Analysis of groundwater quality using water quality index and conventional graphical methods: the Volta region,Ghana

Conventional graphical and statistical methods were used with water quality indices to characterize the hydrochemistry of groundwater from the northern part of the Volta region of Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area, and to determine the suitability of groundwater from the area for drinking purposes. The Q-mode cluster analysis reveals three main water groups. The groups established from the Q-mode HCA appear to indicate different degrees of weathering which could further indicate varying levels of fracturing aquifer hydraulic properties. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. Mineral activity diagrams for the CaO–Na₂O–Al₂O₃–SiO₂–H₂O and CaO–MgO–Al₂O₃–SiO₂–H₂O systems plotted for the area indicate stability in the smectite field and attribute hydrochemistry to the weathering of silicate minerals. Silicate mineral weathering and the effects of precipitation appear to be pervasive among all the three main geological terrains, whereas carbonate weathering is localized among the Voltaian aquifers. Cation exchange does not appear to play a significant role in the hydrochemistry but mild Water quality indices (WQI) were calculated for the samples using the concentrations of Na⁺, Ca²⁺, Mg²⁺, Cl⁻, NO₃ ⁻, F⁻, and EC at the various sample locations. The WQI values indicate that groundwater from the study area is of excellent quality for drinking purposes. WQI values from groundwater samples are averagely higher than samples taken from surface water sources in the area. This implies that geology has had an impact on the WQI of groundwater in the area.     

Environmental geochemistry and quality assessment of surface and subsurface water of Mahi River basin, western India

The hydrogeochemical study of surface and subsurface water of Mahi River basin was undertaken to assess the major ion chemistry, solute acquisition processes and water quality in relation to domestic and irrigation uses. The analytical results show the mildly acidic to alkaline nature of water and dominance of Na⁺ and Ca²⁺ in cationic and HCO₃ ⁻ and Cl⁻ in anionic composition. In general, alkaline-earth elements (Ca²⁺ + Mg²⁺) exceed alkalis (Na⁺ + K⁺) and weak acids (HCO₃ ⁻) dominate over strong acids (SO₄ ²⁺ + Cl⁻) in majority of the surface and groundwater samples. Ca²⁺–Mg²⁺–HCO₃ ⁻ is the dominant hydrochemical facies both in surface and groundwater of the area. The weathering of rock-forming minerals mainly controlled the solute acquisition process with secondary contribution from marine and anthropogenic sources. The higher concentration of sodium and dissolved silica, high equivalent ratios of (Na⁺ + K⁺/TZ⁺), (Na⁺ + K⁺/Cl⁻) and low ratio of (Ca²⁺ + Mg²⁺)/(Na⁺ + K⁺) suggest that the chemical composition of the water is largely controlled by silicate weathering with limited contribution from carbonate weathering and marine and anthropogenic sources. Kaolinite is the possible mineral that is in equilibrium with the water, implying that the chemistry of river water favors kaolinite formation. Assessment of water samples for drinking purposes suggests that the majority of the water samples are suitable for drinking. At some sites concentrations of TDS, TH, F⁻, NO₃ ⁻ and Fe are exceeding the desirable limit of drinking. However, these parameters are well within the maximum permissible limit except for some cases. To assess the suitability for irrigation, parameters like SAR, RSC and %Na were calculated. In general, both surface and groundwater is of good to suitable category for irrigation uses except at some sites where high values of salinity, %Na and RSC restrict its uses.     

Hydrogeochemistry and pollution assessment of quaternary–tertiary aquifer in the Liwa area,United Arab Emirates

