Single Particle Characterisation of the Aerosol in the Marine Boundary Layer and Free Troposphere over Tenerife, NE Atlantic, during ACE-2

In the framework of the 2nd Aerosol Characterization Experiment (ACE-2), in June and July 1997, size segregated samples were collected for single particle analysis on the island of Tenerife, in both the marine boundary layer (MBL) and the free troposphere (FT), to study the characteristics of the North Atlantic aerosol. A systematic assessment was made of the aerosol under background conditions and when the environment was perturbed by European emissions and/or Saharan dust. The aerosol particles were analysed by automated and manual SEM-EDX, followed by cluster analysis to identify the different particle types and their abundance. Basing on back trajectory calculations, particle numbers and volume concentrations, different periods can be identified regarding the origin of the sampled air masses. In the FT, the air masses were classified as clean Atlantic, Saharan dust from Africa or pollution from Europe. In the MBL, air masses were classified as clean, polluted or perturbed by emissions from Europe. For both the FT and MBL samples, the main changes in chemical composition were observed between the fine and coarse mode aerosol. The FT fine mode aerosol is dominated by S-poor aluminosilicates (62%) in the event of the dust samples or sulphates, carbonaceous particles (20%) and S-rich aluminosilicates (46%) in the polluted samples. For the larger fractions, a strong decreasing trend was observed for the sulphates (less than 20%) and carbonaceous particles (10%) in the polluted samples. The MBL fine mode was completely dominated by S-rich particles (polluted 55% and perturbed 59%), and to a lesser extent, carbonaceous and aged sea salt particles. In the coarse mode, the polluted air mass is dominated by sea salt particles (62%). Contrary to the fine fraction, the polluted air mass in the coarse fraction contained 5.3% of S-rich particles. The combined interpretation of the data from the analysis of size-fractioned particles and the calculated backward trajectories for air masses coming from Europe, Africa and the Atlantic, results in better insights on aerosol chemistry, especially for the comparison of the particle composition in the FT and the MBL.     

Iodine Chemistry and its Role in Halogen Activation and Ozone Loss in the Marine Boundary Layer: A Model Study

A detailed set of reactions treating the gas and aqueous phase chemistry of the most important iodine species in the marine boundary layer (MBL) has been added to a box model which describes Br and Cl chemistry in the MBL. While Br and Cl originate from seasalt, the I compounds are largely derived photochemically from several biogenic alkyl iodides, in particular CH2I2, CH2ClI, C2H5I, C3H7I, or CH3I which are released from the sea. Their photodissociation produces some inorganic iodine gases which can rapidly react in the gas and aqueous phase with other halogen compounds. Scavenging of the iodine species HI, HOI, INO2, and IONO2 by aerosol particles is not a permanent sink as assumed in previous modeling studies. Aqueous-phase chemical reactions can produce the compounds IBr, ICl, and I2, which will be released back into the gas phase due to their low solubility. Our study, although highly theoretical, suggests that almost all particulate iodine is in the chemical form of IO-3. Other aqueous-phase species are only temporary reservoirs and can be re-activated to yield gas phase iodine. Assuming release rates of the organic iodine compounds which yield atmospheric concentrations similar to some measurements, we calculate significant concentrations of reactive halogen gases. The addition of iodine chemistry to our reaction scheme has the effect of accelerating photochemical Br and Cl release from the seasalt. This causes an enhancement in ozone destruction rates in the MBL over that arising from the well established reactions O(1D) + H2O 2OH, HO2 + O3 OH + 2O2, and OH + O3 HO2 + O2. The given reaction scheme accounts for the formation of particulate iodine which is preferably accumulated in the smaller sulfate aerosol particles.     

