Enantioselectivity of polychlorinated biphenyl atropisomers in sediment and biota from the Turtle/Brunswick River estuary,Georgia, USA

To investigate the potential for enantioselective transformation and accumulation, the enantiomer distributions of seven polychlorinated biphenyl (PCB) atropisomers were measured in the sediment and biota from a sub-tropical estuary heavily contaminated with Aroclor 1268, a technical mixture of highly chlorinated PCB congeners. Enantiomer fractions (EFs) of PCBs 91, 95, 136, 149, 174, 176, and 183 in marsh sediment, invertebrate, forage and predatory fish species, and bottlenose dolphins were determined. Non-racemic EFs greater than 0.75 were found in sediments for PCBs 136 and 174, likely the result of microbial dechlorination. Although enantiomer fractions in grass shrimp (Palaemonetes spp.) mirrored those of sediment, fish species had EFs that differed significantly from sediment or grass shrimp. Similarly, bottlenose dolphins were also found to contain non-racemic quantities of PCBs 91, 136, 174, 176, and 183. Non-racemic EFs in these biota were likely a result of both uptake of non-racemic proportions of PCBs from the diet and enantioselective biotransformation.     

Distribution of polychlorinated biphenyls in the water, sediment and fish from the Pearl River estuary, China

The concentrations and distribution of polychlorinated biphenyls were determined in water, surface sediments and fishes from the estuaries of Pearl River, PR China. The results showed that the concentrations ranged from 2.47 ng l-1 to 6.75 ng l-1 in water, from 11.13 ng g-1 to 23.23 ng g-1 in sediments (dry weight) and from 68.64 ng g-1 to 316.85 ng-1 in fish (lipid weight). It was found that the feeding habits of fish were very significant in the accumulation of polychlorinated biphenyls and pattern of congeners. Carnivorous and benthic fishes such as eel (Anguilla japonica) and Chinese sea catfish (Arius sinensis) were found to have high concentrations of polychlorinated biphenyls and of high-chlorinated congeners, while herbivores such as shad (Clupanodon punctatus) and mullet (Mugil cephalus) exhibited an opposite trend. Congeners IUPAC Nos. 153, 138, 118, 87/81, 170 and 52 were found frequently in most samples (both sediment and fish). In comparison with other places in the world, the concentration of polychlorinated biphenyls in sediment and fish from the estuary of Pearl River were low.     

Channel stability and sediment source assessment in streams draining a Piedmont watershed in Georgia,USA

Streams can be classified as stable or unstable, depending on the stage of channel evolution. Many streams of the southern Piedmont in United States have high sediment loads and are listed as impaired under the total maximum daily load (TMDL) program and may be unstable. It is not clear as to what the target (reference) load or remediation measures should be for unstable streams. The objective of this study was to determine the relative channel stability for a typical southern Piedmont stream using rapid geomorphic assessments (RGAs) and sediment yield analysis. The results were supported through a sediment fingerprinting analysis. RGAs were performed along 52 reaches on the North Fork Broad River (NFBR) main stem and two tributaries. Annual sediment yields were calculated and compared with yields in the southern Piedmont for stable streams that are resilient to degradation or aggradation and unstable streams that are susceptible to such disturbances. Majority of the NFBR main stem was found to be unstable with signs of geomorphic instability in the form of degradation and aggradation. The estimated average annual sediment yield was 0·78 T ha^?1 year^?1. By comparison, the median annual yield is 0·20 T ha^?1 year^?1 for stable streams and 0·48 T ha^?1 year^?1 for unstable streams in the Piedmont ecoregion with comparable drainage basin size. We conclude that the NFBR is in an unstable stage of channel evolution. Sediment fingerprinting proved that majority of the stream‐suspended sediment emanated from eroding stream channels. The methods outlined in this study have implications for the reference condition and remediation efforts related to stream turbidity and stream channel restoration. Copyright © 2010 John Wiley & Sons, Ltd.     

Phthalate ester plasticizers,DDT, DDE and polychlorinated biphenyls in biota from the Gulf of Mexico

The levels of phthalate ester plasticizers, DDT, DDE and polychlorinated biphenyls (PCBs) were determined in the tissues of 18 species of marine organisms from the northwestern Gulf of Mexico. Low levels of the most widely used phthalate, di-(2-ethylhexyl) phthalate, were found in the majority of the samples; no other phthalates were detected. DDT, DDE and PCBs were found in all samples, but at somewhat lower levels than those found in our 1971 survey. A decrease in p,p′-DDT/p,p′-DDE ratios relative to 1971 was also noted.     

Water and sediment dynamics in the estuary and mouth area of the Seine River

The principal features of the hydrological regime of the Seine River mouth area are discussed. Attention is focused on studying the dynamics of water and sediments in the estuary of the Seine River and in its tidal mouth area under the combined effect of seasonal variations in river runoff and tides. The history of development and improvement of the estuary is described.     