This study presents the data on the hydrochemical characteristics and isotope chemistry of Liwa aquifer, which could be useful to clarify the hydrochemical facies and hydrogeological regime in the study area. Electric conductivity and total dissolved solid values show that the investigated water is slightly brackish, due to the effect of evaporation and the occurrences of evaporite rocks in the adjacent Sabkhas of Abu Dhabi. Major cations and anions arranged according to their decreasing concentrations are: Na⁺ > Ca⁺² > K⁺ > Mg⁺² and Cl⁻ > HCO₃ ⁻ > SO₄⁻², respectively. As sodium is the dominate cation and chloride is the prevailing anion, hydrochemically the groundwater of Liwa can be classified as Na–Cl rich, predominantly chloridic. Ion concentrations increase towards the northeast and presumably coincide with the lithological sources of ions. Factors affecting the hydrochemistry of the groundwater of the investigated area include the effect of weathering of soil and rocks, evaporation and agricultural activities. Stable isotopes of oxygen and hydrogen show that the shallow aquifers contain a single water type that originated in a distinct climatic regime. This water type deviates from the local meteoric water line, as well as from the Eastern Mediterranean Meteoric Water Line, suggesting potential evaporation of recharged water prior to infiltration. The waters are poor in tritium, and thus can be considered generally as indication for recharge prior to 1952. The degradation of groundwater quality can be attributed to evaporation and agricultural practices in most cases.     

Environmental geochemistry and quality assessment of mine water of Jharia coalfield,India

A long mining history and unscientific exploitation of Jharia coalfield caused many environmental problems including water resource depletion and contamination. A geochemical study of mine water in the Jharia coalfield has been undertaken to assess its quality and suitability for domestic, industrial and irrigation uses. For this purpose, 92 mine water samples collected from different mining areas of Jharia coalfield were analysed for pH, electrical conductivity (EC), major cations (Ca²⁺, Mg²⁺, Na⁺, K⁺), anions (F⁻, Cl⁻, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻), dissolved silica (H₄SiO₄) and trace metals. The pH of the analysed mine water samples varied from 6.2 to 8.6, indicating mildly acidic to alkaline nature. Concentration of TDS varied from 437 to 1,593 mg L⁻¹ and spatial differences in TDS values reflect the variation in lithology, surface activities and hydrological regime prevailing in the region. SO₄ ²⁻ and HCO₃ ⁻ are dominant in the anion and Mg²⁺ and Ca²⁺ in the cation chemistry of mine water. High concentrations of SO₄ ²⁻ in the mine water of the area are attributed to the oxidative weathering of pyrites. Ca–Mg–SO₄ and Ca–Mg–HCO₃ are the dominant hydrochemical facies. The drinking water quality assessment indicates that number of mine water samples have high TDS, total hardness and SO₄ ²⁻ concentrations and needs treatment before its utilization. Concentrations of some trace metals (Fe, Mn, Ni, Pb) were also found to be above the desirable levels recommended for drinking water. The mine water is good to permissible quality and suitable for irrigation in most cases. However, higher salinity, residual sodium carbonate and Mg-ratio restrict its suitability for irrigation at some sites.     

Hydrochemical appraisal of groundwater and its suitability in the intensive agricultural area of Muzaffarnagar district,Uttar Pradesh,India

Muzaffarnagar is an economically rich district situated in the most fertile plains of two great rivers Ganga and Yamuna in the Indo-gangetic plains, with agricultural land irrigated by both surface water as well as groundwater. An investigation has been carried out to understand the hydrochemistry of the groundwater and its suitability for irrigation uses. Groundwater in the study area is neutral to moderately alkaline in nature. Chemistry of groundwater suggests that alkaline earths (Ca + Mg) significantly exceed the alkalis (Na + K) and weak acids exceed the strong acids (Cl + SO₄), suggesting the dominance of carbonate weathering followed by silicate weathering. Majority of the groundwater samples (62%) posses Ca–Mg–HCO₃ type of hydrochemical species, followed by Ca–Na–Mg–HCO₃, Na–Ca–Mg–HCO₃, Ca–Mg–Na–HCO₃–Cl and Na–Ca–HCO₃–SO₄ types. A positive high correlation (r ² = 0.928) between Na and Cl suggests that the salinity of groundwater is due to intermixing of two or more groundwater bodies with different hydrochemical compositions. Barring a few locations, most of the groundwater samples are suitable for irrigation uses. Chemical fertilizers, sugar factories and anthropogenic activities are contributing to the sulphate and chloride concentrations in the groundwater of the study area. Overexploitation of aquifers induced multi componential mixing of groundwater with agricultural return flow waters is responsible for generating groundwater of various compositions in its lateral extent.     

