甘肃冯家场金矿床地质特征及找矿方向

冯家场金矿床位于祁连—北秦岭加里东造山带接合部位,金矿化严格受震旦—奥陶系李子园群木其滩组和近EW向断裂及小山坡闪长岩枝联合控制。在2 0km2矿区范围发现4条等间距平行展布的金矿化带,金矿化主体为石英脉型,次为构造蚀变岩型。金矿物以银金矿为主,次为金银矿。金的赋存状态以粒间金为主,裂隙金和包裹体金次之,最大粒度0 58mm×0 96mm×0 22mm,Au品位8×10-6～10×10-6。成矿阶段包括石英脉、黄铁矿 石英、黄铁矿细脉、多金属硫化物、方解石 石英阶段,多金属硫化物阶段为主要成矿阶段。已发现的金矿化断裂与岩体内外接触带为本区找矿方向。     

黑龙江砂宝斯金矿地质特征及找矿方向

砂宝斯金矿产于中侏罗统陆相碎屑岩中 ,有 6条矿化带 ,走向近 SN,矿带间距 2 0 0～ 4 0 0 m。矿石类型主要为蚀变砂岩和构造破碎蚀变岩型。矿化与硅化 -黄铁矿化带关系密切。矿床可化分为4个成矿期、 6个成矿阶段。矿带受断裂构造控制 ,硫同位素研究表明 ,部分成矿物质来源于深部 ,由岩浆活动带出 ,侵入岩参与了成矿作用。根据研究区内已发现的 6处金水系沉积物异常 (异常值高者达 2 0 .3× 10 -9)以及区域构造、岩浆活动特征 ,预测矿区内应以 、 号矿体为主 ,在矿体深部及矿区南部寻找隐伏矿体 ;矿区外围宜在有利的基底构造、中侏罗统地层及其与岩体的内外接触带寻找破碎蚀变岩型和石英脉型金矿。     

内蒙古虎拉林爆破角砾岩型金矿床特征

虎拉林金矿区主要地层为中侏罗统绣峰组陆源碎屑岩，岩浆岩以燕山期花岗斑岩和石英斑岩为主。在地层与岩体接触带附近发育爆破角砾岩，金矿(化)体主要受断裂控制而产于爆破角砾岩筒(带)中。矿区内已圈出6条矿(化)体，总体走向近SN，以1、2号为主要矿体。成矿与爆破角砾岩有关，形成一体多型的矿化分布形式。δ^34S变化范围为-0．2‰-0．8‰，具有深源岩浆S特征。S和Pb同位素、流体包裹体、稀土元素等特征表明，成矿物质来自地壳深部或地幔，成矿流体以深部岩浆热液为主。^39Al/^40Ari法测得金矿成矿年龄为135．5Ma。     

新疆哈密马庄山金矿成矿流体成冈及金沉淀机制的探讨

马庄山大型金矿位于阿齐克库都克东部 ,分布有中晚石炭世的中酸性火山岩及相应的次火山岩。近 2 0条矿体产于其中。矿石平均品位为 6.4× 1 0 -6。成矿流体均一温度的峰值在 2 4 0～ 2 60℃ ,成矿深度为 1 .6～ 2 .3km,具有浅成成矿的特点。成矿流体成分摩尔浓度比值 m K m N a (0 .1 0～ 0 .81 )、m2N a m Ca2 (0 .0 0 1～ 0 .338)、 mΣCl mΣS和 mΣC mΣS等比值 ,成矿条件参数p H值为 5.8～ 7.4,氧逸度 (f O2 ) 1 .9× 1 0 -5 5～ 2 .9× 1 0 -47Pa,硫逸度 (f S2 )约为 1 0 -1 3 Pa;Eh值为 - 0 .6e V流体 δ3 4 S值为 3.94‰～ 4.98‰ ,均随还原参数 Hy[Hy=(CO CH4) / CO2 ]和温度有规律变化。且矿石和脉石中的金含量也与 Hy成正比。矿石和脉石 REE配分图和微量元素特征与岩浆岩相似 ,代表着成矿物质来源与围岩岩浆岩关系密切。推断岩浆来源的成矿流体经地下水的混合作用是金沉淀的重要机制。     

内蒙古中部地区绿岩型金矿地质特征及成矿远景预测

内蒙古中部大青山—乌拉山地区发育有太古宙和元古宙两个时代和类型的绿岩带,太古宙绿岩中Au平均含量为2 .8×10 - 9～32×10 - 9,元古宙绿岩中Au平均含量为2 .6×10 - 9～34×10 - 9,与其他岩类相比,绿岩含矿性高,常赋存有大、中型金矿床。大青山—乌拉山地区金矿可划分为5种类型:1似层状细脉浸染型,如摩天岭金矿;2沉积变质层控型,如卯独庆和油篓沟金矿;3钾长蚀变-石英脉型,如乌拉山金矿;4蚀变岩-石英脉复合型,如东伙房金矿;5石英脉型,如后石花金矿。前两种属于元古宙绿岩型金矿,后三种属于太古宙绿岩型金矿,目前,该区已发现70余处金矿床(点)。根据谢学锦的地球化学找矿理论和本区地质特征,区内选出6个地球化学块体作为找矿远景区,它们是:1西河子—新地沟—红盘;2银号—二道洼—上高台;3阿玛乌素—西山湾—白乃庙;4黑敖包—赛乌素—查干此老;5金盆—麻迷图—满洲窑;6乌拉山—榆树湾。预测6个地球化学块体金金属量6 75 5 0 t,表明本区具有良好的成矿的物质基础和找矿远景。     