Hygroscopic growth of aerosol particles and its influence on nucleation scavenging in cloud: Experimental results from Kleiner Feldberg

The hygroscopic growth of individual aerosol particles has been measured with a Tandem Differential Mobility Analyser. The hygroscopic growth spectra were analysed in terms of diameter change with increasing RH from 20% to 85%. The measurements were carried out during the GCE cloud experiment at Kleiner Feldberg, Taunus, Germany in October and November 1990.Two groups of particles with different hygroscopic growth were observed. The less-hygroscopic group had average growth factors of 1.11, 1.04 and 1.02 for particle diameters of 50, 150 and 300 nm, respectively. The more-hygroscopic group had average growth factors of 1.34, 1.34, and 1.37 for the same particle diameters. The average fraction of less-hygroscopic particles was about 50%. Estimates of the soluble fractions of the particles belonging to the two groups are reported.Hygroscopic growth spectra for total aerosol, interstitial aerosol and cloud drop residuals were measured. A comparison of these hygroscopic growths of individual aerosol particles provides clear evidence for the importance of hygroscopic growth in nucleation scavenging. The measured scavenged fraction of particles as a function of diameter can be explained by the hygroscopic growth spectra.     

Observations of the evolution of the aerosol, cloud and boundary‐layer characteristics during the 1st ACE‐2 Lagrangian experiment

During the 1st Lagrangian experiment of the North Atlantic Regional Aerosol Characterisation Experiment (ACE‐2), a parcel of air was tagged by releasing a smart, constant level balloon into it from the Research Vessel Vodyanitskiy . The Meteorological Research Flight's C‐130 aircraft then followed this parcel over a period of 30 h characterising the marine boundary layer (MBL), the cloud and the physical and chemical aerosol evolution. The air mass had originated over the northern North Atlantic and thus was clean and had low aerosol concentrations. At the beginning of the experiment the MBL was over 1500 m deep and made up of a surface mixed layer (SML) underlying a layer containing cloud beneath a subsidence inversion. Subsidence in the free troposphere caused the depth of the MBL to almost halve during the experiment and, after 26 h, the MBL became well mixed throughout its whole depth. Salt particle mass in the MBL increased as the surface wind speed increased from 8 m s⁻¹ to 16 m s⁻¹ and the accumulation mode (0.1μm to 3.0 μm) aerosol concentrations quadrupled from 50 cm⁻³ to 200 cm⁻³. However, at the same time the total condensation nuclei (>3 nm) decreased from over 1000 cm⁻³ to 750 cm⁻³. The changes in the accumulation mode aerosol concentrations had a significant effect on the observed cloud microphysics. Observational evidence suggests that the important processes in controlling the Aitken mode concentration which, dominated the total CN concentration, included, scavenging of interstitial aerosol by cloud droplets, enhanced coagulation of Aitken mode aerosol and accumulation mode aerosol due to the increased sea salt aerosol surface area, and dilution of the MBL by free tropospheric air.     

Factors affecting boundary-layer wind shear over the Indian Ocean during FGGE

Statistics on the vertical wind shear in the boundary layer over the Indian Ocean were examined for the causes of regional and seasonal changes. Low-level cloud motions and surface ship wind reports were used to define the vertical shear. Temperature data from the ship reports were analyzed for boundary-layer stability related to the observed shears. Smaller wind shears were found in areas of large negative air-sea temperature difference (unstable boundary layers). The thermal wind effects were very small over most of the tropical Indian Ocean. The largest factor affecting the speed shear was the strength of the wind itself. Larger speed shear was found under high wind conditions. A small reduction in the direction difference between cloud and ship observations also was found under higher speeds. The scatter of cloud-ship comparisons around the mean (dispersion) also decreased for higher wind speeds. Daily gridded cloud motion and ship wind speed data had a correlation coefficient of 0.8 with a scatter of 1.9 m s^-1 (r.m.s.) around the mean difference.     

Monitoring of Short-Term Heavy Metal Deposition by Accumulation in Epiphytic Lichens (Hypogymnia Physodes (L.) Nyl.)