Distributions of polychlorinated biphenyls in the Daliao River estuary of Liaodong Bay,Bohai Sea (China)

The distributions of 41 polychlorinated biphenyls (PCBs) were determined in the aqueous phase, suspended particulate matter (SPM), and sediment of the Daliao River estuary in Liaodong Bay, Bohai Sea (China). The total PCB concentrations ranged from 5.51 to 40.28 ng L⁻¹ in the surface water, from 6.78 to 66.55 ng L⁻¹ dry weight in the SPM, and from 0.83 to 7.29 ng g⁻¹ dry weight in the sediment. The PCB concentrations in water, SPM, and sediment were moderate relative to those reported for other estuary and marine systems around the world. Sedimentary PCB concentrations decreased offshore due to the active deposition of laterally transported river-borne particles. The predominance of the highly chlorinated congeners for the water, SPM, and sediment samples are an indication of either a lack of degradation or the presence of nearby or recent releases into the environment.     

Lateral dynamics and associated transport of sediment in the upper reaches of a partially mixed estuary,Chesapeake Bay,USA

Data from time series of transects made over a tidal period across a section of the upper Chesapeake Bay, USA, reveal the influence of lateral dynamics on sediment transport in an area with a deep channel and broad extents of shallower flanks. Contributions to lateral momentum by rotation (Coriolis plus channel curvature), cross channel density gradients and cross channel surface slope were estimated, and the friction and acceleration terms needed to complete the balance were compared to patterns of observed lateral circulation. During ebb, net rotation effects were larger because of river velocity and reinforcement of Coriolis by curvature. During flood, stratification was greater because of landward advection of strong vertical density gradients. Together, the ebb intensified lateral circulation and flood intensified stratification focused sediment and sediment transport along the left side of the estuary (looking seaward). The tendency for greater stratification on flood and net sediment flux toward the left-hand shoal are contrary to more common models which, in the northern hemisphere, predict greater resuspension on flood and move sediment toward the right-hand shoal. These tidal asymmetries interact with the lateral circulation to focus net sediment flux on the left side of the estuary, and to produce net ebb directed sediment transport at the surface of the same order of magnitude as net flood directed sediment transport at the bottom.     

Partitioning behavior of perfluorinated compounds between sediment and biota in the Pearl River Delta of South China

Surface sediment and biota were collected from 12 sampling sites – seven along the Pearl River Delta and five along the Hong Kong coastline. Perfluorinated compound (PFC) concentrations were detected using a high-performance-liquid-chromatogram–tandem-mass-spectrometry system. Analytical results indicated that the total PFC concentrations were in the range of 0.15–3.11 ng/g dry weight in sediments, while the total PFC concentrations in oyster and mussel samples were between 0.46–1.96 and 0.66–3.43 ng/g wet weight, respectively. The major types of PFCs detected in the sediment samples were perfluorooctanesulfonic acid (PFOS) and perfluorobutanoic acid (PFBA), with concentrations ranging from low limits of quantification to 0.86 ± 0.12 ng/g dry weight and 1.50 ± 0.26 ng/g dry weight, respectively. In bivalve samples, PFOS was the dominant contaminant with concentrations ranging from 0.25 ± 0.09 to 0.83 ± 0.12 ng/g wet weight in oysters and 0.41 ± 0.14 to 1.47 ± 0.25 ng/g wet weight in mussels. An increase in PFC concentration was found to be correlated with increased human population density in the study areas.     

Effects of irrigation withdrawals on streamflows in a karst environment: lower Flint River Basin,Georgia, USA

Extensive implementation of centre pivot irrigation systems occurred between 1970 and 1980 in the lower Flint River Basin (FRB) of southwestern Georgia, USA. Groundwater within this karstic system is in direct hydraulic connection with regional streams, many of which are incised through the overburden into underlying limestone. We used long‐term U.S. Geological Survey gaging station data to evaluate multiple flow metrics of two tributaries (Ichawaynochaway Creek and Spring Creek) in the lower FRB to determine the extent of changes in stream behaviour since irrigation practices intensified. We compared pre‐ and post‐irrigation flow duration curves, 1‐, 7‐, and 14‐day minimum flows, and 8‐day (seasonal) and annual baseflow recession slopes, in addition to evaluating regional climate data to determine whether significant differences existed between the pre‐ and post‐irrigation periods. Our results showed significant changes in low‐flow durations in the post‐irrigation record for both gages, including a decrease by an order of magnitude for 98% exceedance flows at Spring Creek. Both gages indicated significant reductions in 1‐, 7‐, and 14‐day low flows. Eight‐day baseflow recession curves (within early summer months) and annual baseflow recession curves became significantly steeper during the post‐irrigation period for Ichawaynochaway Creek. We also found that a significant relationship existed between winter and summer minimum flows in both streams in the pre‐irrigation period which was disrupted in post‐irrigation years. Regional climate data for the study period revealed no significant changes in rainfall totals or frequency of drought; however, there was evidence for a shift in seasonal rainfall patterns. Copyright © 2011 John Wiley & Sons, Ltd.     

