Simulation of the interaction of galactic cosmic‐ray protons with meteoroids: On the production of radionuclides in thick gabbro and iron targets irradiated isotropically with 1.6 GeV protons

Abstract— Thick spherical targets made of gabbro (R = 25 cm) and of steel (R = 10 cm) were irradiated isotropically with 1.6 GeV protons at the Saturne synchrotron at Laboratoire National Saturne (LNS)/CEN Saclay in order to simulate the interaction in space of galactic cosmic‐ray (GCR) protons with stony and iron meteoroids. Proton fluences of 1.32 × 10¹⁴ cm^?2 and 2.45 × 10¹⁴ cm^?2 were received by the gabbro and iron sphere, respectively, which corresponds to cosmic‐ray exposure ages of about 1.6 and 3.0 Ma. Both artificial meteoroids contained large numbers of high‐purity target foils of up to 28 elements at different depths. In these individual target foils, elementary production rates of radionuclides and rare gas isotopes were measured by x‐ and γ‐spectrometry, by low‐level counting, accelerator mass spectrometry (AMS), and by conventional rare gas mass spectrometry. Also samples of the gabbro itself were analyzed. Up to now, for each of the experiments, ～500 target‐product combinations were investigated of which the results for radionuclides are presented here. The experimental production rates show a wide range of depth profiles reflecting the differences between low‐, medium‐, and high‐energy products. The influence of the stony and iron matrices on the production of secondary particles and on particle transport, in general, and consequently on the production rates is clearly exhibited by the phenomenology of the production rates as well as by a detailed theoretical analysis. Theoretical production rates were calculated in an a priori way by folding depth‐dependent spectra of primary and secondary protons and secondary neutrons calculated by Monte Carlo techniques with the excitation functions of the underlying nuclear reactions. Discrepancies of up to a factor of 2 between the experimental and a priori calculated depth profiles are attributed to the poor quality of the mostly theoretical neutron excitation functions. Improved neutron excitation functions were obtained by least‐squares deconvolution techniques from experimental thick‐target production rates of up to five thick‐target experiments in which isotropic irradiations were performed. A posteriori calculations using the adjusted neutron cross sections describe the measured depth profiles of all these simulation experiments within 9%. The thus validated model calculations provide a basis for reliable physical model calculations of the production rates of cosmogenic nuclides in stony and iron meteorites as well as in lunar samples and terrestrial materials.     

Simulation of the interaction of galactic cosmic ray protons with meteoroids: On the production of 3H and light noble gas isotopes in isotropically irradiated thick gabbro and iron targets

Abstract— Thick spherical targets, one made of gabbro (R = 25 cm) and one made of iron (R = 10 cm), were irradiated isotropically with 1.6 GeV protons at Laboratoire National Saturne (LNS)/Saclay to simulate the interactions of galactic cosmic ray protons with meteoroids in space. At various depths, both artificial meteoroids contained a large number of high‐purity, single‐element target foils and chemical compounds of up to 28 target elements. In these individual target foils, the elemental production rates of radionuclides and noble gas isotopes were measured. Here, we report the results for the light noble gas isotopes ^3,4He, ^20,21,22Ne, and ^36,38,39Ar for the most cosmochemically relevant target elements as well as for some meteoritic material from Jilin, Farmington, and Cape York. From ³He analyses done several years apart, ³H diffusive losses during sample storage have been obtained, and direct as well as cumulative ³He production rates for O, Mg, Al, Si, Fe, Ni, and the meteoritic material are given. Losses by diffusion of tritium from metallic Mg and Fe are found to occur on time scales of months, while metallic Al, Si, and stone meteorites are much more retentive. The production rate ratios P(³H)/P(³He)_d obtained in the simulation experiments are 0.73, 1.28, and 1.16 for O, Al, and Si, respectively. These rates are based on our best knowledge about the ³H and ³He production rates and should, therefore, replace data published earlier (Leya et al. 2000a). The earlier calculations for ⁴He, ^20,21,22Ne, and ^36,38,39Ar remain valid. The new modeled correlation ³He_cum/²¹Ne versus ²²Ne/²¹Ne for chondrites exposed to cosmic rays with an energy spectrum characterized by a modulation parameter of φ = 650 MeV is in fair agreement with the empirical relationship (“Berne plot”). However, for small meteorites and little shielding in larger ones, there are systematic differences that most likely are due to an underestimation of the spallogenic ²²Ne/²¹Ne ratio by ?2%.     