Many lichens are very sensitive to air pollution due to their symbiotic nature. However, they are generally less sensitive to toxic effects of trace elements; therefore they can be used as accumulator organisms for estimating concentrations of these elements in the environment. Heavy metal accumulation in lichens is a commonly used bioindication method for assessing heavy metal ambient levels. An active biomonitoring method was used for the determination of short-term accumulation of zinc, lead, arsenic and cadmium by epiphytic lichens transplanted at different localities in Slovenia polluted by heavy metals. The atomic absorption spectrophotometry method was used for the determination of heavy metal content in lichen thalli. The content of heavy metals in lichens collected in the background area with clean air (Rogla, Pohorje Mountains) was used as the reference value. Lichens were transplanted from Rogla using the branch transplantation technique for a period of 6 months in the surroundings of Slovenian thermal power plants (Velenje, otanj, Zavodnje, Veliki Vrh, Vnajnarje, and Dobovec) and close to the lead and zinc ore smelter at erjav. The monthly accumulation of heavy metals was comparable within years at selected locations. Heavy metal pollution was the highest at erjav despite of remediation of lead and zinc ore smelter. The monthly accumulation of all four heavy metals was statistically significantly higher in lichens exposed at erjav than at other localities.     

云凝结核数浓度对华东地区一次飑线过程发展的影响

利用WRF模式对2016年5月2日华东地区的一次飑线过程进行数值模拟,通过开展5组不同初始云凝结核数浓度的数值试验,讨论了污染对飑线发展的影响,并用Q矢量散度进行分析,结果表明:轻度污染下飑线线状结构最完整,强对流组织形式最紧密,而污染过重或过轻均导致飑线强对流组织分散甚至断裂;轻、中度污染对飑线降水有增强作用,而污染程度过重或过轻均对降水有限制作用;从清洁大气加深到轻度污染,强回波区宽度增大,强回波的高度升高,回波强度增强,随着污染继续加深,强回波区宽度减小,强回波的高度降低,回波强度减弱;轻度污染时,垂直速度、涡度和散度的强度较强;飑前低压在轻度污染时强度最强,雷暴高压、尾流低压和冷池则是随着污染加深而逐步减弱,但重度污染时,雷暴高压、尾流低压和冷池又增强;随着污染加深,对流云区不稳定性先增强后减弱,轻度污染下不稳定性最强;除了雪粒子外,其他水凝物粒子混合比含量均在轻度污染下达到最大值,而雪粒子混合比含量的最大值是在重度污染下出现的;推导了非地转非静力平衡的Q矢量散度方程,理论分析和计算结果均表明Q矢量辐合区对应上升运动,辐散区对应下沉运动。在较清洁和轻度污染的情况下,Q矢量散度高值区最强。     

On the Regulation of Climate: A Sulfate Particle Feedback Loop Involving Deep Convection

We propose a climate stabilizing feedback loop involving biogenic sulfur. The mechanism is similar to the "CLAW" hypothesis (Charlson et al., 1987) but does not require the active participation of the ocean biota. The magnitude of the feedback response in this loop is derived by convective transport of biogenic sulfur over tropical oceans into the middle and high troposphere. Once aloft, the sulfur is oxidized into low-volatile species which nucleate new particles that later subside back into the subtropical marine boundary layer (MBL) and serve as cloud condensation nuclei (CCN). The MBL clouds are susceptible to albedo modification by changes in CCN concentrations (Platnick and Twomey, 1995). We envision that as global temperatures rise the sea surface warms, convective mass transport of sulfur will rise and the increased mass of sulfur in the upper troposphere will lead to higher numbers of particles or a shift in the particle size distribution to larger sizes. In either case, there is an increase in the number of particles large enough to act as CCN in the air subsiding backinto the MBL. The increase in CCN increases the cloud albedo, decreases the solar input to the surface and the temperature decreases. More measurements are needed to confirm whether the magnitude of increased sulfur carried through the loop as a function of increased sea surface temperature is sufficient to close the loop and regulate the climate.     

