Environmental geochemistry of the derelict Webbs Consols mine,New South Wales,Australia

Small-scale mining and mineral processing at the Webbs Consols polymetallic PbZnAg deposit in northern New South Wales, Australia has caused a significant environmental impact on streams, soils and vegetation. Unconfined waste rock dumps and tailings dams are the source of the problems. The partly oxidised sulphidic mine wastes contain abundant sulphides (arsenopyrite, sphalerite, galena) and oxidation products (scorodite, anglesite, smectite, Fe-oxyhydroxides), and possess extreme As and Pb (wt% levels) and elevated Ag, Cd, Cu, Sb and Zn values. Contemporary sulphide oxidation, hardpan formation, crystallisation of mineral efflorescences and acid mine drainage generation occur within the waste repositories. Acid seepages (pH 1.9–6.0) from waste dumps, tailings dams and mine workings display extreme As, Pb and Zn and elevated Cd, Cu and Sb contents. Drainage from the area is by the strongly contaminated Webbs Consols Creek and although this stream joins and is diluted by the much larger Severn River, contamination of water and stream sediments in the latter is evident for 1–5 km, and 12 km respectively, downstream of the mine site. The pronounced contamination of local and regional soils and sediments, despite the relatively small scale of the former operation, is due to the high metal tenor of abandoned waste material and the scarcity of neutralising minerals. Any rehabilitation plan of the site should include the relocation of waste materials to higher ground and capping, with only partial neutralisation of the waste to pH 4–5 in order to limit potential dissolution of scorodite and mobilisation of As into seepages and stream waters.     

Arsenic contamination at the Mole River mine,northern New South Wales

Mining and processing of arsenopyrite ore at the Mole River mine in the 1920–1930s resulted in abandoned mine workings, waste dumps and an arsenic oxide treatment plant. Weathering of waste material (2.6–26.6 wt% As) leads to the formation of water soluble, As‐bearing mineral salts (pharmacolite, arsenolite, krautite) and sulfates which affect surface waters after rainfall events. Highly contaminated soils, covering about 12 ha at the mine, have extreme As (mean 0.93 wt%) and elevated Fe, Ag, Cu, Pb, Sb and Zn values compared with background soils (mean 8 ppm As). Regionally contaminated soils have a mean As content of 55 ppm and the contaminated area is estimated to be 60 km². The soils have acquired their metal enrichments by hydromorphic dispersion from the dissolution of As‐rich particulates, erosion of As‐rich particulates from the dumps, and atmospheric fall‐out from processing plant emissions. Stream sediments within a radius of 2 km of the mine display metal enrichments (62 ppm to 27.5 wt% As) compared with the mean background of 23 ppm As. This enrichment has been caused by erosion and collapse of waste‐dump material into local creeks, seepages and ephemeral surface runoff, and erosion and transportation of contaminated soil into the local drainage system. Water samples from a mine shaft and waste‐dump seepages have the lowest pH (4.1) and highest As values (up to 13.9 mg/L), and contain algal blooms of Klebsormidium sp. The variable flow regime of the Mole River causes dilution of As‐rich drainage waters to background values (mean 0.0086 mg/L As) within 2.5 km downstream. Bioaccumulation of As and phytotoxicity to lower plants has been observed in the mine area, but several metal‐tolerant plant species (Angophora floribunda, Cassinia laevis, Chrysocephalum apiculatum, Cymbopogon refractus, Cynodon dactylon, Juncus subsecundus and Poa sieberiana) colonise the periphery of the contaminated site.     

Environmental geochemistry of the Gulf Creek copper mine area, north-eastern New South Wales, Australia

 Past mining and smelting of sulphide ore (pyrite-chalcopyrite-sphalerite) at the abandoned Gulf Creek mine has resulted in a stream highly contaminated by acid mine drainage (pH: 2.2–3.4), as well as degradation of local soil and vegetation. Physical dispersion of secondary metal-bearing minerals from abandoned ore and waste dumps into Gulf Creek and adsorption and coprecipitation of dissolved metals and metalloids in the stream bed cause elevated Ag, As, Cd, Cu, Fe, Pb and Zn values in stream sediments. The bioavailability of individual heavy metals to freshwater organisms changes downstream, however, selective bioaccumulation processes in algae reject readily bioavailable Zn and concentrate less bioavailable Cu. Polluted soils in the vicinity of the mine and smelter sites are subject to continuing soil erosion and either support no vegetation, or a depauperate flora with certain species showing bioaccumulation of metals and resistance to high metal contents. Rehabilitation of disturbed areas should involve covering and sealing sulphidic mine waste or removal of ore and waste dumps, installation of a physical and chemical plant or construction of a wetland environment (plus anoxic lime drains), and import of topsoil and planting of local, metal-tolerant plant species. Received: 17 March 1998 / Accepted: 6 October 1998     