History of lunar meteorites Queen Alexandra Range 93069, Asuka 881757, and Yamato 793169 based on noble gas isotopic abundances,radionuclide concentrations,and chemical composition

Abstract— We investigated the characteristics and history of lunar meteorites Queen Alexandra Range 93069, Yamato 793169 and Asuka 881757 based on the abundances of all stable noble gas isotopes, the concentrations of the radionuclides ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁸¹Kr, and the abundances of Mg, Al, K, Ca, Fe, Cl, Sr, Y, Zr, Ba, and La. Based on the solar wind and cosmic-ray irradiations, QUE 93069 is the most mature lunar meteorite studied up to now. The ⁴⁰Ar/³⁶Ar ratio of the trapped component is 1.87 ± 0.16. This ratio corresponds to a time when the material was exposed to solar and lunar atmospheric volatiles ～400 Ma ago. On the other hand, Yamato 793169 and Asuka 881757 contain very little or no solar noble gases, which indicates that these materials resided in the top layer of the lunar regolith only briefly or not at all. For all lunar meteorites, we observe a positive correlation of the concentrations of cosmic-ray produced with trapped solar noble gases. The duration of lunar regolith residence for the lunar meteorites was calculated based on cosmic-ray produced ²¹Ne, ³⁸Ar, ⁷⁸Kr, ⁸³Kr, and ¹²⁶Xe and appropriate production rates that were derived based on the target element abundances and the shielding indicator ¹³¹Xe/¹²⁶Xe. For QUE 93069, Yamato 793169, and Asuka 881757, we obtained 1000 ± 400 Ma, 50 ± 10 Ma, and <1 Ma, respectively. Both Asuka 881757 and Yamato 793169 show losses of radiogenic ⁴He from U and Th decay and Yamato 793169 also ⁴⁰Ar loss from K-decay. For Asuka 881757, we calculate a K-Ar gas retention age of 3100 ± 600 Ma and a ²⁴⁴Pu-¹³⁶Xe fission age of 4240 ± 170 Ma. This age is one of the oldest formation ages ever observed for a lunar basalt. The exposure history of QUE 93069 after ejection from the Moon was derived from the radionuclide concentrations: ejection 0.16 ± 0.03 Ma ago, duration of Moon-Earth transit 0.15 ± 0.02 Ma and fall on Earth <0.015 Ma ago. This ejection event is distinguished temporally from those which produced the other lunar meteorites. We conclude that six to eight events are necessary to eject all the known lunar meteorites.     

Noble gases and nitrogen in Raghunathpura (IIAB) and Nyaung (IIIAB) iron meteorites

Noble gases and nitrogen were measured in two adjacent samples each from the Raghunathpura (IIAB) and the Nyaung (IIIAB) iron meteorite falls. Light noble gases in both the meteorites were of pure cosmogenic origin. Using (³He/⁴He)_c ratios and the production systematic of Ammon et al. ( 2009 ), we estimated the sample depth and meteoroid size for Nyaung (~8 cm depth in a ~15 cm radius object) and Raghunathpura (~12–14 cm depth in a ~25 cm object). We derived cosmic ray exposure ages of 1710 ± 256 Ma (for Nyaung, the highest reported so far for the IIIAB group) and 224 ± 34 Ma (for Raghunathpura). Variable amounts of trapped Kr and Xe were found in both meteorites. The phase Q‐like elemental ratio (⁸⁴Kr/¹³²Xe) suggests that the trapped component is of indigenous origin, and most likely hosted in the heterogeneously distributed micro‐inclusions of troilite/schreibersite. Trapped phase Q component is being reported for the first time, for a IIAB iron meteorite. Both meteorites showed light isotopic composition for nitrogen, and need at least two N components to explain the observed N isotopic systematic. Variable amounts of trapped noble gases and the presence of more than one N component suggest that the magmatic process that formed the parent body of these meteorites either could not completely homogenize or completely degas all the phases.     

Lunar surface exposure models for meteorites Elephant Moraine 96008 and Dar al Gani 262 from the Moon

Abstract— We derived the cosmic‐ray and solar particle exposure history for the two lunar meteorites Elephant Moraine (EET) 96008 and Dar al Gani (DaG) 262 on the basis of the noble gas isotopic abundances including the radionuclide ⁸¹Kr. For EET 96008, we propose a model for the exposure to cosmic rays and solar particles in three stages on the Moon: an early stage ～500 Ma ago, lasting less than 9 Ma at a shallow shielding depth of 20 g/cm², followed by a stage when the material was buried, without exposure, until it was exposed in a recent stage. This recent stage, at a shielding depth in a range of 200–600 g/cm², lasted for ～26 Ma until ejection. This model is essentially the same as that previously found for lunar meteorite EET 87521; thus, pairing of the two Elephant Moraine lunar meteorites that were recovered on the same icefield in Antarctica is confirmed by our data. The cosmic‐ray‐produced isotopes, the trapped solar and lunar atmospheric noble gases, as well as the radionuclide ⁸¹Kr observed for the DaG 262 lunar meteorite are consistent with a one‐stage lunar exposure history. The average burial depth of the Dar al Gani material before ejection was within a range of 50–80 g/cm². The exposure to cosmic rays at this depth lasted 500–1000 Ma. This long residence time for Dar al Gani at relatively shallow depth explains the high concentrations of implanted solar noble gases.     

