Talc friction in the temperature range 25°–400 °C: Relevance for Fault-Zone Weakening

Talc is one of the weakest minerals that is associated with fault zones. Triaxial friction experiments conducted on water-saturated talc gouge at room temperature yield values of the coefficient of friction, μ (shear stress, τ/effective normal stress, σ′_N) in the range 0.16–0.23, and μ increases with increasing σ′_N. Talc gouge heated to temperatures of 100°–400 °C is consistently weaker than at room temperature, and μ < 0.1 at slow strain rates in some heated experiments. Talc also is characterized by inherently stable, velocity-strengthening behavior (strength increases with increasing shear rate) at all conditions tested. The low strength of talc is a consequence of its layered crystal structure and, in particular, its very weak interlayer bond. Its hydrophobic character may be responsible for the relatively small increase in μ with increasing σ′_N at room temperature compared to other sheet silicates.Talc has a temperature–pressure range of stability that extends from surficial to eclogite-facies conditions, making it of potential significance in a variety of faulting environments. Talc has been identified in exhumed subduction zone thrusts, in fault gouge collected from oceanic transform and detachment faults associated with rift systems, and recently in serpentinite from the central creeping section of the San Andreas fault. Typically, talc crystallized in the active fault zones as a result of the reaction of ultramafic rocks with silica-saturated hydrothermal fluids. This mode of formation of talc is a prime example of a fault-zone weakening process. Because of its velocity-strengthening behavior, talc may play a role in stabilizing slip at depth in subduction zones and in the creeping faults of central and northern California that are associated with ophiolitic rocks.     

Convergence structures of the Peru trench between 10°S and 14°S

High resolution seafloor studies of the Peru Trench between 10°S and 14°S with the GLORIA long-range side-scan sonar system show that the Nazca plate is broken by numerous normal faults as it bends into the trench. These bending-induced faults strike subparallel to the trench axis and overprint and cut across spreading fabric structures of the plate. They commonly form grabens having widths and spacings of 3–5 km and extend for as much as 100 km along strike. Vertical displacements are generally 200 m or more by the time they reach the trench axis. Turbidite deposits are found in the trench north of 11.5°S. Both turbidite and pelagic sediments are folded and temporarily accreted to the base of the overriding plate along the length of the trench axis. They are apparently subsequently implaced in the grabens by slumping and subducted with the Nazca plate. The Mendaña Fracture Zone, which intersects the trench between 9°40′S and 10°35′S, appears to be the locus of a seaward propagating rift that is forming in response to subduction-induced extensional stresses in the Nazca plate.     

Regional soil-gas helium distribution of the Ely and Delta 1° × 2° quadrangles, Basin and Range Province

A reconnaissance soil-gas helium survey was made in the Ely, Nevada and Delta, Utah 1° × 2° quadrangles in the Basin and Range Province. Helium concentrations in 510 samples ranged from −147 to 441 ppb He with respect to ambient air. The median helium value for the study area was 36 ppb. Concentrations of more than 100 ppb He and less than −20 ppb He occur more commonly in the Ely quadrangle and are especially numerous in the western one-half of this quadrangle. Interpretation of the data reveals that the helium concentrations reflect the rock type, particularly the silicic volcanic occurrences, and the geological structure of the area created by crustal extension. The regional soil-gas helium distribution is important information to consider when interpreting anomalies from detailed surveys.     

Phase Chemistry Study of the Zabuye Salt Lake Brine: Isothermal Evaporation at 15°C and 25°C

Zabuye Salt Lake in Tibet, China is a carbonate-type salt lake, which has some unique characteristics that make it different from other types of salt lakes. The lake is at the latter period in its evolution and contains liquid and solid resources. Its brine is rich in Li, B, K and other useful minor elements that are of great economic value. We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15°C and 25°C. The crystallization sequence of the primary salts from the brine at 25°C is halite (NaCl) → aphthitalite (3K2SO4·Na2SO4) → zabuyelite (Li2CO3)→ trona (Na2CO3·NaHCO3·2H2O) → thermonatrite (Na2CO3·H2O) → sylvite (KCl), while the sequence is halite (NaCl) → sylvite (KCl) → trona (Na2CO3·NaHCO3·2H2O) → zabuyelite (Li2CO3) → thermonatrite (Na2CO3·H2O) → aphthitalite (3K2SO4·Na2SO4) at 15°C. They are in accordance with the metastable phase diagram of the Na+, K+-Cl?, CO32?, SO42?-H2O quinary system at 25°C, except for Na2CO3·7H2O which is replaced by trona and thermonatrite. In the 25°C experiment, zabuyelite (Li2CO3) was precipitated in the early stage because Li2CO3 is supersaturated in the brine at 25°C, in contrast with that at 15°C, it precipitated in the later stage. Potash was precipitated in the middle and late stages in both experiments, while boron was concentrated in the early and middle stages and precipitated in the late stage.     