Granite-hosted gold mineralization at Timbarra, northern New South Wales, Australia

The Timbarra gold deposits, located in the southern New England Fold Belt of New South Wales, Australia, represent an economically significant and distinctive member of the intrusion-related class of gold deposits. The five known deposits possess a total identified mineral resource of 16.8 Mt at 0.73 g/t gold, for a total of 396,800 contained ounces. The granites in the Timbarra region form a texturally complex, zoned pluton. The gold deposits are found within the Stanthorpe leucomonzogranite (242 to 238 Ma), which intrudes and forms a core to the more mafic, barren, Bungulla monzogranite (248 to 243 Ma). Gold is disseminated in the roof zone (upper 240 m) of a fractionated, magnetite- and ilmenite-bearing, I-type leucomonzogranite phase of the Stanthorpe body. The entire gold resource occurs in the areally extensive main leucomonzogranite pluton and is hosted by a medium- to coarse-grained granite. Disseminated ore is present in all five deposits, comprises >95% of the overall resource at Timbarra, and occurs predominantly as gently dipping, tabular to lenticular bodies that are conformably constrained beneath a fine-grained aplite carapace and internal aplite layers. The disseminated ore consists of gold-bearing muscovite-chlorite-carbonate alteration and infill of primary miarolitic cavities within massive leucomonzogranite or microgranite, and contains no discernable vein, joint, or fracture control at the outcrop or hand specimen scale. Structurally controlled mineralization forms the remaining 5% of the Timbarra resource, and comprises minor, low-density (0.02 to 0.25 per meter), vein-dikes and quartz-molybdenite veins emplaced along steeply dipping east-southeast, east-northeast, and north-northeast striking cooling joints. Both mineralization styles and alteration share a common paragenetic sequence of mineral precipitation. Quartz, perthitic K-feldspar, minor biotite, and albite are the earliest and most abundant infill minerals and commonly line primary cavities and vein-dikes. Subsequent minerals include coeval arsenopyrite, pyrite, fluorite, and molybdenite. The latest minerals include muscovite, chlorite, gold, calcite, silver-bismuth telluride, lead-bismuth telluride, and rare galena and chalcopyrite. The gold ore has a low total sulfide mineral concentration (Б%). Ore contains elevated concentrations of Bi, Ag, Te, As, Mo, and Sb; gold is strongly correlated with Bi, Ag, and Te, but only weakly with Mo, As, and Sb. Gold grains are generally <1 to 50 µm in size, but rarer grains as large as 1 mm in diameter have been observed. Gold fineness ranges from 950 to 600, and varies both within and between individual grains for a given deposit. The moderately oxidized I-type host granite, low-sulfide (Б%) ores, Au-Bi-Ag-Te geochemical signature, muscovite-chlorite-carbonate alteration assemblage, and low-salinity aqueous and carbonic fluids suggest that Timbarra is part of the newly recognized intrusion-related gold deposit class. Timbarra is distinguished from other intrusion-related gold deposits by the disseminated mineralization style within pervasively altered granite, forming gently dipping, tabular to lenticular ore zones.     

Gold mineralisation and advanced argillic alteration at the Dobroyde prospect,central New South Wales

Gold mineralisation at the Dobroyde prospect in central New South Wales is hosted by a zoned alteration system characterised by peripheral propylitic alteration, grading inwards through argillic and advanced argillic alteration to a siliceous altered core. Overprinting textures indicate that propylitic, argillic, advanced argillic and siliceous assemblages were successively superimposed on each other. Au grades between 0.3–0.8 ppm are associated with siliceous alteration and cross‐cutting pyrite veinlets. Higher Au grades are associated with barite veins that cut the pyrite veinlets. Native Au, native Te, Au, Pb and Hg tellurides, Pb selenide, chalcopyrite, Zn‐sphalerite and tennantite‐tetrahedrite occur in the barite veins. Microscopic pyrophyllite shears cut the barite veins. The location of the Dobroyde prospect, the orientation of its internal alteration zonation and the orientation of auriferous barite veins in the core of the prospect are controlled by a 330°‐striking fault. Movement on this fault, synchronous with hydrothermal activity, at some time between the Late Ordovician and mid‐Devonian controlled the development of successive phases of brecciation, siliceous alteration, pyrite and later barite‐Au veining in the prospect core. The restricted distribution of auriferous barite veins within the siliceous altered core of the prospect is inferred to be controlled by the relatively brittle rheology of this assemblage during deformation, and its location on the fault that formed the main hydrothermal fluid conduit. Alteration zones distal from this fault remain unmineralised. The Dobroyde prospect may be a product of the same Early Devonian metallogenic epoch as the paragenetically similar Temora and Peak Hill deposits. All three deposits/prospects appear to be localised in splays of either the Gilmore Fault Zone or the Parkes Thrust.     

