Identification of landslide susceptibility zones in Gish River basin,West Bengal,India

The occurrence of landslide in the hilly region of Darjeeling during monsoon season is a matter of serious concern. Every year this natural hazard damages the major roads at several places and thus disrupts the transport and communication system in this region. This paper tries to prepare a landslide susceptibility zone (LSZ) map for the Gish River basin. A total number of 16 spatial parameters have been taken for this study and these are categorised under six factor clusters or groups for example, triggering factors, protective factor, lithological factors, morphometric factors, hydrological factors and anthropogenic factors. The LSZ map is prepared by integrating all the parameters adopting the weighting base as logistic regression. The landslide susceptibility map shows that nearly 9.11% of the area falls under the very high landslide-susceptible zone while 40.28% of the area of the total basin lies under the very low landslide-susceptible zone. The landslide-susceptible model is validated through the receiver operating characteristic curve. This curve shows 86% success rate in defining landslide-susceptible zones and 83.40% prediction rate for the occurrence of landslides. The spatial relationship between the landslide susceptibility model and other factors’ groups shows that the morphometric factors’ cluster (mainly slope) is the focalone for the determination of landslide-susceptible zone.     

Tidal effects on groundwater dynamics in shallow coastal aquifers—southeast coast of Tamilnadu,India

Tides play a significant role in the coastal environment; the mangroves, back waters, creeks, and the coastal groundwater interface. Tidal range has been calculated by using TIDECAL software. This study attempts to find the relation between water table condition and tides in the shallow coastal aquifers. The study was conducted by selecting 12 open wells along the coast of the southern part of Cuddalore to the northern part of Nagapattinam district of Tamilnadu. Observations were made in situ for water table fluctuation, dissolved oxygen (DO), and electrical conductivity (EC) for 24 h during full moon (FM) and new moon (NM) of every 2 h. The present study shows the relationship between tidal variations with respect to water table fluctuations and helps to understand the behavior of DO and EC. An interpolation technique, inverse distance weighted (IDW) method was used to obtain the spatial distribution map. The temporal and the spatial relationships between water table fluctuation, EC, and DO were also used in order to understand the coastal ecosystem in the natural environment.     

Groundwater pollution by arsenic concentration in sedimentary aquifers in the Indo-Gangetic Basin of Nepal

Naturally occurring arsenic （As） in groundwater of sedimentary aquifers has emerged as a global problem, and the Indo-Gangetic Basin of Nepal is no exception. In the sedimentary aquifers of the Indo-Gangetic Basin, arsenic enrichment and mobilization in groundwater by natural processes is considered an issue of major environmental health concern. About 11 million people, 47% of Nepali＇s total population living in the region and approximately 90% of them are relying on groundwater as their major source of drinking water. Moreover, 205555 ha of agricultural land in the basin are irrigated by groundwater through large numbers of deep and shallow irrigation tubewells for extensive cultivation of crops which has lead to creation of other pathways for arsenic ingestion among the people living in the region. It is estimated that around 0.5 million people in the basin are living at risk of arsenic poisoning In addition, some recent research shows the prevalence of dermatosis related to arsenicosis from 1.3% to 5.2 % and the accumulation of arsenic in biological samples like hair and nails much higher than the acceptance level. In these circumstances, the source of the natural arsenic concentration in groundwater of the Indo-Gangetic Basin is quite essential to explore. Therefore, to investigate the source of arsenic and management of arseniferious groundwater used for human consumption and irrigation, along with treatment or avoidance, is clearly an issue of research concern. Present research is carried out to understand the source of natural arsenic and its mobilization in groundwater of the Indo-Gangetic Basin. For this, we have collected bedrock, aquifer sediments and water samples from the study area. Sediment samples were taken from different lithofacies viz. clay, silt, sand and sandy gravels from groundwater aquifer where arsenic concentration is high. Water samples were taken from domestic shallow and deep tubewells in grid pattern. Bedrock samples were collected from source of the aquifer sediment, northern part of the Indo-Gangetic Basin, especially from the Siwalik and Lesser Himalaya. This paper particularly focuses on geology, mineralogy, hydro-geochemistry and sedimentary analysis of the high arsenic affected districts; Rautahat, Sarlahi, Parsa, and Kailali of Nepal.     