Solar-proton-produced neon in shergottite meteorites and implications for their origin

Abstract— Measured Ne isotopes in samples of shergottite ALHA77005 show variations in ²¹Ne/²²Ne ratios and ²¹Ne abundances that are consistent with the presence of two cosmogenic components: a component produced by nuclear interactions of galactic cosmic rays (GCR) and a component produced at shallow shielding depths (～0–3 cm) by energetic solar flare protons (SCR). We suggest that the ²¹Ne/²²Ne ratio generally can be used to distinguish between SCR and GCR components in many meteorite types. Analysis of cosmogenic Ne produced in chondrite mineral separates, eucrites, and anorthositic lunar rocks, all having diverse major element compositions, indicate that the GCR ²¹Ne/²²Ne ratio increases modestly with relative Mg content. Data for hundreds of chondrite analyses suggest that SCR Ne is present in no more than a very small fraction of chondrites. Examination of literature data for other shergottites, however, indicate that all of these meteorites contain SCR Ne but that it is apparently absent in other SNC meteorites. The ubiquitous presence of SCR Ne in shergottites, in contrast to most other types of meteorites, suggests that the martian origin of shergottites gave them different orbital parameters compared to other meteorites. This in turn may have contributed to slower entry velocities and lesser surface ablation in the atmosphere or even to higher SCR production rates.     

Noble gases in presolar diamonds III: Implications of ion implantation experiments with synthetic nanodiamonds

Abstract— A series of experiments carried out by Koscheev et al. (1998, 2001, 2004, 2005) showed that the bimodal release of heavy noble gases from meteoritic nanodiamonds can be reproduced by a single implanted component. This paper investigates the implications of this result for interpreting the noble gas compositions of meteoritic nanodiamonds and for their origin and history. If the bimodal release exhibited by meteorite diamonds reflects release of the P3 noble gas component, then the composition inferred for the pure Xe‐HL end member changes slightly, the excesses of heavy krypton isotopes that define Kr‐H become less extreme, evidence appears for a Kr‐L component, and the nucleosynthetic contribution to argon becomes much smaller. After correction for cosmogenic neon inherited from the host meteorites, the neon in presolar diamonds shows evidence for pre‐irradiation, perhaps in interstellar space, and a nucleosynthetic component perhaps consistent with a supernova source. After a similar correction, helium also shows evidence for presolar irradiation and/or a nucleosynthetic component. For the case of presolar irradiation, due to the small size of the diamonds, a large entity must have been irradiated and recoiling product nuclei collected by the nanodiamonds. The high ³He/²¹Ne ratio (?43) calls for a target with a (C + O)/heavier‐element ratio higher than in chondritic abundances. Bulk gas + dust (cosmic abundances) meet this criteria, as would solids enriched in carbonaceous material. The long recoil range of cosmogenic ³He argues against a specific phase. The excess ³He in presolar diamonds may represent trapped cosmic rays rather than cosmogenic ³He produced in the vicinity of the diamond crystals.     