An unusual manganese silicate occurrence at the Hoskins mine,Grenfell district,New South Wales

Stratiform manganese silicate rocks overlie jasper and metabasah in the ?Middle Silurian Hoskins Formation at the Hoskins manganese mine near Grenfell, NSW. Two dominant mineral assemblages occur in the Mn silicate rocks: (1) a “reduced’ assemblage, probably gradational into underlying jasper, containing abundant rhodonite and/or tephroite, plus subordinate carbonates, quartz, hausmannite, spessartine and Ba minerals, and (2) a well‐laminated ‘oxidized’ assemblage rich in red Mn‐rich alkali pyroxene and amphibole, braunite, manganoan pectolite and minor Mn‐rich mica, alkali feldspars, carbonates, quartz and barite. Several Mn silicates implicitly contain trivalent Mn. The Mn silicate rocks are rich in Mn, Ba and Sr, and also contain anomalously high Co, Cu, As and W; oxidized assemblages are alkali‐rich. Bulk compositions and geological setting suggest a submarine volcanic exhalative origin for the precursors of the Mn silicate rocks and jasper. Metamorphism has occurred at upper greenschist facies with original high oxygen fugacity conditions in the exhalative sediments being largely reflected in the resulting assemblages. Although analogues of the reduced Mn silicate rocks are widespread in metamorphosed Mn deposits, equivalents of the oxidized assemblages appear to be particularly uncommon.     

The present-day stress field of New South Wales,Australia

The Australian continent displays the most complex pattern of present-day tectonic stress observed in any major continental area. Although plate boundary forces provide a well-established control on the large-scale (>500 km) orientation of maximum horizontal stress (S_Hmax), smaller-scale variations, caused by local forces, are poorly understood in Australia. Prior to this study, the World Stress Map database contained 101 S_Hmax orientation measurements for New South Wales (NSW), Australia, with the bulk of the data coming from shallow engineering tests in the Sydney Basin. In this study we interpret present-day stress indicators analysed from 58.6 km of borehole image logs in 135 coal-seam gas and petroleum wells in different sedimentary basins of NSW, including the Gunnedah, Clarence-Moreton, Sydney, Gloucester, Darling and Bowen–Surat basins. This study provides a refined stress map of NSW, with a total of 340 (A–E quality) S_Hmax orientations consisting of 186 stress indicators from borehole breakouts, 69 stress measurements from shallow engineering methods, 48 stress indicators from drilling-induced fractures, and 37 stress indicators from earthquake focal mechanism solutions. We define seven stress provinces throughout NSW and determine the mean orientation of the S_Hmax for each stress province. The results show that the S_Hmax is variable across the state, but broadly ranges from NE–SW to ESE–WNW. The S_Hmax is approximately E–W to ESE–WNW in the Darling Basin and Southeastern Seismogenic Zone that covers the west and south of NSW, respectively. However, the present-day S_Hmax rotates across the northeastern part of NSW, from approximately NE–SW in the South Sydney and Gloucester basins to ENE–WSW in the North Sydney, Clarence-Moreton and Gunnedah basins. Comparisons between the observed S_Hmax orientations and Australian stress models in the available literature reveal that previous numerical models were unable to satisfactorily predict the state of stress in NSW. Although clear regional present-day stress trends exist in NSW, there are also large perturbations observed locally within most stress provinces that demonstrate the significant control on local intraplate sources of stress. Local S_Hmax perturbations are interpreted to be due to basement topography, basin geometry, lithological contrasts, igneous intrusions, faults and fractures. Understanding and predicting local stress perturbations has major implications for determining the most productive fractures in petroleum systems, and for modelling the propagation direction and vertical height growth of induced hydraulic fractures in simulation of unconventional reservoirs.     