Salinization of groundwater in arid and semi-arid zones: an example from Tajarak,western Iran

Study of the groundwater samples from Tajarak area, western Iran, was carried out in order to assess their chemical compositions and suitability for agricultural purposes. All of the groundwaters are grouped into two categories: relatively low mineralized of Ca–HCO₃ and Na–HCO₃ types and high mineralized waters of Na–SO₄ and Na–Cl types. The chemical evolution of groundwater is primarily controlled by water–rock interactions mainly weathering of aluminosilicates, dissolution of carbonate minerals and cation exchange reactions. Calculated values of pCO₂ for the groundwater samples range from 2.34 × 10⁻⁴ to 1.07 × 10⁻¹ with a mean value of 1.41 × 10⁻² (atm), which is above the pCO₂ of the earth’s atmosphere (10^−3.5). The groundwater is oversaturated with respect to calcite, aragonite and dolomite and undersaturated with respect to gypsum, anhydrite and halite. According to the EC and SAR the most dominant classes (C3-S1, C4-S1 and C4-S2) were found. With respect to adjusted SAR (adj SAR), the sodium (Na⁺) content in 90% of water samples in group A is regarded as low and can be used for irrigation in almost all soils with little danger of the development of harmful levels of exchangeable Na⁺, while in 40 and 37% of water samples in group B the intensity of problem is moderate and high, respectively. Such water, when used for irrigation will lead to cation exchange and Na⁺ is adsorbed on clay minerals while calcium (Ca²⁺) and magnesium (Mg²⁺) are released to the liquid phase. The salinity hazard is regarded as medium to high and special management for salinity control is required. Thus, the water quality for irrigation is low, providing the necessary drainage to avoid the build-up of toxic salt concentrations.     

Pleistocene chemical weathering history of Asian arid and semi-arid regions recorded in loess deposits of China and Tajikistan

Quaternary loess-soil sequences in China and Tajikistan are valuable archives of the chemical weathering history for arid and semi-arid regions of Asia. The development of new proxies independent of grain size are vital to reconstruct the long-term chemical weathering history of eolian deposits. In this study, we analyze major elemental and Rb, Sr, and Ba concentrations of decarbonated residue from representative loess and soil units along a north-south transect on the Chinese Loess Plateau and compare these concentrations among different grain-size fractions. Results show that most of the elemental abundances and ratios vary considerably among different grain-size fractions for both loess and paleosols, indicating transport-driven compositional differentiation of minerals during subaerial transport. However, (CaO + Na₂O + MgO)/TiO₂ ratios show little variation among different size fractions for the loess-soil transect. Loess-soil sequences at Lingtai (northern China) and Chashmanigar (southern Tajikistan) for the past 1.50-1.77 Ma show lower (CaO + Na₂O + MgO)/TiO₂ ratios in soil units than in adjacent loess horizons, in good agreement with greater weathering intensity in soils than in loess units. The (CaO + Na₂O + MgO)/TiO₂ ratio of the decarbonated residue is therefore a reliable proxy for chemical weathering of loess deposits that is independent of grain size. The (CaO + Na₂O+MgO)/TiO₂ ratios of the Lingtai and Chashmanigar sections display a relatively regular oscillation within a narrow range in the early Pleistocene, and a rapid increase in average values and in variance from 0.85-0.6 Ma to the present, indicating lowered chemical weathering intensity in both the dust source regions and the depositional areas. This event may be causally related to the expansion of northern hemisphere ice and/or the regional tectonic uplift of high mountains in Asia since the mid-Pleistocene.     

Hydrogeochemical processes in the groundwater environment of Heihe River Basin,northwest China