Spallation recoil II: Xenon evidence for young SiC grains

Abstract— We have determined the recoil range of spallation xenon produced by irradiation of Ba glass targets with ?1190 and ?268 MeV protons, using a catcher technique, where spallation products are measured in target and catcher foils. The inferred range for ¹²⁶Xe produced in silicon carbide is ?0.19 μm, which implies retention of ?70% for ¹²⁶Xe produced in “typical” presolar silicon carbide grains of 1 μm size. Recoil loss of spallation xenon poses a significantly smaller problem than loss of the spallation neon from SiC grains. Ranges differ for the various Xe isotopes and scale approximately linearly as function of the mass difference between the target element, Ba, and the product. As a consequence, SiC grains of various sizes will have differences in spallation Xe composition. In an additional experiment at ?66 MeV, where the recoil ranges of ²²Na and ¹²⁷Xe produced on Ba glass were determined using γ‐spectrometry, we found no evidence for recoil ranges being systematically different at this lower energy. We have used the new data to put constraints on the possible presolar age of the SiC grains analyzed for Xe by Lewis et al. (1994). Uncertainties in the composition of the approximately normal Xe component in SiC (Xe‐N) constitute the most serious problem in determining an age, surpassing remaining uncertainties in Xe retention and production rate. A possible interpretation is that spallation contributions are negligible and that trapped ¹²⁴Xe/¹²⁶Xe is ?5% lower in Xe‐N than in Q‐Xe. But also for other reasonable assumptions for the ¹²⁴Xe/¹²⁶Xe ratio in Xe‐N (e.g., as in Q‐Xe), inferred exposure ages are considerably shorter than theoretically expected lifetimes for interstellar grains. A short presolar age is in line with observations by others (appearance, grain size distribution) that indicate little processing in the interstellar medium (ISM) of surviving (crystalline) SiC. This may be due to amorphization of SiC in the ISM on a much shorter time scale than destruction, with amorphous SiC not surviving processing in the early solar system. A large supply of relatively young grains may be connected to the proposed starburst origin (Clayton 2003) for the parent stars of the mainstream SiC grains.     

Noble gas study of the Saratov L4 chondrite

Abstract– We have determined the elemental abundances and the isotopic compositions of noble gases in a bulk sample and an HF/HCl residue of the Saratov (L4) chondrite using stepwise heating. The Ar, Kr, and Xe concentrations in the HF/HCl residue are two orders of magnitude higher than those in the bulk sample, while He and Ne concentrations from both are comparable. The residue contains only a portion of the trapped heavy noble gases in Saratov; 40 ± 9% for ³⁶Ar, 58 ± 12% for ⁸⁴Kr, and 48 ± 10% for ¹³²Xe, respectively. The heavy noble gas elemental pattern in the dissolved fraction is similar to that in the residue but has high release temperatures. Xenon isotopic ratios of the HF/HCl residue indicate that there is no Xe‐HL in Saratov, but Ne isotopic ratios in the HF/HCl residue lie on a straight line connecting the cosmogenic component and a composition between Ne‐Q and Ne‐HL. This implies that the Ne isotopic composition of Q has been changed by incorporating Ne‐HL (Huss et al. 1996) or by being mass fractionated during the thermal metamorphism. However, it is most likely that the Ne‐Q in Saratov is intrinsically different from this component in other meteorites. The evidence of this is a lack of correlation between the isotopic ratio of Ne‐Q and petrologic types of meteorites (Busemann et al. 2000). A neutron capture effect was observed in the Kr isotopes, and this process also affected the ¹²⁸Xe/¹³²Xe ratio. The ³He and ²¹Ne exposure ages for the bulk sample are 33 and 35 Ma, respectively.     

Isotopic composition of trapped and cosmogenic noble gases in several Martian meteorites

Abstract— Isotopic abundances of the noble gases were measured in the following Martian meteorites: two shock glass inclusions from Elephant Moraine (EET) 79001, shock vein glass from Shergotty and Yamato (Y) 793605, and whole-rock samples of Allan Hills (ALH) 84001 and Queen Alexandra Range (QUE) 94201. These glass samples, when combined with literature data on a separate single glass inclusion from EET 79001 and a glass vein from Zagami, permit examination in greater detail of the isotopic composition of Ne, Ar, Kr, and Xe trapped from the Martian atmosphere. The isotopic composition of Martian Ne, if actually present in these glasses, remains poorly defined. The ⁴⁰Ar/³⁶Ar ratio of trapped Martian atmospheric Ar is probably considerably lower than the nominal ratio of 3000 measured by Viking, and data on impact glasses suggest a value of ～1900. The atmospheric ³⁶Ar/³⁸Ar ratio is ≤4.0. Martian atmospheric Kr may be enriched in lighter isotopes by ～0.5%/amu compared to both solar-wind Kr and to the Martian composition previously reported. The isotopic composition of Xe in these glasses agrees with that previously reported in the literature. The Martian atmospheric ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are higher than those reported by Viking by factors of ～2.5–1.6 (depending on the ⁴⁰Ar/³⁶Ar ratio adopted) and ～1.8, respectively, and are discussed in a separate paper. Cosmogenic gases indicate space exposure ages of 2.7 ± 0.6 Ma for QUE 94201 and Shergotty and 14 ± 1 Ma for ALH 84001. Small amounts of ²¹Ne produced by energetic solar protons may be present in QUE 94201 but are not present in ALH 84001 or Y-793605. The space exposure age for Y-793605 is 4.9 ± 0.6 Ma and appears to be distinctly older than the ages for basaltic shergottites. However, uncertainties in cosmogenic production rates still makes somewhat uncertain the number of Martian impact events required to produce the exposure ages of Martian meteorites.     