Differentiation trends in the Warrumbungle Volcano,New South Wales,Australia

The volcanic rocks of the Warrumbungle Shield volcano in central western New South Wales, Australia show two distinct differentiation trends. One trend of differentiation extends from alkali basalts to phonolitic trachytes becoming increasingly undersaturated with silica and a second differentiation trend extends from trachybasalts to quartzbearing trachyte that becomes progressively more oversaturated. The differentiation trends are the product of low pressure fractional crystallisation of an alkali basalt in a high level magma chamber.Differentiated rocks of the Nandewar Volcano in New South Wales differs from that of the Warrumbungle Volcano in several significant respects. In the Nandewar Volcano, for example, the parental magma is an olivine basalt, the differentiation trend is towards silica rich trachytes and very siliceous alkali rhyolites.The differentiated alkaline rocks from the large shield volcanoes of the Pacific display many affinities to the differentiated alkaline rocks from the shield volcanoes of the Australian continent. On Tahiti a moderately undersaturated alkaline magma has produced contrasting differentiates, silica saturated trachytes; and phonolites. In Hawaii the alkaline volcanic rocks have differentiated to produce oversaturated trachytes. By contrast, in the Galápagos Islands where the parental magma is a tholeiitic basalt the differentiation trend is towards very siliceous trachytes and quartz syentites.The divergent trends of differentiation in the Warrumbungle Shield can be traced via the intermediate lineage members to compositional differences between the basic lineage members. The temperature, pressure and fugacity of oxygen and water have controlled the path and extent of differentiation in high level magma chambers at 8–9 kb or less. Differing degrees of saturation of the basic lineage members are attributed to differing degrees of pyroxene or eclogite fractionation at high pressures. Progressively more undersaturated rocks have been derived at increasing depths or origin.

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Zusammenfassung Die Vulkangesteine des Warrumbungle-Vulkans im mittelwestlichen Neusüdwales, Australien, zeigen zwei verschiedene Differentiationstendenzen. Die eine erstreckt sich von alkalischen Basalten bis zu phonolitischen Trachyten, die immer stärker kieselsäure-untersättigt werden. Die andere erstreckt sich von Trachytbasalten bis quarzhaltigem Trachyt, der immer stärker übersättigt wird. Die Differentiationstendenzen ergeben sich aus der fraktionierten Kristallisation bei niederem Druck von einem alkalischen Basalt in einer nahe der Oberfläche liegenden Magmakammer.Differenziertes Gestein des Nandewar-Vulkans in Neusüdwales unterscheidet sich in einigen wesentlichen Punkten von dem des Warrumbungle-Vulkans. In dem Nandewar-Vulkan ist z. B. das Stammagma ein olivinhaltiger Basalt. Dazu tendiert es zu siliziumhaltigen Trachyten und sehr siliziumhaltigen alkalischen Rhyoliten.Das differenzierte alkalische Gestein von den großen Vulkanen des Pazifiks zeigt viele Ähnlichkeiten mit dem differenzierten alkalischen Gestein von den Vulkanen auf dem australischen Festland. Auf Tahiti hat ein mäßig untersättigtes alkalisches Magma kontrastierende Varianten, Phonolite und siliziumgesättigte Trachyte hervorgebracht. Auf Hawaii hat sich das alkalische Vulkangestein differenziert, wobei übersättigte Trachyte entstanden sind. Dagegen tendiert es auf den Galapagos-Inseln, wo das Stammagma ein tholeiitischer Basalt ist, zu sehr siliziumhaltigen Trachyten und Quarzsyeniten.Die divergierenden Differationstendenzen in dem Warrumbungle-Vulkan lassen sich durch die intermediären Stammglieder auf Zusammensetzungsunterschiede zwischen den früheren Stammgliedern zurückführen. Die Temperatur, der Druck und die Flüchtigkeit des Sauerstoffs und des Wassers haben den Vorgang und das Maß der Differentiation in nahe der Oberfläche begrabenen Magmakammern bei 8–9 kb. oder weniger kontrolliert. Verschiedene Sättigungsgrade der früheren Stammglieder werden verschiedenen Graden von Pyroxenoder Eklogit-Fraktionierung bei hohem Druck zugeschrieben. Zunehmend stärker untersättigtes Gestein ist bei wachsender Entstehungstiefe hervorgebracht worden.