The Heihe River Basin is a typical arid inland river basin for examining stress on groundwater resources in northwest China. The basin is composed of large volumes of unconsolidated Quaternary sediments of widely differing grain size, and during the past half century, rapid socio-economic development has created an increased demand for groundwater resources. Understanding the hydrogeochemical processes of groundwater and water quality is important for sustainable development and effective management of groundwater resources in the Heihe River basin. To this end, a total of 30 representative groundwater samples were collected from different wells to monitor the water chemistry of various ions and its quality for irrigation. Chemical analysis shows that water presents a large spatial variability of chemical facies (SO₄ ²⁻–HCO₃⁻, SO₄ ²⁻–Cl⁻, and Cl⁻–SO₄ ²⁻) as groundwater flow from recharge area to discharge area. The ionic ratio indicates positive correlation between the flowing pairs of parameters: Cl⁻ and Na⁺(r = 0.95), SO₄ ²⁻ and Na⁺ (r = 0.84), HCO₃ ⁻ and Mg²⁺(r = 0.86), and SO₄ ²⁻ and Ca²⁺ (r = 0.91). Dissolution of minerals, such as halite, gypsum, dolomite, silicate, and Mirabilite (Na₂SO₄·10H₂O) in the sediments results in the Cl⁻, SO₄ ²⁻, HCO₃ ⁻, Na⁺, Ca²⁺ and Mg²⁺ content in the groundwater. Other reactions, such as evaporation, ion exchange, and deposition also influence the water composition. The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. The results show that most of the groundwater samples are suitable for irrigation uses barring a few locations in the dessert region in the northern sub-basin.     

Sources of deep groundwater salinity in the southwestern zone of Bangladesh

Twenty groundwater samples were collected from two different areas in Satkhira Sadar Upazila to identify the source of salinity in deep groundwater aquifer. Most of the analyzed groundwater is of Na–Cl–HCO₃ type water. The trends of anion and cation are Cl⁻ > HCO₃ ⁻ > NO₃ ⁻ > SO₄ ²⁻ and Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, respectively. Groundwater chemistry in the study area is mainly governed by rock dissolution and ion exchange. The dissolved minerals in groundwater mainly come from silicate weathering. The salinity of groundwater samples varies from ~1 to ~5%, and its source is possibly the paleo-brackish water which may be entrapped during past geologic periods.     

A study on hydrochemical characteristics of surface and sub-surface water in and around Perumal Lake,Cuddalore district,Tamil Nadu,South India

Hydrogeochemical investigations are carried out in and around Perumal Lake, Cuddalore district, South India in order to assess its suitability in relation to domestic and agricultural uses. The water samples (surface water = 16; groundwater = 12) were analyzed for various physicochemical attributes like pH, electrical conductivity (EC), sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), magnesium (Mg²⁺), chloride (Cl⁻), bicarbonate (HCO₃ ⁻), sulfate (SO₄ ²⁻), phosphate (PO₄), silica (H₄SiO₄) and total dissolved solids (TDS). Major hydrochemical facies were identified using Piper trilinear diagram. Hydrogeochemical processes controlling the water chemistry are water–rock interaction rather than evaporation and precipitation. Interpretation of isotopic signatures reveals that groundwater samples recharged by meteoric water with few water–rock interactions. A comparison of water quality in relation to drinking water quality standard proves that the surface water samples are suitable for drinking purpose, whereas groundwater in some areas exceeds the permissible limit. Various determinants such as sodium absorption ratio (SAR), percent sodium (Na%), residual sodium carbonate (RSC) and permeability index (PI) revealed that most of the samples are suitable for irrigation.     

Hydrochemical characteristics and quality assessment of shallow groundwater in a coastal area of Southwest Bangladesh

In this study, the hydrochemical characteristics of shallow groundwater in a coastal region (Khulna) of southwest Bangladesh have been evaluated based on different indices for drinking and irrigation uses. Water samples were collected from 26 boreholes and analyzed for major cations and anions. Other physico-chemical parameters like pH, electrical conductivity (EC), and total dissolved solids were also measured. Most groundwater is slightly alkaline and largely varies in chemical composition, e.g. EC ranges from 962 to 9,370 μs/cm. The abundance of the major ions is as follows: Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ = Cl⁻ > HCO₃ ⁻ > SO₄ ²⁻ > NO₃ ⁻. Interpretation of analytical data shows two major hydrochemical facies (Na⁺–K⁺–Cl⁻–SO₄ ²⁻ and Na⁺–K⁺–HCO₃ ⁻) in the study area. Salinity, total hardness, and sodium percentage (Na%) indicate that most of the groundwater samples are not suitable for irrigation as well as for domestic purposes and far from drinking water standard. Results suggest that the brackish nature in most of the groundwaters is due to the seawater influence and hydrogeochemical processes.     