Particle size distributions of methanesulfonate in the tropical pacific marine boundary layer

Fourteen high-volume cascade impactor samples were collected during a January-February, 1990, research cruise in the tropical Pacific from Panama to 180°. Aqueous extracts of the samples were analyzed for methanesulfonate (MSA), sulfate, and the seasalt tracer ion magnesium. The majority of MSA size distributions showed no pronounced maximum on submicrometer particles, as has been observed elsewhere. Analysis of the data indicated that MSA was distributed essentially uniformly with the effective surface area of particles >0.5 m in radius, which were primarily seasalt. Relatively less MSA was found in smaller particles which were primarily sulfate. These results are consistent with those from theoretical and laboratory experimental studies reported in the literature which suggest that MSA produced from photochemical oxidation of dimethylsulfide condenses on pre-existing particles in strong preference to nucleating into new particles. This implies that MSA may not contribute appreciably to enhancing cloud condensation nucleus populations in the remote tropical marine atmosphere.     

Landscape changes over a region in east Germany and their impact upon the processes of its atmospheric water-cycle

Summary Simulations replicating urbanization and/or different landscapes following the cessation of open-pit mining were performed with a non-hydrostatic meso--scale model. Except for cloud and precipitating particles the daily domain averages of the variables of state hardly differ under calm wind conditions. Nevertheless, the single land-use changes which are associated with urbanization, open-pit mines or the flooding of open-pit mines may appreciably or even significantly affect the local processes of the atmospheric water-cycle over and downwind of the land-use changes. Of the three, urbanization affects the local weather the least significantly, and flooding the open-pit mines causes the most significant changes. Generally, the most significant differences (at 90% or better statistical-significance level) occur for the liquid- and solid-water substances, the soil-wetness-factors, and the vertical component of the wind-vectors. The last changes strongly influence the paths of cloud and precipitation formation by the interaction ofcloud-microphysics-dynamics. In contrast to all other quantities for which a land-use change causes significant differences, the differences between cloud and precipitating particles are often not reflected in the environs of the landuse change.With 16 Figures     

Turbulence in Continental Stratocumulus,Part I: External Forcings and Turbulence Structures

Comprehensive, ground-based observations from the US Department of Energy Atmospheric Radiation Measurements program Southern Great Plains site are used to study the variability of turbulence forcings and cloud-scale turbulence structures in a continental stratocumulus cloud. The turbulence observations are made from an upward facing cloud (35 GHz) Doppler radar. Cloud base and liquid water path are characterized using a lidar at the surface and a microwave radiometer. The turbulence characterizations are compared and contrasted with those observed in marine stratocumulus clouds. During the 16-h observation period used in this study the cloud-base and cloud-top heights evolve with time and changes in liquid water path observed by the radiometer are consistent with variations in cloud depth. Unlike marine stratocumulus clouds, a diurnal cycle of cloud thickness and liquid water path is not observed. The observed surface latent, sensible, and virtual sensible heat fluxes and the radiative fluxes exhibit a diurnal cycle with values increasing from sunrise to afternoon and decreasing afterwards. During the night, the sensible heat, virtual sensible heat and the net radiative fluxes at the surface are slightly negative. Solar radiative heating prevails in the cloud layer during the day and strong radiative cooling exists at cloud top even during the day. Unlike marine stratocumulus, surface heating described by the convective velocity scale \(W_\mathrm{s}^{*}\) and cloud-top cooling described by \(W_\mathrm{r}^{*}\) are both important in driving the in-cloud turbulence during the day, whereas cloud-top cooling is the exclusive contributor during the night. The combined \(W_\mathrm{s}^{*}\) and \(W_\mathrm{r}^{*}\) (the total velocity scale \(W_\mathrm{t}^{*})\) provides a useful way to track the evolution of the turbulence structure in the cloud. The variance of the radar-measured radial velocity, which is related to resolved turbulence, follows the diurnal cycle and is consistent with the total velocity scale \(W_\mathrm{t}^{*}\) variations. It is higher during the day and lower during the night, which is contrary to that in marine stratocumulus. The \(W_\mathrm{t}^{*}\) values are lowest around sunset when the radiative cooling is also small due to upper-level clouds observed above the low-level stratus. The vertical distribution of the variance results from the surface heating during the day and cloud-top cooling during the night. The squared spectrum width, which is related to turbulence structures within the radar sampling volume (unresolved turbulence) also follows the diurnal cycle. Its vertical distribution indicates that the unresolved turbulence more closely relates to the processes near cloud top. Turbulence in the cloud requires about an hour to respond to the external forcings of surface heating and cloud-top radiative cooling. Positive skewness prevails during the day and negative skewness prevails at night with a sharp transition around sunset. Resolved turbulence dominates near cloud base whereas unresolved turbulence dominates near cloud top. The turbulence characteristics and variability defined in this study can be used to evaluate the time evolution of turbulence structures in large eddy simulation forced by surface and cloud-top radiative forcings.     