Amphibole—a key indicator mineral for petrogenesis of the Purulia carbonatite, West Bengal, India

The Purulia carbonatite of West Bengal, India is a dyke occurring within the 100 km long South Purulia Shear Zone (SPSZ), which marks the boundary between the Singhbhum Group of Rocks and the Chhotanagpur Granite Gneissic Complex (CGGC). It is composed essentially of calcite with apatite, amphibole, phlogopite, biotite, magnetite and ilmenite as common accessories. Based on optical properties and mineral chemistry two varieties of the amphibole are recognized: magnesiokatophorite and richterite. The latter is characterized by a relatively high content of Si and Na, while the former is enriched in Al and Ca. Such a composition of the amphibole is characteristic for the intermediate to the late stage carbonatite development. These two co-existing amphiboles reflect a sudden variation in total pressure within the magma chamber during the intrusion of the carbonatite dyke. It is inferred that the magnesiokatophorite started crystallizing first along with calcite and apatite. Subsequently, the ascent of carbonatitic magma to a more shallow depth (hypabyssal) resulted in the formation of the richterite. The difference in amphibole composition reflects a variation in the total pressure within the magma chamber that took place during the formation of the Purulia carbonatite. However, an alternative explanation, such as wallrock contamination, or liquid immiscibility, followed by carbonate magma segregation or magma mixing, may also be possible. There is, however, no evidence corroborating such an interpretation.     

Zinc contamination in river water and sediments at Taisyu Zn–Pb mine area,Tsushima Island,Japan

Tsushima Island is one of the oldest zinc-lead mining areas in Japan. River water and sediment samples were collected mainly from Taishu area to determine the contamination level of Zn and to clarify its behaviour in the natural system. Among the water samples analysed, 64% exceeded the standard environmental limit of 0.03 µg ml^− 1 for Zn. In most cases, Zn concentration in sediment samples also exceeded the standard value, and the concentration varied from 86.75–7490.07 µg g^− 1. The mineralogical constituents in sediments were almost similar and quartz had the strongest peak, but the interior part of the ores had many minerals, with galena having the highest proportion. Considering the enrichment factor values (EFc), 12 samples have values of more than 50, indicating a high pollution load for Zn. This study revealed that the sulphide ores, and contaminated sediments, are the possible contamination sources of Shiine River, and Zn dissolution occurred by reactions, such as desorption and ion exchange.     

Geochemistry of pillow basalts from Bompoka,Andaman–Nicobar islands,Bay of Bengal,India

Pillow lavas in Bompoka island of the Andaman–Nicobar islands, forming a part of Sunda–Burmese forearc, are composed of plagioclase and clinopyroxene microphenocrysts in a fine-grained ferruginous groundmass along with glass. They are also characterized by several quench plagioclase and clinopyroxene morphologies. Zr/TiO₂ versus Nb/Y relationship of these pillow lavas show that these are tholeiitic basalts in composition. These basalts have low MgO (5.19–6.12 wt%), Ni (84–118 ppm), and Cr (144–175 ppm) abundance and high FeO^(T)/MgO (1.71–1.92) ratios, reflecting their fractionated nature. In Th/Yb versus Nb/Yb and Ti/Yb versus Nb/Yb binary diagrams, they show N-MORB affinity. However, La/Nb–Y and Ce/Nb–Th/Nb relationships along with a slight LREE depleted (La_N/Yb_N = 0.75–0.82) pattern and high Ba/Zr (0.28–0.40) ratios and LILE (K, Rb, Ba, Sr and Th) enrichment relative to N-MORB, suggest their back-arc basin basalt affinity. It is inferred that these pillow basalts have been derived from a metasomatised N-MORB-like mantle source in a trench-distal (wider) back-arc basin, probably near the leading edge of the Eurasian continent during Early to Late Cretaceous times, prior to the currently active Andaman–Java subduction system.     