Controls on the chemical composition of groundwater from alluvial aquifers in the Wanaka and Wakatipu basins, Central Otago, New Zealand

 Groundwater in alluvial aquifers of the Wakatipu and Wanaka basins, Central Otago, New Zealand, has a composition expressed in equivalent units of Ca²⁺≫Mg²⁺≅Na⁺>K⁺ for cations, and HCO₃ ^–≫SO₄ ^2->NO₃ ^–≅Cl^– for anions. Ca²⁺ and HCO₃ ^– occur on a 1 : 1 equivalent basis and account for >80% of the ions in solution. However, some groundwater has increased proportions of Na⁺ and SO₄ ^2-, reflecting a different source for this water. The rock material of the alluvial aquifers of both basins is derived from the erosion and weathering of metamorphic Otago Schist (grey and green schists). Calcite is an accessory mineral in both the grey and green schists at <5% of the rock. Geological mapping of both basins indicates that dissolution of calcite from the schist is the only likely mechanism for producing groundwater with such a constant composition dominated by Ca²⁺ and HCO₃ ^– on a 1 : 1 equivalent basis. Groundwater with higher proportions of Na⁺ and SO₄ ^2- occurs near areas where the schist crops out at the surface, and this groundwater represents deeper and possibly older water derived from basement fluids. Anomalously high K⁺ in the Wakatipu basin and high NO₃ ^– concentrations in the Wanaka basin cannot be accounted for by interaction with basement lithologies, and these concentrations probably represent the influence of anthropogenic sources on groundwater composition. Received, June 1996 Revised, March 1997, July 1997 Accepted, July 1997     

Chemical heterogeneity in an enderbite-hosted pseudotachylite,eastern India: evidence for syn-deformation multi-reaction melting in pseudotachylite

The origin of chemical and mineralogical heterogeneity in tens-of-microns wide layers and domains in enderbite-hosted couple-of-centimeters wide pseudotachylite vein is examined based on the results of BSE and X-ray element imaging, and electron probe microanalyses of major elements of host-rock minerals, clasts, microphenocrysts, and pseudotachylite matrix. The pseudotachylite layers and domains containing variable proportions of orthopyroxene and magnetite microphenocrysts continue as mantles around quartz, K-feldspar, plagioclase and garnet clasts. The clasts are chemically modified along margins and intra-clast pseudotachylite injections. The chemical modifications are extensive in smaller clasts <5 μm diameter. At least three chemically distinct layers and domains in the pseudotachylite, and their fine-grained matrices, plot in sharply defined, well-segregated and non-overlapping fields in FeO + MgO−Al₂O₃–SiO₂, FeO–CaO–MgO and CaO–Na₂O–K₂O and FeO vs. FeO/FeO + MgO diagrams. The compositions of the layers and domains—smeared between a feldspar + quartz component and a ferromagnesian component of garnet + Fe–Ti oxides (±orthopyroxene)—possibly correspond to fractionated quenched melts, or admixtures of microphenocrysts that cannot be resolved by the microbeam techniques employed. The compositional variations are incompatible with deformation-driven crystal fractionation in melt. Instead the layers and domains possibly are crystal-melt mushes produced by syn-deformation ultra-high temperature (1,250–1,375°C) melting reactions involving variable proportions of host-rock minerals determined by time-transient local phase aggregates experiencing strain. The similar element variation trends in pseudotachylite examined here and those reported from anorthosite, metapelite and charnockite elsewhere suggests local phase aggregate controlled multi-reaction melting is a phenomenon commoner than hitherto realized in pseudotachylites.     

The stability and origin of sodicgedrite in ultrahigh-temperature Mg-Al granulites: a case study from the Gondwana suture in southern India

