well as the effects of flares on solar disk‐integrated spectra. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

40Ar‐39Ar and cosmic‐ray exposure ages of nakhlites—Nakhla,Lafayette, Governador Valadares—and Chassigny

Abstract– We present ⁴⁰Ar‐³⁹Ar dating results of handpicked mineral separates and whole‐rock samples of Nakhla, Lafayette, and Chassigny. Our data on Nakhla and Lafayette and recently reported ages for some nakhlites and Chassigny ( Misawa et al. 2006 ; Park et al. 2009 ) point to formation ages of approximately 1.4 Ga rather than 1.3 Ga that is consistent with previous suggestions of close‐in‐time formation of nakhlites and Chassigny. In Lafayette mesostasis, we detected a secondary degassing event at approximately 1.1 Ga, which is not related to iddingsite formation. It may have been caused by a medium‐grade thermal event resetting the mesostasis age but not influencing the K‐Ar system of magmatic inclusions and the original igneous texture of this rock. Cosmic‐ray exposure ages for these meteorites and for Governador Valadares were calculated from bulk rock concentrations of cosmogenic nuclides ³He, ²¹Ne, and ³⁸Ar. Individual results are similar to literature data. The considerable scatter of T₃, T₂₁, and T₃₈ ages is due to systematic uncertainties related to bulk rock and target element chemistry, production rates, and shielding effects. This hampers efforts to better constrain the hypothesis of a single ejection event for all nakhlites and Chassigny from a confined Martian surface terrain ( Eugster 2003 ; Garrison and Bogard 2005 ). Cosmic‐ray exposure ages from stepwise release age spectra using ³⁸Ar and neutron induced ³⁷Ar from Ca in irradiated samples can eliminate errors induced by bulk chemistry on production rates, although not from shielding conditions.     

A composite Fe,Ni‐FeS and enstatite‐forsterite‐diopside‐glass vitrophyre clast in the Larkman Nunatak 04316 aubrite: Origin by pyroclastic volcanism

Abstract– We studied the mineralogy, petrology, and bulk, trace element, oxygen, and noble gas isotopic compositions of a composite clast approximately 20 mm in diameter discovered in the Larkman Nunatak (LAR) 04316 aubrite regolith breccia. The clast consists of two lithologies: One is a quench‐textured intergrowth of troilite with spottily zoned metallic Fe,Ni which forms a dendritic or cellular structure. The approximately 30 μm spacings between the Fe,Ni arms yield an estimated cooling rate of this lithology of approximately 25–30 °C s^?1. The other is a quench‐textured enstatite‐forsterite‐diopside‐glass vitrophyre lithology. The composition of the clast suggests that it formed at an exceptionally high degree of partial melting, perhaps approaching complete melting, and that the melts from which the composite clast crystallized were quenched from a temperature of approximately 1380–1400 °C at a rate of approximately 25–30 °C s^?1. The association of the two lithologies in a composite clast allows, for the first time, an estimation of the cooling rate of a silicate vitrophyre in an aubrite of approximately 25–30 °C s^?1. While we cannot completely rule out an impact origin of the clast, we present what we consider is very strong evidence that this composite clast is one of the elusive pyroclasts produced during pyroclastic volcanism on the aubrite parent body ( Wilson and Keil 1991 ). We further suggest that this clast was not ejected into space but retained on the aubrite parent body by virtue of the relatively large size of the clast of approximately 20 mm. Our modeling, taking into account the size of the clast, suggests that the aubrite parent body must have been between approximately 40 and 100 km in diameter, and that the melt from which the clast crystallized must have contained an estimated maximum range of allowed volatile mass fractions between approximately 500 and approximately 4500 ppm.     

Magnetostratigraphy of the impact breccias and post‐impact carbonates from borehole Yaxcopoil‐1, Chicxulub impact crater,Yucatán,Mexico

Abstract— We report the magnetostratigraphy of the sedimentary sequence between the impact breccias and the post‐impact carbonate sequence conducted on samples recovered by Yaxcopoil‐1 (Yax‐1). Samples of impact breccias show reverse polarities that span up to ～56 cm into the post‐impact carbonate lithologies. We correlate these breccias to those of PEMEX boreholes Yucatán‐6 and Chicxulub‐1, from which we tied our magnetostratigraphy to the radiometric age from a melt sample from the Yucatán‐6 borehole. Thin section analyses of the carbonate samples showed a significant amount of dark minerals and glass shards that we identified as the magnetic carriers; therefore, we propose that the mechanism of magnetic acquisition within the carbonate rocks for the interval studied is detrital remanent magnetism (DRM). With these samples, we constructed the scale of geomagnetic polarities where we find two polarities within the sequence, a reverse polarity event within the impact breccias and the base of the post‐impact carbonate sequence (up to 794.07 m), and a normal polarity event in the last ～20 cm of the interval studied. The polarities recorded in the sequence analyzed are interpreted to span from chron 29r to 29n, and we propose that the reverse polarity event lies within the 29r chron. The magnetostratigraphy of the sequence studied shows that the horizon at 794.11 m deep, interpreted as the K/T boundary, lies within the geomagnetic chron 29r, which contains the K/T boundary.     