Ejection ages from krypton‐81‐krypton‐83 dating and pre‐atmospheric sizes of martian meteorites

Abstract— Cosmic‐ray exposure (CRE) ages and Mars ejection times were calculated from the radionuclide ⁸¹Kr and stable Kr isotopes for seven martian meteorites. The following ⁸¹Kr‐Kr CRE ages were obtained: Los Angeles = 3.35 ± 0.70 Ma; Queen Alexandra Range 94201 = 2.22 ± 0.35 Ma; Shergotty = 3.05 ± 0.50 Ma; Zagami = 2.98 ± 0.30 Ma; Nakhla = 10.8 ± 0.8 Ma; Chassigny = 10.6 ± 2.0 Ma; and Allan Hills 84001 = 15.4 ± 5.0 Ma. Comparison of these ages with previously obtained CRE ages from the stable noble gas nuclei ³He, ²¹Ne, and ³⁸Ar shows excellent agreement. This indicates that the method for the production rate calculation for the stable nuclei is reliable. In all martian meteorites we observe effects induced by secondary cosmic‐ray produced epithermal neutrons. Epithermal neutron fluxes, φ_n (30–300 eV), are calculated based on the reaction ⁷⁹Br(n, γβ)⁸⁰Kr. We show that the neutron capture effects were induced in free space during Mars‐Earth transfer of the meteoroids and that they are not due to a pre‐exposure on Mars before ejection of the meteoritic material. Neutron fluxes and slowing down densities experienced by the meteoroids are calculated and pre‐atmospheric sizes are estimated. We obtain minimum radii in the range of 22–25 cm and minimum masses of 150–220 kg. These results are in good agreement with the mean sizes reported for model calculations using current semiempirical data.     

Galactic cosmic ray‐produced 129Xe and 131Xe excesses in troilites of the Cape York iron meteorite

Abstract— The flux of galactic cosmic rays (GCR) in the solar system appears to change with time. Based on the abundances in iron meteorites of cosmogenic nuclides of different half lives, Lavielle et al. (1999) found that the GCR flux increased in recent times (<100 Ma) by about 38% compared to average flux in the past 150 Ma to 700 Ma ago. A promising technique for calibrating the GCR flux during the past ?50 Ma, based on the ¹²⁹I and ¹²⁹Xe pair of nuclides, was discussed earlier (Marti 1986; Murty and Marti 1987). The ¹²⁹I‐¹²⁹Xe_n chronometer provides a shielding‐independent system as long as the exposure geometry remained fixed. It is especially suitable for large iron meteorites (Te‐rich troilite) because of the effects by the GCR secondary neutron component. Although GCR‐produced Xe components were identified in troilites, several issues require clarifications and improvements; some are reported here. We developed a procedure for achieving small Xe extraction blanks which are required to measure indigenous Xe in troilites. The ¹²⁹Xe and ¹³¹Xe excesses (¹²⁹Xe_n, ¹³¹Xe_n) due to neutron reactions in Te are correlated in a stepwise release run during the troilite decomposition. Our data show that indigenous Xe in troilite of Cape York has isotopic abundances consistent with ordinary chondritic Xe (OC‐Xe), in contrast to a terrestrial signature which was reported earlier. Two methods are discussed which assess and correct for an interfering radiogenic ¹²⁹Xe_r component from extinct ¹²⁹I. The corrected ¹²⁹Xe_n concentration in troilite D4 of Cape York yields a cosmic ray exposure (CRE) age of 82 ± 7 Ma consistent, within uncertainties, with reported data (Murty and Marti 1987; Marti et al. 2004).     

New noble gas data of primitive and differentiated achondrites including Northwest Africa 011 and Tafassasset