Mg-Al-rich rocks from the Palghat-Cauvery Shear Zone System (PCSZ) within the Gondwana suture zone in southern India contain sodicgedrite as one of the prograde to peak phases, stable during T = 900–990°C ultrahigh-temperature metamorphism. Gedrite in these samples is Mg-rich (Mg/[Fe + Mg] = X _Mg = 0.69–0.80) and shows wide variation in Na₂O content (1.4–2.3 wt.%, Na^A = 0.33–0.61 pfu). Gedrite adjacent to kyanite pseudomorph is in part mantled by garnet and cordierite. The gedrite proximal to garnet shows an increase in Na^A and Al^IV from the core (Na^A = 0.40–0.51 pfu, Al^IV = 1.6–1.9 pfu) to the rim (Na^A = 0.49–0.61 pfu, Al^IV = 2.0–2.2 pfu), suggesting the progress of the following dehydration reaction: Ged + Ky → Na-Ged + Grt + Crd + H₂O. This reaction suggests that, as the reactants broke down during the prograde stage, the remaining gedrite became enriched in Na to form sodicgedrite, which is regarded as a unique feature of high-grade rocks with Mg-Al-rich and K–Si-poor bulk chemistry. We carried out high-P-T experimental studies on natural sodicgedrite and the results indicate that gedrite and melt are stable phases at 12 kbar and 1,000°C. However, the product gedrite is Na-poor with only <0.13 wt.% Na₂O (Na^A = 0.015–0.034 pfu). In contrast, the matrix glass contains up to 8.5 wt.% Na₂O, suggesting that, with the progressive melting of the starting material, Na was partitioned into the melt rather than gedrite. The results therefore imply that the occurrence of sodicgedrite in the UHT rocks of the PCSZ is probably due to the low H₂O activity during peak P-T conditions that restricted extensive partial melting in these rocks, leaving Na partitioned into the solid phase (gedrite). The occurrence of abundant primary CO₂-rich fluid inclusions in this rock, which possibly infiltrated along the collisional suture during the final amalgamation of the Gondwana supercontinent, strengthens the inference of low water activity.     

Evaluation of groundwater quality with emphasis on fluoride concentration in Nalbari district,Assam, Northeast India

This study was carried out to analyze groundwater quality in selected villages of Nalbari district, Assam, India, where groundwater is the main source of drinking water. 40 groundwater samples collected from hand pumps and analyzed for pH, EC, TDS, Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, Cl⁻ and F⁻. Chemical analysis of the groundwater showed that mean concentration of cations in (mg/L) is in the order Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ while for anions it is HCO₃ ⁻ > Cl⁻ > SO₄ ²⁻ > F⁻. Fluoride concentration was recorded in the range of 0.02–1.56 mg/L. As per the desirable and maximum permissible limits for fluoride in drinking water recommended by WHO and by Bureau of Indian Standards (BIS), which is 1.5 mg/L, the groundwater of about 97% of the samples were found to be suitable for drinking purpose. The suitability of the groundwater for irrigation purpose was investigated by some determining factors such as sodium adsorption ratio, soluble sodium percentage, Kelly’s ratio and electrical conductivity. The value of the sodium absorption ratio and electrical conductivity of the groundwater samples were plotted in the US Salinity laboratory diagram for irrigation water. Most of the groundwater samples fall in the field of C2S1 and C3S1 indicating medium to high salinity and low sodium water, which can be used for irrigation on almost all types of soil with little doubt of exchangeable sodium. The hydrochemical facies shows that the groundwater is Ca-HCO₃ type.     

Assessment of the impact of industrial effluents on water quality in Patancheru and environs, Medak district, Andhra Pradesh, India

The effects of multiple industrial-pollutant sources on the groundwater system were evaluated in the Industrial Development Areas (IDAs) of Medak district, Andhra Pradesh (AP), India. The quality of groundwater in the region has been affected negatively due to the discharge of effluents on open land and into ponds, tanks, and streams. Water samples from surface-water bodies, dug wells,and bore wells were analyzed for their major ion concentrations. The high values of electrical conductivity (EC) and concentrations of Na⁺, Ca²⁺, Cl^–, and HCO₃ ^– indicate the impact of industrial effluents. Based on the hydrochemistry, the groundwater is classified into various types, such as sodium-chloride, sodium-bicarbonate, calcium-chloride, and magnesium-chloride, and its suitability for drinking and irrigation has been assessed. The present studies made it possible to demarcate areas of contaminated groundwater and those prone to contamination in the near future. Water in the area has deteriorated all along Nakka Vagu up to a maximum distance of 500–700 m from the eastern bank. The groundwater quality in and around Patancheru (to a depth of 30 m) has become hazardous. Some possible remedial measures are suggested. Electronic Publication     