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Résumé Les roches volcaniques du Volcan Warrumbungle, dans la partie centrale de la Nouvelle-Galles du Sud (Australie), montrent deux tendances distinctes de différenciation. L'une de ces tendances s'étend des basaltes alcalins aux trachytes phonolitiques qui deviennent de plus en plus sous-saturés en silice. L'autre tendance de différenciation s'étend des trachy-basaltes aux trachytes quartzifères, qui deviencent de plus en plus sursaturés. Ces tendances de différenciation sont le résultat de la cristallisation fractionnée, sous faible pression, d'un basalte alcalin dans une chambre magmatique proche de la surface.Les roches différenciées du volcan Nandewar en Nouvelle-Galles du Sud différent sous plusieurs aspects importants de celles du volcan Warrumbungle. Dans le volcan Nandewar, par exemple, le magma originel est un basalte à olivine; la différenciation tend vers des trachytes contenant de la silice et des rhyolites alcalines très siliceuses.La roche alcaline différenciée des grands volcans du Pacifique montre beaucoup d'affinités avec celle des volcans du continent australien. A Tahiti un magma alcalin moyennement sous-saturé a produit des roches différenciées très diverses: des trachytes saturés en silice et des phonolites. A Hawaii les roches volcaniques alcalines se sont différenciées pour produire enfin des trachytes sursaturés. Par contre aux Iles Galapagos, où le magma originel est un basalte tholéiitique, la tendance de la différenciation va vers des trachytes très siliceux et des syénites quartzifères.Les tendances divergentes de la différenciation dans le Warrumbungle remontent par des termes intermédiaires à des différences de composition entre les premiers membres dérivés du magma originel.La température, la pression et la fugacité de l'oxygène et de l'eau ont réglé le processus et l'étendue de la différenciation dans les chambres magmatiques enfouies à proximité de la surface, sous une pression de 8–9 kb ou moins. C'est à différents degrés de saturation des premiers membres du magma originel que sont attribués les différents degrés de fractionnement du pyroxène ou de l'éclogite à haute pression. C'est toujours une roche de plus en plus sous-saturée qui est engendrée par augmentation de sa profondeur d'origine.

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The Prospect Alkaline Diabase-Picrite Intrusion New South Wales, Australia

The Prospect intrusion is a dish-shaped alkaline diabase-picritemass 315–400 ft thick intruded into shale at a depth ofabout 600 ft. Picrite, containing more than 25 per cent olivine,occupies the lower half of the intrusion. In the upper half,alkaline diabase, averaging less than 5 per cent olivine, isconcentrated under structural highs of the contact, and alkalineolivine diabase, containing 10 to 25 per cent olivine, is concentratedunder structural lows. These rocks are separated from the shaleby a fine-grained chilled margin. Vertical sections through the picrite zone show a regular antipatheticvariation of modal olivine and plagioclase with a zone of maximumolivine concentration near the bottom; bulk rock compositionsshow an antipathetic relation between MgO plus total iron andall other constituents. Modal and bulk composition variationsare more erratic in the upper half of the intrusion, but analcite,alkali feldspar, and opaque minerals reach maximum concentrationsin this part of the intrusion. The pyroxene content remainsnearly constant in the major rock types. Trends of olivine andplagioclase composition and grain size vary regularly with heightin the intrusion and cross boundaries between major rock typeswithout deflexion. Olivine becomes progressively more fayaliticfrom the base of the picrite zone to the upper chilled margin,but the plagioclase curve has a trend toward more calcic compositionsin the picrite zone. Mean sizes of plagioclase, pyroxene, andolivine increase upwards between the chilled margins. The lower chilled margin is slightly less mafic than the bulkcomposition of the intrusion and may represent a pre-emplacementdifferentiate, but the major part of the differentiation occurredduring emplacement at the present site. Grain size and otherdata indicate that crystallization took place more rapidly fromthe base than from the top of the intrusion, and a variety ofinternal structures indicate that crystallization and differentiationtook place as the magma was intruded over a considerable periodof time. As consolidation of the intrusion proceeded, the liquid becameenriched in all constituents except magnesium and ferrous ironuntil consolidation of alkaline diabase began (when about 70per cent of the whole intrusion had solidified); at that stagethe proportion of calcium, titanium, and ferric iron in theliquid was reduced and the proportion of silica, alumina, andalkalis increased. Processes of differentiation that contributed most to the originof the main rock types are: diffusion, independently of crystallization,of volatiles, alkalis, and possibly calcium into the structurallyhigh parts of the intrusion; gravity accumulation of olivinethat crystallized a short distance above the main front of consolidationas it moved upwards from the base of the intrusion; and upwarddiffusion of salic constituents and downward diffusion of maficones over concentration gradients produced by crystallization. Removal of volatiles from the lower part of the intrusion beforecrystallization reduced the oxidation ratio in the liquid andresulted in a low proportion of ferric iron minerals; crystallizationof abundant olivine (average composition about Fo₇₀), however,prevented enrichment of the liquid in iron. Addition of volatilesto the upper part of the intrusion retarded crystallizationand raised the oxidation ratio to a level at which a relativelyhigh proportion of ferric iron minerals crystallized. Subordinate processes that contributed to the formation of themain rock types as well as to less abundant ones include gravityaccumulation of heavy minerals that were dispersed in the magmaat the time of emplacement, filter pressing caused by localbuttressing around irregularities of the contact, crystal sortingby viscous flow, and gas transfer. Pegmatitic differentiates are ascribed to a complex diffusionprocess along pressure and concentration gradients caused byshear on laminar flow planes. Syenite may have originated byreplacement of pegmatite, but aplites occupy true dilationaistructures and apparently represent liquid remaining after crystallizationof the adjacent rock.     