Global 1° × 1° thermal model TC1 for the continental lithosphere: Implications for lithosphere secular evolution

This paper reports a new 1° × 1° global thermal model for the continental lithosphere (TC1). Geotherms for continental terranes of different ages (> 3.6 Ga to present) constrained by reliable data on borehole heat flow measurements (Artemieva, I.M., Mooney, W.D. 2001. Thermal structure and evolution of Precambrian lithosphere: a global study. J. Geophys. Res 106, 16387–16414.), are statistically analyzed as a function of age and are used to estimate lithospheric temperatures in continental regions with no or low-quality heat flow data (ca. 60% of the continents). These data are supplemented by cratonic geotherms based on electromagnetic and xenolith data; the latter indicate the existence of Archean cratons with two characteristic thicknesses, ca. 200 and > 250 km. A map of tectono-thermal ages of lithospheric terranes complied for the continents on a 1° × 1° grid and combined with the statistical age relationship of continental geotherms (z = 0.04  t + 93.6, where z is lithospheric thermal thickness in km and t is age in Ma) formed the basis for a new global thermal model of the continental lithosphere (TC1). The TC1 model is presented by a set of maps, which show significant thermal heterogeneity within continental upper mantle, with the strongest lateral temperature variations (as large as 800 °C) in the shallow mantle. A map of the depth to a 550 °C isotherm (Curie isotherm for magnetite) in continental upper mantle is presented as a proxy to the thickness of the magnetic crust; the same map provides a rough estimate of elastic thickness of old (> 200 Ma) continental lithosphere, in which flexural rigidity is dominated by olivine rheology of the mantle.Statistical analysis of continental geotherms reveals that thick (> 250 km) lithosphere is restricted solely to young Archean terranes (3.0–2.6 Ga), while in old Archean cratons (3.6–3.0 Ga) lithospheric roots do not extend deeper than 200–220 km. It is proposed that the former were formed by tectonic stacking and underplating during paleocollision of continental nuclei; it is likely that such exceptionally thick lithospheric roots have a limited lateral extent and are restricted to paleoterrane boundaries. This conclusion is supported by an analysis of the growth rate of the lithosphere since the Archean, which does not reveal a peak in lithospheric volume at 2.7–2.6 Ga as expected from growth curves for juvenile crust.A pronounced peak in the rate of lithospheric growth (10–18 km³/year) at 2.1–1.7 Ga (as compared to 5–8 km³/year in the Archean) well correlates with a peak in the growth of juvenile crust and with a consequent global extraction of massif-type anorthosites. It is proposed that large-scale variations in lithospheric thickness at cratonic margins and at paleoterrane boundaries controlled anorogenic magmatism. In particular, mid-Proterozoic anorogenic magmatism at the cratonic margins was caused by edge-driven convection triggered by a fast growth of the lithospheric mantle at 2.1–1.7 Ga. Belts of anorogenic magmatism within cratonic interiors can be caused by a deflection of mantle heat by a locally thickened lithosphere at paleosutures and, thus, can be surface manifestations of exceptionally thick lithospheric roots. The present volume of continental lithosphere as estimated from the new global map of lithospheric thermal thickness is 27.8 (± 7.0) × 10⁹ km³ (excluding submerged terranes with continental crust); preserved continental crust comprises ca. 7.7 × 10⁹ km³. About 50% of the present continental lithosphere existed by 1.8 Ga.     

Temperature effects on engineering properties of loess: Application to a loess of the Parisian Basin from 5°c to 80°c

Huret, C., Cojean, R. and Deveughéle, M., 1988. Temperature effects on engineering properties of loess: application to a loess of the Parisian Basin from 5°C to 80°C. Eng. Geol., 25: 209–228.