Geochemistry of groundwater in the alluvial plain of Tucumán province, Argentina

The Salí River hydrogeological basin is one of the most productive artesian basins in Argentina. It is located in the southeastern part of the province of Tucumán, northwestern Argentina, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. Three hydrochemical zones are defined in the study area and the processes that control the chemical composition of the water are manifestly different in each zone. The dissolution of halite, sodium sulphate, and gypsum explains part of the contained Na⁺, K⁺, Cl^–, SO₄ ^2–, and Ca²⁺, but other processes, such as cation exchange, calcite precipitation, weathering of aluminosilicates, and gas exchange with the atmosphere, also contribute to the water composition. The assessment of contamination indicators, such as pH, dissolved organic matter, dissolved oxygen, phosphate, and nitrate, indicates that the groundwater is suitable for human consumption. However, biological contamination has been detected in samples from some wells, especially those near the Salí River. Electronic Publication     

Water quality assessment of groundwater in some rock types in parts of the eastern region of Ghana

A baseline study involving analyses of subsurface water samples from the Cape Coast granitoid complex, Lower Birimian, Togo Formation and the Voltaian Group, was carried out to assess their suitability for drinking, domestic and agricultural purposes. Study results show that pH within the range (3.0 ≤ pH ≤ 6.5) constitutes 74% of the boreholes analysed, and 51% have hardness values ranging from 7.89 to 73.24 mg/l as CaCO₃ and are described as soft. Total dissolved solids are less than 1,000 mg/l and generally characterized by low conductivity values, of which 95% are within the range (55 ≤ EC ≤ 1,500 μS/cm). The mean values of the major cations (Ca²⁺, Mg²⁺, Na⁺, K⁺) and anions (SO₄²⁻, Cl⁻, HCO₃⁻) are all within the World Health Organisation (WHO) standards. Five (5) of the boreholes sampled have nitrate (NO₃⁻) contamination. Even though NO₃⁻ contamination and acidic waters exist in some of the boreholes, the majority of the boreholes are excellent for drinking and domestic purposes. Assessment of the groundwaters for agricultural irrigation revealed three main categories. These are low salinity–low sodicity (C1–S1), medium salinity–low sodicity (C2–S1) and high salinity–low sodicity (C3–S1), using the US Salinity Laboratory (USSL) classification scheme. As much as 95% of the samples plotted in the ‘excellent to good’ and ‘good to permissible’ categories on the Wilcox diagram. The groundwater in the study area may therefore be regarded as good for irrigation activities. The major identifiable geochemical processes responsible for the evolution of the various ions are mineral weathering and chemical reactions.     

Geothermometry applications for the Balıkesir thermal waters,Turkey

In this study, reservoir temperatures of Balıkesir geothermal waters in northwestern Turkey are estimated with various geochemical models. The geothermal fluids in the region are represented by Na–SO₄, Na–HCO₃ and Ca–HCO₃ type waters with discharge temperatures up to 98°C. It was determined that the solubility of silica in most of the waters is controlled by the chalcedony phase. Equilibrium states of the Balıkesir thermal waters studied by means of Na–K–Mg–Ca diagram, mineral saturation calculations and activity diagrams in the system composed of Na₂O–CaO–K₂O–Al₂O₃–SiO₂–H₂O phases approximate a reservoir temperature of about 120°C. Most of the waters are found to be equilibrated with calcite, chalcedony ± quartz and muscovite at predicted temperature ranges, similar to those calculated from the chemical geothermometers.     

Geochemistry of groundwater,Burdwan District,West Bengal,India

Hydrogeochemical investigations are carried out in the different blocks of Burdwan district, West Bengal, India in order to assess its suitability for drinking as well as irrigation water purpose. Altogether 49 representative groundwater samples are collected from bore wells and the water chemistry of various ions viz. Ca²⁺, Mg²⁺, Na⁺, K⁺, CO₃²⁻, HCO₃⁻, Cl⁻, SO₄²⁻ and NO₃⁻ are carried out. The chemical relationships in Piper and Gibbs diagram suggest that the groundwater mainly belongs to alkali type and Cl⁻ group and are controlled by rock dominance. A comparison of groundwater quality in relation to drinking water quality standards proves that most of the water samples are suitable for drinking water purpose whereas groundwater in some areas of the district has high salinity and high sodium adsorption ratio (SAR), indicating unsuitability for irrigation water and needs adequate drainage.