Late Quaternary evolution of Lake Urana,New South Wales,Australia

Lake Urana is a well-preserved relict lake in the semi-arid Riverine Plain of southeastern Australia. A compound lunette at its eastern shoreline consists of a quartz-sand-dominated unit (Bimbadeen Formation), thermoluminescence (TL) dated at 30 ka to 12 ka, and a clay and sand facies unit (Coonong Formation), dated at 55 ka to 35 ka. The intervening period indicates a phase of periodically exposed lake floor and soil formation. The older wet phase conforms well with similar environments recorded from the same period at Lake Mungo. However, the return to high water levels from 30 ka to 12 ka departs sharply from the generally accepted palaeoclimatic model from Australia, which demands severe glacial maximum desiccation and widespread construction of clay lunettes. Although hydrological budgets calculated for Lake Urana and nearby Lake Cullivel require high glacial maximum water levels they do not support higher precipitation.     

Historical pollution variability from abandoned mine sites,Greater Blue Mountains World Heritage Area,New South Wales,Australia

Core and surface sediments from the Tonalli River, a tributary of the artificial lake, Lake Burragorang, in the Blue Mountains National Park, New South Wales, Australia, were studied to evaluate the spatio-temporal distribution of pollutants from the Yerranderie silver-lead-zinc mine site, abandoned in the late 1920s. A sediment core was collected in the mouth of the Tonalli River, at its junction with Lake Burragorang, and surface sediment samples were collected in the Tonalli River and its tributaries. The concentrations of Pb, As, Zn, Cu, Cd, Hg and Ag in the sediments were determined by ICP-MS and ICP-AES techniques. Temporal variability of metal concentrations was established through ²¹⁰Pb dating of the core sediments and compared with published historical records, rainfall records and bushfire data. Metal concentrations in core sediments showed an overall increase around the year 1950 as well as increases coincident with heavy rainfall. Spatially, metal concentrations were up to 400 times the guideline limit around mine sites but decreased rapidly with distance downstream of the mines.     

Ordovician Intrusive-related Gold-Copper Mineralization in West-Central New South Wales, Australia

Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly distributed within two Ordovician volcano-intrusive belts of the Lachlan Fold Belt: the Orange-Wellington Belt and the Parkes-Narromine Belt. Available isotopic age data suggest that mineralization of the three types of deposits is essentially coeval with the Ordovician intrusive rocks (480-430 Ma).Porphyry gold-copper deposits can be further divided into two groups. The first group is associated with monzonite showing shoshonitic features, represented by Cadia and Goonumbla. The second group is associated with diorite and dacite, including the Copper Hill and Cargo gold-copper deposits. Gold skarn is associated with Late Ordovician (430-439 Ma) monzonitic intrusive complexes in the Junction Reefs area (Sheahan-Grants, Frenchmans, and Cor-nishmens), Endeavour 6, 7 and 44, Big and Little Cadia     

Notes on framboidal pyrite from Allandale New South Wales,Australia

Pyrite masses composed of compacted pyrite framboids in chalcedony in weathered andesites at Allandale, New South Wales, Australia, show evidence of colloidal origin and contemporaneous deposition of pyrite and silica. Free framboids and framboidal clusters in the chalcedony show indications of crystallization into pyrite polyhedra and pyrite octahedra.     