Tracer and hydrometric study of preferential flow in large undisturbed soil cores from the Georgia Piedmont,USA

We studied the temporal patterns of tracer throughput in the outflow of large (30 cm diameter by 38 cm long) undisturbed cores from the Panola Mountain Research Watershed, Georgia. Tracer breakthrough was affected by soil structure and rainfall intensity. Two rainfall intensities (20 and 40 mm hr⁻¹) for separate Cl⁻ and Br⁻ amended solutions were applied to two cores (one extracted from a hillslope soil and one extracted from a residual clay soil on the ridge). For both low and high rainfall intensity experiments, preferential flow occurred in the clay core, but not in the hillslope core. The preferential flow is attributed to well‐developed interpedal macrochannels that are commonly found in structured clay soils, characteristic of the ridge site. However, each rainfall intensity exceeded the matrix infiltration capacity at the top of the hillslope core, but did not exceed the matrix infiltration capacity at the middle and bottom of the hillslope core and at all levels in the clay core. Localized zones of saturation created when rainfall intensity exceeds the matrix infiltration capacity may cause water and tracer to overflow from the matrix into macrochannels, where preferential flow occurs to depth in otherwise unsaturated soil. Copyright © 1999 John Wiley & Sons, Ltd.     

Polychlorinated biphenyls in the Brisbane River estuary, Australia

The concentrations of PCBs in water, sediments, fish (6 species), crustacea (3 species), molluscs (1 species), polychaetes (mixed species) and birds (1 species) from the Brisbane River estuary were determined. Levels were comparable to other similar situations elsewhere. No relationship was found between trophic class and PCB concentration although pelicans at the highest trophic level examined exhibited the highest muscle tissue concentration (i.e., 15.7 mg kg⁻¹ on a wet weight basis). The pattern of distribution of PCBs within body tissues of fish was closely related to lipid content.     

The effect of secondary circulation on the salt distribution in a sinuous coastal plain estuary: Satilla River,GA, USA

An analysis of observational data suggests salt exchange in a sinuous coastal plain estuary is significantly impacted by counter-rotating residual horizontal eddies formed by channel curvature in meandering channels. The parts of adjacent eddies that advect material downstream follow the deep part of the channel where the flow continually criss-crosses from one side of the channel to the other and follows a relatively unimpeded trajectory to the sea. On the other hand, the parts of adjacent eddies that advect material upstream cross the channel at a different location where it encounters a series of shoals. In this case, the resulting upstream transport of salt is relatively inefficient and retards the rate at which salt can disperse upstream into the estuary. The strength of these circulations is modulated by the spring/neap cycle, allowing for a stronger gravitational mode of exchange to develop near neap tides, but has minimal impact on the length of the salt intrusion. It is suggested that the impeded upstream salt transport accounts for the observation that an impulse of river discharge advects a given isohaline 10 km downstream in 20 days, but that after the impulse, 70 days are required to return the isohaline to a similar position, counter to the notion of a simple dependence of intrusion length on river discharge.     

Understanding the temporal dynamics of the wandering Renous River,New Brunswick,Canada

Wandering rivers are composed of individual anabranches surrounding semi‐permanent islands, linked by single channel reaches. Wandering rivers are important because they provide habitat complexity for aquatic organisms, including salmonids. An anabranch cycle model was developed from previous literature and field observations to illustrate how anabranches within the wandering pattern change from single to multiple channels and vice versa over a number of decades. The model was used to investigate the temporal dynamics of a wandering river through historical case studies and channel characteristics from field data. The wandering Renous River, New Brunswick, was mapped from aerial photographs (1945, 1965, 1983 and 1999) to determine river pattern statistics and for historical analysis of case studies. Five case studies consisting of a stable single channel, newly formed anabranches, anabranches gaining stability following creation, stable anabranches, and an abandoning anabranch were investigated in detail. Long profiles, hydraulic geometry, channel energy, grain size and sediment mobility variables were calculated for each channel. Within the Renous study area, the frequency of channel formation and abandonment were similar over the 54 years of analysis, indicating that the wandering pattern is being maintained. Eight anabranches were formed through avulsions, five were formed through the emergence of islands from channel bars and 11 anabranches were abandoned. The stable anabranch pair displayed similar hydraulic geometry and channel energy characteristics, while unstable anabranch pairs did not. The anabranch pair that gained stability displayed more similar channel energy characteristics than the anabranch pair that was losing stability (abandoning). It appears that anabranch pairs with similar energy characteristics are more stable than anabranches where these characteristics are out of balance. This is consistent with the hypothesis that anabranch pairs of similar length will be more stable than those with dissimilar lengths. Copyright © 2005 John Wiley & Sons, Ltd.     