山东焦家金矿床的成因探讨

焦家金矿明显受断裂破碎带控制,围岩蚀变强烈,是我国特有的重要金矿类型。本文通过矿床地质特征、矿物中流体包裹体和稳定同位素研究确定焦家金矿成矿温度为310℃,压力800×10~5pa,fo_2为10~(-34)—10~(-36)。成矿溶液为富钾、氯的流体。金来自胶东群含金建造,成矿与尚庄花岗闪长岩有关,为中深,中温岩浆热液金矿床。     

阿尔金北缘大平沟金矿床成因

大平沟金矿是阿尔金北缘地区近年来新发现的一个中型金矿床。它受韧性剪切带构造的控制,矿化类型为蚀变糜棱岩型夹少量钾长石石英脉型。文章通过地质地球化学的研究,探讨了该矿床的成因。稀土元素、硫同位素、铅同位素和锶同位素地球化学特征反映成矿物质主要来源于变质岩;流体包裹体和氢氧同位素反映成矿流体主要来源于变质水,有少量重熔岩浆水和大气降水的混入,成矿温度198～2 90℃,成矿流体密度0 .791～0 .971g/cm3 ;盐度w(NaCleq) =2 .0 3%～5 .5 % ,成矿压力(42 0～72 0 )×10 5Pa ,成矿深度为1.6 1～2 .6 8km。石英流体包裹体Rb_Sr等时线年龄表明成矿时代为加里东期。大平沟金矿床属于中温动力变质热液成因矿床。     

华北地台北缘中段金矿床成矿年代学研究

华北地台北缘中段是我国重要的金矿化集中区。文中采用石英的4 0 Ar - 39Ar法和单颗粒锆石的U -Pb测年法 ,结合前人资料 ,提出本区绿岩带初生型金矿床的成矿时代为古元古代—新太古代 ,其中辽西排山楼金矿的成矿时代为 (2 10 5 .2± 10 .4)Ma ,金厂峪金矿的成矿时代为 (2 5 39± 2 3)Ma ,小营盘金矿的成矿时代为180 0Ma左右。构造期后再生型金矿床的成矿时代为燕山晚期—华力西中期 ,其中东坪金矿床的成矿时代为(35 0 .9± 0 .9)Ma ,冀东头道门子沟金矿的成矿时代为 (2 17.32± 2 .0 4)Ma ,峪耳崖金矿床的成矿时代为燕山早期 ,金厂沟梁和二道沟金矿的成矿时代为燕山晚期。     

成矿流体演化与成矿物理化学

成矿流体是富含挥发分 (CO2 、CH4等 )是具有较高含盐度的特殊地质流体。本文讨论了在流体演化过程中挥发分的来源 ,指出主要来自水岩作用、有机质分解及地幔去气和岩浆 ;碱金属及卤素同样具有多来源的性质 ,以海水、含盐系淋滤、建造水为主要来源 ,含盐系重熔可以形成富含碱金属的成矿流体。流体演化过程中氢氧同位素、硫同位素的分馏主要与温度、水岩比值或硫源丰度有关。一个重要的结论是 ,成矿流体的形成主要与地质作用有关 ,而流体来源是次要的。海底热水流体的地球化学特征以高δ3 4 S值、中稀土富集及正铕异常为特征。本文总结了热水流体成矿物理化学条件 ,指出水热流体物相点 :1) 10 80℃ ,7.5× 10 8Pa水溶液与硅酸岩熔浆分熔点 ;2 )水溶液的第二个临界点是气水溶液的超临界点 (374.15℃ ,2 .2 1× 10 7Pa) ;3)水溶液的沸点 (≥ 10 0℃ ,≥ 1× 10 5Pa) ;4)水溶液的冰点 (≤ 0℃ ,1× 10 5Pa) ;5 )H2 O CO2 体系的不混溶温度点 (2 6 6℃ ,2 .15×10 8Pa[1 3 ] 等是重要的成矿相变点。     

新疆东天山石英滩金矿流体包裹体地球化学

石英滩金矿地处塔里木板块北缘阿奇山—雅满苏火山弧,容矿围岩为下二叠统阿其克布拉克组陆相火山岩,控矿构造为破火山口环形断裂。流体包裹体特征和温度等参数研究表明石英滩金矿以低温(129℃～236℃)、低盐度(1.91wt%NaCl～2.74wt%NaCl)和浅成(成矿时压力为3×106～32×106Pa,深度小于1km)为特征;流体包裹体稀土元素研究初步得出成矿流体来自中酸性岩浆和火山岩。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。