26Al‐26Mg systematics of Ca‐Al‐rich inclusions,amoeboid olivine aggregates,and chondrules from the ungrouped carbonaceous chondrite Acfer 094

Abstract— We report in situ magnesium isotope measurements of 7 porphyritic magnesium‐rich (type I) chondrules, 1 aluminum‐rich chondrule, and 16 refractory inclusions (14 Ca‐Al‐rich inclusions [CAIs] and 2 amoeboid olivine aggregates [AOAs]) from the ungrouped carbonaceous chondrite Acfer 094 using a Cameca IMS 6f ion microprobe. Both AOAs and 9 CAIs show radiogenic ²⁶Mg excesses corresponding to initial ²⁶Al/²⁷Al ratios between ～5 × 10^?5 ～7 × 10^?5 suggesting that formation of the Acfer 094 CAIs may have lasted for ～300,000 years. Four CAIs show no evidence for radiogenic ²⁶Mg; three of these inclusions (a corundum‐rich, a grossite‐rich, and a pyroxene‐hibonite spherule CAI) are very refractory objects and show deficits in ²⁶Mg, suggesting that they probably never contained ²⁶Al. The fourth object without evidence for radiogenic ²⁶Mg is an anorthite‐rich, igneous (type C) CAI that could have experienced late‐stage melting that reset its Al‐Mg systematics. Significant excesses in ²⁶Mg were observed in two chondrules. The inferred ²⁶Al/²⁷Al ratios in these two chondrules are (10.3 ± 7.4) × 10^?6 (6.0 ± 3.8) × 10^?6 (errors are 2σ), suggesting formation 1.6^+1.2_‐0.6 and 2.2^+0.4_‐0.3 Myr after CAIs with the canonical ²⁶Al/²⁷Al ratio of 5 × 10^?5. These age differences are consistent with the inferred age differences between CAIs and chondrules in primitive ordinary (LL3.0–LL3.1) and carbonaceous (CO3.0) chondrites.     

A petrographic,chemical, and isotopic study of calcium‐aluminum‐rich inclusions and aluminum‐rich chondrules from the Axtell (CV3) chondrite

Abstract— Petrographic, compositional, and isotopic characteristics were studied for three calcium‐aluminum‐rich inclusions (CAIs) and four plagioclase‐bearing chondrules (three of them Al‐rich) from the Axtell (CV3) chondrite. All seven objects have analogues in Allende (CV3) and other primitive chondrites, yet Axtell, like most other chondrites, contains a distinctive suite of CAIs and chondrules. In common with Allende CAIs, CAIs in Axtell exhibit initial ²⁶Al/²⁷Al ratios ((²⁶Al/²⁷Al)₀) ranging from ～5 × 10^?5 to <1.1 × 10^?5, and plagioclase‐bearing chondrules have (²⁶Al/²⁷Al)₀ ratios of ～3 × 10^?6 and lower. One type‐A CAI has the characteristics of a FUN inclusion. The Al‐Mg data imply that the plagioclase‐bearing chondrules began to form >2 Ma after the first CAIs. As in other CV3 chondrites, some objects in Axtell show evidence of isotopic disturbance. Axtell has experienced only mild thermal metamorphism (<600 °C), probably not enough to disturb the Al‐Mg systematics. Its CAIs and chondrules have suffered extensive metasomatism, probably prior to final accretion. These data indicate that CAIs and chondrules in Axtell (and other meteorites) had an extended history of several million years before their incorporation into the Axtell parent body. These long time periods appear to require a mechanism in the early solar system to prevent CAIs and chondrules from falling into the Sun via gas drag for several million years before final accretion. We also examined the compositional relationships among the four plagioclase‐bearing chondrules (two with large anorthite laths and two barred‐olivine chondrules) and between the chondrules and CAIs. Three processes were examined: (1) igneous differentiation, (2) assimilation of a CAI by average nebular material, and (3) evaporation of volatile elements from average nebular material. We find no evidence that igneous differentiation played a role in producing the chondrule compositions, although the barred olivine compositions can be related by addition or subtraction of olivine. Methods (2) and (3) could have produced the composition of one chondrule, AXCH‐1471, but neither process explains the other compositions. Our study indicates that plagioclase‐bearing objects originated through a variety of processes.