We present here an experimental work about the engineering behaviour of a calcareous loess from the Parisian Basin, the Rungis loess, in a temperature range of 5°C and 80°C. Mechanical testings on a collapsed and remolded material were realized with a specific apparatus. It allows us to give a stress and temperature history to the material while the process remains simple.

The temperature speeds up primary consolidation which is attained five times quicker at 80°C than at 20°C. The viscous flow of the skeleton and the compressibility are also increased in the same range. The consolidation phenomenon is theoretically analysed using both the classical Terzaghi approach and a rate process theory. The volume variations induced by a modification of the sample temperature is analysed and each phenomenon (thermic dilation, double layer modification, granular rearrangement) is emphasized.

All along this work, we have evaluated the specific characteristics of the loess: granularity, geochemistry, physico—chemical forces and structure. We emphasized the study of the microstructure of the material using pore size distribution measures by mercury intrusion and scanning electron microscopy. This permits us to relate the mechanical behaviour of the material to its micro-structure and to the pysico—chemical properties of the particles.     

Rôles respectifs de l''advection et de la décantation sur la ride médio-atlantique (40° à 50°N)

Coring at 45 sites in the North Atlantic permitted to determine flux velocity and chemical composition of pelagic sediments. Piston cores were used to carry out a comparative study between the post-glacial period (10,000 yr. B.P. until present) and last glacial period (75,000–10,000 yr. B.P.). Special attention has been paid to the Mid-Atlantic Ridges-Azores-Iceland area, where an enrichment of chemical elements was observed with regards to “regional ocean ground noise”, perceived on an isolated seamount of the abyssal plain.This “ground noise” characterized by the presence of Pb, Rb, U, Th, illite and chlorite, is associated to a settling vertical flux since the surface brought by surface currents and wind transport since the North American shield: sediments, here, are continental soil erosion products.The ridge is clearly enriched by Ba, Br, Fe, Ti, Mn, Cu, Ni, Co and As. Ba and Br are mostly associated with planktonic carbonates. Part of Ba may be linked to the ridge's activity. Basalt weathering on the ridge supplies a part of Fe in excess. Hydrothermal activity may account for Mn, Cu, Co, Ni and As enrichment. Most of the excess observed may be explained by intrusion of advective inputs from erosion Icelandic products (Fe, Ti, Cu, Ta, Sc and smectites), probably transported by Norwegian bottom currents.Advective flux (Icelandic-Faeroan basaltic materials) and flux linked to submarine ridge activity represent 30% of inorganic sedimentation. Vertical flux (North American continental-derived terrigenous materials) represent 70% of inorganic sedimentation. These percentages are very similar to those which were calculated for the Pacific.

Résumé

Les vitesses d'accumulation (flux) et les compositions chimiques ont été déterminées pour des sédiments pélagiques, dans 45 sites de l'océan Atlantique Nord. Les échantillons, prélevés par carottage Kullenberg, ont permis de réaliser une étude comparative de la période post-glaciaire (10.000 ans B.P. à nos jours) et du dernier glaciaire (75.000–10.000 ans B.P.). Notre attention s'est portée particulièrement sur la dorsale médioatlantique Açores-Islande où l'on observe des enrichissements en éléments chimiques par rapport au “bruit de fond océanique régional” appréhendé sur un dôme isolé dans la plaine abyssale.À ce bruit de fond, caractérisé par Pb, Rb, U, Th, illite et chlorite, est associé un flux vertical mis en place par décantation depuis la surface, apporté par le vent et les courants de surface depuis le craton nord-américain; il s'agit des produits d'érosion des sols continentaux.L'enrichissement de la dorsale est net pour Ba, Br, Fe, Ti, Mn, Cu, Ni, Co et As.Ba et Br précipite en grande partie avec les carbonates planctoniques. Une partie de Ba peut être associée à l'activité de la ride. L'altération des basaltes de la ride fournit une partie du Fe en excès. L'activité hydrothermale peut expliquer les enrichissements en Mn, Cu, Co, Ni et As.L'essentiel de l'excès observé est expliqué par un apport advectif de produits d'érosion de l'Islande (Fe, Ti, Cu, Ta, Sc et smectites). Leur vecteur serait le courant de fond de la mer de Norvège.Le flux advectif (matériaux basaltiques islando-faeroan) et le flux liéà l'activité sousmarine de la dorsale représenterait 29% de la sédimentation inorganique.Le flux vertical (matériaux continentaux terrigènes nord-américain) représenterait 71% de la sédimentation inorganique. Ces chiffres sont très proches de ceux qui ont été évalués dans le Pacifique.     