Abstract— This work reports on the noble gas inventory of 3 new acapulcoites, 3 brachinites, 2 new eucrites from the Dar al Gani region in Libya, the unique achondrite Dar al Gani (DaG) 896 from the same locality, the new eucrite‐like achondrite Northwest Africa (NWA) 011, and the controversial sample Tafassasset. We determined cosmic ray exposure and gas retention ages, evaluated shielding conditions, and discuss the trapped noble gas component of the specimens. All exposure ages are within the known range of stony meteorites and partly confirm previously established age clusters. Shielding conditions vary, suggesting substantial shielding for all 3 brachinites and Tafassasset. We cannot exclude, however, that the Mg‐rich composition of brachinites simply simulates heavy shielding. Regarding the trapped component, we found Q‐like compositions only for the acapulcoite Thiel Mountains (TIL) 99002. The brachinite Elephant Moraine (EET) 99402 yields a high, subsolar ³⁶Ar/¹³²Xe ratio of ?400 along with a slightly elevated ⁸⁴Kr/¹³²atio, indicating minor atmospheric contamination. All the other samples, particularly the eucrite DaG 983, are characterized by clearly elevated Ar/Kr/Xe ratios due to significant terrestrial alteration. Tafassasset exhibits noble gas parameters that are different from those of CR chondrites, including a relatively high cosmic ray exposure age, the absence of a solar component, low ¹³²Xe concentrations, a low trapped ³⁶Ar/¹³²Xe ratio of ?30, and a noticeable amount of radiogenic ¹²⁹Xe. Similar attributes have been observed for some primitive achondrites. These attributes are also consistent with the metamorphic character of the sample. We, therefore, consider Tafassasset's noble gas record to be inconclusive as to its classification (primitive achondrite versus metamorphosed CR chondrite).     

Cosmogenic and fissiogenic noble gases and 81Kr-Kr exposure age clusters of eucrites

Abstract— The isotopic composition and concentrations of noble gases were measured in the eucrites Bereba, Cachari, Caldera, Camel Donga, Chervony Kut, Ibitira, Jonzac, Juvinas, Millbillillie, Moore County, Padvarninkai, Pasamonte, Pomozdino, Serra de Magé, Sioux County, and Vetluga. The distribution of ⁸¹Kr-Kr exposure ages shows “clusters” at (7 ± 1) Ma, (10 ± 1) Ma, (14 ± 1) Ma, (22 ± 2) Ma, and (37 ± 1) Ma that agree with those for howardites, eucrites, and diogenites (HED) at (6 ± 1) Ma, (12 ± 2) Ma, (21 ± 4) Ma, and (38 ± 8) Ma. This most likely indicates a common origin of HED meteorites. Correlation equations for the shielding-sensitive cosmogenic ratios ⁷⁸Kr/⁸³Kr, ⁸⁰Kr/⁸³Kr, ⁸²Kr/⁸³Kr, and ¹²⁴Xe/¹³¹Xe were obtained. Comparison with data from simulation experiments suggests that most eucrites were exposed to the cosmic radiation as somewhat large meteoroids with diameters of ～1 m or more. The shielding-dependence of the ⁷⁸Kr and ¹²⁶Xe production rates was found to be small, with a few exceptions the variations aren <10%–15%. Concentrations of spallogenic ³He indicate diffusive losses of up to 70% that can be, in first approximation, described by a model of quasi-continuous losses during the exposure to the cosmic radiation with a loss rate of the order of ～3 × 10^?8 a^?1. Radiogenic ⁴He shows additional substantial losses that occurred at the time of, or prior to, the separation of the meteoroids from their parent body. Typical ⁴⁰Ar retention in eucrites is 50%–60% which corresponds to a ⁴⁰Ar-K retention age of 3.4–3.6 Ga. In all analyzed unbrecciated eucrites, the retention is distinctly larger (70%–100%). The ²⁴⁴Pu fission ratio (⁸⁶Kr/¹³⁶Xe)_Pu, was evaluated from the data on Pomozdino samples to be 0.039 ± 0.014.     

Primitive xenon in diogenites and plutonium-244-fission xenon ages of a diogenite,a howardite,and eucrites

Abstract The ²⁴⁴Pu-fission-¹³⁶Xe retention ages of howardites, eucrites, and diogenites (HEDs) show that these meteorites have retained Xe since they were formed about 4500 Ma ago. For the Garland diogenite and the Millbillillie eucrite, we obtain fission Xe ages of 4525 ± 40 Ma and 4486 ± 40 Ma, respectively. If Xe isotope data reported by other workers are also considered, we conclude that the monomict equilibrated eucrites Camel Donga, Juvinas, and Millbillillie formed about 40 Ma later than Pasamonte, a polymict unequilibrated eucrite. Stannern, a monomict equilibrated brecciated eucrite, yields a ²⁴⁴Pu-¹³⁶Xe age of 4442 Ma. The ⁴⁰K-⁴⁰Ar retention ages fall, for most HEDs, into the 1000–4000 Ma age range, indicating that ⁴⁰Ar is generally not well retained. The good retentivity for Xe of HEDs allows us to study primordial trapped Xe in these meteorites. Except for Shalka, in which other authors found Kr and Xe from terrestrial atmospheric contamination only, we present for the first time Kr and Xe isotopic data for diogenites. We studied Ellemeet, Garland, Ibbenbühren, Shalka, and Tatahouine. We show that Tatahouine contains two types of trapped Xe: a terrestrial contamination acquired by an irreversible adsorption process and released at pyrolysis temperatures up to 800 °C, and indigenous primordial Xe released primarily between 800 °C and 1200 °C. The isotopic composition of this primordial Xe is identical to that proposed earlier to be present in primitive achondrites and termed U-Xe or “primitive” Xe, but it has not been directly observed in achondrites until now. This type of primitive Xe is important for understanding the evolution of other Xe reservoirs in the Solar System. Terrestrial atmospheric Xe (corrected for fission Xe and radiogenic Xe from outgassing of the Earth) is related to it by a mass dependent fractionation favoring the heavier Xe isotopes. This primitive Xe is isotopically very similar to solar Xe except for ¹³⁴Xe and ¹³⁶Xe. Solar Xe appears to contain an enrichment of unknown origin for these isotopes relative to the primitive Xe.     