SEM-EDX Characterisation of Tropospheric Aerosols in the Negev Desert (Israel)

Individual aerosol particles collected in the Negev desert in Israel during a summer and winter campaign in 1996–1997 were analysed by scanning electron microscopy with energy-dispersive X-ray analysis. Hierarchical cluster analysis was performed to interpret the data on the basis of particle diameter and composition. Eleven particle classes (groups) provided clues on sources and/or particle formation. The summer samples were enriched in sulphates and mineral dusts; the winter samples contained more sea salts, aged sea salts, and industrial particles. The fine size fraction below 1 m diameter was enriched in secondary particles and showed evidence of atmospheric processing. The secondary sulphate particles were mainly attributed to long-range transport. A regional conversion from calcite to calcium sulphate occurred during summer. Industrial particles originating from local pollution appeared during winter.     

A simple non‐linear analytical relationship between aerosol accumulation number and sub‐micron volume, explaining their observed ratio in the clean and polluted marine boundary layer

We propose an analytical expression for the relation between aerosol accumulation number and sub‐micron volume over the marine boundary layer (MBL), based on a simple balance equation. By providing appropriate source and sink terms which account for entrainment, coagulation, in‐cloud scavenging and condensational growth, the model is able to reproduce the observed ratio between MBL particles larger than 80 nm diameter (as a proxy for accumulation mode number) and submicron aerosol volume, from freshly polluted to background conditions. Entrainment and coagulation are essential in predicting the observed ratio. Budget and lifetime calculations show that, due to relatively low source rates of oceanic non‐sea‐salt‐sulfate and sea‐salt, the anthropogenic signature in aerosol volume remains significant even after 8 days of MBL transport.     

Clear‐sky closure studies of lower tropospheric aerosol and water vapor during ACE‐2 using airborne sunphotometer, airborne in‐situ, space‐borne, and ground‐based measurements

We report on clear‐sky column closure experiments (CLEARCOLUMN) performed in the Canary Islands during the second Aerosol Characterization Experiment (ACE‐2) in June/July 1997. We present CLEARCOLUMN results obtained by combining airborne sunphotometer and in‐situ (optical particle counter, nephelometer, and absorption photometer) measurements taken aboard the Pelican aircraft, space‐borne NOAA/AVHRR data and ground‐based lidar and sunphotometer measurements. During both days discussed here, vertical profiles flown in cloud‐free air masses revealed 3 distinctly different layers: a marine boundary layer (MBL) with varying pollution levels, an elevated dust layer, and a very clean layer between the MBL and the dust layer. A key result of this study is the achievement of closure between extinction or layer aerosol optical depth (AOD) computed from continuous in‐situ aerosol size‐distributions and composition and those measured with the airborne sunphotometer. In the dust, the agreement in layer AOD (λ=380–1060 nm) is 3–8%. In the MBL there is a tendency for the in‐situ results to be slightly lower than the sunphotometer measurements (10–17% at λ=525 nm), but these differences are within the combined error bars of the measurements and computations.     