Seasonal variation of polychlorinated biphenyl concentrations in the southern part of the Baltic Sea

The impact of seasonal fluctuations in forcing factors such as atmospheric concentration, temperature, and biological productivity on the concentration of polychlorinated biphenyls (PCBs) in the surface water of the southern part of the Baltic Sea was investigated. Water samples were collected on eight cruises over 2 years. A clear seasonal variability in dissolved PCB concentrations was observed with higher levels in summer than in winter and spring. This was attributed to changes in atmospheric concentrations and water temperature, based on measurements showing the PCB levels in the atmosphere and surface water to be close to a partitioning equilibrium. Concentrations in the suspended particulate material (SPM) fraction were also variable, and when the quotient of the organic carbon normalised concentration in SPM and the dissolved concentration was calculated (i.e., the bioaccumulation factor (BAF)), a seasonal pattern was observed which was consistent with kinetic limitations on partitioning into particles caused by plankton growth. However, seasonal variability in the partitioning properties of the SPM may also contribute to this variability.     

Effects of urbanization on stream water quality in the city of Atlanta,Georgia, USA

A long‐term stream water quality monitoring network was established in the city of Atlanta, Georgia during 2003 to assess baseline water quality conditions and the effects of urbanization on stream water quality. Routine hydrologically based manual stream sampling, including several concurrent manual point and equal width increment sampling, was conducted ～12 times annually at 21 stations, with drainage areas ranging from 3·7 to 232 km². Eleven of the stations are real‐time (RT) stations having continuous measures of stream stage/discharge, pH, dissolved oxygen, specific conductance, water temperature and turbidity, and automatic samplers for stormwater collection. Samples were analyzed for field parameters, and a broad suite of water quality and sediment‐related constituents. Field parameters and concentrations of major ions, metals, nutrient species and coliform bacteria among stations were evaluated and with respect to watershed characteristics and plausible sources from 2003 through September 2007. Most constituent concentrations are much higher than nearby reference streams. Concentrations are statistically different among stations for several constituents, despite high variability both within and among stations. Routine manual sampling, automatic sampling during stormflows and RT water quality monitoring provided sufficient information about urban stream water quality variability to evaluate causes of water quality differences among streams. Fecal coliform bacteria concentrations of most samples exceeded Georgia's water quality standard for any water‐usage class. High chloride concentrations occur at three stations and are hypothesized to be associated with discharges of chlorinated combined sewer overflows, drainage of swimming pool(s) and dissolution and transport during rainstorms of CaCl₂, a deicing salt applied to roads during winter storms. One stream was affected by dissolution and transport of ammonium alum [NH₄Al(SO₄)₂] from an alum‐manufacturing plant; streamwater has low pH (<5), low alkalinity and high metals concentrations. Several trace metals exceed acute and chronic water quality standards and high concentrations are attributed to washoff from impervious surfaces. Published in 2009 by John Wiley & Sons, Ltd.     

Plutonium,radiocesium and radiocobalt in sediments of the Hudson River estuary

Anthropogenic radionuclides have reached the Hudson estuary as global fallout from nuclear weapons testing and through local releases from commercial nuclear reactors. Significant activities of²³⁸Pu and^239,240Pu (fallout-derived),¹³⁴Cs and⁶⁰Co (reactor-released), and¹³⁷Cs (derived from both sources), have accumulated in the sediments throughout the estuary, with the primary zone of accumulation near the downstream end of the system in New York harbor. The estuary appears to have trapped nearly all of the^239,240Pu delivered as fallout, and consequently, ocean dumping of dredged harbor sediment is currently the primary means for the net transport of these nuclides to coastal waters. In contrast, only 10–30% of the¹³⁷Cs,¹³⁴Cs and⁶⁰Co delivered to the estuary have been retained on the fine particles which accumulate at a rapid rate in the harbor.The primary factors which have governed the distribution of anthropogenic radionuclides in Hudson sediments are: (1) spread of fine particles labeled with both fallout and reactor nuclides throughout the axis of the estuary, (2) differences in timing of the peak fallout years (1962–1964) and years of maximum reactor releases (1971–1972), (3) large variations in sediment accumulation rates, ranging from a few millimeters per year or less to many tens of centimeters per year, (4) appreciable desorption of¹³⁷Cs and¹³⁴Cs from particles at higher salinities, and (5) possible enhanced desorption of⁶⁰Co at higher salinities (relative to¹³⁴Cs and¹³⁷Cs) which may be associated with the release of reduced manganese from the harbor sediments.