Abundance and isotopic composition of noble gases in metal and graphite of the Bohumilitz IAB iron meteorite

Abstract— Abundances and isotopic compositions of noble gases in metal and graphite of the Bohumilitz IAB iron meteorite were measured. The abundance ratios of spallogenic components in metal reveal a ³He deficiency which is due to the diffusive loss of parent isotopes, that is, tritium (Tilles, 1963; Schultz, 1967). The diffusive loss likely has been induced by thermal heating by the Sun during cosmic‐ray exposure (～160 Ma; Lavielle et al, 1999). Thermal process such as impact‐induced partial loss may have affected the isotopic composition of spallogenic Ne. The ¹²⁹Xe/¹³¹Xe ratio of cosmogenic components in the metal indicates an enhanced production of epi‐thermal neutrons. The abundance ratios of spallogenic components in the graphite reveal that it contained small amounts of metal and silicates. The isotopic composition of heavy noble gases in graphite itself was obtained from graphite treated with HF/HCl. The isotopic composition of the etched graphite shows that it contains two types of primordial Xe (i.e., Q‐Xe and El Taco Xe). The isotopic heterogeneity preserved in the Bohumilitz graphite indicates that the Bohumilitz graphite did not experience any high‐temperature event and, consequently, must have been emplaced into the metal at subsolidus temperatures. This situation is incompatible with an igneous model as well as the impact melting models for the IAB‐IIICD iron meteorites as proposed by Choi et al. (1995) and Wasson et al (1980).     

Trapping of noble gases in proton-irradiated silicate smokes

Abstract— We have measured Ne, Ar, Kr and Xe in Si₂O₃ “smokes” that were condensed on Al substrates, vapor-deposited with various mixtures of CH₄, NH₃, H₂O and noble gases at 10 K and subsequently irradiated with 1 MeV protons to simulate conditions during grain mantle formation in interstellar clouds. The noble gases were analyzed using conventional stepwise heating and static noble gas mass spectrometry. Neither Ne nor Ar is retained by the samples upon warming to room temperature, but Xe is very efficiently trapped and retained. Kr is somewhat less effectively retained, typically depleted by factors of about 10–20 relative to Xe. Isotopic fractionation favoring the heavy isotopes of Xe and Kr of about 5–10‰/amu is observed. Correlations between the specific chemistry of the vapor deposition and heavy noble gas retention are most likely the result of competition by the various species for irradiation-produced trapping sites. The concentration of Xe retained by some of these smokes exceeds that observed in phase Q of meteorites and, like phase Q, they do not seem to be carriers of the light noble gases. Such artificially prepared material may, therefore, offer clues concerning the incorporation of the heavy planetary noble gases in meteoritic material and the nature of phase Q.     

Noble gas record,collisional history,and pairing of CV,CO, CK,and other carbonaceous chondrites