Solubility of silica polymorphs in electrolyte solutions, I. Activity coefficient of aqueous silica from 25° to 250°C, Pitzer''s parameterisation

Within the framework of Pitzer's specific interaction model, interaction parameters for aqueous silica in concentrated electrolyte solutions have been derived from Marshall and co-authors amorphous silica solubility measurements. The values, at 25°C, of the Pitzer interaction parameter (λ_SiO2(aq)−i) determined in this study are the following: 0.092 (i = Na⁺), 0.032 (K⁺), 0.165 (Li⁺), 0.292 (Ca²⁺, Mg²⁺), −0.139 (SO₄²⁻), and −0.009 (NO₃⁻). A set of polynomial equations has been derived which can be used to calculate λ_SiO2(aq)−i for these ions at any temperature up to 250°C. A linear relationship between the aqueous silica-ion interaction parameters (λ_SiO2(aq)−i) and the surface electrostatic field (Z_i/r_e,i) of ions was obtained. This empirical equation can be used to estimate, in first approximation, λ_SiO2(aq)−i if no measurements are available. From this parameterisation, the calculated activity coefficient of aqueous silica is 2.52 at 25°C and 1.45 at 250°C in 5 m NaCl solution. At lower concentrations, e.g. 2 m NaCl, the activity coefficient of silica is 1.45 at 25°C and 1.2 at 250°C. Hence, in practice, it is necessary to take into account the activity coefficient of aqueous silica (λ_SiO2(aq)≠1) in hydrothermal solutions and basinal brines where the ionic strength exceeds 1. A comparison of measured [Marshall, W.L., Chen, C.-T.A., 1982. Amorphous silica solubilities, V. Prediction of solubility behaviour in aqueous mixed electrolyte solutions to 300°C. Geochim. Cosmochim. Acta 46, 289–291.] and computed amorphous silica solubility, using this parameterisation, shows a good agreement. Because the effect of individual ions on silicate and silica polymorph solubilities are additive, the present study has permitted to derive Pitzer interaction parameters that allow a precise computation of γ_SiO2(aq) in the Na---K---Ca---Mg---Cl---SO₄---HCO₃---SiO₂---H₂O system, over a large range of salt concentrations and up to temperatures of 250°C.     

Chemistry of the 350°C hot springs on the crest of the East Pacific rise at 21°N

Hydrothermal fields on submarine spreading centres were first studied systematically during dives of the deep submersible ALVIN on the crest of the Galapagos Ridge in 86°W in the spring of 1977. While the exiting waters had temperatures only about 20°C above that of the ambient water column detailed analysis of their chemistry showed them to be formed by mixing of cold sea water (as “ground-water”) with a hydrothermal endmember of approximate temperature 350°C. Subsequently fields of hot springs with this temperature were found on the crest of the East Pacific Rise at 21°N by ALVIN in 2 600 metres water depth. Reconnaissance water sampling of these systems was made in November 1979 and a detailed study has just been completed (November 1981).The 350°C solutions are completely depleted of their original sea-water concentrations of Mg and SO₄. They are acid with a pH (25°C, 1 atmos) of 3.6 and an acidity of 400 μeq/kg. They contain about 7 mmol/kg of H₂S. The isotopic composition of this sulphur and the arsenic to sulphur ratio in the solutions indicate that about 85% of it is of igneous origin. The “soluble elements” Li, K and Rb are strongly enriched over the sea-water values, as are Ca and Ba. Sr is present at close to the sea-water concentrations however the isotopic compositon is identical to that of the basalts. The exiting solutions are clear and homogeneous super-critical fluids of in situ density approximately 0.65 g/cm³. Velocities in the throat of the orifices are around 1.5 m/sec. The iron concentrations are 1.8 mmol/kg and the Fe/Mn ratio is about 3. The reconnaissance samples gave Zn of 120 μol/kg and Cu and Ni of about 15 μol/kg.Upon mixing with sea-water the hot springs precipitate a voluminous black “smoke” predominantly composed of fine-grained FeS. Anhydrite is precipitated around the throat of the orifice producing chimney-like constructional features up to 10-m high. As these grow vertically the anydrite is replaced by sulphide minerals. The outer surface of the chimneys is colonized by several species of worms that secrete mats of tubes, up to several centimetres in diameter, composed of a tough organic material. Lateral growth of the chimneys via leaks in their walls leads to precipitation of sulphide minerals in a morphology controlled by the organic mats. All the numerous extinct sulphide deposits in the area have this characteristic surface texture.The active deposits on the EPR are unlike ophiolite type massive sulphides chemically, mineralogically and texturally. However, they do represent the primary precipitate. It appears that during lateral growth and coalescence of the chimneys in a given field the original deposit is reworked chemically as the 350°C solutions stream through the disequilibrium rapidly precipitated material. A “zone refined” substrate results consisting of coarsely crystalline, permeable relatively pure pyrite. This secondary deposit is, of course, capped with juvenile chimneys. It is these that probably constitute the ochres, the oxidized surficial zones of massive sulphides historically worked for silver and other elements present at only trace levels in the bulk deposit.     