Chemical weathering rates in the Alaknanda–Bhagirathi river basins in Himalayas,India

The Alaknanda and Bhagirathi rivers flow through the Higher and Lesser Himalayas and confluence at Devprayag, which represents the origin of the Ganga (or Ganges) river. In the present study, a vast number of temporal and spatial samples of the river waters were collected and analyzed for major cations and anions. In addition, more recent and time series water flow data have been obtained and based on these inputs, a more refined dissolved flux rates have been estimated. The Alaknanda and Bhagirathi rivers show significant variations in chemical compositions during different seasons. Carbonate rock weathering is responsible for more than 70% of the chemical compositions in the river waters. The chemical weathering rates show seasonal variations and are much higher during non-monsoon season. The dissolved flux of Alaknanda river is much higher (1.80 × 10⁶ tons yr^?1) as compared to the Bhagirathi river (0.34 × 10⁶ tons yr^?1). The chemical weathering rates in the basin vary between 85 and 155 tons km^?2 yr^?1, which is significantly higher compared to the global average of ～24 tons km^?2 yr^?1.     

Arsenic mobilization in alluvial soils of Punjab, North–West India under flood irrigation practices

A laboratory investigation was carried out to examine the mechanism of arsenic (As) mobilization under flooded conditions (24 and 240 h) in 18 alluvial soils of Punjab, North–West India. Total dissolved As increased from a range of 3–16 μg L^?1 (mean 9 μg L^?1) to a range of 33–1,761 μg L^?1 (mean 392 μg L^?1) with the increase in flooding period from 24 to 240 h. The amount of As mobilization varied depending upon redox potential (pe) created by flooding conditions. After 24 h of flooded conditions, pe of soil water suspension ranged from ?1.75 to 0.77 (mean ?0.24). Increasing the flooding period to 240 h, pe of soil water suspension decreased in the range of ?4.49 to ?2.74 (mean ?3.29). Pourbaix diagram identified arsenate (HAsO₄ ^2?) as predominant species in most of the alluvial soil–water suspensions under oxidized conditions, after 24 h of equilibration period, which ultimately transformed to arsenite (H₃AsO₃ ⁰) after 240 h of anaerobic condition due to more reduced status. The solid phase identified was orpiment (As₂S₃). Identification of iron and manganese species in alluvial soil water suspension by Pourbaix diagram indicated decline in both soluble Fe²⁺ and SO₄ ^2? concentration due to the formation of iron sulfide mineral phase after 240 h under anaerobic conditions. In these soils, decline in soluble Fe was also due to the precipitation of vivianite [Fe₃(PO₄)₂·8H₂O]. Elevated arsenic content and low pe value were measured in aquifers located in paddy growing fields comparative to aquifers of other sites. Large degree of variability in As concentrations was recorded in aquifers located at same sites. Thus, it is better to analyze each aquifer for their As content rather than to depends on the prediction on As content of neighbouring wells. The present investigation elucidates that flood irrigation practices in Punjab for growing paddy crop could induce the geochemical conditions favorable to mobilize arsenic from surface soils which could eventually elevate its content in the underlying shallow aquifers. Water abstracted from these aquifers by hand pumps or tube wells for drinking purposes could create hazards for local population due to loading with arsenic concentration above the safe limits. Thus, to avoid further contamination of shallow aquifers with arsenic, it is advisable to shift the flooded rice cultivation to other upland crops having lesser water requirement.     

Drought severity modeling of upper Bhima river basin,western India,using GIS–AHP tools for effective mitigation and resource management

Natural Hazards - The combination of geographic information system (GIS) and analytic hierarchy process (AHP) performs the drought vulnerability assessment of larger areas efficiently. The drought...     