Characteristics of Turbulent Transfer during Episodes of Heavy Haze Pollution in Beijing in Winter 2016/17

We analyzed the structure and evolution of turbulent transfer and the wind profile in the atmospheric boundary layer in relation to aerosol concentrations during an episode of heavy haze pollution from 6 December 2016 to 9 January 2017. The turbulence data were recorded at Peking University’s atmospheric science and environment observation station. The results showed a negative correlation between the wind speed and the PM_2.5 concentration. The turbulence kinetic energy was large and showed obvious diurnal variations during unpolluted (clean) weather, but was small during episodes of heavy haze pollution. Under both clean and heavy haze conditions, the relation between the non-dimensional wind components and the stability parameter z/L followed a 1/3 power law, but the normalized standard deviations of the wind speed were smaller during heavy pollution events than during clean periods under near-neutral conditions. Under unstable conditions, the normalized standard deviation of the potential temperature σ _θ /|θ_*| was related to z/L, roughly following a –1/3 power law, and the ratio during pollution days was greater than that during clean days. The three-dimensional turbulence energy spectra satisfied a –2/3 power exponent rate in the high-frequency band. In the low-frequency band, the wind velocity spectrum curve was related to the stability parameters under clear conditions, but was not related to atmospheric stratification under polluted conditions. In the dissipation stage of the heavy pollution episode, the horizontal wind speed first started to increase at high altitudes and then gradually decreased at lower altitudes. The strong upward motion during this stage was an important dynamic factor in the dissipation of the heavy haze.     

The influence of aerosol particle composition on cloud droplet formation

A difference in partitioning between cloud droplets and interstitial air for two chemical species (elemental carbon and sulphur) with different expected behaviour in nucleation scavenging was observed in clouds at Mt. Kleiner Feldberg (825 m asl), near Frankfurt, Germany. The fraction of sulphur incorporated in cloud droplets was always higher than the fraction of elemental carbon. This difference in partitioning has also been observed in fog but under different pollution conditions in the Po Valley, Italy. Both these studies were based on bulk samples. In the present study at Kleiner Feldberg, impactor samples of the particles in the interstitial air and the cloud droplet residuals were taken and a single particle analysis was done on the samples. It was found that, for a given particle size, the majority of particles forming cloud droplets were soluble and that insoluble particles preferentially remained in the interstitial air.     

Study of background aerosols in the Antarctic troposphere

Systematic year-round observations of submicron aerosols were carried out at Syowa Station (69°00'S, 39°35'E) in 1978. On the basis of the results of these observations, it is concluded that two types of aerosols originating from different sources are present in the Antarctic croposphere. With the intrusion of maritime air, mostly in the polar night months, sea salt particles and ammonium sulfate particles contained originally in the clean maritime air are dominant. The size distribution of such aerosols is monomodal, having a single mode at around 0.03 m in radii. On the other hand, in the sunlit months, sulfuric acid droplets are predominant and the size distribution is bimodal, having an additional mode at around 0.005 m in radii. Those sulfuric acid particles seem to be formed photochemically within a specific layer in the mid to lower troposphere over Antarctica. Most Antarctic submicron particles are of tropospheric origin, not of stratospheric nor anthropogenic origin.     

Numerical simulation of January 28 cold air outbreak during GALE part II: The mesoscale circulation and marine boundary layer