Abstract— Concentration and isotopic composition of the light noble gases as well as of ⁸⁴Kr, ¹²⁹Xe, and ¹³²Xe have been measured in bulk samples of 60 carbonaceous chondrites; 45 were measured for the first time. Solar noble gases were found in nine specimens (Arch, Acfer 094, Dar al Gani 056, Graves Nunataks 95229, Grosnaja, Isna, Mt. Prestrud 95404, Yamato (Y) 86009, and Y 86751). These meteorites are thus regolith breccias. The CV and CO chondrites contain abundant planetary‐type noble gases, but not CK chondrites. Characteristic features of CK chondrites are high ¹²⁹Xe/¹³²Xe ratios. The petrologic type of carbonaceous chondrites is correlated with the concentration of trapped heavy noble gases, similar to observations shown for ordinary chondrites. However, this correlation is disturbed for several meteorites due to a contribution of atmospheric noble gases, an effect correlated to terrestrial weathering effects. Cosmic‐ray exposure ages are calculated from cosmogenic ²¹Ne. They range from about 1 to 63.5 Ma for CO, CV, and CK classes, which is longer than exposure ages reported for CM and CI chondrites. Only the CO3 chondrite Isna has an exceptionally low exposure age of 0.15 Ma. No dominant clusters are observed in the cosmic‐ray exposure age distribution; only for CV and CK chondrites do potential peaks seem to develop at ～9 and ～29 Ma. Several pairings among the chondrites from hot deserts are suggested, but 52 of the 60 investigated meteorites are individual falls. In general, we confirm the results of Mazor et al. (1970) regarding cosmic‐ray exposure and trapped heavy noble gases. With this study, a considerable number of new carbonaceous chondrites were added to the noble gas data base, but this is still not sufficient to obtain a clear picture of the collisional history of the carbonaceous chondrite groups. Obviously, the exposure histories of CI and CM chondrites differ from those of CV, CO, and CK chondrites that have much longer exposure ages. The close relationship among the latter three is also evident from the similar cosmic‐ray exposure age patterns that do not reveal a clear picture of major breakup events. The CK chondrites, however, with their wide range of petrologic types, form the only carbonaceous chondrite group which so far lacks a solar‐gas‐bearing regolith breccia. The CK chondrites contain only minute amounts of trapped noble gases and their noble gas fingerprint is thus distinguishable from the other groups. In the future, more analyses of newly collected CK chondrites are needed to unravel the genetic and historic evolution of this group. It is also evident that the problems of weathering and pairing have to be considered when noble gas data of carbonaceous chondrite are interpreted.     

Bhawad LL6 chondrite: Chemistry,petrology, noble gases,nuclear tracks,and cosmogenic radionuclides

Abstract— Chemical and mineral analysis of the Bhawad chondrite, which fell in Rajasthan in 2002, suggest that this stone belongs to LL6 group of chondrites. Based on helium, neon, and argon isotopes, it has a cosmic ray exposure age of 16.3 Ma. The track density in the olivines shows a narrow range of 1.7–6.8 times 10⁶/cm². The ²²Na/²⁶Al ratio of 1.13 is about 25% lower than the solar cycle average value of about 1.5, but is consistent with irradiation of the meteoroid to modulated galactic cosmic ray fluxes as expected for a fall around the solar maximum. The cosmogenic records indicate a pre‐atmospheric radius of about 7.5 cm. Based on U/Th‐⁴He and K‐⁴⁰Ar, the gas retention ages are low (about 1.1 Ga), indicating a major thermal event or shock event that lead to the complete loss of radiogenic ⁴He and ⁴⁰Ar and the partial loss of radiogenic ¹²⁹Xe and fission Xe from ²⁴⁴Pu.     

81Kr‐Kr age and multiple cosmic‐ray exposure history of the Vaca Muerta mesosiderite

Abstract– Noble gas isotopic compositions were measured for a eucritic pebble and bulk material of a silicate–metal mixture from the Vaca Muerta mesosiderite as well as pyroxene and plagioclase separated from the eucritic pebble by total melting and stepwise heating methods. Trapped noble gases were degassed completely by a high‐temperature thermal event, probably at the formation of the Vaca Muerta parent body (VMPB). The presence of fissiogenic Xe isotopes from extinct ²⁴⁴Pu in the bulk samples might be a result of rapid cooling from an early high‐temperature metamorphism. High concentrations of cosmogenic noble gases enabled us to determine precise isotopic ratios of cosmogenic Kr and Xe. Spallogenic Ne from Na and unique Ar isotopic compositions were observed. The ⁸¹Kr‐Kr exposure age of 168 ± 8 Myr for the silicate pebble is distinctly longer than the age of 139 ± 8 Myr for the bulk samples. The precursor of the pebble had been irradiated on the surface of the VMPB for more than 60 Myr (first stage irradiation), with subsequent incorporation into bulk materials approximately 4 Gyr ago. The Vaca Muerta meteorite was excavated from the VMPB 140 Myr ago (second stage irradiation). Relative diffusion rates among the cosmogenic Ar, Kr, and Xe based on data obtained by stepwise heating indicate that Kr and Xe can be partially retained in pyroxene and plagioclase under the condition that resets the K‐Ar system. This result supports the presence of fission Xe and of excess concentration of cosmogenic Kr, which could have survived the thermal event approximately 3.8 Gyr ago.