Mixing of geothermal and non-geothermal fluids in shallow aquifers in the Germencik-Nazilli area,Büyük Menderes Basin (SW Turkey)

This study observes groundwater hydrochemical characteristics during mixing between geothermal and non-geothermal fluids in Germencik–Nazilli area in the Büyük Menderes Basin (SW Turkey). Hydrogeochemical features of 32 non-geothermal, geothermal and surface samples were studied. The mean temperatures of the geothermal reservoirs are calculated to be 150–240 °C in Germencik field, based on Na-K-Mg geothermometry. Hydrochemical characteristics of Germencik geothermal fluid differ from non-geothermal fluids, mainly Na-Cl-HCO₃-type geothermal fluid, while non-geothermal fluid is mostly Ca-Mg-HCO₃-SO₄ type. High contents of some minor elements in geothermal fluids are most likely sourced from prolonged water-rock interaction, reflecting the signals of flow paths and residence times. A mass-balance approach was used to calculate mixing ratios between geothermal and non-geothermal fluids based on B, Cl and Na concentrations. Germencik field is considerably characterised by rising geothermal fluids and overlying non-geothermal fluids. The amount of water stored in the Quaternary aquifer evolved from a deep thermal source is low in Germencik (.5–40% geothermal fluid in non-geothermal wells). Mixing between geothermal and non-geothermal fluids has been caused by groundwater utilisation practices and is increased close to active faults. Irrigation of the shallow groundwater composition is considered as influx of low-temperature geothermal fluid.     

Paragenesis of Cr-rich muscovite and chlorite in green-mica quartzites of Saigaon–Palasgaon area,Western Bastar Craton,India

Journal of Earth System Science - Green mica (fuchsite or chromian-muscovite) is reported worldwide in the Archaean metasedimentary rocks, especially quartzites. They are generally associated with...     

Distribution and behavior of heavy metals in a river polluted by acid mine drainage in the Dabaoshan mine area, China

Acid mine drainage （AMD） has been recognized as a major environmental pollution problem over past decades. This pollutant effluent is complex and is characterized by elevated concentrations of iron and sulfate, low pH, and high concentrations of a wide variety of metals depending on the host rock geology. Massive inadvertent discharges from acid mines have given rise to dramatic cases of ecological damage. These events indicate an improved understanding of the mechanism controlling metal transport to the river is important, since the aquatic ecology will be affected, to some degree, dependent on the phase （dissolved or particulate） in which the metal is transported. In this study, polluted water samples were collected along the Hengshi River near the Dabaoshan mine, Guangdong, China, in April 2005. The concentrations of dissolved Cu, Zn, Cd and Pb have been determined using ICP-MS and the chemical speciation of those metals in suspended particles was examined using BCR methods and SEM/EDX mineralogical analysis. Combining these two sets of data, the intention was to develop geochemical concepts, which explain the behavior of Cu, Zn, Cd and Pb in particle-water interactions of heavy metals in AMD. The results show that the dissolved heavy metals exhibited non-conservative behavior in the Hengshi River. The dissolved and particulate Cu, Zn, Cd and Pb have the similar spatial distribution, which decreased gradually along the river except in the lower reaches because of the absorption-desorption between dissolved and particulate phases. Although the metal concentrations in both phases were elevated, dissolved metals were dominant and had the maximum concentrations in the low pH region.     

The variation in thickness and composition of coal seams and its use in interpretation of palaeocurrents — A case study from the Raniganj Coalfield,West Bengal,India

The petrological and chemical composition of a coal reflects all its inherent characters. Together with the variation in thickness of the coal seams, these aspects have been studied in detail around Salanpur (Raniganj Coalfield), India. The data reveal that any coal seam having its mother material supplied continuously from the same source will show a variation in its composition, the resultant being closely related to the environmental factors of the site of deposition, namely its morphology, including the disposition of its channel axis, and the palaeocurrent direction. Thus, it is suggested that these coal-seam properties may be used just as other sedimentary parameters in interpreting the characteristics of the site of deposition and depositing current.     