Sedimentology of the Middle Devonian Timor Limestone,northeastern New South Wales,Australia

The microfacies assemblages and their distribution within the Middle Devonian Timor Limestone, exposed in the Timor Valley of northeastern New South Wales, Australia are described, and a depositional model for the carbonate buildup presented.Two broad lithological divisions are clearly recognizable within this thick (345 m) but lensoidal mass. Lime wackestones/packstones dominate the lower 200–215 m of the buildup while lime grainstones characterize the upper 130 m. Using cluster-sorting techniques on 697 modally analysed limestone samples, five microfacies and several subgroups each characterized by a unique combination of allochems have been recognized within this gross subdivision.The microfacies data and field observations suggest that carbonate sedimentation was initiated in an open marine shelf environment. It began simply because local conditions were favourable for calcareous organisms to become established. The benthos flourished ultimately spreading out over an area of 25 km². Although reefal in outline, the limestone is a bedded deposit containing chiefly comminuted skeletal debris and never had the ecologic potential to form a wave-resistant mass.Lime mud sedimentation began in a sublittoral environment. Abundant calcareous algae throughout most of the lower two-thirds of the buildup suggest that deposition occurred within the photic zone. In succeeding horizons, pellet and intraclast lime grainstones gradually replace the lime mud dominated microfacies, indicating that carbonate deposition slowly outpaced basin subsidence and shoal-water conditions developed over the buildup. During the buildup's final stage, a transgression occurred resulting in quieter marine conditions and the deposition of coral lime wackestones in the former shoal area.Carbonate sedimentation was terminated by an extensive marine tuff killing the calcareous benthos. No further extensive carbonate sedimentation during the Middle Devonian is recorded in the Timor Valley.     

Exploration rock geochemistry for gold, Parkes, New South Wales, Australia

The London-Victoria lode-type Au deposit near Parkes, New South Wales, was discovered in 1863 and became the subject of modern exploration in 1980 after about 75 years of little or no activity. The deposit lies within Palaeozoic tuffaceous, andesitic rocks. Soil geochemistry was the main technique used to define drill targets, and the deposit is now at an advanced state of assessment for probable development.Rock geochemistry is being investigated as an aid in drill-core interpretation in the search for extensions to the London-Victoria deposit and other similar deposits in the district.At an early stage of the rock-geochemical work it became clear that minor basemetal mineralization was also present in the structural hanging wall at between 30 and 70 m from the lode Au deposit. Interpretation of the geochemical signatures for major elements (Ca, Mg, Na, K, Fe) and trace elements (Cu, Pb, Zn, Mn) is confused by an overlap and merging of responses from the Au and base-metal mineralization. The measurement of bromine-soluble Sb, As, Bi, and Te, together with the more conventional major and trace elements, permits discrimination between geochemical halos related to the Au and those resulting from minor base metal mineralization.The results demonstrate the use of rock geochemistry for Au exploration, its usefulness in drawing attention to geological features, and the utility of bromine-soluble trace elements commonly associated with gold mineralization.     

Drainage sampling for uranium in the Torrington district, New South Wales, Australia

A brief orientation study has been conducted to evaluate the use of drainage geochemical sampling for U in the granitic and forested terrain of the Torrington district of northeastern New South Wales. Anomalous U levels are present in both stream sediments and waters draining a known W prospect containing accessory U. The U dispersion is affected by interrelated environmental factors such as catchment physiography and the organic content of the stream sediments. The influence of organic content on U level in stream sediments is most significant. Variation in sediment organic content is related to accumulation of vegetal organic debris and charcoal in stream channels by sheetwashing of sparsely covered forest floors particularly in catchments of high topographic relief. The U is apparently absorbed onto the organic material from ephemerally flowing stream waters. Temporal variations in U content of stream sediment are indicated which necessitate careful consideration in planning and interpreting the results of a survey in this environment.     

Early Devonian synorogenic alluvial-fan deposits of the Maccullochs Range,western New South Wales

The Early Devonian, Maccullochs Range beds (new) of the Winduck Interval largely comprise non-marine fine-grained sheet-flood-deposited sandstones which lie in the southeast sector of the Darling Basin Conjugate Fault System. Deposition of the >2.5 km-thick sequence occurred on the Wilcannia, Towers and Coolabah Bore alluvial fans, that were sourced largely from lightly indurated sandstone caps overlying a large basement high lying north of the Darling River Lineament, and also from west of Maccullochs Range (Coolabah Bore Fan). Four lithofacies are recognised. Lithofacies 1, massive sandstone, is proximal and was deposited from hyperconcentrated sheet floods. The more distal lithofacies 2 is partly massive, partly laminated and partly affected by soft sediment slumping during its deposition. It contains 1.3 – 3.5 m-thick sheet-flood successions that rarely show cross-bedding. Lithofacies 3 and 4 are minor: lithofacies 3, stream-flood deposited, comprises coarse-grained, pebbly sandstone and lithofacies 4, transient playa lake deposits that are locally intercalated with lithofacies 2. In lithofacies 2, thick massive fine-grained sandstone is commonly overlain by laminated sandstone that was deformed when soft. Incised channel deposits in lithofacies 2 deposits are rare and palaeosols were not discovered. Permanency of the positions of two of the alluvial fans, and by inference their feeder streams, remained unchanged for ～9 million years. The fans overlie probable floodplain deposits observed in a quarry in the easternmost part of the study area. Marine fossils are very minor in the range—the brachiopod Howellella jaqueti at one locality indicates an Early Devonian age for one of the brief marine incursions into what was normally an alluvial-fan environment. Very brief marine incursions elsewhere in the group are deduced from the presence of very rare fossil gastropods.     