A comparative study on the dissolution and solubility of hydroxylapatite and fluorapatite at 25 °C and 45 °C

Dissolution of the synthetic hydroxylapatite (HAP) and fluorapatite (FAP) in pure water was studied at 25 °C and 45 °C in a series of batch experiments. The XRD, FT-IR and SEM analyses indicated that the synthetic, microcrystalline HAP and FAP with apatite structure used in the experiments were found to have no obvious variation after dissolution except that the existence of OH groups in FT-IR spectra for FAP after 2880 h dissolution was observed. During the HAP dissolution (0–4320 h), the aqueous calcium and phosphate concentrations reached the maxima after 120 h and then decreased slowly with time. For the FAP dissolution in pure water, after a transient time of 1440 h (< 60 d), element concentrations and pH became constant suggesting attainment of a steady-state between the solution and solid. During early stages of the FAP dissolution reaction (< 72–120 h), mineral components were released in non-stoichiometric ratios with reacted solution ratios of dissolved Ca:P, Ca:F and P:F being lower than mineral stoichiometric ratios of Ca₅(PO₄)₃F, i.e., 1.67, 5.0 and 3.0, respectively. This indicated that F were preferentially released compared to Ca from the mineral structure. The mean K_sp values were calculated by using PHREEQC for HAP of 10^− 53.28 (10^− 53.02–10^− 53.51) and for FAP of 10^− 55.71 (10^− 55.18–10^− 56.13) at 25 °C, the free energies of formation ΔG_f^o[HAP] and ΔG_f^o[FAP] were calculated to be − 6282.82 kJ/mol and − 6415.87 kJ/mol, respectively.     

Differential Late Paleozoic active margin evolution in South-Central Chile (37°S–40°S) – the Lanalhue Fault Zone

The N–S oriented Coastal Cordillera of South Central Chile shows marked lithological contrasts along strike at 38°S. Here, the sinistral NW–SE-striking Lanalhue Fault Zone (nomen novum) juxtaposes Permo-Carboniferous magmatic arc granitoids and associated, frontally accreted metasediments (Eastern Series) in the northeast with a Late Carboniferous to Triassic basal-accretionary forearc wedge complex (Western Series) in the southwest. The fault is interpreted as an initially ductile deformation zone with divergent character, located in the eastern flank of the basally growing, upwarping, and exhuming Western Series. It was later transformed and reactivated as a semiductile to brittle sinistral transform fault. Rb–Sr data and fluid inclusion studies of late-stage fault-related mineralizations revealed Early Permian ages between 280 and 270 Ma for fault activity, with subsequent minor erosion. Regionally, crystallization of arc intrusives and related metamorphism occurred between 306 and 286 Ma, preceded by early increments of convergence-related deformation. Basal Western Series accretion started at >290 Ma and lasted to 250 Ma. North of the Lanalhue fault, Late Paleozoic magmatic arc granitoids are nearly 100 km closer to the present day Andean trench than further south. We hypothesize that this marked difference in paleo-forearc width is due to an Early Permian period of subduction erosion north of 38°S, contrasting with ongoing accretion further south, which kinematically triggered the evolution of the Lanalhue Fault Zone. Permo-Triassic margin segmentation was due to differential forearc accretion and denudation characteristics, and is now expressed in contrasting lithologies and metamorphic signatures in todays Andean forearc region north and south of the Lanalhue Fault Zone.