Seasonal variations of arsenic at the sediment–water interface of Poyang Lake,China

Arsenic species including arsenite, arsenate, and organic arsenic were measured in the porewaters collected from Poyang Lake, the largest freshwater lake of China. The vertical distributions of dissolved arsenic species and some diagenetic constituents [Fe(II), Mn(II), S(−II)] were also obtained in the same porewater samples in summer and winter. In sediments the concentration profiles of total As and As species bound to Fe–Mn oxyhydroxides and to organic matter were also determined along with the concentrations of Fe, Mn and S in different extractable fractions. Results indicate that, in the summer season, the concentrations of total dissolved As varying from 3.9 to 55.8 μg/L in sediments were higher than those (5.3–15.7 μg/L) measured in the winter season, while the concentrations of total As species in the solid phase varied between 10.97 and 25.32 mg/kg and between 7.84 and 30.52 mg/kg on a dry weight basis in summer and winter, respectively. Seasonal profiles of dissolved As suggest downward and upward diffusion, and the flux of dissolved As across the sediment–water interface (SWI) in summer and winter were estimated at 3.88 mg/m² a and 0.79 mg/m² a, respectively. Based on porewater profiles and sediment phase data, the main geochemical behavior of As was controlled by adsorption/desorption, precipitation and molecular diffusion. The solubility and migration of inorganic As are controlled by Fe–Mn oxyhydroxides in summer whereas they appear to be more likely controlled by both amorphous Fe–Mn oxyhydroxides and sulfides in winter. A better knowledge of the cycle of As in Poyang Lake is essential to a better management of its hydrology and for the environmental protection of biota in the lake.     

Heavy metal distribution and contamination in soils of Thane–Belapur industrial development area,Mumbai, Western India

There is a growing public concern over the potential accumulation of heavy metals in soil, owing to rapid urban and industrial development in the last decade in India. Therefore, an attempt was made to investigate the pollution caused due to excessive accumulation of heavy metals in soils near Thane–Belapur industrial belt of Mumbai. Soil samples were collected from surrounding industrial areas and were analyzed for toxic/heavy metals by X-ray fluorescence spectrometer. The analytical results indicate that the soils in the study area were enriched with Cu, Cr, Co, Ni and Zn. The concentration ranges were: Cu 3.10–271.2 mg/kg (average 104.6 mg/kg), Cr 177.9–1,039 mg/kg (average 521.3 mg/kg), Co 44.8–101.6 mg/kg (average 68.7 mg/kg), Ni 64.4–537.8 mg/kg (average 183.6 mg/kg) and Zn 96.6–763.2 mg/kg (average 191.3 mg/kg). The visualization of spatial data is made by preparing distribution maps of heavy metal concentration in soils and co-relation diagrams. These results highlight the need for instituting a systematic and continuous monitoring of the study area for heavy metals and other forms of pollution to ensure that pollution does not become a serious problem in future.     

Kink bands in thrust regime: Examples from Srinagar–Garhwal area,Uttarakhand, India

This paper deciphers the late stress systems involved in the development of kink bands in the perspective of thrust regime. In kink bands, the correlation coefficient for α–β plots is positive near thrusts and negative away from thrusts. The plots show nearly linear relationship near thrusts and non-linear relationship away from thrusts. The rotation was prominent mechanism of kink band formation near thrusts and rotation coupled with shearing, along the kink planes away from thrusts. Along thrusts σ ₁ is horizontal E–W trend and it rotates to horizontal N–S trend away from the thrust. The proposed model establishes that (1) the shearing along kink planes led to angular relationship, β < α and (2) the kink planes of conjugate kinks could be used for paleostress analysis even in those cases where shearing along these planes has occurred.     