A sulphur isotope study of the Broken Hill deposit,New South Wales,Australia

Sulphur isotopic compositions of sulphides within garnet-rich rocks and high-grade ore from the Broken Hill deposit, New South Wales, Australia, have been determined and show a range of values of –3.3 to +6.7 per mil. Thermochemical considerations, including the spread of values of ³⁴S, suggest that the deposit was derived from a mixed source of sulphur in which seawater, reduced by inorganic processes, mixed with magmatic sulphur or that sulphate from contemporaneous seawater was reduced biogenically at low temperatures. Thermochemical considerations also suggest that pyrrhotite formed by desulphidation of pyrite so that the original Fe-S-O assemblage was pyrite ± magnetite.³⁴S measurements show a broad range which is considered to be due to isotopic reequilibration during retrograde metamorphism and analytical and sampling technique. These data should not be used to indicate original temperatures of deposition or metamorphic temperatures associated with the various metamorphic events.     

Phanerozoic stratigraphy and structure of the northern Barrier Ranges,western New South Wales

Devonian strata near Fowlers Gap and Nundooka Stations, northern Barrier Ranges comprise ～2.7 km of sparsely fossiliferous, fluvially deposited sandstones (Mulga Downs Group). These strata are subdivided into the Coco Range Sandstone (oldest, Emsian‐Eifelian) found west of the north‐trending Nundooka Creek Fault, and the Nundooka Sandstone (youngest, ?Frasnian‐Famennian found east of the fault). Eleven stratigraphic units are mapped and two of these in the Coco Range Sandstone are formally named as The Valley Tank Arenite and Copi Dam Arenite Members. The Coco Range Sandstone and Nundooka Sandstone are tentatively correlated with strata in the Bancannia Trough. Deposition of the Coco Range Sandstone and Nundooka Sandstone was, however, separate from that of the Bancannia Trough, probably due to topographic highs which occurred east of the Western Boundary Fault.

The Coco Range Sandstone is cut by northeast‐trending faults splaying from the Nundooka Creek Fault. These faults have vertical planes and are thought to predate deposition of the Nundooka Sandstone. In the Late Cretaceous the Nundooka Creek and Western Boundary Faults became active and areas west of these faults were uplifted to form Coco Range and Bald Hill. This fossil landscape was progressively buried by deposition of the Palaeocene‐Eocene Eyre Formation until it was half covered by strata. During the Oligocene silcrete of the Cordillo Surface formed and was overlain conformably by the sandy Doonbara Formation (Miocene). Since the Miocene, much of the Eyre Formation has been removed by erosion to exhume a Late Cretaceous landscape. Subsequently in the ?Pliocene there was some faulting along the Nundooka Creek and Western Boundary Faults because locally the Cordillo Surface and the Doonbara Formation dip toward the faults at 30–72°. At three localities there is evidence of probable Quaternary activity on the Nundooka Creek and the Western Boundary Faults (downthrow to the east) suggesting a different style of tectonics from that in the Miocene.     

Scaling property of regional floods in New South Wales Australia

Regional flood frequency analysis (RFFA) is often used in hydrology to estimate flood quantiles when there is a limitation of at-site recorded flood data. One of the commonly used RFFA methods is the index flood method, which is based on the assumptions that a region satisfies criterion of simple scaling and it can be treated homogeneous. Another RFFA method is quantile regression technique where prediction equations are developed for flood quantiles of interest as function of catchment characteristics. In this paper, the scaling property of regional floods in New South Wales (NSW) State in Australia is investigated. The results indicate that the annual maximum floods in NSW satisfy a simple scaling assumption. The application of a heterogeneity test, however, reveals that NSW flood data set does not satisfy the criteria for a homogeneous region. Finally, a set of prediction equations are developed for NSW using quantile regression technique; an independent test shows that these equations can provide reasonably accurate design flood estimates with a median relative error of about 27%.