A two-dimensional (2-D) mesoscale numerical model is applied to simulate the January 28 cold-air outbreak over the Gulf Stream region during the Intensive Observation Period-2 (IOP-2) of the 1986 Genesis of Atlantic Lows Experiment (GALE). The model utilizes a turbulence closure which involves the turbulent kinetic energy (TKE) and dissipation () equations and combines the level 2.5 formulations of Mellor and Yamada (1982) for better determination of the eddy Prandtl number.The modeled marine boundary layer (MBL) is in good agreement with the observations (Wayland and Raman, 1989) showing a low-level jet west of the Gulf Stream warm core and a constrained boundary layer due to the middle-level (2–4.5 km) stable layer. The MBL-induced single cloud and rain band first appears east of the Gulf Stream boundary, and then moves offshore at the speed of the circulation front. The front, however, moves slightly slower than the ambient flow. Removal of the tropopause does not influence the low-level circulation and the movement of the front. The speed of the front is slightly larger in the baroclinic downshear flow than in the barotropic flow. The results also indicate that the observed high cloud streets propagating downwind of the Gulf Stream may be related to upper-level baroclinic lee waves triggered by an elevated density mountain. The density mountain waves, however, become evanescent as the baroclinity (which gives a larger Scorer parameter) is removed.The modeled 2-D circulation systems are found to be sensitive to differing eddy Prandtl numbers, in contrast to the 1-D model results presented in Part I. Sensitivities become increasingly important as the clouds begin to interact with the MBL. A constant eddy Prandtl number of unity produces a more slantwise convection compared to that by the level 2.5 case. Cloud development is stronger in slantwise convection than in upright convection. The fastest development of clouds can be explained in terms of the conditional symmetric instability (CSI), which begins as the MBL baroclinity becomes sufficiently large.     

Evaluation of cloud and precipitation parameterization using a single-column model: A TWP-ICE case study

Cloud and precipitation parameterization schemes are evaluated, and their sensitivity to the method and/or parameters used to determine cloud physical processes is examined using a singlecolumn version of the Unified Model (SCUM). In the experiment for TWP-ICE, cloud fraction is overestimated (underestimated) in the upper (lower) troposphere due to the wet (dry) bias. The precipitation rate is well simulated during the active monsoon period, but overestimated during the suppressed monsoon and clear skies periods. In the moist convection scheme, trigger condition and entrainment process affect the lower tropospheric humidity through the impact on convective occurrence frequency and intensity, respectively. Strengthening the trigger condition and using the adaptive entrainment method alleviate the low-level dry bias. In the microphysics scheme, more large-scale precipitation is produced with prognostic rain, due to rain sedimentation considering vertical velocity of rain drop, than with diagnostic rain. Less ice/snow deposition with the prognostic two-ice category results in lower ice water content and upper-level cloud fraction than with the diagnostic splitting method for the twoice category. In the cloud macrophysics scheme, the prognostic cloud fraction and cloud/ice water content scheme produces a larger cloud fraction and more cloud/ice water content than the diagnostic scheme, mainly due to detrainment from moist convection (cloud source) that surpasses the effect of convective heating and drying (cloud sink). This affects temperature by influencing the radiative, convective, and microphysical processes. The experiment with combined modifications in cloud and precipitation schemes shows that interaction between modified moist convection and cloud macrophysics schemes results in more alleviation of the cold bias not only at the lower levels but also at the upper levels.     

Analysis of the Saharan dust regional transport

Summary The Balkan Peninsula is situated in the impact zone of Saharan dust storms. The case of Saharan dust transport to Belgrade in the period of 14–17 April 1994 is analyzed using the Eta model for synoptic and meso scale processes. Air back trajectories are calculated at six model levels from 434 up to 5129m with horizontal grid resolutions of 1°×1° and 10×10. Following cyclonic circulation the dust was picked up from North Africa, and transported over Mediterranean. Simultaneously, according to the analysis of the three lowest trajectories, transport of trace metals from Macedonia and southern Serbia by the Koshava wind might be dominant in the observed episode. Turbulent flow enhanced the coagulation process of initially clean dust particles with particles containing Pb and Cd. The coagulation and scavenging processes below and in clouds increased deposition rates of Pb and Cd in Belgrade in the course of wet removal, and consequently trough resuspension processes. Dry deposition samples contained characteristic particles up to 30µm in diameter with Fe content of 11 to 15 atomic% and significant ratio Si/Fe of 3 to 5, determined for selected single particles by the SEM/EDX method. Following dry and wet deposition of Cd and Pb, a residual effect of dustfall is noticed throughout the vegetational period.