Does geodiversity correlate with land use/land cover diversity? A case study of Birbhum district,West Bengal,India

The spatial knowledge of the relationships between geodiversity and land use/land cover diversity may become crucial to forming modern land use policies and consequently, it may also become fruitful in regional development. But, there is no work in the literature that emphasises the relationships between geodiversity and land use/land cover diversity, especially in a country like India which has a large variety of abiotic elements and also has a large variety of land use/land cover patterns in its territory and hence, has tremendous scope for such kind of work. Therefore, in the present work to partially fill the research gap, an attempt has been made to explore the relationships between geodiversity and land use/land cover diversity of the Birbhum district, India following the principles of richness index. The spatial correlations between geodiversity and land use/land cover diversity have been examined statistically by applying both correlation and regression analyses. The result shows a linear positive correlation between geodiversity and land use/land cover diversity of the concerned district that implies the fact that the areas of high geodiversity are also associated with the areas of high land use/land cover diversity and vice versa.     

Contamination of water and soil by the Erdenet copper–molybdenum mine in Mongolia

As one of the largest copper–molybdenum (Cu–Mo) mines in the world, the Erdenet Mine in Mongolia has been active since 1978 and is expected to continue operations for at least another 30 years. In this study, the potential impacts of mining activities on the soil and water environments have been evaluated. Water samples showed high concentrations of sulfate, calcium, magnesium, Mo, and arsenic, and high pH values in the order of high to low as follows: tailing water > Khangal River > groundwater. Statistical analysis and the δ²H and δ¹⁸O values of water samples indicate that the tailing water directly affects the stream water and indirectly affects groundwater through recharge processes. Soil and stream sediments are highly contaminated with Cu and Mo, which are major elements of ore minerals. Based on the contamination factor (CF), the pollution load index (PLI), and the degree of contamination (C_d), soil appears to be less contaminated than stream sediments. The soil particle size is similar to that of tailing materials, but stream sediments have much coarser particles, implying that the materials have different origins. Contamination levels in stream sediments display a tendency to decrease with distance from the mine, but no such changes are found in soil. Consequently, soil contamination by metals is attributable to wind-blown dusts from the tailing materials, and stream sediment contamination is caused by discharges from uncontained subgrade ore stock materials. Considering the evident impact on the soil and water environment, and the human health risk from the Erdenet Mine, measures to mitigate its environmental impact should be taken immediately including source control, the establishment of a systematic and continuous monitoring system, and a comprehensive risk assessment.     

Geochemical distribution of arsenic,cadmium, lead and zinc in river sediments affected by tailings in Zimapán,a historical polymetalic mining zone of México

High arsenic (As) groundwater is widely distributed in northwestern Hetao Plain, an arid region with sluggish groundwater flow. Observed As concentration in groundwater from wells ranges from 76 to 1,093 μg/l. Most water samples have high total dissolved solids, with Cl and HCO₃ as the dominant anions and Na as the dominant cation. The major hydrochemical types of most saline groundwaters are Na–Mg–Cl–HCO₃ and Na–Mg–Cl. By contrast, fresh groundwaters generally belong to the Na–Mg–HCO₃ type. High concentrations of arsenic in shallow aquifers are associated with strongly reducing conditions, as evidenced by high concentrations of dissolved organic carbon, ammonium, as well as dissolved sulfide and Fe, dominance of arsenite, relatively low concentrations of nitrate and sulfate, and occasionally high content of dissolved methane (CH₄). High As groundwaters from different places at Hetao Plain experienced different redox processes. Fluoride is also present in high As groundwater, ranging between 0.40 and 3.36 mg/l. Although fluorosis poses an additional health problem in the region, it does not correlate well with As in spatial distribution. Geochemical analysis indicates that evapotranspiration is an important process controlling the enrichment of Na and Cl, as well as trace elements such as As, B, and Br in groundwater. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.